CN112273717A - Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof - Google Patents
Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof Download PDFInfo
- Publication number
- CN112273717A CN112273717A CN202011189272.2A CN202011189272A CN112273717A CN 112273717 A CN112273717 A CN 112273717A CN 202011189272 A CN202011189272 A CN 202011189272A CN 112273717 A CN112273717 A CN 112273717A
- Authority
- CN
- China
- Prior art keywords
- particles
- optionally
- cellulose
- wet
- flavoring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002245 particle Substances 0.000 title claims abstract description 201
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 160
- 238000001816 cooling Methods 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 79
- 239000011248 coating agent Substances 0.000 claims abstract description 76
- 239000000843 powder Substances 0.000 claims abstract description 76
- 239000000463 material Substances 0.000 claims abstract description 67
- 239000000779 smoke Substances 0.000 claims abstract description 43
- 239000008187 granular material Substances 0.000 claims abstract description 42
- 238000001125 extrusion Methods 0.000 claims abstract description 37
- 229920002678 cellulose Polymers 0.000 claims abstract description 34
- 239000001913 cellulose Substances 0.000 claims abstract description 34
- 239000000796 flavoring agent Substances 0.000 claims abstract description 31
- 239000000126 substance Substances 0.000 claims abstract description 30
- 235000019634 flavors Nutrition 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000007888 film coating Substances 0.000 claims abstract description 11
- 238000009501 film coating Methods 0.000 claims abstract description 11
- 230000008569 process Effects 0.000 claims abstract description 11
- 238000005563 spheronization Methods 0.000 claims abstract description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 43
- 229920001223 polyethylene glycol Polymers 0.000 claims description 43
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 41
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 41
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 41
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 41
- 239000000243 solution Substances 0.000 claims description 39
- 229920002301 cellulose acetate Polymers 0.000 claims description 38
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 30
- 239000007864 aqueous solution Substances 0.000 claims description 28
- 235000010980 cellulose Nutrition 0.000 claims description 28
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000012798 spherical particle Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 19
- 238000005469 granulation Methods 0.000 claims description 16
- 230000003179 granulation Effects 0.000 claims description 16
- 229920001747 Cellulose diacetate Polymers 0.000 claims description 15
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 15
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 15
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 15
- 239000011247 coating layer Substances 0.000 claims description 14
- 239000000284 extract Substances 0.000 claims description 14
- 238000007873 sieving Methods 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- 235000013599 spices Nutrition 0.000 claims description 13
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims description 12
- 244000269722 Thea sinensis Species 0.000 claims description 12
- 239000001856 Ethyl cellulose Substances 0.000 claims description 10
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 10
- 229920001249 ethyl cellulose Polymers 0.000 claims description 10
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000003205 fragrance Substances 0.000 claims description 9
- 240000004160 Capsicum annuum Species 0.000 claims description 8
- 241000207199 Citrus Species 0.000 claims description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 8
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 8
- 235000020971 citrus fruits Nutrition 0.000 claims description 8
- 235000013355 food flavoring agent Nutrition 0.000 claims description 8
- 229920000609 methyl cellulose Polymers 0.000 claims description 8
- 239000001923 methylcellulose Substances 0.000 claims description 8
- 235000010981 methylcellulose Nutrition 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 8
- 229920008347 Cellulose acetate propionate Polymers 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 235000005979 Citrus limon Nutrition 0.000 claims description 6
- 244000131522 Citrus pyriformis Species 0.000 claims description 6
- 241000533293 Sesbania emerus Species 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 6
- 238000009837 dry grinding Methods 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- 235000000346 sugar Nutrition 0.000 claims description 6
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 5
- 229920000881 Modified starch Polymers 0.000 claims description 5
- 238000000889 atomisation Methods 0.000 claims description 5
- 230000002708 enhancing effect Effects 0.000 claims description 5
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 5
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 5
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 5
- 230000002572 peristaltic effect Effects 0.000 claims description 5
- 229940093429 polyethylene glycol 6000 Drugs 0.000 claims description 5
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims description 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 240000002234 Allium sativum Species 0.000 claims description 4
- 240000000662 Anethum graveolens Species 0.000 claims description 4
- 244000056139 Brassica cretica Species 0.000 claims description 4
- 235000003351 Brassica cretica Nutrition 0.000 claims description 4
