CN105778632A - Water-resistant net-flavor waterborne ceramic simulating coating and preparation method thereof - Google Patents
Water-resistant net-flavor waterborne ceramic simulating coating and preparation method thereof Download PDFInfo
- Publication number
- CN105778632A CN105778632A CN201610348562.4A CN201610348562A CN105778632A CN 105778632 A CN105778632 A CN 105778632A CN 201610348562 A CN201610348562 A CN 201610348562A CN 105778632 A CN105778632 A CN 105778632A
- Authority
- CN
- China
- Prior art keywords
- water
- preparation
- parts
- mixed liquor
- based ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000011248 coating agent Substances 0.000 title claims abstract description 39
- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000000796 flavoring agent Substances 0.000 title abstract description 4
- 239000000919 ceramic Substances 0.000 title abstract 3
- 239000000843 powder Substances 0.000 claims abstract description 39
- 239000002245 particle Substances 0.000 claims abstract description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 229920002261 Corn starch Polymers 0.000 claims abstract description 15
- 239000008120 corn starch Substances 0.000 claims abstract description 15
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 14
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 14
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 14
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000013034 phenoxy resin Substances 0.000 claims abstract description 13
- 229920006287 phenoxy resin Polymers 0.000 claims abstract description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 44
- 238000004140 cleaning Methods 0.000 claims description 27
- 238000013019 agitation Methods 0.000 claims description 22
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000007863 gel particle Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 238000006073 displacement reaction Methods 0.000 claims description 10
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 10
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 238000003763 carbonization Methods 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 229910052599 brucite Inorganic materials 0.000 claims description 6
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000005011 phenolic resin Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 238000001179 sorption measurement Methods 0.000 abstract description 9
- 241001313857 Bletilla striata Species 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000005051 trimethylchlorosilane Substances 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 2
- 238000004887 air purification Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/02—Dextran; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to the field of coating and discloses a water-resistant net-flavor waterborne ceramic simulating coating and a preparation method thereof. The coating comprises the following components in parts by mass: 10-20 parts of calcite powder, 10-20 parts of heavy calcium carbonate powder, 8-12 parts of calcium carbonate, 2-4 parts of bletilla striata powder, 1-3 parts of corn starch, 0.5-1.5 parts of carboxymethyl cellulose, 0.5-1.5 parts of phenoxy resin, 0.5-1.5 parts of glutaraldehyde, 1-3 parts of air purifying particles and 45-55 parts of water. The water-resistant net-flavor waterborne ceramic simulating coating provided by the invention has the advantages of relatively good water resistance, air purifying function, large adsorption capacity, long purifying time and good air purifying effect.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of water-fast clean taste type Water-based ceramic-imitating coating and preparation side thereof
Method.
Background technology
Along with the raising of people's living standard, the health for self is the most increasingly paid close attention to.In recent years about newly
The report of the room air pollution after finishing and leukemic sickness rate relation is also more common in media.Therefore, people
Increasingly focus on the feature of environmental protection of finishing material when finishing.
During interior decoration, plank, glue, wall covering, furniture the most more or less contain formaldehyde,
The harmful substances such as benzene homologues, all can gradually distribute in the even many decades of several years after finishing, thus affect people
The health of body.Water-based ceramic-imitating coating in the market, because its decorative effect is fine and smooth, bright and clean, simple and elegant, valency
Lattice are the highest, and formula environmental protection, gradually promoted.But its construction technology is numerous and diverse, and wet-rub resistance is poor.
Meanwhile, current market also occurs in that the coating with air-cleaning function of relatively multiple types.Such as Shen
Please number be 201410251188.7 Chinese patent disclose aqueous air cleaning paint, including following quality hundred
The component of proportion by subtraction: water 25%～30%；Dispersant 0.5%～1%；Nanometer anion powder 10%；Color filters:
25%～30%；Air cleaning auxiliary agent 1%～5%；Acrylic emulsion: 30%～35%；Auxiliary agent: 1%～3%.
The nuisances such as the aqueous air cleaning paint energy Long-term absorption that this invention is made and decomposition formaldehyde in indoor air
Matter, thus play the effect purifying air, can also absorb and decompose the perfume (or spice) in air by photocatalyst effect
The abnormal flavour such as acetaldehyde, acetic acid and the ammonia of smoke, decomposed odour weight, it is also possible to antimildew and antibacterial, simultaneously this sky
Gas purifies paint and does not contains harmful organic solvent, nontoxic, tasteless, environmental protection, water-fast, weather-proof, ageing-resistant,
Cold-hot good cycle, adhesive force is strong, and paint film is smooth soft, good decorating effect, storing and transporting security, uses
Convenient, can be widely used on exterior wall and the interior wall of building construction.
