CN105707066A - Sandalwood essential oil liquid mosquito-repellent incense and preparing method thereof - Google Patents

Sandalwood essential oil liquid mosquito-repellent incense and preparing method thereof Download PDF

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Publication number
CN105707066A
CN105707066A CN201610058581.3A CN201610058581A CN105707066A CN 105707066 A CN105707066 A CN 105707066A CN 201610058581 A CN201610058581 A CN 201610058581A CN 105707066 A CN105707066 A CN 105707066A
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China
Prior art keywords
essential oil
sandalwood essential
mosquito
butyl
liquid
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CN201610058581.3A
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CN105707066B (en
Inventor
许银亚
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LONGYAN TENGHUI MACHINERY MANUFACTURE Co.,Ltd.
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许银亚
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The invention discloses sandalwood essential oil liquid mosquito-repellent incense and a preparing method thereof. The sandalwood essential oil liquid mosquito-repellent incense is composed of, by weight, 0.5-2.5 parts of metofluthrin, 0.1-0.5 part of sandalwood essential oil, 50-60 parts of diethylene glycol monobutyl ether, 0.05-0.15 part of 4-sodium cumenesulfonate, 0.1-0.5 part of synergist, 0.1-0.5 part of antioxygen and 35-45 parts of water. The sandalwood essential oil liquid mosquito-repellent incense is fresh and fragrant, has a strong repelling and killing effect on mosquitoes, is environmentally friendly, powerful in pesticide effect, safe, nonflammable, stable in volatilization and capable of reducing the indoor volatile matter content and is an ideal selection for healthy home life.