- 235000003343 Brassica rupestris Nutrition 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 235000002566 Capsicum Nutrition 0.000 claims description 4
- 235000007862 Capsicum baccatum Nutrition 0.000 claims description 4
- 235000002568 Capsicum frutescens Nutrition 0.000 claims description 4
- 235000005747 Carum carvi Nutrition 0.000 claims description 4
- 240000000467 Carum carvi Species 0.000 claims description 4
- 244000223760 Cinnamomum zeylanicum Species 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- 240000000560 Citrus x paradisi Species 0.000 claims description 4
- 235000002787 Coriandrum sativum Nutrition 0.000 claims description 4
- 244000018436 Coriandrum sativum Species 0.000 claims description 4
- 235000007129 Cuminum cyminum Nutrition 0.000 claims description 4
- 244000304337 Cuminum cyminum Species 0.000 claims description 4
- 235000003392 Curcuma domestica Nutrition 0.000 claims description 4
- 244000008991 Curcuma longa Species 0.000 claims description 4
- 244000004281 Eucalyptus maculata Species 0.000 claims description 4
- 240000006927 Foeniculum vulgare Species 0.000 claims description 4
- 235000004204 Foeniculum vulgare Nutrition 0.000 claims description 4
- 235000008694 Humulus lupulus Nutrition 0.000 claims description 4
- 244000025221 Humulus lupulus Species 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 235000013628 Lantana involucrata Nutrition 0.000 claims description 4
- 240000005183 Lantana involucrata Species 0.000 claims description 4
- 235000006677 Monarda citriodora ssp. austromontana Nutrition 0.000 claims description 4
- 235000009421 Myristica fragrans Nutrition 0.000 claims description 4
- 244000270834 Myristica fragrans Species 0.000 claims description 4
- 240000009023 Myrrhis odorata Species 0.000 claims description 4
- 235000007265 Myrrhis odorata Nutrition 0.000 claims description 4
- 235000010676 Ocimum basilicum Nutrition 0.000 claims description 4
- 240000007926 Ocimum gratissimum Species 0.000 claims description 4
- 239000006002 Pepper Substances 0.000 claims description 4
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 4
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 4
- 235000006990 Pimenta dioica Nutrition 0.000 claims description 4
- 240000008474 Pimenta dioica Species 0.000 claims description 4
- 235000012550 Pimpinella anisum Nutrition 0.000 claims description 4
- 235000016761 Piper aduncum Nutrition 0.000 claims description 4
- 240000003889 Piper guineense Species 0.000 claims description 4
- 235000017804 Piper guineense Nutrition 0.000 claims description 4
- 235000008184 Piper nigrum Nutrition 0.000 claims description 4
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 4
- 241001247145 Sebastes goodei Species 0.000 claims description 4
- 244000223014 Syzygium aromaticum Species 0.000 claims description 4
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 4
- 235000006468 Thea sinensis Nutrition 0.000 claims description 4
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 4
- 244000299461 Theobroma cacao Species 0.000 claims description 4
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 4
- 240000002657 Thymus vulgaris Species 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 240000006909 Tilia x europaea Species 0.000 claims description 4
- 235000009499 Vanilla fragrans Nutrition 0.000 claims description 4
- 244000263375 Vanilla tahitensis Species 0.000 claims description 4
- 235000012036 Vanilla tahitensis Nutrition 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000443 aerosol Substances 0.000 claims description 4
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 4
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims description 4
- 235000020279 black tea Nutrition 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000001511 capsicum annuum Substances 0.000 claims description 4
- 239000001728 capsicum frutescens Substances 0.000 claims description 4
- 235000017803 cinnamon Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 235000003373 curcuma longa Nutrition 0.000 claims description 4
- 235000021438 curry Nutrition 0.000 claims description 4
- 235000013399 edible fruits Nutrition 0.000 claims description 4
- 235000004611 garlic Nutrition 0.000 claims description 4
- 235000009569 green tea Nutrition 0.000 claims description 4
- 239000010954 inorganic particle Substances 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- 235000013372 meat Nutrition 0.000 claims description 4
- 235000013336 milk Nutrition 0.000 claims description 4
- 239000008267 milk Substances 0.000 claims description 4
- 210000004080 milk Anatomy 0.000 claims description 4
- 235000010460 mustard Nutrition 0.000 claims description 4
- 229960002715 nicotine Drugs 0.000 claims description 4
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims description 4
- 239000001702 nutmeg Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 4
- 239000004626 polylactic acid Substances 0.000 claims description 4
- 239000011164 primary particle Substances 0.000 claims description 4
- 235000013616 tea Nutrition 0.000 claims description 4
- 239000001585 thymus vulgaris Substances 0.000 claims description 4
- 235000013976 turmeric Nutrition 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 4
- 238000001238 wet grinding Methods 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229940069445 licorice extract Drugs 0.000 claims description 3
- 239000011146 organic particle Substances 0.000 claims description 3
- 244000099147 Ananas comosus Species 0.000 claims description 2
- 235000007119 Ananas comosus Nutrition 0.000 claims description 2
- 229920000623 Cellulose acetate phthalate Polymers 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 2
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 2
- 229930195725 Mannitol Natural products 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000954 Polyglycolide Polymers 0.000 claims description 2
