CN105725270A - Preparation method of astaxanthin particles and application thereof in cigarette filter sticks - Google Patents
Preparation method of astaxanthin particles and application thereof in cigarette filter sticks Download PDFInfo
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- CN105725270A CN105725270A CN201610127716.7A CN201610127716A CN105725270A CN 105725270 A CN105725270 A CN 105725270A CN 201610127716 A CN201610127716 A CN 201610127716A CN 105725270 A CN105725270 A CN 105725270A
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- astaxanthin
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
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- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses a preparation method of astaxanthin particles and application thereof in cigarette filter sticks.Astaxanthin powder, tobacco leaf powder, a binding agent and natural plant extracts are adopted as raw materials, a wetting agent and the raw materials are uniformly mixed to prepare softwood, and pelleting and drying are performed to obtain astaxanthin particles.In the cigarette filter stick forming process, the astaxanthin particles are uniformly spread in filter stick strands according to the addition amount of 1-3 mg/mm or added into a cavity reserved in the filter sticks, and the binary composite filter sticks or the ternary composite filter sticks or ternary cavity particle composite filter sticks are prepared.According to the astaxanthin particles, fragrance of cigarettes can be enriched, the smoke fineness is improved, and the cigarette suction quality is improved; meanwhile, free radicals in main stream smoke of cigarettes can be effectively removed.
Description
Technical field
The invention belongs to cigarette material and applied technical field thereof.
Background technology
Free radical be the class that produces in organism metabolic processes can individualism, there is high oxidation activity, with the molecule of one or several unpaired electronics or atom, including ultra-oxygen anion free radical, hydroxy radical etc., its chemical property is quite active.When pathological changes occurs in body, free radical dynamic equilibrium is broken, and free radical generating rate is more than body supersession rate, and the accumulation of a large amount of free radicals may cause body aging to accelerate, and the disease such as induced tumor, cardiovascular.The removing of free radical depends on the participation of antioxidant, and the anti-oxidizing compounds extracted in natural product, owing to himself toxicity is low, the advantage of abundance, extensively it is subject to the attention of researcher and consumers.
Astaxanthin is one of carotenoid main in marine animal, has extremely strong singlet-oxygen quenching and Scavenging ability, is a kind of chain breaking antioxidants.Astaxanthin is possible to prevent radical pair fat, nucleic acid and protein etc. to produce destruction.Big quantity research finds, ketone group in carotenoid and hydroxyl and number thereof number can interfere significantly on the ability of its antioxidation.It is reported, astaxanthin antioxidative ability, higher than more than 10 times of beta-carotene, is more than 500 times of vitamin E.Therefore, current astaxanthin is all widely used in food additive, aquaculture, cosmetics, health product and medical industry.Patent CN104082741A provides a kind of soft capsule of fur seal containing astaxanthin, principle active component is: Adeps Phocae vitulinae and astaxanthin oil, major auxiliary burden is water, vitamin E, glycerol and edible animal gelatin, it has reached can effectively prevent cardiovascular and cerebrovascular disease, and immunity can be improved, remove interior free yl, play the effect of slow down aging.Patent CN103767070A discloses Squalene and applies with the preparation method of astaxanthin compositions liquid precursor liposome and the base harm reduction of dropping in Medicated cigarette thereof.But, astaxanthin is applied in Medicated cigarette rarely have report with the form of Particles dispersed filter stick.
Summary of the invention
An object of the present invention is in that to make up the vacancy of prior art, it is provided for preparing a kind of energy scavenging free radicals and can improve the astaxanthin granule filter stick of cigarette odor-absorbing.It is a further object of the present invention to provide the application in cigarette filter rod of the described astaxanthin granule.
The technical scheme realizing the object of the invention is as follows:
The preparation method of a kind of astaxanthin granule, with astaxanthin powder, Nicotiana tabacum L. powder, binding agent and extracted form natural plant for raw material, mixs homogeneously wetting agent with raw material and prepares into soft material, again through pelletize, drying, obtain astaxanthin granule.
The step of the preparation method of astaxanthin granule of the present invention is as follows:
(1) 60～70 parts of astaxanthin powder, 10～20 parts of offal powder, binding agent 0.3～20 part, mix homogeneously are weighed by weight；
(2) weigh natural extract 1～15 part, wetting agent 100～160 parts by weight, mix homogeneously with the mixed-powder of step (1) and prepare into soft material；
(3) soft material that step (2) obtains is prepared granule by extruder granulation technique；
(4) step (3) described granule is placed in 60～80 DEG C of baking ovens dries to moisture content 6%～8%, obtain astaxanthin granule.
