CN105670792A - Preparing method and application of cigarette filter tip expansion granular material - Google Patents
Preparing method and application of cigarette filter tip expansion granular material Download PDFInfo
- Publication number
- CN105670792A CN105670792A CN201610075661.XA CN201610075661A CN105670792A CN 105670792 A CN105670792 A CN 105670792A CN 201610075661 A CN201610075661 A CN 201610075661A CN 105670792 A CN105670792 A CN 105670792A
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- Prior art keywords
- reactor
- bead material
- expanded bead
- cigarette
- granular material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
Abstract
The invention discloses a preparing method and application of a cigarette filter tip expansion granular material. The solid granular material is placed into a reactor to be heated in a closed mode, when pressure in the reactor reaches a certain value, heating continues to be carried out, then an opening of the reactor is opened instantly, the solid granular material is expanded rapidly and burst instantly to obtain burst particles; then the particles are smashed or pelletized according to the needed particle size, so that the expansion granular material is obtained. When the expansion granular material is applied, the expansion granular material is added into a filter stick conventionally, the actual addition amount is subjected to the cigarette sensory evaluation optimum, and generally, the addition amount for each cigarette is 5-30 mg. Holes are formed in the material, fragrance ingredients can be released effectively, the raw materials are utilized to the maximum degree, the quantity of the adopted raw materials is saved, and the production cost is saved; meanwhile, smoke ingredients can be adsorbed, and the effect of reducing some postponing ingredients is achieved; the selection range of perfuming materials is widened.
Description
Technical field
The present invention relates to technical field of cigarettes, specifically the preparation method of a kind of cigarette filter expanded bead material and application.
Background technology
Having made since first cigarette filter of filtering material come out with Cotton Gossypii from nineteen thirty, filter plug just becomes a pith in Cigarette design. Along with the progress of Nicotiana tabacum L. science and technology and being continually changing of consumer demand, cigarette filter plays increasingly key player in cigarette. The effect of cigarette filter has been transitioned into carrying brand culture from simple filtration flue gas effect, and the effect of transmission product individuality comes up. Particularly in high-grade cigarette, it had both embodied image product, individual character, has enriched again high quality, has improved the price grade of product.
In the last few years, cigarette filter occurs in that deeper of change, develops from common single cellulose acetate filter, the filter tip made to polynary filter tip, multiple material and Flavoring filter direction. These novel filter plug obtain the favor of cigarette manufacturer and consumer just gradually, especially the application in Medicated cigarette of the natural plants granular materials, cause the extensive concern of each big cigarette manufacturer.
The granular materials being applied to cigarette filter at present is a lot, and such as kieselguhr, activated carbon, silica gel etc., they have special configuration of surface and many cavity structures, and cigarette smoke creates efficient selective adsorption capacity, and its loose structure mainly plays adsorption. But current used filter tip perfuming granular materials is pore-free material mostly, it is possible to smoke contacts simply on surface, the fragrance component of internal layer is difficult to release. The fragrance component of perfuming granule itself is mostly natural component, and therefore that the change of flue gas is more fixing, selectable material is less.
If filter tip granular materials can carry out certain processing transformation, intragranular fragrance component is enable more effectively to discharge;The absorption of part smoke components can be realized because of loose structure again, be beneficial to the efficient application of natural perfuming granule.
Summary of the invention
It is difficult to discharge internal fragrance for solving existing perfuming granule, cause the problems such as perfuming granule selectable range restriction, the present invention provides preparation method and the application of a kind of cigarette filter expanded bead material, undertaken common native granular material expanding pore-creating and fragrance restructuring, form new additives of filter tip granular materials.
The present invention is realized by following technical proposal: the preparation method of a kind of cigarette filter expanded bead material, through following each step:
(1) it is placed in reactor by solid particulate materials airtight heating, when the pressure of inside reactor reaches 1.5～3 atmospheric pressure, then continuous heating 5～15 minutes, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain; Heat owing to solid particulate materials is placed in closed reactor so that solid particulate materials is in the state of High Temperature High Pressure, and the temperature in reactor constantly raises, and in reactor, the pressure of gas also constantly increases; When the lid of reactor is opened, solid particulate materials is suddenly released at normal temperatures and pressures, gas in reactor expands rapidly, pressure quickly reduces, pressure difference inside and outside solid particulate materials is made to become big, cause that solid particulate materials inner high voltage steam also sharply expands, the instantaneous solid particulate materials that pops, explosion grain, simultaneously structure within solid particulate materials and character will change, and make the composition in solid particulate materials discharge, or each composition reacts mutually, realize fragrance component restructuring, complete the pore-creating of solid particulate materials;
(2) step (1) gained is expanded grain to be undertaken pulverizing or pelletize by desired particle size, namely obtain expanded bead material.