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- 240000000513 Santalum album Species 0.000 claims description 2
- 235000008632 Santalum album Nutrition 0.000 claims description 2
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 229940081735 acetylcellulose Drugs 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 229940081734 cellulose acetate phthalate Drugs 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 238000004108 freeze drying Methods 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 235000001727 glucose Nutrition 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 2
- 229920003132 hydroxypropyl methylcellulose phthalate Polymers 0.000 claims description 2
- 229940031704 hydroxypropyl methylcellulose phthalate Drugs 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 claims description 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000008101 lactose Substances 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- 239000000594 mannitol Substances 0.000 claims description 2
- 235000010355 mannitol Nutrition 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000010451 perlite Substances 0.000 claims description 2
- 235000019362 perlite Nutrition 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 2
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims description 2
- 229920001610 polycaprolactone Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000004633 polyglycolic acid Substances 0.000 claims description 2
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 229920005992 thermoplastic resin Polymers 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 244000061176 Nicotiana tabacum Species 0.000 claims 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 claims 1
- UEHUZQKLOWYOMO-UHFFFAOYSA-N diethylazanium;acetate Chemical compound CC(O)=O.CCNCC UEHUZQKLOWYOMO-UHFFFAOYSA-N 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 1
- 230000000391 smoking effect Effects 0.000 abstract description 48
- 230000007794 irritation Effects 0.000 abstract description 5
- 125000003118 aryl group Chemical group 0.000 abstract description 4
- 238000011156 evaluation Methods 0.000 description 31
- 241000208125 Nicotiana Species 0.000 description 24
- 230000001953 sensory effect Effects 0.000 description 14
- 239000008188 pellet Substances 0.000 description 12
- 238000005096 rolling process Methods 0.000 description 11
- 238000009826 distribution Methods 0.000 description 10
- 239000011246 composite particle Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 229930007503 menthone Natural products 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- VJMAITQRABEEKP-UHFFFAOYSA-N [6-(phenylmethoxymethyl)-1,4-dioxan-2-yl]methyl acetate Chemical compound O1C(COC(=O)C)COCC1COCC1=CC=CC=C1 VJMAITQRABEEKP-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0225—Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
Abstract
A flavoring and cooling granule for cigarette comprises cellulose, derivatives and flavoring substances. The granules are formed by mixing aromatic substance powder, cellulose and derivative powder, and the mass content of the natural aromatic powder is 20-100%. The preparation method of the aroma-enhancing and cooling particles for cigarettes comprises the steps of mixing aroma substance powder with cellulose and derivative powder, and preparing the aroma-enhancing and cooling particles through a wet extrusion and spheronization process. According to the preparation method of the cigarette flavor-enhancing and temperature-reducing particles with the coating, cellulose and derivative particles are prepared by taking cellulose and derivative powder as materials through a wet extrusion spheronization process; then coating a layer containing the flavor substances on the surfaces of the cellulose and derivative particles by a fluidized film coating mode. The invention is applied to the cigarette filter stick, can reduce the smoke temperature, simultaneously reduce the irritation of smoke, bring no miscellaneous gas, improve the smoke aroma amount and the aroma holding time, and improve the cigarette smoking quality.
Description
Technical Field
The invention belongs to the technical field of tobacco, and relates to smoke treatment, in particular to a structure for reducing the smoke temperature and increasing aroma of cigarettes.
Background
Consumers enjoy the aroma of cigarettes by smoking. For cigarette consumers, it is required that not only is the less harmful the cigarette is, the better it is, but also the cigarette has a high quality of smoking taste, resulting in a pleasant and pleasant feeling of smell and taste.
The addition of tobacco essence and flavor in the cut tobacco of cigarette is a conventional and necessary technical means. In the combustion process of the tobacco shreds, the flavors and fragrances have chemical reaction and physical action at the same time, and because the flavors and fragrances have chemical reaction when the tobacco shreds are combusted, the original characteristic aroma components of the flavors and fragrances must change, so that the original aroma of the tobacco shreds is influenced, and the formula needs to be repeatedly and massively adjusted to be matched with the tobacco shreds, thereby achieving the effect of improving the smoking quality of cigarettes. At present, the technology of researchers in the aspect is mature, the space for improving the quality of cigarettes is relatively limited, and related novel materials are needed to be searched from the non-combustion section of the cigarettes to improve and improve the aroma of the cigarettes, increase the sweet feeling and the fluid production feeling of the cigarette smoke and reduce the irritation of the cigarette smoke.
