CN108355695A - A kind of special diatom ooze and preparation method having the interior purifying formaldehyde for turning light - Google Patents
A kind of special diatom ooze and preparation method having the interior purifying formaldehyde for turning light Download PDFInfo
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- CN108355695A CN108355695A CN201810112962.4A CN201810112962A CN108355695A CN 108355695 A CN108355695 A CN 108355695A CN 201810112962 A CN201810112962 A CN 201810112962A CN 108355695 A CN108355695 A CN 108355695A
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- diatom ooze
- diatomite
- reflective layer
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 180
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 83
- 238000006243 chemical reaction Methods 0.000 claims abstract description 77
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 56
- 238000012545 processing Methods 0.000 claims abstract description 41
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 38
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002253 acid Substances 0.000 claims abstract description 22
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 21
- 235000019738 Limestone Nutrition 0.000 claims abstract description 21
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 21
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006028 limestone Substances 0.000 claims abstract description 21
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 21
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 19
- 239000004816 latex Substances 0.000 claims abstract description 19
- 229920000126 latex Polymers 0.000 claims abstract description 19
- 229920005594 polymer fiber Polymers 0.000 claims abstract description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 66
- 239000000243 solution Substances 0.000 claims description 64
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 39
- 239000003349 gelling agent Substances 0.000 claims description 26
- 230000015572 biosynthetic process Effects 0.000 claims description 19
- 238000001914 filtration Methods 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 11
- 239000004332 silver Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- 238000005342 ion exchange Methods 0.000 claims description 9
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical group [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims description 9
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 5
- 229910001863 barium hydroxide Inorganic materials 0.000 claims description 5
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 claims description 4
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 claims description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 4
- 229940082484 carbomer-934 Drugs 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 13
- 238000005286 illumination Methods 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 21
- 238000003837 high-temperature calcination Methods 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 8
- 238000007598 dipping method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 229930040373 Paraformaldehyde Natural products 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920002866 paraformaldehyde Polymers 0.000 description 6
- 239000011941 photocatalyst Substances 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 238000004887 air purification Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 230000000505 pernicious effect Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- -1 furniture appliance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The present invention relates to the technical fields of purifying formaldehyde, disclose a kind of special diatom ooze and preparation method having the interior purifying formaldehyde for turning light.Including following preparation process：（1）Diatomite is calcined after acid solution impregnates and obtains the diatomite of precision processing；（2）Silver nitrate and ammonia spirit is added, silver forms reflective layer in diatomaceous surface and micropore after reaction；（3）Light conversion agent is formed into gel, diatomite, lye containing reflective layer is added, conversion layer is formed in diatomaceous surface and micropore after reaction；（4）Diatomite containing reflective layer and conversion layer is mixed with diatom ooze with nano silicon nitride carbon, water, latex powder, kaolin, lime stone, polymer fiber.For compound diatom ooze produced by the present invention compared with common diatom ooze, the conversion layer that surface is formed effectively converts light energy into absorbable light, and reflective layer can be by light energy reflected to catalyst surface, significant increase intensity of illumination and the efficiency of light energy utilization.
Description
Technical field
The present invention relates to the technical fields of purifying formaldehyde, disclose a kind of special diatom having the interior purifying formaldehyde for turning light
Mud and preparation method.
Background technology
With the improvement of living standards, how the use of a large amount of ornament materials, furniture appliance, lead to a large amount of chemicals appearance
Interior, many poisonous and hazardous substances are stealthily threaten the health of human body, and room air pollution, which has become, endangers the mankind
" the stealthy killer " of health.Therefore, Techniques for Indoor Air Purification is very urgent.Currently used indoor air purification skill
Art has：Absorption method, filtration method, photocatalytic oxidation, anion method, Ozone etc..
