CN105695134A - 一种具有防雾功能的玻璃清洗剂 - Google Patents
一种具有防雾功能的玻璃清洗剂 Download PDFInfo
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- 239000011521 glass Substances 0.000 title claims abstract description 61
- 239000012459 cleaning agent Substances 0.000 title abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 29
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 29
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 claims abstract description 8
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 claims abstract description 8
- 239000000015 trinitrotoluene Substances 0.000 claims abstract description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 34
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000003240 coconut oil Substances 0.000 claims description 10
- 235000019864 coconut oil Nutrition 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 7
- 235000013599 spices Nutrition 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 229910021645 metal ion Inorganic materials 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- 239000005639 Lauric acid Substances 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000003599 detergent Substances 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 239000005304 optical glass Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 229920005479 Lucite® Polymers 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 208000011580 syndromic disease Diseases 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
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- C11D3/2017—Monohydric alcohols branched
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
- C11D3/245—Organic compounds containing halogen containing fluorine
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
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Abstract
本发明公开了一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：辛基酚聚氧乙烯醚12～20％、椰油酸聚氧乙烯醚2～5％、壬基酚聚氧乙烯醚0.3～0.8％、二氯四氟乙烷2～3％、三硝基甲苯0.1～0.3％、非离子表面活性剂0.1～0.4％、防雾剂20～30％、助剂0.1～0.2％，余量为去离子水。本发明提供的玻璃清洗剂为不含金属离子的玻璃清洗剂，具有良好的清洗效果，去污能力可达98％以上，而且不损伤精密玻璃部件；所述玻璃清洗剂具有长效防雾功能，擦后干净明亮，且不必水洗，避免玻璃制品在有温差的情况下与水汽产生雾膜，为人们的日常生活带来方便。
Description
技术领域
本发明涉及玻璃清洗/清洁剂领域，具体涉及一种具有防雾功能的玻璃清洗剂。
背景技术
玻璃清洗剂为主要适用于有机玻璃、无机玻璃、光学玻璃、树脂玻璃等各种玻璃用品和光学镜片、眼镜镜片、泳镜镜片、摄影器材镜头、高档精密玻璃仪器的高效清洁制剂。
在现实生活中，人们经常使用自来水或洗洁精来代替玻璃清洗剂用于玻璃的清洁，因为人们印象中玻璃为高耐腐蚀性制品，但事实上，当玻璃在大气和弱酸等介质中使用一段时间后，用肉眼即可观察到玻璃表面粗糙、污染和斑点腐蚀等迹象。长期使用自来水或劣质清洗剂将导致清洗效果差，也可导致精密玻璃部件腐蚀损坏、与玻璃连接的零配金属部件腐蚀和污损等情况的产生。
在日常生活中，玻璃在遇冷时产生的雾膜给我们造成了不少的麻烦。譬如在冬季，人们从温暖的室内走出室外时，眼镜立刻结出一层雾膜，进而模糊了视线，这种现象还经常出现在镜子、数码相机、望远镜的镜头等玻璃制品上；而在冬季或雨季，汽车车窗玻璃也会起雾，尤其是车前窗挡风玻璃和后视镜起雾时，严重影响驾驶员的视线，妨碍驾驶安全，如果长期打开空调来驱雾，效果并不明显，加上长期使用空调除湿还会增加不少油耗，司机为了清除前窗玻璃的雾而经常在驾驶过程中使用毛巾擦拭，存在极大的安全驾驶隐患。
发明内容
针对现有技术不足，本发明提供了一种具有防雾功能的玻璃清洗剂，在取得良好清洁效果的同时，使玻璃具有长效防雾功能。
本发明解决上述技术问题采用的技术方案为：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚12～20％、椰油酸聚氧乙烯醚2～5％、壬基酚聚氧乙烯醚0.3～0.8％、二氯四氟乙烷2～3％、三硝基甲苯0.1～0.3％、非离子表面活性剂0.1～0.4％、防雾剂20～30％、助剂0.1～0.2％，余量为去离子水。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:1～2:5～10:20～30。
进一步地，所述助剂为染料、香料中的至少一种。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