The air cleaning composition of above-mentioned coating is activated carbon, and activated carbon has higher porosity, has preferably
Adsorption.But at present purify the coating of composition using activated carbon as major air and there is also many shortcomings:
1. the adsorption capacity of activated carbon is less, and general absorption effective persistent period is 1 year, and the releasing of harmful gas
It is long-term for putting, and therefore cannot meet long-term air cleaning requirement；2. activated carbon has preferable hygroscopicity,
While absorption harmful gas, also can adsorb substantial amounts of moisture, cause it with regard to limited adsorption capacity quilt
Occupy.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of water-fast clean taste type Water-based ceramic-imitating coating and
Preparation method.The water-fast clean taste type Water-based ceramic-imitating coating of the present invention has preferable resistance to water, and has air
Purification function, adsorption capacity is big, purifies timeliness long, good air purification effect.
The concrete technical scheme of the present invention is: a kind of water-fast clean taste type Water-based ceramic-imitating coating, including following quality
The component of part:
Calcite in powder 10-20 part,
Dry powder 10-20 part,
Calcium carbonate 8-12 part,
Pseudobulbus Bletillae (Rhizoma Bletillae) powder 2-4 part,
Corn starch 1-3 part,
Carboxymethyl cellulose 0.5-1.5 part,
Phenoxy resin 0.5-1.5 part,
Glutaraldehyde 0.5-1.5 part,
Air cleaning particle 1-3 part,
Water 45-55 part.
Preferred as the technical program, described water-fast clean taste type Water-based ceramic-imitating coating also includes 50-150 part face
Material.
A kind of preparation method of water-fast clean taste type Water-based ceramic-imitating coating, step is:
1), by activated carbon composite colloidal sol, TiO 2 sol, aluminium hydroxide 50-70:30-50:1-3 in mass ratio
Mix homogeneously, obtains complex sol, after complex sol is aged 36-72h, with the dehydrated alcohol of excess to multiple
Close colloidal sol and carry out solvent displacement 24-48h, then with the normal hexane of excess, complex sol is carried out solvent displacement
12-36h, then removes normal hexane, obtains pluralgel；Pluralgel is dried at 60-100 DEG C
30-40min；Then between 200-500 DEG C, carry out half carbonization, obtain half carbide, half carbide is cleaned,
Be dried, pulverize after, obtain half carbonized gas gel particle；By trim,ethylchlorosilane with normal hexane it is by volume
1-3:10 mixes, and obtains hydrophobically modified liquid, and half carbonized gas gel particle is dispersed to dredging of its 5-10 times of quality
In water modification liquid, at 30-40 DEG C, modified 4-8h, prepares air cleaning particle.
In the inventive solutions, dope preparing process is compounded with air cleaning particle, this air
Purify particle with activated carbon composite colloidal sol and TiO 2 sol as primary raw material, first prepare mixed sols, by colloidal sol
After making pluralgel, first it is dried moisture removal, then carries out half carbonization, after half carbonization, obtain half charcoal
Activating QI gel particle；The half carbonized gas gel particle that the method prepares, has higher one-tenth porosity, specific surface
Long-pending big, adsorption capacity is big, preferable to the adsorption effect of harmful substance in air.And owing to its carbonization is incomplete,
The intensity of internal gutter structure is higher, good stability of the dimension, and brittle fracture is less likely to occur structure.Double charcoal
Activating QI gel particle carries out hydrophobically modified, on the one hand it can be avoided that coating imbibition, cracking, promotes water-fast
Property；On the other hand it can prevent from adsorbing in a large number moisture in air, occupy inner space.Aluminium hydroxide can
Resolving into aluminium oxide and water after being heated, aluminium oxide can promote the wearability of coating, and water is by energy after thermal evaporation
Enough pores in the material, strengthen absorbability, kill two birds with one stone.
