CN107857516A - A kind of Multifunctional diatom ooze wall material - Google Patents
A kind of Multifunctional diatom ooze wall material Download PDFInfo
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- CN107857516A CN107857516A CN201711116547.8A CN201711116547A CN107857516A CN 107857516 A CN107857516 A CN 107857516A CN 201711116547 A CN201711116547 A CN 201711116547A CN 107857516 A CN107857516 A CN 107857516A
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- wall material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
- C04B2111/00827—Photocatalysts
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2061—Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/343—Crack resistant materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The present invention relates to a kind of Multifunctional diatom ooze wall material, is made up of by weight ratio diatomite, calcined zeolite powder, sepiolite powder, quartz sand, anticracking fiber, plant cellulose, thickening powder and photocatalyst.Diatomite, calcined zeolite powder, sepiolite powder, quartz sand are well mixed after pickling is dried with anticracking fiber, plant cellulose, thickening powder, photocatalyst.Zeolite powder and sepiolite powder of the invention by adding calcining in diatomite, the porosity and specific surface area of wall material are added by pickling, while harmful substance is adsorbed, can be with adsorption moisture, play the purpose of regulation indoor humidity, add anticracking fiber and plant cellulose, improve the mechanical strength of wall material, prevent cracked after constructing, use glutinous rice tackifier, harmful substance will not be discharged, it is green, add mesoporous molecular sieve carried titanium dioxide and zinc oxide, both titanium dioxide and zinc oxide photocatalysis activity had been improved, can the thorough harmful substance such as decomposing formaldehyde, it can sterilize simultaneously.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of Multifunctional diatom ooze wall material.
Background technology
It is well known that the construction after household blank is completed in building household field to wall is particularly important, thus have
Selection to wall material.Traditional home decoration wall material is broadly divided into paint class, the major class of wallpaper two, and both wall materials are in the process used
In, in the presence of different degrees of VOC emission, especially formaldehyde, serious threat health.It is with the development of the social economy, existing
Moderns require finishing more and more higher, and people propose more while high-grade decorative effect is pursued to the feature of environmental protection of wall material
High requirement, in order to meet the needs of people, some, which occurs, in the market can adsorb and purify the wall of harmful substance in air
Material, especially diatom ooze wall material, turn into the typical case of environmental protection building material instantly, are widely used in recent years, and diatom ooze is
Formed by the remains sedimentation of unicellular water plant diatom, form several nanometers to more than ten nanometers of micropore, its ultramicropore is than wood
Charcoal it is more go out 5000 to 6000 times, the formaldehyde to dissociate in air, benzene, harmful substance and the hydrone such as ammonia can be adsorbed, had
Good chemically and physically stability, has broader development prospect compared to traditional indoor set material.In the market
There is substantial amounts of diatom ooze wall material, with the addition of the tackifier such as latex powder, pulverized limestone mostly, these materials are often with diatomite etc.
Material reaction is bonded together, plug diatomaceous hole, in order to improve intensity, hygroscopicity with the addition of bentonite, kaolin,
The materials such as attapulgite, but diatomaceous adsorptivity is not improved significantly.
The content of the invention
It is an object of the invention to provide a kind of multi-functional diatom ooze wall material, for solving existing diatom ooze wall material hole
Rate is low, the problems such as adsorptivity difference.
To achieve the above object, the present invention from the zeolite of calcining by being used as auxiliary material, by chemical method to diatom ooze
The raw material of wall material carries out soaking and washing, increases porosity, improves absorption property.Realized especially by following technical scheme：
A kind of Multifunctional diatom ooze wall material, by weight including following components：
Further, the diatom ooze wall material includes following components by weight：
Further, the diatomaceous granularity is 200~400 mesh, and the granularity of calcined zeolite powder is 200~300 mesh, sea
The granularity of afrodite powder is 200~400 mesh, and the granularity of quartz sand is 100~200 mesh；
Further, the anticracking fiber is polyester fiber or polypropylene fibre, and length is 1~5mm；
Further, the plant cellulose is methylcellulose, hydroxymethyl cellulose, hydroxypropyl cellulose or ethoxy
One or more in cellulose；
Further, the thickening powder is glutinous rice rubber powder；
Further, the photocatalyst is mesoporous molecular sieve carried titanium dioxide and zinc oxide, and particle diameter is 200~500 mesh；
A kind of preparation method of Multifunctional diatom ooze wall material, comprises the following steps：
(1) diatomite, calcined zeolite powder, sepiolite powder and quartz sand are weighed by weight ratio, are added to concentration as 20
In~30% acid soak, stirring immersion 12~24 hours, wet-milling is filtered to obtain；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) anticracking fiber, plant cellulose, photocatalyst and thickening powder are weighed by weight ratio is added to step (2) institute
Obtain in mixed-powder, be put into agitator and be uniformly mixed.
