CN105707065B - Flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof - Google Patents
Flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof Download PDFInfo
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- CN105707065B CN105707065B CN201610058222.8A CN201610058222A CN105707065B CN 105707065 B CN105707065 B CN 105707065B CN 201610058222 A CN201610058222 A CN 201610058222A CN 105707065 B CN105707065 B CN 105707065B
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- essential oil
- flores aurantii
- mosquito
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses a kind of flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof.The flores aurantii essential oil vaporizer mosquito liquid is made up of the raw material of following weight parts：0.5 2.5 parts of fluorine chlorine ether chrysanthemum esters, 0.1 0.5 parts of flores aurantii essential oils, 50 60 parts of triethylene glycol butyl ether, 0.05 0.15 part of 4 cumene sodium sulfonate, 0.1 0.5 parts of synergist, 0.1 0.5 parts of antioxidant, 35 45 parts of water.The flores aurantii essential oil vaporizer mosquito liquid of the present invention, the pure and fresh fragrance of taste, effect is killed with stronger to mosquito, it is a kind of environment-friendly liquid mosquito-repellent incense, it has that drug effect is powerful, safety is non-combustible, volatilization is stable, moreover it is possible to reduces indoor organic volatile matter content, is the ideal chose of healthy life staying idle at home.
Description
Technical field：
The present invention relates to a kind of mosquito-repellent incense, and in particular to a kind of flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof.
Background technology：
Mosquito is a kind of worldwide sanitary insect pest, and its all one's life passes through ovum, larva, pupa, four periods of adult.Mosquito is main
Be to be that it is one of communication media of infectious disease.It was found that the disease of mosquitoes spread is up to as many as kind more than 80.In the whole world, about
There are 1,200,000 people to infect filariasis.The disease of the mosquito meeting infectious disease toxicity of most of kind, including yellow fever, dengue fever, Japan
Encephalitis, St. Louis encephalitis, polyarthirtis, Rift Valley fever (Rift Valley fever), contract elder brother Gen Yare and West Nile
Heat.On earth, then without which kind of animal than mosquito there is bigger harm to the mankind.The mosquito serious threat mankind as can be seen here
Health, these disgusting mosquitoes are only driven, epidemic infectious diseases could be controlled, human health could be ensured, improve people
Quality of life.
For many years, people develop and have used substantial amounts of hygienic insecticide product, for killing mosquitoes.Mosquito-repellent incense is most ancient
Natural drug mosquito repellent method.Just there is culicifuge incense rod made of Chinese medicine early in Southern Song Dynasty's period.In modern mosquito-repellent incense containing effectively into
It is pyrethrins to divide, and it plays the role of mosquito.After burning mosquito incense, pyrethrins in mosquito-repellent incense evaporates with smog,
Send out in the air of interior, make the neural paralysis of mosquito, then mosquito or it is born get killed, or four dissipate and escape, and are driven so as to play
The current mosquito-repellent incense production industry insecticidal active ingredient of effect of mosquito-killing, mainly cypermethrin, Prallethrin, allethrin, life
The pyrethrins such as thing chrysanthemum ester, the nerve that can benumb mosquito cause it dead.
Electric liquid device is actually mosquito liquid and the general name for making the electronic thermostatic heater that decoction uniformly volatilizees, preceding
Person claims mosquito-driving liquid, and the latter claims electric heater.In electric liquid device work, after electric heater accesses power supply, PTCR elements are just
Heating is started to warm up, afterwards by the PTCR elements temp regulating function of itself, its temperature is remained certain value.PTCR members
Heat caused by part is volatilized core by radiant heat transfer to decoction, is drawn to from medicinal liquid bottle decoction by core capillarity of volatilizing
Plug upper end, decoction is improved under heat radiation heating and be vaporized speed, after the insecticidal active ingredient in space reaches finite concentration,
Just mosquito is produced and driven, so as to knock down and kill mosquito.Electric liquid device because its using it is light, smokelessly without dust, drug effect
The features such as stabilization, high-efficiency low-toxicity, welcome by consumer.
Existing electric liquid device formula system is with alkane solvent, pyrethroid, antioxidant and essence etc. for group
Point, form homogeneous system by mixing, stirring solvent.Alkane solvent is due to being that rectifying etc. is formed, and its carbochain is distributed more widely, especially
It is that wherein low-carbon paraffin easily forms organic volatile i.e. VOC, in the daily life staying idle at home of consumer, electric heating liquid mosquito can be passed through
Fragrant heating brings certain influence using the pollution that domestic environment is caused with volatilization naturally to consumer health.