Some porous and special-fragrance granular materials are added into the cigarette filter stick to improve or promote the quality of cigarette products, and the method is a novel and effective research direction with development prospect. For example: the particle filter stick disclosed in patent application CN103054186A 'A traditional Chinese medicine composite particle filter stick and a preparation method thereof' can effectively reduce the tar content in cigarettes and play a certain role in enhancing aroma and keeping moisture of the cigarettes; the composite plant particles disclosed in patent application CN203884686U functional film composite particles and filter sticks thereof can not only exert the effects of environmental protection, aroma enhancement and moisture retention of natural plants, but also effectively adsorb organic harmful substances in cigarette smoke; patent application CN104705783A, A Filter tip additive material capable of improving sensory characteristics of smoke and application thereof, discloses that inorganic porous particles can improve sensory quality of cigarettes and can effectively reduce contents of harmful components such as tar, total particulate matter and the like in smoke; the coffee starch composite particles disclosed in patent application CN103271443A, namely preparation method of coffee starch composite particles and application of the coffee starch composite particles in cigarette filters, can reduce smoke irritation, improve smoke aroma quality and aroma quantity, improve cigarette smoking quality and form the characteristic style of strong-flavor cigarettes.
Various plant particle materials disclosed in the prior art generally use porous inorganic materials in the preparation process, and can bring offensive odor to smoke while perfuming, thereby influencing the sensory analysis feeling of consumers. As for the activated carbon or the porous inorganic material flavor-carrying particles, the blades for cutting the filter stick are easily damaged in the filter stick and cigarette production processes, the cigarette production efficiency is affected, and sufficient use safety is also lacked.
Aiming at the defects of the filter stick particle material and the filter stick particle technology, how to select proper material and process technology reduces the irritation of cigarette smoke and enriches the fragrance of the cigarette while introducing no miscellaneous gas into the smoke is a new demand for improving and enhancing the smoking quality of the cigarette.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a cigarette aromatized cellulose acetate particle, a preparation method and application thereof. The aromatized cellulose acetate particles are prepared by using cellulose acetate and natural aromatic powder or synthetic essence and spice as main components and adopting a wet extrusion rolling coating method. Because the cellulose acetate has chemical homology with the traditional cellulose diacetate for cigarettes, the cigarette flavor-enhancing agent does not bring miscellaneous gas to the smoke while enhancing the flavor of the smoke, thereby avoiding influencing the smoking feeling of consumers.
The flavored cellulose acetate particles provided by the present invention can be achieved by the following two methods. The first method comprises the following steps: mixing natural fragrant powder and cellulose acetate powder, and preparing fragrant cellulose acetate particles by a wet extrusion spheronization process; the aroma-enhancing particles prepared by the method have natural aroma, and are safe, non-toxic and free of miscellaneous gas. The second method comprises the following steps: cellulose diacetate powder is used as a material, cellulose acetate particles are prepared by a wet extrusion and rounding process, and then a coating containing essence and flavor is coated on the surfaces of the particles in a fluidized film coating mode; the aroma-enhancing particles prepared by the method have the characteristic of long aroma slow-release time.
Specifically, the flavoring and cooling particles for the cigarette comprise cellulose, derivatives and flavoring substances.
Further, the aroma-enhancing and temperature-reducing particles for the cigarettes are formed by mixing aroma substance powder, cellulose and derivative powder, wherein the mass content of the aroma powder is 20-100%.
Optionally, the cellulose and derivatives include: cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, methyl cellulose, ethyl cellulose, carboxymethyl cellulose, and the like.
Optionally, the particles have a particle size in the range of 150 microns to 2000 microns.
Optionally, the fragrant substance is a natural fragrant material, an extract of a natural fragrant material, or a perfume.
Optionally, the addition amount of the extract or essence of the natural fragrant material accounts for 0.02% -5% of the flavoring and cooling particles.
Optionally, the flavor material powder has an average particle size of 75 microns or less.
Optionally, the fragrant substance is present in a coating covering the outside of the cellulose and derivative particles; the fragrance substance accounts for 0.2-0.6% of the whole coating.