Binding agent of the present invention is any one or two or more mixture in sodium carboxymethyl cellulose, chitosan, polyvinyl alcohol.Described natural extract is any one or two or more mixture in Fructus Mali pumilae extract, Fructus Jujubae extract, Flos Lonicerae extract, and described wetting agent is any one in water, ethanol or ethanol water.Described prilling adopts extrusion-spheronization pelletizing or waves pelletize.The present invention can by the drying screened astaxanthin granule obtaining 20～60 orders of granule of step (4).
Astaxanthin granule prepared by the present invention application in cigarette filter rod, it is in cigarette filter tip shaping process, astaxanthin granule uniformly it is sprinkled upon in filter stick tow according to the addition of 1～3mg/mm or adds in the cavity that filter stick is reserved, preparing into binary compound filter candle or Three-element composite filter core or ternary cavity Particles dispersed filter stick.
The present invention at least has the advantage that
(1) astaxanthin, offal and extracted form natural plant are carried out composite by the inventive method, can enrich Medicated cigarette cigarette perfume effectively reducing, improve flue gas exquisiteness, improve the suction quality of Medicated cigarette in cigarette mainstream flue gas while free radical；
(2) institute of the present invention raw material sources is extensive, and raw material is easy to get, with low cost, has higher safety；
(3) production technology of the present invention is relatively simple, and operability and standardization are strong, it is simple to realize industrialized production, have a good application prospect.
Detailed description of the invention
The present invention is described in detail below in conjunction with detailed description of the invention.But, protection scope of the present invention is not limited to the preferred implementation that the following specifically describes.
Embodiment 1
Weigh 60 parts of astaxanthin powder, 10 parts of offal powder, sodium carboxymethyl cellulose 1 part, mix homogeneously by weight；Weigh Fructus Mali pumilae extract 5 parts, 100 parts of water, with astaxanthin powder, offal powder, sodium carboxymethyl cellulose mixed-powder mix homogeneously, prepare into soft material.By soft material by extrusion-spheronization pelletizing machine, preparing shaped granule, dried by granule in 60 DEG C of baking ovens, screening obtains the astaxanthin granule of 20～60 orders, and its granule moisture content is 6%.
Embodiment 2
Weigh 65 parts of astaxanthin powder, 15 parts of offal powder, chitosan 0.3 part, mix homogeneously by weight；Weigh Fructus Jujubae extract 1 part, 10% ethanol water 120 parts, with astaxanthin powder, offal powder, chitosan mixed-powder mix homogeneously, prepare into soft material.By soft material by extrusion-spheronization pelletizing machine, preparing shaped granule, dried by granule in 65 DEG C of baking ovens, screening obtains the astaxanthin granule of 20～60 orders, and its granule moisture content is 6.5%.
Embodiment 3
Weigh 70 parts of astaxanthin powder, 20 parts of offal powder, 20 parts of mix homogeneously of polyvinyl alcohol by weight；Weigh Flos Lonicerae extract 10 parts, Fructus Jujubae extract 5 parts, 70% ethanol 160 parts, with astaxanthin powder, offal powder, polyvinyl alcohol mixed-powder mix homogeneously, prepare into soft material.By soft material by waving comminutor, preparing shaped granule, dried by granule in 80 DEG C of baking ovens, screening obtains the astaxanthin granule of 20～60 orders, and its granule moisture content is 8%.
Application Example 1
By the astaxanthin granule prepared by embodiment 1 by filter stick formation equipment, prepare into binary compound filter candle, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:20, and wherein charge bar section is 10mm, the addition 1mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 2
By the astaxanthin granule prepared by embodiment 2 by filter stick formation equipment, prepare into Three-element composite filter core, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:10:10, and wherein charge bar section is 10mm, the addition 2mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 3
By the astaxanthin granule prepared by embodiment 3 by filter stick formation equipment, prepare into ternary cavity composite filter, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and cavity segment is 10mm, the addition 3mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 4
By the astaxanthin granule prepared by embodiment 1 by filter stick formation equipment, prepare into Three-element composite filter core, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:10:10, and wherein charge bar section is 10mm, the addition 2mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 5
By the astaxanthin granule prepared by embodiment 2 by filter stick formation equipment, prepare into binary compound filter candle, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:20, and wherein charge bar section is 10mm, the addition 1mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 6
By the astaxanthin granule prepared by embodiment 3 by filter stick formation equipment, prepare into Three-element composite filter core, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:10:10, and wherein charge bar section is 10mm, the addition 2mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 7
By the astaxanthin granule prepared by embodiment 1 by filter stick formation equipment, prepare into ternary cavity composite filter, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and cavity segment is 10mm, the addition 3mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 8
By the astaxanthin granule prepared by embodiment 2 by filter stick formation equipment, prepare into ternary cavity composite filter, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and cavity segment is 10mm, the addition 3mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Application Example 9
By the astaxanthin granule prepared by embodiment 3 by filter stick formation equipment, prepare into binary compound filter candle, and then prepare into Medicated cigarette.Its filter stick specification is 30mm, and compound is than for 10:20, and wherein charge bar section is 10mm, the addition 1mg/mm of astaxanthin granule.Cigarette sample is smoked panel test by prepared Medicated cigarette according to the Sensory Quality of Cigarette evaluation criterion in GB GB5606.5-2005, and adopts the gaseous phase free radical detection method of routine to carry out the detection of free radical scavenging activity.Sensory evaluating smoking's result is as shown in table 1, and free radical scavenging efficiency is as shown in table 2.