Description

Sandalwood essential oil vaporizer mosquito liquid and preparation method thereof
Technical field:
The present invention relates to a kind of mosquito incense, be specifically related to a kind of sandalwood essential oil vaporizer mosquito liquid and preparation method thereof.
Background technology:
Mosquito is a kind of worldwide sanitary insect pest, and its all one's life, larva, when pupa, adult four through ovum Phase.Mosquito is importantly that it is one of communication media of infectious disease.It was found that the disease of mosquitoes spread Disease reaches more than kind more than 80.In the whole world, there are about 1,200,000 people and infect filaricide.The mosquito of major part kind Can the disease of infectious disease toxicity, including yellow fever, dengue fever, Japanese encephalitis, St. Louis encephalitis, multiple Property arthritis, Rift Valley fever (Rift Valley fever), contract elder brother Gen Yare and west Nile fever.On earth, Which kind of animal is not had to have bigger harm to the mankind than mosquito again.The mosquito serious threat mankind as can be seen here Health, only drives these disgusting mosquitoes, could control epidemic infectious diseases, could ensure people Class is healthy, improves the quality of life of people.
For many years, people develop and employ substantial amounts of hygienic insecticide product, for killing mosquitoes.Mosquito Perfume (or spice) is the most ancient natural drug anophelifuge way.As far back as the Southern Song Dynasty, just there is the culicifuge incense that Chinese medicine is made in period Rod.Containing effective ingredient in modern mosquito incense is pyrethrin, and it has the effect of mosquito.After burning mosquito incense, Pyrethrin in mosquito incense evaporates along with smog, sends out in indoor air, makes the nerve of mosquito Paralysis, then mosquito or born get killed, or four dissipate and run away, thus the current mosquito of effect playing mosquito killer Fragrant production industry insecticidal active ingredient, mainly cypermethrin, Prallethrin, allethrin, biological chrysanthemum The pyrethrins such as ester, the nerve that can benumb mosquito causes its death.
Electric liquid device actually mosquito liquid and the electronic thermostatic heater making medicinal liquid uniformly volatilize General name, the former claims mosquito-driving liquid, the latter to claim electric heater.In electric liquid device work, work as electric heater After accessing power supply, PTCR element begins to the heating that heats up, and relies on the temperature of PTCR element self afterwards Regulatory function, makes its temperature remain certain value.The heat that PTCR element produces is passed by heat radiation It is delivered to medicinal liquid volatilization core, is drawn to plug upper end, make from medicinal liquid bottle by medicinal liquid by volatilization core capillarity Medicinal liquid raising under heat radiation heats is vaporized speed, after the insecticidal active ingredient in space reaches finite concentration, Just mosquito is produced and drive, thus knock down and kill mosquito.Electric liquid device is because of its light, nothing of use Cigarette, without features such as dust, efficacy stability, high-efficiency low-toxicities, is welcome by consumer.
Existing electric liquid device formula system is with alkane solvent, pyrethroid, antioxidant and perfume (or spice) Essences etc. are component, form homogeneous system by mixing, stirring solvent.Alkane solvent is owing to being the shapes such as rectification Becoming, its carbochain is distributed more widely, and wherein low-carbon paraffin is easily formed organic volatile i.e. VOC, In the daily life staying idle at home of consumer, can be used by the heating of electric liquid device and volatilization causes house naturally The pollution of habitat environment, brings certain impact to consumer health.
The invention provides a kind of sandalwood essential oil vaporizer mosquito liquid, be the vaporizer mosquito liquid of a kind of safety and environmental protection.
Summary of the invention:
For deficiencies of the prior art, one of the technical problem to be solved is to provide A kind of sandalwood essential oil vaporizer mosquito liquid.
One of the technical problem to be solved is to provide the preparation side of above-mentioned sandalwood essential oil vaporizer mosquito liquid Method.
The technical problem of the present invention, is achieved by following technical proposals:
A kind of sandalwood essential oil vaporizer mosquito liquid, is made up of the raw material of following weight parts: 0.5-2.5 part methoxy benzyl fluorine Chrysanthemum ester, 0.1-0.5 part sandalwood essential oil, 50-60 part butyl, 0.05-0.15 part 4-isopropylbenzene sulphur Acid sodium, 0.1-0.5 part synergist, 0.1-0.5 part antioxidant, 35-45 part water.
Preferably, described synergist is alantolactone and/or isoalantolactone.
It is highly preferred that described synergist is by the different Radix Inulae of 40-60wt% alantolactone and 40-60wt% Lactone forms.
Preferably, described antioxidant is 2,4-dimethyl-6-tert-butyl phenol and/or 2,6-di-t-butyl-4- Methylphenol.
It is highly preferred that described antioxidant by 40-60wt%2,4-dimethyl-6-tert-butyl phenol and 40-60wt%2,6-di-tert-butyl-4-methy phenol forms.
Present invention also offers the preparation method of above-mentioned sandalwood essential oil vaporizer mosquito liquid, by metofluthrin, Sandalwood essential oil, butyl, synergist, antioxidant mix homogeneously, add 4-isopropyl sulfonic acid Sodium mix homogeneously, it is eventually adding water mix homogeneously.
Concrete, in the present invention:
Metofluthrin, No. CAS: 240494-70-6.
Sandalwood essential oil, i.e. Oleum Santali albi, No. CAS: 8006-87-9.
Butyl, No. CAS: 112-34-5.
4-cumene sodium sulfonate, No. CAS: 32073-22-6.
Alantolactone, No. CAS: 546-43-0.
Isoalantolactone, No. CAS: 470-17-7.
2,4-dimethyl-6-tert-butyl phenols, No. CAS: 1879-09-0.
2,6-di-tert-butyl-4-methy phenols, No. CAS: 128-37-0.
The sandalwood essential oil vaporizer mosquito liquid of the present invention, the pure and fresh fragrance of taste, mosquito is had and stronger kills work With, it is a kind of environment-friendly liquid mosquito incense, it has, and drug effect is powerful, safety is non-combustible, volatilization is stable, also Indoor organic volatile matter content can be reduced, be the ideal chose of healthy life staying idle at home.
Detailed description of the invention:
Below in conjunction with embodiment, the present invention is described further, the following stated, only to the present invention Preferred embodiment, not does the restriction of other forms, any technology being familiar with this specialty to the present invention Personnel are changed to the Equivalent embodiments changed on an equal basis possibly also with the technology contents of the disclosure above.Every Without departing from the present invention program content, any letter following example done according to the technical spirit of the present invention Single amendment or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Sandalwood essential oil vaporizer mosquito liquid raw material (weight portion): 1.2 parts of metofluthrin, 0.2 part of Lignum Santali Albi essence Oil, 55 parts of butyl, 0.1 part of 4-cumene sodium sulfonate, 0.3 part of synergist, 0.3 part of antioxygen Agent, 40 parts of deionized waters.
Described synergist is obtained by 50wt% alantolactone and 50wt% isoalantolactone mix homogeneously Arrive.
Described antioxidant is by 50wt%2,4-dimethyl-6-tert-butyl phenol and 50wt%2,6-di-t-butyl -4-methylphenol mix homogeneously obtains.
The preparation method of sandalwood essential oil vaporizer mosquito liquid:
Metofluthrin, sandalwood essential oil, butyl, synergist, antioxidant are mixed and stirs Mix uniformly, add 4-cumene sodium sulfonate and be mixed and stirred for uniformly, be eventually adding deionized water mixing also Stir.Obtain the sandalwood essential oil vaporizer mosquito liquid of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described synergist is only alantolactone. Obtain the sandalwood essential oil vaporizer mosquito liquid of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described synergist is only isoalantolactone. Obtain the sandalwood essential oil vaporizer mosquito liquid of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described antioxidant is only 2,4-dimethyl-6- Tert-butyl phenol.Obtain the sandalwood essential oil vaporizer mosquito liquid of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described antioxidant is only 2,6-di-t-butyl -4-methylphenol.Obtain the sandalwood essential oil vaporizer mosquito liquid of embodiment 5.
Test case 1
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out indoor harmacological effect test, uses GB18418-2009 domestic sanitary parasite killing articles for use electric liquid device standard, tests.In this standard In, it is qualified that KT50 value (boxing method)≤10 minute can be judged to, and the time, the shortest explanation was to mosquito driving and killing Effect is the best, and test data are shown in Table 1.
Table 1: vaporizer mosquito liquid indoor harmacological effect table (boxing method)
KT50 value
Embodiment 1 4 points 33 seconds
Embodiment 2 7 points 04 second
Embodiment 3 6 points 51 seconds
Embodiment 4 6 points 16 seconds
Embodiment 5 6 points 28 seconds
Comparing embodiment 1-3, embodiment 1 (alantolactone, isoalantolactone are compounding) mosquito driving and killing Effect, hence it is evident that be better than embodiment 2-3 (single raw material in alantolactone, isoalantolactone)；Ratio Relatively embodiment 1 and embodiment 4-5, embodiment 1 (2,4-dimethyl-6-tert-butyl phenols, 2, the tertiary fourth of 6-bis- Base-4-methylphenol compounds) mosquito driving and killing effect, hence it is evident that it is better than embodiment 4-5 (2, the 4-tertiary fourths of dimethyl-6- Single raw material in base phenol, 2,6 di tert butyl 4 methyl phenol).
Test case 2
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out toxotest, with reference to health ministry " duty Industry impatient property chemicals toxic disease in the blood system diagnostic criteria " and " Chinese medicine, natural drug immunity poison Technological guidance's principle of Journal of Sex Research " standard, formulate test case of the present invention.
Experiment kind: two young age white mice.
Experimental technique:
(1) experiment condition: laboratory temperature (27 ± 2) DEG C
(2) experimental provision: in two 25 square metres of mutually synthermal laboratorys, each placement one is big 80 × 80 × 80cm of little same size is fine and closely woven ventilative netted to be shrouded.
(3) experimental procedure: by two young age white mice be separately respectively put in the netted of two laboratorys and shroud In, and be divided into matched group and smoke mosquito incense group of the present invention, give respectively do not smoke mosquito incense of the present invention and smoke the present invention Mosquito incense, measures children's white mice body weight in age, observes hematology's biochemical indexes, changes in histopathology and stop Only smoke the recovery situation etc. after mosquito incense of the present invention.Place mosquito incense of the present invention time to be arranged on netted shroud in from The end 30 centimeters.Dosage: electrical heating mosquito incense, keeps 24 hours life-time service.Time: continuously Use one month, observe matched group and smoke the white mice in young age of mosquito incense group of the present invention, the life-time service present invention Mosquito incense to children age white mice toxicity and side effect.Cleaning: shroud interior two days cleanings once.
Result: after two young age white mice blood tests, every biochemical indicator is normally, shows this Children white mice in age is had no side effect by bright mosquito incense, when only having more than that indoor mosquito incense smog is the denseest 24 hours, needs Window and take a breath 10-15 minute, draw blood first 8 hours not to two children's white mice in age feeds.
Conclusion: life-time service mosquito incense of the present invention to children age white mice without any toxicity.
Test case 3
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out acute oral toxicity test, contaminates latter 5 points Clock activities in rats increases, and continues about 2 minutes, and activity transfers to normally, and diet is normal, and the observation period is without extremely Dying, LD50 is more than 5000 mgs/kg, belongs to actual nontoxic.
Test case 4
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out acute inhalation toxicity test, rat after contamination Diet activity no abnormality seen, the observation period, LD50 was more than 10 grams/cubic metre, belongs to actual nothing without death Poison.
Test case 5
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out skin patch test, experimental group skin erythema Forming scoring sum with edema is 0, illustrates to have no stimulation skin.
Test case 6
The sandalwood essential oil vaporizer mosquito liquid of embodiment 1-5 is carried out eye irritant test, and experimental group acute ocular stimulates Integration number is 0, illustrates to have no stimulation mucosa.