The solid particulate materials of described step (1) is natural plants granular materials or the composite of load essence and flavoring agent.
After solid particulate materials in reactor is usually heated by the pressure of described step (1) inside reactor, the high pressure produced due to the decomposition of solid particulate materials internal component, spilling, can pass through further to add composition (such as water) of easily vaporizing, the high pressure produced in heating process, or directly filling into gas in reactor produces high pressure.
The described gas that fills into is nitrogen.
Desired particle size in described step (2) is 30～60 orders.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the amount of being actually added into is as the criterion with Medicated cigarette sensory evaluation optimum, and generally the addition of every Medicated cigarette is 5～30mg.
Advantage that the present invention possesses and effect: common native granular material is carried out expanding pore-creating and fragrance restructuring by the present invention, forms new additives of filter tip granular materials. Material internal and outside flavor component are recombinated by this preparation method, make the fragrance component of material produce different changes, have expanded the range of choice of existing perfuming material; Material is carried out internal pore-creating, has enable flavor component effectively to discharge, farthest utilized raw material the consumption that economizes in raw materials very much, saved production cost. Perfuming material is as porous adsorbing material simultaneously, is adding to after in filter tip, it is possible to achieve the absorption of partial fume composition, is reducing the effect of some extension composition; Natural scents composition in perfuming material is achieved a degree of processed by the method, has widened the range of choice of perfuming material. This preparation method controls to obtain multiple different granular materials according to different material choice and temperature, and easy to operation.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described, but is not limited to material and the condition lifted.
Embodiment 1
(1) niblet that feed liquid soaked (sucrose solution of corn distiller's dried grain 10wt% soaks 6h) is placed in reactor airtight heating, the high pressure that inside reactor produces due to the decomposition of niblet internal component, spilling, when inside reactor temperature reach 250 DEG C, pressure reach 2 atmospheric pressure time, continuous heating 10 minutes again, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained expansion grain being crushed to granularity is 35 orders, namely obtains expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 10mg.
The final cigarette product prepared, in its flue gas, Semen Maydis is aromatic strongly fragrant, and organoleptic quality is obviously improved, and tar reduces about 0.2mg.
Comparative example: it is 35 orders that the niblet (sucrose solution of corn distiller's dried grain 10wt% soaks 6h) above-mentioned feed liquid soaked directly is crushed to granularity, adds routinely to filter stick, and the addition of every Medicated cigarette is 10mg. Gained cigarette product, in its flue gas, Semen Maydis perfume (or spice) sense organ is difficult to discover, and organoleptic quality is not improved, and tar reduces about 0.07mg.
Embodiment 2
(1) dry Fructus Crataegi is directly ground to Fructus Crataegi grain, be dipped into again containing sucrose 5wt%, Tremella extract 3wt% aqueous solution in, soak time is 1h, Fructus Crataegi grain feed liquid soaked is placed in reactor airtight heating, the high pressure that inside reactor produces due to Fructus Crataegi intragranular portion ingredient breakdown, spilling, when the temperature of inside reactor reach 300 DEG C, pressure reach 3 atmospheric pressure time, continuous heating 5 minutes again, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 40 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 5mg.
The final cigarette product prepared, its flue gas coordinates sense and moisture feeling strengthens, and organoleptic quality is obviously improved, and tar reduces about 0.1mg.
Comparative example: it is 35 orders that the Fructus Crataegi grain above-mentioned feed liquid soaked directly is crushed to granularity, adds routinely to filter stick, and the addition of every Medicated cigarette is 5mg. Gained cigarette product, in its flue gas, flue gas is coordinated to feel substantially unchanged with moisture feeling, and perfume quantity reduces, and organoleptic quality is deteriorated, and tar reduces about 0.05mg.
Embodiment 3
(1) baking or the cigarette strain after drying directly are crushed to clastic, with the aqueous solution soaking 30min containing 5wt% Fructus Tamarindi Indicae extract, cigarette strain chip feed liquid soaked is placed in reactor airtight heating, nitrogen is filled in reactor, when the temperature of inside reactor reach 400 DEG C, pressure reach 1.5 atmospheric pressure time, then continuous heating 15 minutes, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 50 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 20mg.