Absorption method be absorption method be using harmful components in certain substances for having an adsorption capacity i.e. adsorbent absorption air from
And reach the method for eliminating noxious pollutant purpose, be the most common purification techniques of current removal indoor volatile organic compounds it
One.Conventional using activated carbon adsorption at present, in recent years, its distinctive adsorptivity due to diatomite, diatom ooze is as indoor
Building, ornament materials, prepare diatomite paint, in order to solve kieselguhr adsorption saturability usually by way of directly mixing
The problem of, it is usually added into photochemical catalyst, realizes constant absorption and the decomposition of PARA FORMALDEHYDE PRILLS(91,95) gas.
In photocatalysis technology, nano titanium dioxide photocatalyst is a kind of tool development potentiality and obtains the light studied extensively
Catalyst, but it is limited by energy gap, limitation in practical applications and operation difficulty.And carbonitride is as a kind of
Non-metal semiconductor materials, energy gap is small, and photoresponse wave-length coverage is wide, has photocatalysis, but energy under visible light
The wave band enough utilized is still relatively narrow, the absorption decomposition rate of PARA FORMALDEHYDE PRILLS(91,95) relatively it is slow therefore, absorption method is combined with photocatalytic method
In development and application, the efficiency of light energy utilization for improving photochemical catalyst and the blockage of the micro orifice for preventing sorbing material are main research topics.
Chinese invention patent application number 201410557051.4 discloses a kind of diatom ooze decoration material for purifying formaldehyde
Material and preparation method thereof.Specifically, the diatom ooze ornament materials of the invention is made of following component as mass fraction：Essence
10.0 ~ 30.0 parts of diatomite processed；20.0 ~ 50.0 parts of powder stuffing；2.0 ~ 5.0 parts of re-dispersible glue powder；Gel rubber material 20.0 ~
40.0 parts；0.5 ~ 1.0 part of decentralized medium；3.0 ~ 8.0 parts of nano-titanium dioxide；1.0 ~ 4.0 parts of modifying agent；Anti-crack fiber 3.0 ~
5.0 part；20 ~ 80 parts of water.The diatom ooze ornament materials of the invention can be effectively increased purifying formaldehyde efficiency and significantly improve purification and hold
Long property, avoids physical absorption from losing the drawbacks such as adsorption effect because of saturation, can accelerate purification speed.In addition, the diatom of the invention
Mud ornament materials also has good thixotropy, suitable for moulding, while meeting the technological requirements such as mechanically spraying, brushing and roller coating,
The beneficial properties such as it is provided simultaneously with water-fast, alkaline-resisting, not dusting, do not crack..
Chinese invention patent application number 201610063507.0 discloses a kind of photocatalyst diatom ooze high-strength light plate, by
The photocatalyst layer of substrate and coating on the surface of the substrate is constituted；The ingredient and mass percent of substrate are as follows：Three-level diatomaceous earth, raw stone
The ingredient of ash, cement, reinforcing fiber, photocatalyst layer is as follows：Graphite phase carbon nitride, surfactant, adhesive, surplus are water；
Reinforcing fiber is the wood pulp of plant fiber, careless paddle, one kind of the glass fibre of chemical fibre or arbitrarily than a variety of.The light of the invention
Catalyst diatom ooze high-strength light plate itself can purify air without any pollution, and purifying formaldehyde performance reaches 92.5%；Formaldehyde is net
Change effect persistence and reaches 90%.
According to above-mentioned, the diatom ooze adsorbance in existing scheme for air purification is limited, and adsorption efficiency is low, and light is being added
When the pernicious gases constant absorption such as catalyst PARA FORMALDEHYDE PRILLS(91,95) decomposes, the micropore translucency on diatom ooze surface is poor, the luminous energy profit of catalyst
It is poor with rate, it can not especially solve the problems, such as that carbonitride light-use wave band is relatively narrow, cause photocatalytic degradation efficiency low, air is net
Change effect is poor, and the present invention proposes a kind of special diatom ooze and preparation method having the interior purifying formaldehyde for turning light, can effectively solve
Certainly above-mentioned technical problem.