2), water is warming up to 80-100 DEG C, the Pseudobulbus Bletillae (Rhizoma Bletillae) powder of 100 mesh sieves will be crossed, cross 100 under agitation
The corn starch of mesh sieve and carboxymethyl cellulose are during in 10-20min, constant-speed material-adding is added to water；It is cooled to 70-80
DEG C, under agitation air cleaning particle is added in water.
Select Pseudobulbus Bletillae (Rhizoma Bletillae) powder, this kind of natural material of corn starch, environmental protection.By carboxymethyl cellulose, the Pseudobulbus Bletillae (Rhizoma Bletillae)
Powder, corn starch first stir at relatively high temperatures, and reason is at such a temperature, has substantial amounts of glue in Pseudobulbus Bletillae (Rhizoma Bletillae) powder
Shape material can be released, then lowers the temperature, it is possible to makes it have preferably vicidity and mobility.
Due to the hydrophobicity of air cleaning particle, cause it poor at aqueous dispersion, and Pseudobulbus Bletillae (Rhizoma Bletillae) powder and corn starch
There is after being at high temperature dissolved in water stronger cladding ability, play the effect of binder, it is possible to air cleaning
Particle wraps up and assists it to disperse.And in the painting process of coating, Pseudobulbus Bletillae (Rhizoma Bletillae) powder and corn starch
Film property is preferable, it is possible to promote flatness and the film property of coating.
3), calcite in powder, dry powder, calcium carbonate are carried out batch mixing, phenoxy resin and glutaraldehyde are mixed
Material, add the material after batch mixing to step 2 under agitation) water in.
Glutaraldehyde and phenoxy resin play the effect of binding agent, additionally, glutaraldehyde also has sterilizing ability, energy
Enough air being carried out sterilizing, phenoxy resin can also promote the resistance to water of coating and resistance to contractility, makes coating resistance to
Clean and be difficult to shrinkage cracking.
4), under heat-retaining condition, dispersed with stirring 30-40min, cooling, prepare water-fast clean taste type Water-based ceramic-imitating
Coating.Preferred as the technical program, the particle diameter of described air cleaning particle is 400-1000 micron.
Preferred as the technical program, half carbonization process of described pluralgel is: by pluralgel with 8-12
DEG C/ramp of min to 200-300 DEG C, keep 30-50min；The most again with the speed liter of 18-22 DEG C
Temperature is to 400-500 DEG C.
Carry out half carbonization as stated above, on the one hand can strengthen the intensity of product, on the other hand can be half
Carbonization process carries out pore, improves containing porosity.
Preferred as the technical program, the preparation method of described activated carbon composite colloidal sol is: by furfural, water solublity
Phenolic resin, CNT, carboxymethyl cellulose, brucite fiber, sodium bicarbonate and water are in mass ratio
3-5:1:0.3-0.5:0.1-0.2:0.03-0.05:0.01-0.03:100 mixes, and obtains first after stirring
Mixed liquor, is added drop-wise to the ammonia that concentration is 0.25-0.75mol/L in the first mixed liquor under agitation,
Making the first mixed liquor is neutrality；Then at 65-75 DEG C, react 8-24h, prepare activated carbon composite colloidal sol.
CNT is hollow tubular, has the duct of nano-scale, is not affecting activated carbon composite colloidal sol as far as possible
On the premise of porosity, it is possible to increase the intensity of material, brucite fiber can improve the toughness of material.Carbonic acid
Hydrogen sodium can pore.
Preferred as the technical program, the rate of addition of described ammonia is 10-20mL/min.
Preferred as the technical program, the preparation method of described TiO 2 sol is: by butyl titanate,
Dehydrated alcohol, sodium bicarbonate 1:20-40:0.1-0.3 in mass ratio mixes, and obtains the second mixed liquor；Will
The hydrochloric acid solution of 1-2mol/L, dehydrated alcohol mix with water 4-6:8-16:5 by volume, obtain the 3rd
Mixed liquor；Under agitation the 3rd mixed liquor is added drop-wise in isopyknic second mixed liquor；Then exist
React 12-24h at 40-50 DEG C, obtain TiO 2 sol.
Preferred as the technical program, the rate of addition of described 3rd mixed liquor is 8-12mL/min.