Claims (6)

1. a sandalwood essential oil vaporizer mosquito liquid, it is characterised in that be made up of the raw material of following weight parts: 0.5-2.5 part metofluthrin, 0.1-0.5 part sandalwood essential oil, 50-60 part butyl, 0.05-0.15 Part 4-cumene sodium sulfonate, 0.1-0.5 part synergist, 0.1-0.5 part antioxidant, 35-45 part water.
2. sandalwood essential oil vaporizer mosquito liquid as claimed in claim 1, it is characterised in that: described synergist For alantolactone and/or isoalantolactone.
3. sandalwood essential oil vaporizer mosquito liquid as claimed in claim 2, it is characterised in that: described synergist It is made up of 40-60wt% alantolactone and 40-60wt% isoalantolactone.
4. the sandalwood essential oil vaporizer mosquito liquid as according to any one of claim 1-3, it is characterised in that: institute The antioxidant stated is 2,4 dimethyl 6 tert butyl phenol and/or 2,6 di tert butyl 4 methyl phenol.
5. sandalwood essential oil vaporizer mosquito liquid as claimed in claim 4, it is characterised in that: described antioxidant By 40-60wt%2,4-dimethyl-6-tert-butyl phenol and 40-60wt%2,6-di-tert-butyl-4-methy phenol Composition.
6. the preparation method of sandalwood essential oil vaporizer mosquito liquid as according to any one of claim 1-5, it is special Levy and be: by metofluthrin, sandalwood essential oil, butyl, synergist, antioxidant mixing Uniformly, add 4-cumene sodium sulfonate mix homogeneously, be eventually adding water mix homogeneously.
CN201610058581.3A 2016-01-28 2016-01-28 Sandalwood essential oil vaporizer mosquito liquid and preparation method thereof Active CN105707066B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04145076A (en) * 1990-10-05 1992-05-19 Morishita Jintan Kk Preventive for anisakiasis
CN101558767A (en) * 2009-05-12 2009-10-21 江西山峰日化有限公司 Composition for driving and killing mosquitoes and preparation method thereof
CN102742572A (en) * 2012-07-27 2012-10-24 广州立白企业集团有限公司 Water-based electric heating liquid mosquito-repellent incense and preparation method thereof
CN103704279A (en) * 2013-12-13 2014-04-09 青岛安信医疗器械有限公司 Electric heated liquid mosquito-repellent incense

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04145076A (en) * 1990-10-05 1992-05-19 Morishita Jintan Kk Preventive for anisakiasis
CN101558767A (en) * 2009-05-12 2009-10-21 江西山峰日化有限公司 Composition for driving and killing mosquitoes and preparation method thereof
CN102742572A (en) * 2012-07-27 2012-10-24 广州立白企业集团有限公司 Water-based electric heating liquid mosquito-repellent incense and preparation method thereof
CN103704279A (en) * 2013-12-13 2014-04-09 青岛安信医疗器械有限公司 Electric heated liquid mosquito-repellent incense

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Effective date of registration: 20201225

Address after: 364101 No. 2, No. 2 Road, high tech Development Zone, Yongding, Longyan, Fujian

Patentee after: LONGYAN TENGHUI MACHINERY MANUFACTURE Co.,Ltd.

Address before: 311825 Zhejiang, Shaoxing, Zhuji, Zhuji City pat Tun Town, Keng West Village, No. 199

Patentee before: Xu Yinya