Invention content
Low for air purification diatom ooze adsorption efficiency using wider at present, adsorbance is limited, traditional and photocatalysis
Technical method there are intensities of illumination poor, the catalyst efficiency of light energy utilization that agent combines, the catalytic degradation efficiency and effect of PARA FORMALDEHYDE PRILLS(91,95) are poor
The problems such as.
To solve the above problems, the present invention uses following technical scheme：
A kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light, the preparation process of the special diatom ooze
For：
（1）Diatomaceous precision processing：First diatomite is impregnated in acid solution, then filters and high temperature is forged at 800 ~ 1000 DEG C
It burns, obtains the diatomite of precision processing；
（2）The formation of reflective layer：First the diatomite of precision processing is added in silver nitrate solution and impregnates 40 ~ 60min, through fully adsorbing
After ion exchange, excess of ammonia aqueous solution is stirred and be added dropwise, 2 ~ 3h is then allowed to stand, refilters, washed, at 100 ~ 120 DEG C
It is dry, 300 ~ 400 DEG C of calcinings are heated to, the silver of generation forms reflective layer in diatomaceous surface and micropore；
（3）The formation of conversion layer：First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, then adds
Enter the diatomite containing reflective layer, be uniformly mixed, be eventually adding lye to the reaction was complete, filtering, drying, on diatomaceous surface and
Conversion layer is formed in micropore；
（4）The preparation of compound diatom ooze：First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasound
It is uniformly dispersed, carbonitride is made to enter in diatomaceous micropore, it is fine then to add latex powder, kaolin, lime stone and polymer
Dimension is uniformly mixed, and compound diatom ooze is made.
Preferably, step（1）The acid solution is one kind in hydrochloric acid solution, sulfuric acid solution, phosphoric acid solution or salpeter solution,
Mass concentration is 3 ~ 6%.
Preferably, step（1）The mass concentration of the silver nitrate solution is 15 ~ 20%；The mass concentration of the ammonia spirit
It is 20 ~ 25%.
Preferably, the step（2）In, by weight, wherein：30 ~ 45 parts of diatomite, the silver nitrate solution of precision processing
20 ~ 30 parts, 35 ~ 40 parts of ammonia spirit.
Preferably, step（3）The light conversion agent is praseodymium oxide.
Preferably, step（3）The gelling agent is one kind in carbomer 934, Acritamer 940 or Carbopol 941.
Preferably, step（3）The lye is one in sodium hydroxide solution, potassium hydroxide solution or barium hydroxide solution
Kind, mass concentration is 10 ~ 15%.
Preferably, the step（3）In, by weight, wherein：56 ~ 71 parts of diatomite, light conversion agent containing reflective layer
15 ~ 20 parts, 5 ~ 10 parts of hydrochloric acid, 1 ~ 2 part of gelling agent, 8 ~ 12 parts of lye.
Preferably, step（4）In the compound diatom ooze, by weight, wherein：Diatom containing reflective layer and conversion layer
30 ~ 40 parts of soil, 5 ~ 10 parts of nano silicon nitride carbon, 26 ~ 52 parts of water, 1 ~ 3 part of latex powder, 4 ~ 8 parts of kaolin, 5 ~ 8 parts of lime stone, polymerization
3 ~ 5 parts of fibres.
A kind of special diatom ooze having the interior purifying formaldehyde for turning light being prepared by the above method, on diatom ooze surface
And one layer of conversion layer is loaded in micropore, ultraviolet light and some visible light can be converted to the absorbable blue light of photochemical catalyst, carried
The high efficiency of photochemical catalyst, can quickly absorb the pernicious gases such as decomposing formaldehyde；And silver is in diatomite surface and micropore
One layer of reflective layer of middle formation, the light converted by conversion layer have efficient by being reflected into photocatalyst surface, compound diatomite
The harmful gas of absorption decomposing formaldehyde etc. effect.