It is compared with the prior art, the invention has the beneficial effects as follows: the water-fast clean taste type Water-based ceramic-imitating of the present invention is coated with
Material has preferable resistance to water, and has air-cleaning function, and adsorption capacity is big, purifies timeliness long, air
Good purification.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of water-fast clean taste type Water-based ceramic-imitating coating, including the component of following mass parts:
Calcite in powder 15 parts, dry powder 15 parts, calcium carbonate 10 parts, Pseudobulbus Bletillae (Rhizoma Bletillae) powder 3 parts, corn starch 2 parts,
Carboxymethyl cellulose 1 part, phenoxy resin 1 part, glutaraldehyde 1 part, 2 parts of air cleaning particle, 50 parts of water.
The preparation process of the water-fast clean taste type Water-based ceramic-imitating coating of the present embodiment is:
1), the preparation of activated carbon composite colloidal sol: by furfural, water soluble phenol resin, CNT, carboxymethyl fibre
Dimension element, brucite fiber, sodium bicarbonate and water 4:1:0.4:0.15:0.04:0.02:100 in mass ratio mixing,
Obtain the first mixed liquor after stirring, under agitation by ammonia that concentration is 0.5mol/L with
The speed of 15mL/min is added drop-wise in the first mixed liquor, and making the first mixed liquor is neutrality；Then anti-at 70 DEG C
Answer 16h, prepare activated carbon composite colloidal sol.
The preparation of TiO 2 sol: by butyl titanate, dehydrated alcohol, sodium bicarbonate 1:30:0.2 in mass ratio
Mixing, obtains the second mixed liquor；By the hydrochloric acid solution of 1.5mol/L, dehydrated alcohol and water 5:12:5 by volume
Mix, obtain the 3rd mixed liquor；Under agitation the 3rd mixed liquor is dripped with the speed of 10mL/min
It is added in isopyknic second mixed liquor；Then at 45 DEG C, react 18h, obtain TiO 2 sol.
By activated carbon composite colloidal sol, TiO 2 sol, the aluminium hydroxide mix homogeneously of 60:40:2 in mass ratio,
To complex sol, after complex sol is aged 54h, with the dehydrated alcohol of excess, complex sol is carried out solvent
Displacement 36h, then carries out solvent displacement 36h with the normal hexane of excess to complex sol, then removes normal hexane,
Obtain pluralgel；Pluralgel is dried 35min at 80 DEG C；Then by pluralgel with 10 DEG C/min
Ramp to 150 DEG C, keep 40min；The most again with the ramp of 20 DEG C to 450 DEG C, obtain half
Carbide, by half carbide clean, be dried, pulverize after, obtain half carbonized gas gel particle.By trimethyl
Chlorosilane mixes for 2:10 by volume with normal hexane, obtains hydrophobically modified liquid, by half carbonized gas gel particle
Being dispersed in the hydrophobically modified liquid of its 7.5 times of quality, modified 6h at 35 DEG C, prepared particle diameter is 400-1000
The air cleaning particle of micron.
2), by water it is warming up to 90 DEG C, the Pseudobulbus Bletillae (Rhizoma Bletillae) powder of 100 mesh sieves will be crossed, cross 100 mesh sieves under agitation
Corn starch and carboxymethyl cellulose during constant-speed material-adding is added to water in 15min；It is cooled to 75 DEG C, in stirring
Under the conditions of air cleaning particle is added in water.
3), calcite in powder, dry powder, calcium carbonate are carried out batch mixing, phenoxy resin and glutaraldehyde are mixed
Material, add the material after batch mixing to step 2 under agitation) water in.
4), under heat-retaining condition, dispersed with stirring 35min, cooling, prepare water-fast clean taste type Water-based ceramic-imitating and be coated with
Material.
Embodiment 2
A kind of water-fast clean taste type Water-based ceramic-imitating coating, including the component of following mass parts:
Calcite in powder 10 parts, dry powder 20 parts, calcium carbonate 8 parts, Pseudobulbus Bletillae (Rhizoma Bletillae) powder 4 parts, corn starch 3 parts,
Carboxymethyl cellulose 0.5 part, phenoxy resin 0.5 part, glutaraldehyde 0.5 part, 1 part of air cleaning particle,
52.5 parts of water.