Optionally, the coating has a thickness of 0.001 to 0.2 mm; optionally, the coating comprises hydroxypropyl methylcellulose, polyethylene glycol, and a flavoring; optionally, the fragrant substance is an extract or essence of a natural fragrant material. Optionally, the extract or essence of natural aromatic material comprises at least one of citrus type essence, fruit type essence, mint type essence, bean type essence, spice type essence, milk type essence, meat type essence, coffee type essence, nut type essence, wine type essence, vegetable type essence;
optionally, the extract or essence of natural flavor material comprises rose essence, jasmine essence, mint essence, sandalwood essence, pineapple essence, lemon essence, licorice extract, tobacco extract;
optionally, the natural aroma material includes clove, tobacco, coffee beans, cocoa, cinnamon, mint, vanilla, tea, green tea, black tea, bay leaves, citrus peel, orange, lemon, lime, grapefruit, cumin, paprika, chili pepper, red pepper, eucalyptus, mint, curry, anise, dill, fennel, allspice, basil, rosemary, pepper, caraway seed, coriander leaves, garlic, mustard, nutmeg, thyme, turmeric, oregano, hops, sugar, other spices, other grains, and any combination therebetween.
The preparation method of the aroma-enhancing and cooling particles for cigarettes comprises the steps of mixing aroma substance powder with cellulose and derivative powder, and preparing the aroma-enhancing and cooling particles through a wet extrusion and spheronization process.
Optionally, wet grinding the cellulose and derivatives into powder with average particle size of 75 μm or less; grinding the flavor substance into powder with average particle size of 75 μm or less by pulverizing and dry grinding; respectively weighing the cellulose, the derivative powder and the fragrant substance powder, adding a hydroxypropyl methyl cellulose aqueous solution, and fully and uniformly stirring on a laboratory wet mixer to obtain wet materials; carrying out wet extrusion granulation on the prepared soft wet material on a wet extruder to obtain a cylindrical strip-shaped object; rounding the cylindrical strip-shaped object on a rounding machine to obtain wet spherical particles; freeze-drying the wet spherical particles to remove water to obtain dried particles; sieving to obtain the flavoring granule with required particle size.
Optionally, the ratio of the cellulose to the derivatives, the flavor powder, and the hydroxypropyl methylcellulose is: (0-0.72): (0.20-0.92): 0.08.
according to the preparation method of the cigarette flavor-enhancing and temperature-reducing particles with the coating, cellulose acetate particles are prepared by taking cellulose and derivative powder as materials through a wet extrusion and rounding process; then coating a coating layer containing fragrant substances on the surface of the cellulose acetate particles by a fluidized film coating mode.
Optionally, wet grinding the cellulose and derivatives into powder with average particle size of 75 μm or less; weighing the cellulose and derivative powder, adding hydroxypropyl methylcellulose aqueous solution, and fully and uniformly stirring on a laboratory wet mixer to obtain a wet material; carrying out wet extrusion granulation on the prepared soft wet material on a wet extruder to obtain a cylindrical strip-shaped object; rounding the cylindrical strip-shaped object on a rounding machine to obtain wet spherical particles; removing moisture from the wet spherical particles to obtain dry primary particles; performing film coating on the primary particles by using a bottom jet fluidized bed; after coating, drying the water on the surface of the particles; taking out, sieving to obtain the aroma-enhancing and temperature-reducing granules with the required particle size.
Optionally, the amount of coating solution is controlled so that the coating film accounts for 5-15% of the final granule mass.
Optionally, the particle bulk density of the temperature reducing particles is from 0.50g/mL to 0.52 g/mL.
Optionally, the coating solution concentration is 5.0%; the main components are hydroxypropyl methylcellulose and polyethylene glycol 6000, and the solvent is water. Wherein the proportion of polyethylene glycol in the main component is 30%, and the proportion of the fragrance substance in the main component is 0.2% -0.6%.
The application of any of the aroma-enhancing and temperature-reducing particles for cigarettes in cigarettes.
40-60mg of the aroma-enhancing and temperature-reducing particles are added into each cigarette filter stick.
Besides the above technical solutions, the present invention can be further expanded as follows:
a granule for increasing flavor and cooling for tobacco.
The particles are inactive particles or active particles or inactive particles of the outer coating layer.
Optionally, the thickness of the outer coating layer of the inactive particles is 0-0.2mm, and the outer coating layer accounts for 0-50% of the mass of the whole particles; the thickness of the outer coating layer of the active particles is 0.001-0.2mm, and the outer coating layer accounts for 0.001-50% of the mass of the whole particles.
Optionally, the inactive particles are less than 3.0mg/cm for nicotine adsorption in the smoke aerosol3The particles of (1).
Optionally, the inactive particles comprise inorganic particles or organic particles.
Optionally, the inorganic particles comprise one or more of alumina, zirconia, calcium carbonate spheres, glass beads, silica, iron, copper, aluminum, gold, platinum, magnesium silicate, or calcium sulfate.