The visible light utilization efficiency of the special diatom ooze of purifying formaldehyde prepared by the method for the test present invention, formaldehyde absorption speed and
Formaldehyde decomposition rate, and be directly blended with carbonitride/diatom ooze and compound diatom ooze obtained is directly blended in titanium dioxide/diatom ooze
It compares, method of the invention has a clear superiority, as shown in table 1.
Table 1：
The present invention provides a kind of special diatom oozes and preparation method having the interior purifying formaldehyde for turning light, with prior art phase
Than the feature and excellent effect protruded is：
1, propose using sequentially formed in diatom ooze surface micro-pore reflective layer and conversion layer preparation have in turn the net of light
Change the method for the special diatom ooze of formaldehyde.
2, by loading one layer of conversion layer in diatom ooze surface and micropore, ultraviolet light and some visible light can be converted
For the absorbable blue light of photochemical catalyst, the efficiency of photochemical catalyst is improved, can quickly absorb the pernicious gases such as decomposing formaldehyde.
3, one layer of reflective layer is formed in diatomite surface and micropore by silver, the light converted by conversion layer passes through reflection
To photocatalyst surface, the utilization rate of intensity of illumination and catalyst to luminous energy can be effectively improved, there is efficient absorb to decompose first
The effect of the pernicious gases such as aldehyde.
4, of the invention to prepare relatively simple, production cost is low, and the feature of environmental protection is good, has fabulous application prospect.
Specific implementation mode
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that hydrochloric acid is molten
Liquid, mass concentration 5%；The temperature of high-temperature calcination is 900 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 18%；The mass concentration of ammonia spirit is 23%；Dipping when
Between be 50min；The time of standing is 2.5h；Drying temperature is 110 DEG C；Calcination temperature is 350 DEG C；
By weight, wherein：38 parts of 25 parts of 37 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is carbomer 934；Lye is sodium hydroxide solution, mass concentration 12%；
By weight, wherein：7 parts of 18 parts of 64 parts of diatomite, light conversion agent, hydrochloric acid containing reflective layer, 1 part of gelling agent, lye
10 parts；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：6 parts of 35 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
40 parts of water, 2 parts of latex powder, 6 parts of kaolin, 7 parts of lime stone, 4 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 1, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Embodiment 2
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that sulfuric acid is molten
Liquid, mass concentration 3%；The temperature of high-temperature calcination is 800 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 15%；The mass concentration of ammonia spirit is 20%；Dipping when
Between be 40min；The time of standing is 3h；Drying temperature is 100 DEG C；Calcination temperature is 300 DEG C；
By weight, wherein：35 parts of 20 parts of 45 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is Acritamer 940；Lye is potassium hydroxide solution, mass concentration 10%；
By weight, wherein：5 parts of 15 parts of 71 parts of diatomite, light conversion agent, hydrochloric acid containing reflective layer, 1 part of gelling agent, lye 8
Part；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：5 parts of 30 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
52 parts of water, 1 part of latex powder, 4 parts of kaolin, 5 parts of lime stone, 3 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 2, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Embodiment 3
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that phosphoric acid is molten
Liquid, mass concentration 6%；The temperature of high-temperature calcination is 1000 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 20%；The mass concentration of ammonia spirit is 25%；Dipping when
Between be 60min；The time of standing is 2h；Drying temperature is 120 DEG C；Calcination temperature is 400 DEG C；
By weight, wherein：40 parts of 30 parts of 30 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is Carbopol 941；Lye is barium hydroxide solution, mass concentration 15%；
By weight, wherein：2 parts of 10 parts of 20 parts of 56 parts of diatomite, light conversion agent, hydrochloric acid, gel powder, lye containing reflective layer
12 parts；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：10 parts of 40 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
26 parts of water, 3 parts of latex powder, 8 parts of kaolin, 8 parts of lime stone, 5 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 3, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Embodiment 4
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that nitric acid is molten
Liquid, mass concentration 4%；The temperature of high-temperature calcination is 850 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 16%；The mass concentration of ammonia spirit is 22%；Dipping when