Table 1 Analyses Methods for Sensory Evaluation Results
Table 2 free radical scavenging activity result
| Sample | Free radical scavenging activity |
| Application Example 1 | 10.3% |
| Application Example 2 | 16.7% |
| Application Example 3 | 25.4% |
| Application Example 4 | 14.3% |
| Application Example 5 | 8.7% |
| Application Example 6 | 15.4% |
| Application Example 7 | 20.3% |
| Application Example 8 | 21.7% |
| Application Example 9 | 10.4% |
Except as otherwise noted, the percentage ratio in the present invention refers both to mass percent.
Claims (7)
1. the preparation method of an astaxanthin granule, it is characterised in that with astaxanthin powder, Nicotiana tabacum L. powder, binding agent and extracted form natural plant for raw material, mixs homogeneously wetting agent with raw material and prepares into soft material, again through pelletize, drying, obtains astaxanthin granule.
2. the preparation method of a kind of astaxanthin granule according to claim 1, it is characterised in that method step is as follows:
(1) 60～70 parts of astaxanthin powder, 10～20 parts of offal powder, binding agent 0.3～20 part, mix homogeneously are weighed by weight；
(2) weigh natural extract 1～15 part, wetting agent 100～160 parts by weight, mix homogeneously with the mixed-powder of step (1) and prepare into soft material；
(3) soft material that step (2) obtains is prepared granule by extruder granulation technique；
(4) step (3) described granule is placed in 60～80 DEG C of baking ovens dries to moisture content 6%～8%, obtain astaxanthin granule.
3. the preparation method of a kind of astaxanthin granule according to claim 1 and 2, it is characterised in that described binding agent is any one or two or more mixture in sodium carboxymethyl cellulose, chitosan, polyvinyl alcohol.
4. the preparation method of a kind of astaxanthin granule according to claim 1 and 2, it is characterized in that, described natural extract is any one or two or more mixture in Fructus Mali pumilae extract, Fructus Jujubae extract, Flos Lonicerae extract, and described wetting agent is any one in water, ethanol or ethanol water.
5. the preparation method of a kind of astaxanthin granule according to claim 1 and 2, it is characterised in that described prilling adopts extrusion-spheronization pelletizing or waves pelletize.
6. the preparation method of a kind of astaxanthin granule according to claim 1 and 2, it is characterised in that by the drying screened astaxanthin granule obtaining 20～60 orders of granule of step (4).
7. the astaxanthin granule prepared such as any one of claim 1-6 application in cigarette filter rod, it is characterized in that, in cigarette filter tip shaping process, astaxanthin granule uniformly it is sprinkled upon in filter stick tow according to the addition of 1～3mg/mm or adds in the cavity that filter stick is reserved, preparing into binary compound filter candle or Three-element composite filter core or ternary cavity Particles dispersed filter stick.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106360805A (en) * | 2016-10-20 | 2017-02-01 | 云南瑞升烟草技术（集团）有限公司 | Novel recombined cigarette filter stick prepared from functional powder material |
| CN109875114A (en) * | 2019-04-17 | 2019-06-14 | 云南中烟工业有限责任公司 | A kind of cigarette functional microsphere and the preparation method and application thereof with nucleocapsid interlayer structure |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106360805A (en) * | 2016-10-20 | 2017-02-01 | 云南瑞升烟草技术（集团）有限公司 | Novel recombined cigarette filter stick prepared from functional powder material |
| CN109875114A (en) * | 2019-04-17 | 2019-06-14 | 云南中烟工业有限责任公司 | A kind of cigarette functional microsphere and the preparation method and application thereof with nucleocapsid interlayer structure |
| CN109875114B (en) * | 2019-04-17 | 2021-09-14 | 云南中烟工业有限责任公司 | Functional microsphere with core-shell sandwich structure for cigarettes and preparation method and application thereof |
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