Optionally, the organic particle comprises one or more of cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, sucrose powder, dextrin, lactose, powdered sugar, glucose, mannitol, starch, methyl cellulose, ethyl cellulose, polylactic acid, polyethylene, polypropylene, polyhydroxybutyrate, poly-epsilon-caprolactone, polyglycolic acid, polyhydroxyalkanoate, or a starch-based thermoplastic resin.
Optionally, the active particles are capable of adsorbing nicotine in the smoke aerosol by more than or equal to 3.0mg/cm3The particles of (1).
Optionally, the active particles comprise one or more of molecular sieves, activated carbon, diatomaceous earth, zeolites, perlite, ceramics, sepiolite, fuller's earth, ion exchange resins.
Optionally, the overcoat layer is a film-forming material.
Optionally, the film-forming material includes one or more of cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylcellulose, ethylcellulose, polyvinylpyrrolidone, polyvinyl acetal diethylamine acetate, styrene maleic acid copolymer, styrene-vinylpyridine copolymer, cellulose acetate phthalate, hydroxypropylmethylcellulose phthalate, cellulose acetate/polyethylene glycol, methylcellulose/polyethylene glycol, carboxymethylcellulose/polyethylene glycol, hydroxypropylmethylcellulose/polyethylene glycol, ethylcellulose/polyethylene glycol, acrylic resin/polyethylene glycol, or polylactic acid.
Optionally, the outer coating contains a flavoring agent. Flavoring agents for film coatings include edible flavors or tobacco extracts.
The edible essence is at least one of citrus type essence, fruit type essence, mint type essence, bean type essence, spicy type essence, milk type essence, meat type essence, coffee type essence, nut type essence, wine type essence, and vegetable type essence.
Optionally, the particle shape comprises one or more of a spherical, spheroidal, pie, flake, ribbon, acicular, polygonal, faceted, or random shape.
Optionally, the particles have an average diameter in at least one dimension of from a lower limit of 50 microns, 100 microns, 150 microns, 200 microns, or 250 microns to an upper limit of 5000 microns, 2000 microns, 1000 microns, 900 microns, or 700 microns.
The preparation method of the flavor enhancing and cooling particles for the cigarettes comprises the following steps:
(1) mixing active/inactive powder, flavoring agent and adhesive solution to prepare wet material;
(2) extruding and cutting the wet material obtained in the step (1) into smooth and compact cylindrical strips with the same diameter by adopting a wet extrusion granulation process, and carrying out rounding molding on the prepared cylindrical strips in a rounding machine to obtain initial wet granules;
(3) drying the initial wet granules, removing water to obtain active/inactive flavored granules.
Optionally, the binder in step (1) includes one or more of hydroxypropyl methylcellulose aqueous solution, pregelatinized starch aqueous solution, or sodium carboxymethyl cellulose.
Optionally, the concentration of the hydroxypropyl methylcellulose aqueous solution or the pregelatinized starch aqueous solution is 8-12%.
Optionally, the mass ratio of the binder to the powder in the step (1) is 1.0-1.2: 1. The mass ratio of the natural fragrant powder to the total powder is as follows: 0.2-1.0.
Optionally, the flavoring agent powder in step (1) is a natural flavoring material including clove, tobacco, coffee bean, cocoa, cinnamon, mint, vanilla, tea, green tea, black tea, bay leaves, citrus peel, orange, lemon, lime, grapefruit, cumin, paprika, chili pepper, red pepper, eucalyptus, mint, curry, anise, dill, fennel, allspice, basil, rosemary, pepper, caraway seed, coriander leaf, garlic, mustard, nutmeg, thyme, turmeric, oregano, other spices, hops, other grains, sugar and any combination thereof; the average grain diameter of the powder after grinding is less than or equal to 50 microns.
Optionally, the rotary extrusion granulator in step (2) is fed at a speed of 23-25rpm and extruded at a speed of 25-30 rpm.
Optionally, the spheronizer in step (2) is operated at 600-700rpm for 1-2 minutes, and then decelerated at 450-500rpm for another 3-4 minutes.
The preparation method of the particles for flavoring and cooling the outer coating layer for the cigarettes comprises the following steps:
(1) coating the surface of the particles with a coating solution by a fluidized bed coating method to form a solid-solid composite phase-change aroma-enhancing coating film layer to obtain initial wet particles;
(2) heating and drying to remove the solvent on the surfaces of the initial wet particles to obtain initial particles;
(3) and screening to obtain the coated particles.
Optionally, the coating solution in the step (1) is more than one of a water-soluble coating solution, an ethanol coating solution or an acetone coating solution.