The invention provides a kind of flores aurantii essential oil vaporizer mosquito liquid, is a kind of vaporizer mosquito liquid of safety and environmental protection.
The content of the invention：
For deficiencies of the prior art, one of the technical problems to be solved by the invention are to provide a kind of flores aurantii
Essential oil vaporizer mosquito liquid.
One of technical problems to be solved by the invention are to provide the preparation method of above-mentioned flores aurantii essential oil vaporizer mosquito liquid.
The technical problem of the present invention, is achieved by following technical proposals：
A kind of flores aurantii essential oil vaporizer mosquito liquid, is made up of the raw material of following weight parts：0.5-2.5 part fluorine chlorine ether chrysanthemums ester, 0.1-
0.5 part of flores aurantii essential oil, 50-60 part triethylene glycols butyl ether, 0.05-0.15 part 4- cumene sodium sulfonates, 0.1-0.5 parts synergist,
0.1-0.5 parts antioxidant, 35-45 part water.
Preferably, described synergist is Ligustilide and/or isoalantolactone.
It is highly preferred that described synergist is made up of 40-60wt% Ligustilides and 40-60wt% isoalantolactones.
Preferably, described antioxidant is 2,4- dimethyl -6- tert-butyl phenols and/or 2,6- di-t-butyl to benzene two
Phenol.
It is highly preferred that described antioxidant is by 40-60wt%2,4- dimethyl -6- tert-butyl phenols and 40-60wt%2,
6- di-tert-butyl hydroquinones form.
Present invention also offers the preparation method of above-mentioned flores aurantii essential oil vaporizer mosquito liquid, by fluorine chlorine ether chrysanthemum ester, flores aurantii essential oil, three
Butyl glycol ether, synergist, antioxidant are well mixed, and are added 4- cumene sodium sulfonates and are well mixed, are eventually adding water mixing
Uniformly.
Specifically, in the present invention：
Fluorine chlorine ether chrysanthemum ester, No. CAS：352271-52-4.
Flores aurantii essential oil, i.e. neroli oil, No. CAS：8016-38-4.
Triethylene glycol butyl ether, No. CAS：143-22-6.
4- cumene sodium sulfonates, No. CAS：32073-22-6.
Ligustilide, No. CAS：4431-01-0.
Isoalantolactone, No. CAS：470-17-7.
2,4- dimethyl -6- tert-butyl phenols, No. CAS：1879-09-0.
2,6- di-tert-butyl hydroquinones, No. CAS：2444-28-2.
The flores aurantii essential oil vaporizer mosquito liquid of the present invention, the pure and fresh fragrance of taste, effect is killed with stronger to mosquito, is a kind of
Environment-friendly liquid mosquito-repellent incense, it has, and drug effect is powerful, safety is non-combustible, volatilization is stable, moreover it is possible to indoor organic volatile matter content is reduced,
It is the ideal chose of healthy life staying idle at home.
Embodiment：
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, is not limited the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.It is every of the invention without departing from the present invention program content, foundation
Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Flores aurantii essential oil vaporizer mosquito liquid raw material (parts by weight)：1.2 parts of fluorine chlorine ether chrysanthemum esters, 0.2 part of flores aurantii essential oil, 55 part of three second two
Alcohol butyl ether, 0.1 part of 4- cumene sodium sulfonate, 0.3 part of synergist, 0.3 part of antioxidant, 40 parts of deionized waters.
Described synergist is obtained by 50wt% Ligustilides and 50wt% isoalantolactones are well mixed.
Described antioxidant is by 50wt%2,4- dimethyl -6- tert-butyl phenols and 50wt%2,6- di-t-butyls to benzene two
Phenol is well mixed to be obtained.
The preparation method of flores aurantii essential oil vaporizer mosquito liquid：
Fluorine chlorine ether chrysanthemum ester, flores aurantii essential oil, triethylene glycol butyl ether, synergist, antioxidant are mixed and stirred for uniformly, adding
4- cumene sodium sulfonates be mixed and stirred for uniformly, be eventually adding deionized water and be mixed and stirred for uniformly.Obtain the flores aurantii of embodiment 1
Essential oil vaporizer mosquito liquid.
Embodiment 2
It is substantially the same manner as Example 1, differ only in：Described synergist is only Ligustilide.Obtain embodiment 2
Flores aurantii essential oil vaporizer mosquito liquid.
Embodiment 3
It is substantially the same manner as Example 1, differ only in：Described synergist is only isoalantolactone.Implemented
The flores aurantii essential oil vaporizer mosquito liquid of example 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in：Described antioxidant is only 2,4- dimethyl -6- tert-butyl benzenes
Phenol.Obtain the flores aurantii essential oil vaporizer mosquito liquid of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in：Described antioxidant is only 2,6- di-tert-butyl hydroquinones.