The final cigarette product prepared, its flue gas coordinates sense and moisture feeling strengthens, and organoleptic quality is obviously improved, and tar reduces about 0.4mg.
Comparative example: it is 35 orders that the cigarette strain chip above-mentioned feed liquid soaked directly is crushed to granularity, adds routinely to filter stick, and the addition of every Medicated cigarette is 20mg. Gained cigarette product, in its flue gas, flue gas coordinates sense and moisture feeling without significant change, and flue gas is roughening, and astringent, and organoleptic quality is decreased obviously, and tar reduces about 0.09mg.
Embodiment 4
(1) the Herba Cymbopogonis Citrari grass blade dried is crushed to graininess, put in the suspension containing Herba Menthae Haplocalycis and Folium Camelliae sinensis powder, the total mass concentration of suspension is 10%, wherein the mass ratio of Herba Menthae Haplocalycis and Folium Camelliae sinensis powder is 1:1, not have Herba Cymbopogonis Citrari grass blade to be advisable, take out dry after stirring 30min, by load the Herba Cymbopogonis Citrari grass blade granule of Herba Menthae Haplocalycis and Folium Camelliae sinensis powder add water (composition of easily vaporizing) infiltrate, it is placed in reactor airtight heating, nitrogen is filled in reactor, when the temperature of inside reactor reaches 200 DEG C, when pressure reaches 1.5 atmospheric pressure, continuous heating 5 minutes again, then moment opens the outlet of reactor, solid particulate materials is made sharply to expand, instantaneous pop, obtain explosion grain,
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 60 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 20mg.
The final cigarette product prepared, the refrigerant sense of its flue gas and moisture feeling strengthen, and organoleptic quality is obviously improved, and tar reduces about 0.1mg.
Comparative example: above-mentioned Herba Cymbopogonis Citrari grass blade granule is directly crushed to granularity is 35 orders, adds routinely to filter stick, and the addition of every Medicated cigarette is 20mg. Gained cigarette product, in its flue gas, the refrigerant sense of flue gas and moisture feeling slightly strengthen, but inconspicuous, and organoleptic quality change is little, and tar reduces about 0.05mg.
Embodiment 5
(1) it is placed in reactor airtight heating by soaking the Lignum Aquilariae Resinatum chip after 0.5h in water, nitrogen is filled in reactor, when the temperature of inside reactor reach 400 DEG C, pressure reach 3 atmospheric pressure time, continuous heating 10 minutes again, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 35 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 30mg.
The final cigarette product prepared, its flue gas Lignum Aquilariae Resinatum taste highlights, and organoleptic quality is obviously improved, and tar reduces about 0.1mg.
Comparative example: it is 35 orders that Lignum Aquilariae Resinatum chip is directly crushed to granularity, adds routinely to filter stick, and the addition of every Medicated cigarette is 30mg. Gained cigarette product, in its flue gas, flue gas Lignum Aquilariae Resinatum taste is inconspicuous, and flue gas equilibrium sense is destroyed, and zest rises, and organoleptic quality declines, and tar reduces about 0.05mg.
Embodiment 6
(1) it is placed in reactor by fresh bamboo chip airtight heating, the high pressure produced due to the decomposition of bamboo chip internal component, spilling, when the temperature of inside reactor reach 100 DEG C, pressure reach 1.5 atmospheric pressure time, continuous heating 5 minutes again, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 35 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 20mg.
The final cigarette product prepared, its flue gas bamboo fragrant highlights, and organoleptic quality is obviously improved, and tar reduces about 0.1mg.
Comparative example: be 35 orders by the fresh direct pelletize of bamboo chip to granularity, adds routinely to filter stick, and the addition of every Medicated cigarette is 20mg. Gained cigarette product, in its flue gas, bamboo fragrant is difficult to discover substantially, and organoleptic quality is without significant change, and tar reduces about 0.05mg.
Embodiment 7
(1) it is placed in reactor by the arbitrary proportion mixture of fructus zizaniae caduciflorae and Oryza glutinosa airtight heating, owing to the mixture internal component of fructus zizaniae caduciflorae and Oryza glutinosa decomposes, overflows and the high pressure that produces, when the temperature of inside reactor reach 150 DEG C, pressure reach 1.5 atmospheric pressure time, continuous heating 5 minutes again, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain pulverizing or pelletize to granularity is 30 orders, namely obtain expanded bead material.
Gained expanded bead material is in use, be added routinely to filter stick by this expanded bead material, and the addition of every Medicated cigarette is 30mg.