Optionally, the water-soluble coating solution comprises more than one of hydroxypropyl methylcellulose/polyethylene glycol aqueous solution, carboxymethyl cellulose/polyethylene glycol aqueous solution or acrylic resin/polyethylene glycol aqueous solution; the solvent is water; the molecular weight of the polyethylene glycol is 1000-20000.
Optionally, the mass concentration of the water-soluble coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass. The essence and spice accounts for 0.1-2% of the total coating liquid.
Optionally, the ethanol coating solution comprises an ethyl cellulose/polyethylene glycol ethanol solution; the solvent is 95% ethanol; the molecular weight of the polyethylene glycol is 1000-20000.
Optionally, the mass concentration of the ethanol coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass. The essence and spice accounts for 0.1-2% of the total coating liquid.
Optionally, the acetone coating solution comprises more than one of a cellulose diacetate/polyethylene glycol acetone solution or a cellulose acetate butyrate/polyethylene glycol acetone solution; the solvent is acetone; the molecular weight of the polyethylene glycol is 1000-20000.
Optionally, the mass concentration of the acetone coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass. The essence and spice accounts for 0.1-2% of the total coating liquid.
Optionally, the coating film layer in the step (1) accounts for 0-50% of the total mass of the granule.
Optionally, the inlet air temperature of the fluidized bed in the step (1) is 40-60 ℃; the material temperature is 30-45 ℃; the diameter of the spray nozzle of the spray gun is 1.0 mm; the atomization pressure is 0.15-0.20 MPa; the flow rate of the pump liquid of the peristaltic pump is 5-15 r/min.
The aroma-enhancing cellulose and the derivative particles are applied to the cigarette filter stick, and sensory evaluation shows that the addition of the aroma-enhancing cellulose and the derivative particles in the filter stick can reduce the temperature and the irritation of smoke, bring no miscellaneous gas, improve the aroma amount and the aroma holding time of the smoke, and improve the smoking quality of cigarettes.
Drawings
FIG. 1 is a schematic representation of a cigarette comprising the flavored cellulose for tobacco and derivative particles of the present invention.
In the figure: 1-cigarette; 2-acetate fiber tow section; 3-flavoring cellulose and derivative particles for tobacco of the invention; 4-cigarette holder.
Detailed Description
The invention is further illustrated below with reference to the figures and examples. The following percentages (%) are by mass unless otherwise indicated.
Example 1
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 48 microns. The dried orange peel is ground by crushing and dry grinding into powder with an average particle size of 45 μm. 0.3 kg of cellulose diacetate powder sample and 0.7 kg of dried orange peel powder are respectively weighed, 1.18 kg of 7.8% hydroxypropyl methyl cellulose (HPMC) aqueous solution is added, and the mixture is fully stirred and mixed evenly on a laboratory wet mixer to prepare wet materials. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 2
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 72 microns. The roasted coffee beans were ground to a powder having an average particle size of 60 μm. 0.4 kg of a cellulose diacetate powder sample and 0.6 kg of coffee bean powder were weighed respectively, 1.12 kg of 7.8% Hydroxypropylmethylcellulose (HPMC) aqueous solution was added, and the mixture was fully stirred and mixed in a laboratory wet mixer to prepare a wet material. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical granules were freeze-dried to remove water, thereby obtaining dried granules. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 3
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 48 microns. The dried orange peel is ground by crushing and dry grinding into powder with an average particle size of 25 μm. 0.4 kg of cellulose diacetate powder sample and 0.6 kg of dried orange peel powder are respectively weighed, 1.08 kg of 12% pregelatinized starch aqueous solution is added, and the mixture is fully stirred and mixed uniformly on a laboratory wet mixer to prepare wet materials. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 4
The dried orange peel is ground by crushing and dry grinding into powder with an average particle size of 40 μm. Weighing 1.0 kg of dried orange peel powder, adding 1.03 kg of 7.8% hydroxypropyl methylcellulose (HPMC) aqueous solution, and fully stirring and uniformly mixing on a laboratory wet mixer to obtain a wet material. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 5