Obtain the flores aurantii essential oil vaporizer mosquito liquid of embodiment 5.
Test case 1
Indoor harmacological effect test is carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid, defended using GB18418-2009 family expenses
Raw desinsection articles for use electric liquid device standard, is tested.In the standard, KT50 values (boxing method)≤10 minute can be judged to
Qualified, the time is shorter, and explanation is better to mosquito driving and killing effect, and test data is shown in Table 1.
Table 1：Vaporizer mosquito liquid indoor harmacological effect table (boxing method)
| KT50 values | |
| Embodiment 1 | 4 points 12 seconds |
| Embodiment 2 | 6 points 32 seconds |
| Embodiment 3 | 6 points 46 seconds |
| Embodiment 4 | 5 points 23 seconds |
| Embodiment 5 | 5 points 39 seconds |
Comparing embodiment 1-3, embodiment 1 (Ligustilide, isoalantolactone compounding) mosquito driving and killing effect, hence it is evident that be better than
Embodiment 2-3 (single raw material in Ligustilide, isoalantolactone)；Comparing embodiment 1 and embodiment 4-5, embodiment 1 (2,
4- dimethyl -6- tert-butyl phenols, 2,6- di-tert-butyl hydroquinones compounding) mosquito driving and killing effect, hence it is evident that better than embodiment 4-5
(single raw material in 2,4 dimethyl 6 tert butyl phenol, 2,6- di-tert-butyl hydroquinones).
Test case 2
Toxotest is carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid, with reference to health ministry《Management of occupational acute
Learn thing Poisoning disease in the blood system diagnostic criteria》And《Chinese medicine, technological guidance's principle of natural drug immunotoxicity research》Mark
Standard, formulate test case of the present invention.
Test species：Two young age small white mouses.
Experimental method：
(1) experiment condition：Laboratory temperature (27 ± 2) DEG C
(2) experimental provision：In two 25 square metres of mutually synthermal laboratories, each one size same size of placement
80 × 80 × 80cm is fine and closely woven ventilative netted to be shrouded.
(3) experimental procedure：By two young age small white mouses be separately respectively put in two laboratories it is netted shroud in, and be divided into pair
According to group and mosquito-repellent incense group of the present invention is smoked, gives respectively and does not smoke mosquito-repellent incense of the present invention and smoke mosquito-repellent incense of the present invention, measure young age small white mouse body weight,
The biochemical index of observation hematology, changes in histopathology and stopping smoke recovery situation after mosquito-repellent incense of the present invention etc..Place this hair
During bright mosquito-repellent incense will be arranged on it is netted shroud it is interior from the centimeters of bottom 30.Dosage：Electrical heating mosquito-repellent incense, keeps for a long time making for 24 hours
With.Time：Continuous use one month, observation control group and the young age small white mouse for smoking mosquito-repellent incense group of the present invention, long-term use of present invention
Toxicity and side effect of the mosquito-repellent incense to young age small white mouse.Cleaning：Clean once within two days in shrouding.
As a result：After two young age small white mouse blood tests, every biochemical indicator is normal, shows mosquito-repellent incense of the present invention to children
Age small white mouse has no toxic side effect, and when only more than 24 hours, indoor mosquito-repellent incense smog is too dense, need to open a window ventilation 10-15 minutes, blood drawing
Do not fed to two young age small white mouses within first 8 hours.
Conclusion：Long-term use of mosquito-repellent incense of the present invention is to young age small white mouse without any toxicity.
Test case 3
Acute oral toxicity test, 5 minutes activities in rats after contamination are carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid
Increase, continues 2 minutes or so, and activity switchs to normally, and diet is normal, and the observation period is more than 5000 mgs/kg without death, LD50,
Belong to actual nontoxic.
Test case 4
Acute inhalation toxicity experiment, rat diet activity after contamination are carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid
No abnormality seen, observation period are more than 10 grams/cubic metre without death, LD50, belong to actual nontoxic.
Test case 5
Skin patch test, experimental group erythema and oedema shape are carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid
It is 0 into scoring sum, explanation has no stimulation of the skin.
Test case 6
Eye irritant test, the acute Eye irritation integration number of experimental group are carried out to embodiment 1-5 flores aurantii essential oil vaporizer mosquito liquid
For 0, illustrate to have no stimulation to mucous membrane.