一种具有防雾功能的玻璃清洗剂的制备方法，包括以下步骤：
将聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇溶于部分去离子水中，配置防雾剂溶液；
将辛基酚聚氧乙烯醚、椰油酸聚氧乙烯醚及壬基酚聚氧乙烯醚溶于剩余的去离子水中，加入步骤1所得防雾剂溶液及其余原料，混合均匀；
调节步骤2所得溶液的PH至7.0～9.0，除泡、包装即得本发明的玻璃清洗剂。
与现有技术相比，本发明提供的玻璃清洗剂为不含金属离子的玻璃清洗剂，清洗效果好，很容易除去玻璃上的各种污垢，包括灰尘、各种食用油、虫胶等，而且不损伤精密玻璃部件；所述玻璃清洗剂呈弱碱性，对玻璃制品清洗以后，无任何残物，去污能力可达98％以上；所述玻璃清洗剂具有长效防雾功能，擦后干净明亮，且不必水洗，避免玻璃制品在有温差的情况下与水汽产生雾膜，为人们的日常生活带来方便。
具体实施方式
下面结合具体实施例对本发明做进一步的说明。
实施例1：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚16％、椰油酸聚氧乙烯醚4％、壬基酚聚氧乙烯醚0.5％、二氯四氟乙烷2％、三硝基甲苯0.2％、非离子表面活性剂0.2％、防雾剂25％、助剂0.1％，去离子水52.0％；所述非离子表面活性剂为除壬基酚聚氧乙烯醚以外的洗涤剂领域常用的表面活性剂。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:1:8:25。
进一步地，所述助剂为染料和香料的复合物，所述染料和香料为洗涤剂领域常用添加剂。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
一种具有防雾功能的玻璃清洗剂的制备方法，包括以下步骤：
将聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇溶于部分去离子水中，配置防雾剂溶液；
将辛基酚聚氧乙烯醚、椰油酸聚氧乙烯醚及壬基酚聚氧乙烯醚溶于剩余的去离子水中，加入步骤1所得防雾剂溶液及其余原料，混合均匀；
采用氨水调节步骤2所得溶液的PH至7.0～9.0，经除泡、包装后即得本发明的玻璃清洗剂。
以下实施例中所述的一种具有防雾功能的玻璃清洗剂的制备方法，其具体步骤同本实施例。
实施例2：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚20％、椰油酸聚氧乙烯醚2％、壬基酚聚氧乙烯醚0.8％、二氯四氟乙烷2％、三硝基甲苯0.3％、非离子表面活性剂0.1％、防雾剂30％、助剂0.1％，去离子水44.7％。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:2:5:30。
进一步地，所述助剂为香料。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
实施例3：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚12％、椰油酸聚氧乙烯醚5％、壬基酚聚氧乙烯醚0.3％、二氯四氟乙烷2％、三硝基甲苯0.3％、非离子表面活性剂0.4％、防雾剂20％、助剂0.2％，去离子水59.8％。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为2:3:15:43。
进一步地，所述助剂为染料和香料的复合物。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
实施例4：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚17％、椰油酸聚氧乙烯醚4％、壬基酚聚氧乙烯醚0.7％、二氯四氟乙烷2％、三硝基甲苯0.2％、非离子表面活性剂0.2％、防雾剂22％、助剂0.1％，去离子水53.8％。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:1.3:7:29。
进一步地，所述助剂为染料。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
实施例5：一种具有防雾功能的玻璃清洗剂，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚16％、椰油酸聚氧乙烯醚5％、壬基酚聚氧乙烯醚0.4％、二氯四氟乙烷2％、三硝基甲苯0.2％、非离子表面活性剂0.4％、防雾剂23％、助剂0.1％，去离子水52.9％。
进一步地，所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:1:8:25。
进一步地，所述助剂为染料和香料的复合物。
进一步地，所述玻璃清洗剂的PH7.0～9.0。
为了观察本发明产品的效果，对去污力、防雾性能进行实验测试，去污力采用CAS144标准，防雾性能按照标准的视图测试方法进行测试，将标准视图表悬挂好，并将视图表上各标志行从最低行向上依次命名等级为10、9、8……2、1，具体的，取实验玻璃片采用本发明的产品进行表面清洗，室温下晾干后置于冰箱内，5min后取出于室温环境中，置于眼前并站立于合适的位置，观察透过此玻璃能看到的标准视图表的最低行，并以该行的等级确定为该产品的防雾等级。以市面常见的玻璃洗涤剂(对照例1)和防雾剂(对照例2)作为对照例。具体测试结果如下表所示：
*防雾次数为截止到防雾等级降低到6时的次数。
Claims (5)
1.一种具有防雾功能的玻璃清洗剂，其特征在于，包括以下重量百分比的原料：
辛基酚聚氧乙烯醚12～20％、椰油酸聚氧乙烯醚2～5％、壬基酚聚氧乙烯醚0.3～0.8％、二氯四氟乙烷2～3％、三硝基甲苯0.1～0.3％、非离子表面活性剂0.1～0.4％、防雾剂20～30％、助剂0.1～0.2％，余量为去离子水。
2.根据权利要求1所述的一种具有防雾功能的玻璃清洗剂，其特征在于：所述防雾剂为聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的复合物，所述聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇的质量比为1:1～2:5～10:20～30。
3.根据权利要求1所述的一种具有防雾功能的玻璃清洗剂，其特征在于：所述助剂为染料、香料中的至少一种。
4.根据权利要求1所述的一种具有防雾功能的玻璃清洗剂，其特征在于：所述玻璃清洗剂的PH7.0～9.0。
5.一种具有防雾功能的玻璃清洗剂的制备方法，其特征在于：包括以下步骤：
(1)将聚乙烯比咯烷酮、脂肪醇聚氧乙烯醚、丙醇、异丙醇溶于部分去离子水中，配置防雾剂溶液；
(2)将辛基酚聚氧乙烯醚、椰油酸聚氧乙烯醚及壬基酚聚氧乙烯醚溶于剩余的去离子水中，加入步骤1所得防雾剂溶液及其余原料，混合均匀；
(3)调节步骤(2)所得溶液的PH至7.0～9.0，除泡、包装即得本发明的玻璃清洗剂。
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