The final cigarette product prepared, its flue gas paddy perfume (or spice) highlights, and organoleptic quality is obviously improved, and tar reduces about 0.1mg.
Comparative example: fructus zizaniae caduciflorae and Oryza glutinosa are directly crushed to granularity is 35 orders, adds routinely to filter stick, and the addition of every Medicated cigarette is 30mg. Gained cigarette product, is difficult in its flue gas experience paddy perfume (or spice) fragrance, and organoleptic quality is substantially without changing, and tar reduces about 0.05mg.
Reactor described in above-described embodiment is conventional equipment, is the resistance to compression canister with gland, and gland is arranged on the nozzle of resistance to compression canister.
Claims (6)
1. the preparation method of a cigarette filter expanded bead material, it is characterised in that through following each step:
(1) it is placed in reactor by solid particulate materials airtight heating, when the pressure of inside reactor reaches 1.5～3 atmospheric pressure, then continuous heating 5～15 minutes, then moment opens the outlet of reactor, make solid particulate materials sharply expand, instantaneous pop, obtain explosion grain;
(2) step (1) gained is expanded grain to be undertaken pulverizing or pelletize by desired particle size, namely obtain expanded bead material.
2. the preparation method of cigarette filter expanded bead material according to claim 1, it is characterised in that: the solid particulate materials of described step (1) is natural plants granular materials or the composite of load essence and flavoring agent.
3. the preparation method of cigarette filter expanded bead material according to claim 1, it is characterized in that: the pressure of described step (1) inside reactor is by adding composition of easily vaporizing, the high pressure produced in heating process, or directly filling into gas in reactor produces high pressure.
4. the preparation method of cigarette filter expanded bead material according to claim 3, it is characterised in that: described in fill into gas be nitrogen.
5. the preparation method of cigarette filter expanded bead material according to claim 1, it is characterised in that: the desired particle size in described step (2) is 30～60 orders.
6. the application of the preparation method gained expanded bead material of arbitrary described cigarette filter expanded bead material in claim 1 to 5, it is characterised in that: being added routinely to filter stick by this expanded bead material, the addition of every Medicated cigarette is 5～30mg.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610075661.XA CN105670792A (en) | 2016-02-03 | 2016-02-03 | Preparing method and application of cigarette filter tip expansion granular material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610075661.XA CN105670792A (en) | 2016-02-03 | 2016-02-03 | Preparing method and application of cigarette filter tip expansion granular material |
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| CN201610075661.XA Pending CN105670792A (en) | 2016-02-03 | 2016-02-03 | Preparing method and application of cigarette filter tip expansion granular material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109700069A (en) * | 2018-12-19 | 2019-05-03 | 河南中烟工业有限责任公司 | Millet perfumed granules and preparation method thereof and composite tip stick |
| CN110464040A (en) * | 2019-07-16 | 2019-11-19 | 河南中烟工业有限责任公司 | A kind of preparation method and application dropping the porous particle that smells good |
| CN113057364A (en) * | 2021-03-18 | 2021-07-02 | 云南还原医学生物科技有限公司 | Method for producing tobacco flavor sustained-release particles based on steam explosion technology and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257670A (en) * | 1998-12-20 | 2000-06-28 | 朱大恒 | Method and equipment for expanding tobacco |
| CN104799433A (en) * | 2015-02-16 | 2015-07-29 | 广东省金叶科技开发有限公司 | Method for treating tea stems to prepare filter stick flavor increasing particles by microwave expansion technology |
-
2016
- 2016-02-03 CN CN201610075661.XA patent/CN105670792A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257670A (en) * | 1998-12-20 | 2000-06-28 | 朱大恒 | Method and equipment for expanding tobacco |
| CN104799433A (en) * | 2015-02-16 | 2015-07-29 | 广东省金叶科技开发有限公司 | Method for treating tea stems to prepare filter stick flavor increasing particles by microwave expansion technology |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109700069A (en) * | 2018-12-19 | 2019-05-03 | 河南中烟工业有限责任公司 | Millet perfumed granules and preparation method thereof and composite tip stick |
| CN110464040A (en) * | 2019-07-16 | 2019-11-19 | 河南中烟工业有限责任公司 | A kind of preparation method and application dropping the porous particle that smells good |
| CN113057364A (en) * | 2021-03-18 | 2021-07-02 | 云南还原医学生物科技有限公司 | Method for producing tobacco flavor sustained-release particles based on steam explosion technology and application |
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Application publication date: 20160615 |