The preparation process of the water-fast clean taste type Water-based ceramic-imitating coating of the present embodiment is:
1), the preparation of activated carbon composite colloidal sol: by furfural, water soluble phenol resin, CNT, carboxymethyl fibre
Dimension element, brucite fiber, sodium bicarbonate and water 3:1:0.3:0.1:0.03:0.01:100 in mass ratio mixing,
Obtain the first mixed liquor after stirring, under agitation by ammonia that concentration is 0.25mol/L with
The speed of 10mL/min is added drop-wise in the first mixed liquor, and making the first mixed liquor is neutrality；Then anti-at 65 DEG C
Answer 8h, prepare activated carbon composite colloidal sol.
The preparation of TiO 2 sol: by butyl titanate, dehydrated alcohol, sodium bicarbonate 1:20:0.1 in mass ratio
Mixing, obtains the second mixed liquor；By the hydrochloric acid solution of 1mol/L, dehydrated alcohol and water 4:8:5 by volume
Mix, obtain the 3rd mixed liquor；Under agitation the 3rd mixed liquor is dripped with the speed of 8mL/min
It is added in isopyknic second mixed liquor；Then at 40 DEG C, react 24h, obtain TiO 2 sol.
By activated carbon composite colloidal sol, TiO 2 sol, the aluminium hydroxide mix homogeneously of 50:30:1 in mass ratio,
To complex sol, after complex sol is aged 36h, with the dehydrated alcohol of excess, complex sol is carried out solvent
Displacement 24h, then carries out solvent displacement 12h with the normal hexane of excess to complex sol, then removes normal hexane,
Obtain pluralgel；Pluralgel is dried 40min at 60 DEG C；Then by pluralgel with 8 DEG C/min
Ramp to 200 DEG C, keep 50min；The most again with the ramp of 18 DEG C to 400 DEG C, obtain half
Carbide, by half carbide clean, be dried, pulverize after, obtain half carbonized gas gel particle.By trimethyl
Chlorosilane mixes for 1:10 by volume with normal hexane, obtains hydrophobically modified liquid, by half carbonized gas gel particle
Being dispersed in the hydrophobically modified liquid of its 5 times of quality, modified 8h at 30 DEG C, prepared particle diameter is 400-1000
The air cleaning particle of micron.
2), by water it is warming up to 80 DEG C, the Pseudobulbus Bletillae (Rhizoma Bletillae) powder of 100 mesh sieves will be crossed, cross 100 mesh sieves under agitation
Corn starch and carboxymethyl cellulose during constant-speed material-adding is added to water in 10min；It is cooled to 70 DEG C, in stirring
Under the conditions of air cleaning particle is added in water.
3), calcite in powder, dry powder, calcium carbonate are carried out batch mixing, phenoxy resin and glutaraldehyde are mixed
Material, add the material after batch mixing to step 2 under agitation) water in.
4), under heat-retaining condition, dispersed with stirring 30min, cooling, prepare water-fast clean taste type Water-based ceramic-imitating and be coated with
Material.
Embodiment 3
A kind of water-fast clean taste type Water-based ceramic-imitating coating, including the component of following mass parts:
Calcite in powder 20 parts, dry powder 10 parts, calcium carbonate 12 parts, Pseudobulbus Bletillae (Rhizoma Bletillae) powder 2 parts, corn starch 1 part,
Carboxymethyl cellulose 1.5 parts, phenoxy resin 1.5 parts, glutaraldehyde 1.5 parts, 3 parts of air cleaning particle,
47.5 parts of water.
The preparation process of the water-fast clean taste type Water-based ceramic-imitating coating of the present embodiment is:
1), the preparation of activated carbon composite colloidal sol: by furfural, water soluble phenol resin, CNT, carboxymethyl fibre
Dimension element, brucite fiber, sodium bicarbonate and water 5:1:0.5:0.2:0.05:0.03:100 in mass ratio mixing,
Obtain the first mixed liquor after stirring, under agitation by ammonia that concentration is 0.75mol/L with
The speed of 20mL/min is added drop-wise in the first mixed liquor, and making the first mixed liquor is neutrality；Then anti-at 75 DEG C
Answer 8h, prepare activated carbon composite colloidal sol.
The preparation of TiO 2 sol: by butyl titanate, dehydrated alcohol, sodium bicarbonate 1:40:0.3 in mass ratio
Mixing, obtains the second mixed liquor；By the hydrochloric acid solution of 2mol/L, dehydrated alcohol and water 6:16:5 by volume
Mix, obtain the 3rd mixed liquor；Under agitation the 3rd mixed liquor is dripped with the speed of 12mL/min
It is added in isopyknic second mixed liquor；Then at 50 DEG C, react 12h, obtain TiO 2 sol.