Between be 45min；The time of standing is 2h；Drying temperature is 105 DEG C；Calcination temperature is 320 DEG C；
By weight, wherein：37 parts of 22 parts of 41 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is carbomer 934；Lye is sodium hydroxide solution, mass concentration 12%；
By weight, wherein：6 parts of 17 parts of 67 parts of diatomite, light conversion agent, hydrochloric acid containing reflective layer, 1 part of gelling agent, lye 9
Part；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：6 parts of 32 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
47 parts of water, 1 part of latex powder, 5 parts of kaolin, 6 parts of lime stone, 3 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 4, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Embodiment 5
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that sulfuric acid is molten
Liquid, mass concentration 5%；The temperature of high-temperature calcination is 950 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 18%；The mass concentration of ammonia spirit is 24%；Dipping when
Between be 55min；The time of standing is 3h；Drying temperature is 115 DEG C；Calcination temperature is 380 DEG C；
By weight, wherein：39 parts of 28 parts of 33 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is Carbopol 941；Lye is potassium hydroxide solution, mass concentration 14%；
By weight, wherein：8 parts of 19 parts of 60 parts of diatomite, light conversion agent, hydrochloric acid containing reflective layer, 2 parts of gelling agent, lye
11 parts；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：9 parts of 38 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
32 parts of water, 3 parts of latex powder, 7 parts of kaolin, 6 parts of lime stone, 5 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 5, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Embodiment 6
（1）The detailed process of diatomaceous precision processing is：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that nitric acid is molten
Liquid, mass concentration 5%；The temperature of high-temperature calcination is 900 DEG C；
（2）The detailed process of the formation of reflective layer is：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 17%；The mass concentration of ammonia spirit is 22%；Dipping when
Between be 55min；The time of standing is 2.5h；Drying temperature is 110 DEG C；Calcination temperature is 360 DEG C；
By weight, wherein：38 parts of 26 parts of 36 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The detailed process of the formation of conversion layer is：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatom containing reflective layer
Soil is uniformly mixed, and is eventually adding lye to the reaction was complete, filtering, drying form in diatomaceous surface and micropore and turn light
Layer；Light conversion agent is praseodymium oxide；Gelling agent is Acritamer 940；Lye is barium hydroxide solution, mass concentration 12%；
By weight, wherein：8 parts of 18 parts of 63 parts of diatomite, light conversion agent, hydrochloric acid containing reflective layer, 2 parts of gelling agent, lye 9
Part；
（4）The detailed process of the preparation of compound diatom ooze is：
First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, make carbonitride into
Enter in diatomaceous micropore, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, is made compound
Diatom ooze；
In compound diatom ooze, by weight, wherein：6 parts of 36 parts of diatomite, nano silicon nitride carbon containing reflective layer and conversion layer,
40 parts of water, 2 parts of latex powder, 5 parts of kaolin, 7 parts of lime stone, 4 parts of polymer fiber.
The special diatom ooze of purifying formaldehyde made from embodiment 6, it can be seen that light utilization efficiency, formaldehyde absorption speed and Formaldehyde decomposition
Rate is as shown in table 2.
Comparative example 1
（1）Diatomaceous precision processing：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that nitric acid is molten
Liquid, mass concentration 5%；The temperature of high-temperature calcination is 900 DEG C；
（2）The formation of conversion layer：
First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, adds the diatomite of precision processing,
It is uniformly mixed, is eventually adding lye to the reaction was complete, filtering, drying form conversion layer in diatomaceous surface and micropore；Turn
Luminescent material is praseodymium oxide；Gelling agent is Acritamer 940；Lye is barium hydroxide solution, mass concentration 12%；
By weight, wherein：8 parts of 18 parts of 63 parts of diatomite, light conversion agent, the hydrochloric acid of precision processing, 2 parts of gelling agent, lye 9
Part；
（3）The preparation of compound diatom ooze：
First the diatomite containing conversion layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, and carbonitride is made to enter diatomite
Micropore in, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, be made compound diatom ooze；
In compound diatom ooze, by weight, wherein：40 parts of 6 parts of 36 parts of diatomite, nano silicon nitride carbon, water, breast containing conversion layer
2 parts of rubber powder, 5 parts of kaolin, 7 parts of lime stone, 4 parts of polymer fiber.