Claims (4)
1. a kind of flores aurantii essential oil vaporizer mosquito liquid, it is characterised in that be made up of the raw material of following weight parts：0.5-2.5 part fluorine chlorine ethers
Chrysanthemum ester, 0.1-0.5 part flores aurantiis essential oil, 50-60 part triethylene glycols butyl ether, 0.05-0.15 part 4- cumene sodium sulfonates, 0.1-0.5
Part synergist, 0.1-0.5 parts antioxidant, 35-45 part water；Described synergist is by 40-60wt% Ligustilides and 40-60wt%
Isoalantolactone forms.
2. flores aurantii essential oil vaporizer mosquito liquid as claimed in claim 1, it is characterised in that：Described antioxidant be 2,4- dimethyl-
6- tert-butyl phenols and/or 2,6- di-tert-butyl hydroquinones.
3. flores aurantii essential oil vaporizer mosquito liquid as claimed in claim 2, it is characterised in that：Described antioxidant by 40-60wt%2,
4- dimethyl -6- tert-butyl phenols and 40-60wt%2,6- di-tert-butyl hydroquinones composition.
4. the preparation method of flores aurantii essential oil vaporizer mosquito liquid as any one of claim 1-3, it is characterised in that：By fluorine chlorine ether
Chrysanthemum ester, flores aurantii essential oil, triethylene glycol butyl ether, synergist, antioxidant are well mixed, and it is equal to add the mixing of 4- cumene sodium sulfonates
It is even, be eventually adding water and be well mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610058222.8A CN105707065B (en) | 2016-01-28 | 2016-01-28 | Flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610058222.8A CN105707065B (en) | 2016-01-28 | 2016-01-28 | Flores aurantii essential oil vaporizer mosquito liquid and preparation method thereof |
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| CN105707065A CN105707065A (en) | 2016-06-29 |
| CN105707065B true CN105707065B (en) | 2018-03-30 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1439265A (en) * | 2003-03-27 | 2003-09-03 | 李鹏飞 | Electric heating mosquito-repellent incense and preparation thereof |
| CN1496984A (en) * | 2002-10-18 | 2004-05-19 | 谢秀琼 | Application of 3-hydroxyphenyl phthale compound in preparing culicifuge |
| CN101558767A (en) * | 2009-05-12 | 2009-10-21 | 江西山峰日化有限公司 | Composition for driving and killing mosquitoes and preparation method thereof |
| CN102742572A (en) * | 2012-07-27 | 2012-10-24 | 广州立白企业集团有限公司 | Water-based electric heating liquid mosquito-repellent incense and preparation method thereof |
| CN103814965A (en) * | 2014-02-28 | 2014-05-28 | 曹以鉴 | Environmentally-friendly electrothermal liquid mosquito-repellent incense |
| CN103931681A (en) * | 2014-04-08 | 2014-07-23 | 许银亚 | Orange blossom liquid mosquito-repellent incense |
| CN104585257A (en) * | 2013-10-30 | 2015-05-06 | 烟台纳克环保科技有限公司 | Non-toxic electrothermal mosquito-repellent incense liquid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04145076A (en) * | 1990-10-05 | 1992-05-19 | Morishita Jintan Kk | Preventive for anisakiasis |
-
2016
- 2016-01-28 CN CN201610058222.8A patent/CN105707065B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1496984A (en) * | 2002-10-18 | 2004-05-19 | 谢秀琼 | Application of 3-hydroxyphenyl phthale compound in preparing culicifuge |
| CN1439265A (en) * | 2003-03-27 | 2003-09-03 | 李鹏飞 | Electric heating mosquito-repellent incense and preparation thereof |
| CN101558767A (en) * | 2009-05-12 | 2009-10-21 | 江西山峰日化有限公司 | Composition for driving and killing mosquitoes and preparation method thereof |
| CN102742572A (en) * | 2012-07-27 | 2012-10-24 | 广州立白企业集团有限公司 | Water-based electric heating liquid mosquito-repellent incense and preparation method thereof |
| CN104585257A (en) * | 2013-10-30 | 2015-05-06 | 烟台纳克环保科技有限公司 | Non-toxic electrothermal mosquito-repellent incense liquid |
| CN103814965A (en) * | 2014-02-28 | 2014-05-28 | 曹以鉴 | Environmentally-friendly electrothermal liquid mosquito-repellent incense |
| CN103931681A (en) * | 2014-04-08 | 2014-07-23 | 许银亚 | Orange blossom liquid mosquito-repellent incense |
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Effective date of registration: 20201217 Address after: 364101 No. 2, No. 2 Road, high tech Development Zone, Yongding, Longyan, Fujian Patentee after: LONGYAN TENGHUI MACHINERY MANUFACTURE Co.,Ltd. Address before: 311825 Zhejiang, Shaoxing, Zhuji, Zhuji City pat Tun Town, Keng West Village, No. 199 Patentee before: Xu Yinya |
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