By activated carbon composite colloidal sol, TiO 2 sol, the aluminium hydroxide mix homogeneously of 70:50:3 in mass ratio,
To complex sol, after complex sol is aged 72h, with the dehydrated alcohol of excess, complex sol is carried out solvent
Displacement 48h, then carries out solvent displacement 36h with the normal hexane of excess to complex sol, then removes normal hexane,
Obtain pluralgel；Pluralgel is dried 30min at 100 DEG C；Then by pluralgel with 12 DEG C/min
Ramp to 300 DEG C, keep 30min；The most again with the ramp of 22 DEG C to 500 DEG C, obtain half
Carbide, by half carbide clean, be dried, pulverize after, obtain half carbonized gas gel particle.By trimethyl
Chlorosilane mixes for 3:10 by volume with normal hexane, obtains hydrophobically modified liquid, by half carbonized gas gel particle
Being dispersed in the hydrophobically modified liquid of its 10 times of quality, modified 4h at 40 DEG C, prepared particle diameter is 400-1000
The air cleaning particle of micron.
2), by water it is warming up to 100 DEG C, the Pseudobulbus Bletillae (Rhizoma Bletillae) powder of 100 mesh sieves will be crossed, cross 100 mesh under agitation
The corn starch of sieve and carboxymethyl cellulose are during in 20min, constant-speed material-adding is added to water；It is cooled to 70-80 DEG C,
Under stirring condition, air cleaning particle is added in water.
3), calcite in powder, dry powder, calcium carbonate are carried out batch mixing, phenoxy resin and glutaraldehyde are mixed
Material, add the material after batch mixing to step 2 under agitation) water in.
4), under heat-retaining condition, dispersed with stirring 40min, cooling, prepare water-fast clean taste type Water-based ceramic-imitating and be coated with
Material.
Raw materials used, equipment in the present invention, unless otherwise noted, is the conventional raw material of this area, equipment；
Method therefor in the present invention, unless otherwise noted, is the conventional method of this area.
The water-fast clean taste type Water-based ceramic-imitating coating that the present invention prepares, its absorption timeliness is 3-5, and 5
The adsorption efficiency of 35-45% can also be kept after Nian.
The above, be only presently preferred embodiments of the present invention, not impose any restrictions the present invention, every
Any simple modification, change and equivalent transformation above example made according to the technology of the present invention essence, all
Still fall within the protection domain of technical solution of the present invention.
Claims (8)
1. a water-fast clean taste type Water-based ceramic-imitating coating, it is characterised in that: include the component of following mass parts:
Calcite in powder 10-20 part,
Dry powder 10-20 part,
Calcium carbonate 8-12 part,
Pseudobulbus Bletillae (Rhizoma Bletillae) powder 2-4 part,
Corn starch 1-3 part,
Carboxymethyl cellulose 0.5-1.5 part,
Phenoxy resin 0.5-1.5 part,
Glutaraldehyde 0.5-1.5 part,
Air cleaning particle 1-3 part,
Water 45-55 part.