1 no-reflection layer of comparative example is formed, the special diatom ooze of purifying formaldehyde obtained, it can be seen that light utilization efficiency, formaldehyde absorption
Speed and Formaldehyde decomposition rate are as shown in table 2.
Comparative example 2
（1）Diatomaceous precision processing：
First diatomite is impregnated in acid solution, then filtering and high-temperature calcination, obtain the diatomite of precision processing；Acid solution is that nitric acid is molten
Liquid, mass concentration 5%；The temperature of high-temperature calcination is 900 DEG C；
（2）The formation of reflective layer：
First the diatomite of precision processing is added in silver nitrate solution and is impregnated, through fully adsorbing and after ion exchange, stirring and be added dropwise
Excess of ammonia aqueous solution is then allowed to stand a period of time, refilters, washs, dries, calcines, and the silver of generation is on diatomaceous surface
And reflective layer is formed in micropore；The mass concentration of silver nitrate solution is 17%；The mass concentration of ammonia spirit is 22%；Dipping when
Between be 55min；The time of standing is 2.5h；Drying temperature is 110 DEG C；Calcination temperature is 360 DEG C；
By weight, wherein：38 parts of 26 parts of 36 parts of diatomite, silver nitrate solution, the ammonia spirit of precision processing；
（3）The preparation of compound diatom ooze：
First the diatomite containing reflective layer is added to the water with nano silicon nitride carbon, ultrasonic disperse is uniform, and carbonitride is made to enter diatomite
Micropore in, then add latex powder, kaolin, lime stone and polymer fiber, be uniformly mixed, be made compound diatom ooze；
In compound diatom ooze, by weight, wherein：40 parts of 6 parts of 36 parts of diatomite, nano silicon nitride carbon, water, breast containing reflective layer
2 parts of rubber powder, 5 parts of kaolin, 7 parts of lime stone, 4 parts of polymer fiber..
Comparative example 2 is formed without conversion layer, the special diatom ooze of purifying formaldehyde obtained, it can be seen that light utilization efficiency, formaldehyde absorption
Speed and Formaldehyde decomposition rate are as shown in table 2.
The test method of above-mentioned performance indicator is：
Using diatom ooze made from radiation of visible light, the wave-length coverage W1 of the absorbable visible light of diatom ooze is measured, it is seen that light wave
Long total size is W, and the visible light utilization efficiency of diatom ooze is calculated with W1/W × 100%.
Absorption cleaning is carried out using diatom ooze PARA FORMALDEHYDE PRILLS(91,95) obtained in confined chamber, the quality for purifying front and back formaldehyde be m1,
M2, the quality of diatom ooze are m, clarification time t, can be by（m1-m2）The infiltration rate of formaldehyde is calculated in/mt.
It is adsorbed using diatom ooze PARA FORMALDEHYDE PRILLS(91,95), after stopping absorption, tests adsorbance, and heating makes undecomposed formaldehyde release
It puts, measures Formaldehyde decomposition amount, the resolution ratio of formaldehyde is can be obtained with decomposition amount/adsorbance.