Further, the acid soak is one kind in hydrochloric acid, sulfuric acid or nitric acid.
The inventive method has the following advantages that：
1st, a kind of Multifunctional diatom ooze wall material of the present invention, calcined zeolite ash, sepiolite powder, quartz sand are added in diatomite
For auxiliary material, zeolite powder greatly increases porosity and specific surface area by calcining, and quartz sand improves the matter of diatom ooze wall material
Sense and intensity, by adding these auxiliary materials, not only increase the porosity of diatom ooze wall material, while harmful substance is adsorbed,
Can also adsorption moisture, reach the purpose for automatically adjusting indoor humidity.
2nd, a kind of Multifunctional diatom ooze wall material of the present invention, anticracking fiber and plant cellulose are added, improves the machine of wall material
Tool intensity, metope is cracked after preventing construction, using glutinous rice tackifier, will not be released while diatom ooze wall material viscosity is increased
Harmful substance is put, it is green.
3rd, the present invention removes diatomite, zeolite powder, quartz sand, sepiolite powder table by carrying out pickling processes to raw material
Attachment in face and hole, improve the porosity and specific surface area of diatom ooze wall material so that diatom ooze wall material formaldehyde adsorption,
The ability of the harmful substances such as VOC greatly improves.
4th, mesoporous molecular sieve carried titanium dioxide and zinc oxide are with the addition of in the present invention, substantially increases titanium dioxide and oxygen
Change the photocatalytic activity of zinc, formaldehyde, toluene etc. effectively can be resolved into CO2And H2O, formaldehyde, first are thoroughly removed so as to reach
The purpose of the harmful substances such as benzene, secondary pollution will not be brought, simultaneous oxidation zinc can also destroy the cell membrane of bacterium, play sterilization
Effect.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Embodiment 1
A kind of Multifunctional diatom ooze wall material：
Formula：Include following components by weight：
Preparation method：
(1) 200 parts of diatomite, 100 parts of calcined zeolite powder, 50 parts of sepiolite powder, 100 parts of quartz sand are weighed by weight,
It is added in the aqueous hydrochloric acid solution that concentration is 20%, stirring immersion 12 hours, filters to obtain wet-milling；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) by weight ratio by 1 part of polyester fiber, 10 parts of methylcellulose, 5 parts of glutinous rice rubber powders, 5 parts of mesopore molecular sieves
Carried titanium dioxide and zinc oxide are added in mixed-powder obtained by step (2), are put into agitator and are uniformly mixed.
Embodiment 2
A kind of Multifunctional diatom ooze wall material：
Formula：Include following components by weight：
Preparation method：
(1) 400 parts of diatomite, 300 parts of calcined zeolite powder, 200 parts of sepiolite powder, 200 parts of quartz sand are weighed by weight,
Concentration is added in 30% aqueous hydrochloric acid solution, stirring immersion 24 hours, to filter to obtain wet-milling；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) by weight ratio by 5 parts of polypropylene fibres, 50 parts of hydroxymethyl celluloses, 10 parts of glutinous rice rubber powders, 15 parts it is mesoporous
Molecular sieve carried titanium dioxide and zinc oxide are added in mixed-powder obtained by step (2), are put into agitator and are stirred
It is even.
Embodiment 3
A kind of Multifunctional diatom ooze wall material：
Formula：Include following components by weight：
Preparation method：
(1) 300 parts of diatomite, 300 parts of calcined zeolite powder, 150 parts of sepiolite powder, 100 parts of quartz sand are weighed by weight,
Concentration is added in 25% aqueous solution of nitric acid, stirring immersion 20 hours, to filter to obtain wet-milling；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) by weight ratio by 5 parts of polyester fibers, 30 parts of hydroxypropyl celluloses, 10 parts of glutinous rice rubber powders, 8 parts mesoporous point
Son sieve carried titanium dioxide and zinc oxide are added in mixed-powder obtained by step (2), are put into agitator and are uniformly mixed
.