2. a preparation method for water-fast clean taste type Water-based ceramic-imitating coating as claimed in claim 1, its feature
It is that step is:
1), by activated carbon composite colloidal sol, TiO 2 sol, aluminium hydroxide 50-70:30-50:1-3 in mass ratio
Mix homogeneously, obtains complex sol, after complex sol is aged 36-72h, with the dehydrated alcohol of excess to multiple
Close colloidal sol and carry out solvent displacement 24-48h, then with the normal hexane of excess, complex sol is carried out solvent displacement
12-36h, then removes normal hexane, obtains pluralgel；Pluralgel is dried at 60-100 DEG C
30-40min；Then between 200-500 DEG C, carry out half carbonization, obtain half carbide, half carbide is cleaned,
Be dried, pulverize after, obtain half carbonized gas gel particle；By trim,ethylchlorosilane with normal hexane it is by volume
1-3:10 mixes, and obtains hydrophobically modified liquid, and half carbonized gas gel particle is dispersed to dredging of its 5-10 times of quality
In water modification liquid, at 30-40 DEG C, modified 4-8h, prepares air cleaning particle；
2), water is warming up to 80-100 DEG C, the Pseudobulbus Bletillae (Rhizoma Bletillae) powder of 100 mesh sieves will be crossed, cross 100 under agitation
The corn starch of mesh sieve and carboxymethyl cellulose are during in 10-20min, constant-speed material-adding is added to water；It is cooled to 70-80
DEG C, under agitation air cleaning particle is added in water；
3), calcite in powder, dry powder, calcium carbonate are carried out batch mixing, phenoxy resin and glutaraldehyde are mixed
Material, add the material after batch mixing to step 2 under agitation) water in；
4), under heat-retaining condition, dispersed with stirring 30-40min, cooling, prepare water-fast clean taste type Water-based ceramic-imitating
Coating.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 2, its feature
Being, the particle diameter of described air cleaning particle is 400-1000 micron.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 2, its feature
Being, half carbonization process of described pluralgel is: by pluralgel with the ramp of 8-12 DEG C/min extremely
200-300 DEG C, keep 30-50min；The most again with the ramp of 18-22 DEG C to 400-500 DEG C.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 2, its feature
Being, the preparation method of described activated carbon composite colloidal sol is: by furfural, water soluble phenol resin, CNT,
Carboxymethyl cellulose, brucite fiber, sodium bicarbonate and water are in mass ratio
3-5:1:0.3-0.5:0.1-0.2:0.03-0.05:0.01-0.03:100 mixes, and obtains first after stirring
Mixed liquor, is added drop-wise to the ammonia that concentration is 0.25-0.75mol/L in the first mixed liquor under agitation,
Making the first mixed liquor is neutrality；Then at 65-75 DEG C, react 8-24h, prepare activated carbon composite colloidal sol.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 5, its feature
Being, the rate of addition of described ammonia is 10-20mL/min.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 2, its feature
Being, the preparation method of described TiO 2 sol is: butyl titanate, dehydrated alcohol, sodium bicarbonate are pressed
Mass ratio 1:20-40:0.1-0.3 mixes, and obtains the second mixed liquor；By the hydrochloric acid solution of 1-2mol/L, nothing
Water-ethanol mixes with water 4-6:8-16:5 by volume, obtains the 3rd mixed liquor；Under agitation will
3rd mixed liquor is added drop-wise in isopyknic second mixed liquor；Then at 40-50 DEG C, react 12-24h,
To TiO 2 sol.
The preparation method of a kind of water-fast clean taste type Water-based ceramic-imitating coating the most as claimed in claim 7, its feature
Being, the rate of addition of described 3rd mixed liquor is 8-12mL/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610348562.4A CN105778632B (en) | 2016-05-24 | 2016-05-24 | A kind of water-fast net taste type Water-based ceramic-imitating coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610348562.4A CN105778632B (en) | 2016-05-24 | 2016-05-24 | A kind of water-fast net taste type Water-based ceramic-imitating coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105778632A true CN105778632A (en) | 2016-07-20 |
| CN105778632B CN105778632B (en) | 2018-03-13 |
Family
ID=56379384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610348562.4A Active CN105778632B (en) | 2016-05-24 | 2016-05-24 | A kind of water-fast net taste type Water-based ceramic-imitating coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105778632B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329828A (en) * | 2018-02-24 | 2018-07-27 | 段宝荣 | Resistance to ag(e)ing, water resistance, oil resistivity Water-based ceramic-imitating coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5512314A (en) * | 1993-02-24 | 1996-04-30 | Warner-Jenkinson Company | Dye compositions and methods for film coating tablets and the like |
| JP3170623B2 (en) * | 1997-01-20 | 2001-05-28 | 小林製薬株式会社 | Aqueous film-forming dispersion |
| CN1422913A (en) * | 2002-12-25 | 2003-06-11 | 王仙桃 | Water-based ceramic-imitating coating |