Table 2：
Claims (10)
1. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light, which is characterized in that the special diatom
The preparation process of mud is：
（1）Diatomaceous precision processing：First diatomite is impregnated in acid solution, then filters and high temperature is forged at 800 ~ 1000 DEG C
It burns, obtains the diatomite of precision processing；
（2）The formation of reflective layer：First the diatomite of precision processing is added in silver nitrate solution and impregnates 40 ~ 60min, through fully adsorbing
After ion exchange, excess of ammonia aqueous solution is stirred and be added dropwise, 2 ~ 3h is then allowed to stand, refilters, washed, at 100 ~ 120 DEG C
It is dry, 300 ~ 400 DEG C of calcinings are heated to, the silver of generation forms reflective layer in diatomaceous surface and micropore；
（3）The formation of conversion layer：First light conversion agent is dissolved in hydrochloric acid, gelling agent is then added dropwise and stirs to form gel, then adds
Enter the diatomite containing reflective layer, be uniformly mixed, be eventually adding lye to the reaction was complete, filtering, drying, on diatomaceous surface and
Conversion layer is formed in micropore；
（4）The preparation of compound diatom ooze：First the diatomite containing reflective layer and conversion layer is added to the water with nano silicon nitride carbon, ultrasound
It is uniformly dispersed, carbonitride is made to enter in diatomaceous micropore, it is fine then to add latex powder, kaolin, lime stone and polymer
Dimension is uniformly mixed, and compound diatom ooze is made.
2. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（1）The acid solution is one kind in hydrochloric acid solution, sulfuric acid solution, phosphoric acid solution or salpeter solution, and mass concentration is
3~6%。
3. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（1）The mass concentration of the silver nitrate solution is 15 ~ 20%；The mass concentration of the ammonia spirit is 20 ~ 25%.
4. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：The step（2）In, by weight, wherein：20 ~ 30 parts of 30 ~ 45 parts of diatomite, silver nitrate solution, the ammonia of precision processing
35 ~ 40 parts of aqueous solution.
5. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（3）The light conversion agent is praseodymium oxide.
6. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（3）The gelling agent is one kind in carbomer 934, Acritamer 940 or Carbopol 941.
7. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（3）The lye is one kind in sodium hydroxide solution, potassium hydroxide solution or barium hydroxide solution, and quality is dense
Degree is 10 ~ 15%.
8. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：The step（3）In, by weight, wherein：15 ~ 20 parts of 56 ~ 71 parts of diatomite, light conversion agent, salt containing reflective layer
5 ~ 10 parts of acid, 1 ~ 2 part of gelling agent, 8 ~ 12 parts of lye.
9. a kind of preparation method for the special diatom ooze having the interior purifying formaldehyde for turning light according to claim 1, feature
It is：Step（4）In the compound diatom ooze, by weight, wherein：30 ~ 40 parts of diatomite containing reflective layer and conversion layer,
5 ~ 10 parts of nano silicon nitride carbon, 26 ~ 52 parts of water, 1 ~ 3 part of latex powder, 4 ~ 8 parts of kaolin, 5 ~ 8 parts of lime stone, polymer fiber 3 ~ 5
Part.
10. a kind of special diatom having the interior purifying formaldehyde for turning light that any one of claim 1 ~ 9 the method is prepared
Mud.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796179A (en) * | 2019-03-25 | 2019-05-24 | 黄河三角洲京博化工研究院有限公司 | A kind of diatom ooze coating with visible light catalytic ability |
| CN113509903A (en) * | 2020-04-09 | 2021-10-19 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
| CN115155306A (en) * | 2022-07-05 | 2022-10-11 | 汕头市优森活新材料科技有限公司 | Efficient remover for indoor formaldehyde and organic volatile matters, and preparation method and application thereof |
-
2018
- 2018-02-05 CN CN201810112962.4A patent/CN108355695A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796179A (en) * | 2019-03-25 | 2019-05-24 | 黄河三角洲京博化工研究院有限公司 | A kind of diatom ooze coating with visible light catalytic ability |
| CN113509903A (en) * | 2020-04-09 | 2021-10-19 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
| CN113509903B (en) * | 2020-04-09 | 2022-06-28 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
| CN115155306A (en) * | 2022-07-05 | 2022-10-11 | 汕头市优森活新材料科技有限公司 | Efficient remover for indoor formaldehyde and organic volatile matters, and preparation method and application thereof |
| CN115155306B (en) * | 2022-07-05 | 2024-01-26 | 汕头市优森活新材料科技有限公司 | Efficient remover for indoor formaldehyde and organic volatile matters, preparation method and application |
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