Embodiment 4
A kind of Multifunctional diatom ooze wall material：
Formula：Include following components by weight：
Preparation method：
(1) 250 parts of diatomite, 200 parts of calcined zeolite powder, 150 parts of sepiolite powder, 150 parts of quartz sand are weighed by weight,
Concentration is added in 22% aqueous sulfuric acid, stirring immersion 16 hours, to filter to obtain wet-milling；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) by weight ratio by 3 parts of polypropylene fibres, 40 parts of hydroxyethyl celluloses, 8 parts of glutinous rice rubber powders, 10 parts it is mesoporous
Molecular sieve carried titanium dioxide and zinc oxide are added in mixed-powder obtained by step (2), are put into agitator and are stirred
It is even.
Although above with general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to the scope of protection of present invention.
Claims (9)
1. a kind of Multifunctional diatom ooze wall material, it is characterised in that the diatom ooze wall material includes following components by weight：
2. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The diatom ooze wall material is by weight
Including following components：
3. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The diatomaceous granularity be 200~
400 mesh, the granularity of calcined zeolite powder is 200~300 mesh, and the granularity of sepiolite powder is 200~400 mesh, and the granularity of quartz sand is
100~200 mesh.
4. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The anticracking fiber be polyester fiber or
Polypropylene fibre, length are 1~5mm.
5. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The plant cellulose is Methyl cellulose
One or more in element, hydroxymethyl cellulose, hydroxypropyl cellulose or hydroxyethyl cellulose.
6. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The thickening powder is glutinous rice rubber powder.
7. Multifunctional diatom ooze wall material according to claim 1, it is characterised in that：The photocatalyst is born for mesopore molecular sieve
Carrying of titanium dioxide and zinc oxide, particle diameter are 200~500 mesh.
8. the preparation method of the Multifunctional diatom ooze wall material according to any one of claim 1~7, it is characterised in that：It is described
Preparation method comprises the following steps：
(1) diatomite, calcined zeolite powder, sepiolite powder and quartz sand are weighed by weight ratio, be added to concentration for 20~
In 30% acid soak, stirring immersion 12~24 hours, wet-milling is filtered to obtain；
(2) after wet-milling obtained by step (1) being carried out into clear water washing, mixed-powder is obtained after drying, grinding；
(3) anticracking fiber, plant cellulose, photocatalyst and thickening powder are weighed by weight ratio, are added to mixed obtained by step (2)
Close in powder, be put into agitator and be uniformly mixed.
9. the preparation method of Multifunctional diatom ooze wall material according to claim 8, it is characterised in that：The acid soak
For one kind in hydrochloric acid, sulfuric acid or nitric acid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711116547.8A CN107857516A (en) | 2017-11-13 | 2017-11-13 | A kind of Multifunctional diatom ooze wall material |
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| CN201711116547.8A CN107857516A (en) | 2017-11-13 | 2017-11-13 | A kind of Multifunctional diatom ooze wall material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054525A (en) * | 2018-09-12 | 2018-12-21 | 吉林省金贝壳新材料科技有限公司 | A kind of antibacterial and mouldproof shell powder paint |
| CN112430407A (en) * | 2020-11-14 | 2021-03-02 | 广东薇氧生态科技有限公司 | Material with air purifying and negative ion releasing functions, preparation method thereof and application thereof in coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054525A (en) * | 2018-09-12 | 2018-12-21 | 吉林省金贝壳新材料科技有限公司 | A kind of antibacterial and mouldproof shell powder paint |
| CN112430407A (en) * | 2020-11-14 | 2021-03-02 | 广东薇氧生态科技有限公司 | Material with air purifying and negative ion releasing functions, preparation method thereof and application thereof in coating |
| CN112430407B (en) * | 2020-11-14 | 2023-08-18 | 广东薇氧生态科技有限公司 | Material with air purifying and negative ion releasing effects, preparation method thereof and application thereof in coating |
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