| CN101880496A (en) * | 2010-07-16 | 2010-11-10 | 核工业二○三研究所技术开发部 | PVC (Polyvinyl Chloride) stone-bumping resistant paint and preparation method thereof |
| CN104250520A (en) * | 2014-09-19 | 2014-12-31 | 苏州云舒新材料科技有限公司 | Acid-resistant asphalt paint and preparation method thereof |
-
2016
- 2016-05-24 CN CN201610348562.4A patent/CN105778632B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5512314A (en) * | 1993-02-24 | 1996-04-30 | Warner-Jenkinson Company | Dye compositions and methods for film coating tablets and the like |
| JP3170623B2 (en) * | 1997-01-20 | 2001-05-28 | 小林製薬株式会社 | Aqueous film-forming dispersion |
| CN1422913A (en) * | 2002-12-25 | 2003-06-11 | 王仙桃 | Water-based ceramic-imitating coating |
| CN101880496A (en) * | 2010-07-16 | 2010-11-10 | 核工业二○三研究所技术开发部 | PVC (Polyvinyl Chloride) stone-bumping resistant paint and preparation method thereof |
| CN104250520A (en) * | 2014-09-19 | 2014-12-31 | 苏州云舒新材料科技有限公司 | Acid-resistant asphalt paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329828A (en) * | 2018-02-24 | 2018-07-27 | 段宝荣 | Resistance to ag(e)ing, water resistance, oil resistivity Water-based ceramic-imitating coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105778632B (en) | 2018-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106007633B (en) | A kind of purification of air diatomite inner wall decoration powder coating and preparation method thereof | |
| CN105542595A (en) | Graphene-diatomaceous-earth anti-formaldehyde coating and preparing method thereof | |
| CN105413629A (en) | Alga-calcium-mineral air purification medium and preparation method and application thereof | |
| CN104774514B (en) | It can adsorb and decompose net taste coating of low VOC of formaldehyde in air and preparation method thereof | |
| CN101348628A (en) | Thick coating material purifying air and preparing method thereof | |
| CN102580703A (en) | Method for preparing efficient air purification material | |
| CN101439279A (en) | Decoration wall material for purifying indoor air as well as preparation method and use thereof | |
| CN103011696B (en) | Environment-friendly wall material for interior wall decoration and preparation method of wall material | |
| CN112430407B (en) | Material with air purifying and negative ion releasing effects, preparation method thereof and application thereof in coating | |
| CN105622017B (en) | Unburned diatom ecological brick and its production method | |
| CN104946051A (en) | Healthy and environment-friendly building inner wall coating | |
| CN104276787A (en) | Preparation method of novel diatom ooze coating | |
| CN105778670B (en) | A kind of environment-friendly type Polyvinyl acetate latex paint and preparation method thereof | |
| CN105778632A (en) | Water-resistant net-flavor waterborne ceramic simulating coating and preparation method thereof | |
| CN105969007B (en) | A kind of acrylic latex coating and preparation method thereof with air-cleaning function | |
| CN106495573B (en) | Modified silicon soil property lake mud building materials and preparation method for inner wall decoration | |
| CN108410366B (en) | Preparation method of silicon-titanium aerogel adsorption and photocatalysis interior wall coating | |
| CN108355695A (en) | A kind of special diatom ooze and preparation method having the interior purifying formaldehyde for turning light | |
| CN105778647B (en) | A kind of water-fast net taste type polyvinyl alcohol water soluble paint and preparation method thereof | |
| CN106242455A (en) | A kind of composite multi-functional meerschaum/kieselguhr basic ring protects chamber interior walls material | |
| CN103496884A (en) | Formaldehyde eliminating coating with dual functions of adsorption and decomposition and preparation method thereof | |
| CN106000078A (en) | Air purifying wallpaper | |
| CN107686290A (en) | Purify antimicrobial form diatom ooze wall material | |
| CN106242363B (en) | A kind of sepiolite with coordination function/diatomite basic ring protects indoor wall material | |
| CN107857516A (en) | A kind of Multifunctional diatom ooze wall material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Hu Zhongyuan Inventor after: Dong Lizhi Inventor after: Zheng Yi Inventor after: Xue Xiaoqian Inventor before: Yang Mousen |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20171116 Address after: 072550 Xushui County of Hebei Province, Chen Yang Street No. 1 Applicant after: HEBEI CHENYANG INDUSTRY&TRADE Group Ltd. Address before: 362121 No. 163 Xinghua alley, Fujian Town, Luoyang Town, Quanzhou Province, Taiwan businessmen's investment zone Applicant before: Yang Mousen |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20180313 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20180313 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160720 Assignee: Chenyang Environmental Protection New Material Co.,Ltd. Assignor: HEBEI CHENYANG INDUSTRY&TRADE Group Ltd. Contract record no.: X2023980033290 Denomination of invention: A water-based porcelain imitation coating with water resistance and taste purification and its preparation method Granted publication date: 20180313 License type: Common License Record date: 20230303 |