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 48 microns. Weighing 1 kg of the above ground powder sample, adding 1.18 kg of 7.8% hydroxypropyl methylcellulose (HPMC) aqueous solution, and fully stirring and uniformly mixing on a laboratory wet mixer to obtain a wet material. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. Drying the wet spherical particles at the temperature of 105-120 ℃ for 5-6 hours, and removing moisture to obtain dry initial particles. And (3) performing film coating on the dried initial granules by adopting a bottom jet fluidized bed, and controlling the using amount of a coating solution to ensure that a coating film accounts for 15% of the mass of the final granules. After coating, the granules are dried for 15 minutes at the air inlet temperature of 40 ℃, and the moisture on the surfaces of the granules is dried. Taking out, and sieving with 14 mesh and 20 mesh sieves to obtain the desired particle size of temperature-reducing granule with bulk density of 0.52 g/mL. The concentration of the coating solution is 5.0%. The main components are hydroxypropyl methylcellulose and polyethylene glycol 6000, and the solvent is water. Wherein the proportion of polyethylene glycol in the main component is 30%, and the proportion of menthone in the main component is 0.2%. The fluidized bed operating conditions were: air inlet temperature: 40 ℃, material temperature: the temperature is 32.5 ℃, the diameter of a spray gun nozzle is 1.0mm, the atomization pressure is 0.17MPa, and the flow rate of the peristaltic pump liquid is 10 r/min.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 6
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 48 microns. Weighing 1 kg of the above ground powder sample, adding 1.18 kg of 7.8% hydroxypropyl methylcellulose (HPMC) aqueous solution, and fully stirring and uniformly mixing on a laboratory wet mixer to obtain a wet material. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. Drying the wet spherical particles at the temperature of 105-120 ℃ for 5-6 hours, and removing moisture to obtain dry initial particles. And (3) performing film coating on the dried initial granules by adopting a bottom jet fluidized bed, and controlling the using amount of a coating solution to ensure that a coating film accounts for 15% of the mass of the final granules. After coating, the granules are dried for 15 minutes at the air inlet temperature of 40 ℃, and the moisture on the surfaces of the granules is dried. Taking out, and sieving with 14 mesh and 20 mesh sieves to obtain the desired particle size of temperature-reducing granule with bulk density of 0.52 g/mL. The concentration of the coating solution is 5.0%. The main components are hydroxypropyl methylcellulose and polyethylene glycol 6000, and the solvent is water. Wherein the proportion of the polyethylene glycol in the main component is 30 percent, and the proportion of the coffee essence in the main component is 0.6 percent. The fluidized bed operating conditions were: air inlet temperature: 40 ℃, material temperature: the temperature is 32.5 ℃, the diameter of a spray gun nozzle is 1.0mm, the atomization pressure is 0.17MPa, and the flow rate of the peristaltic pump liquid is 10 r/min.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 7
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 48 microns. Weighing 1 kg of the above ground powder sample, adding 1.18 kg of 7.8% hydroxypropyl methylcellulose (HPMC) aqueous solution, and fully stirring and uniformly mixing on a laboratory wet mixer to obtain a wet material. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. Drying the wet spherical particles at the temperature of 105-120 ℃ for 5-6 hours, and removing moisture to obtain dry initial particles. And (3) performing film coating on the dried initial particles by adopting a bottom jet fluidized bed, and controlling the using amount of a coating solution to ensure that a coating film accounts for 5% of the mass of the final particles. After coating, the granules are dried for 15 minutes at the air inlet temperature of 40 ℃, and the moisture on the surfaces of the granules is dried. Taking out, and sieving with 14 mesh and 20 mesh sieves to obtain the desired particle size of temperature-reducing granule with bulk density of 0.50 g/mL. The concentration of the coating solution is 5.0%. The main components are hydroxypropyl methylcellulose and polyethylene glycol 6000, and the solvent is water. Wherein the proportion of polyethylene glycol in the main component is 30%, and the proportion of menthone in the main component is 0.2%. The fluidized bed operating conditions were: air inlet temperature: 40 ℃, material temperature: the temperature is 32.5 ℃, the diameter of a spray gun nozzle is 1.0mm, the atomization pressure is 0.17MPa, and the flow rate of the peristaltic pump liquid is 10 r/min.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 8
Industrial cellulose diacetate was wet ground to a powder with an average particle size of 40 microns. The dried orange peel is ground by crushing and dry grinding into powder with an average particle size of 45 μm. 0.8 kg of cellulose diacetate powder sample and 0.2 kg of dried orange peel powder are respectively weighed, 1.20 kg of 7.8% hydroxypropyl methyl cellulose (HPMC) aqueous solution is added, and the mixture is fully stirred and mixed uniformly on a laboratory wet mixer to prepare wet materials. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared flavoring particles are directly added into cigarette filter sticks, and 40-60mg of flavoring particles can be added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 9
400 g of microcrystalline cellulose with the average particle size of 65 microns, 20 g of licorice extract and 1.0 kg of 7.8% hydroxypropyl methyl cellulose (HPMC) aqueous solution are respectively added into a laboratory wet granulator, and are fully stirred and uniformly mixed to prepare wet materials. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Example 10
1000 g of cellulose acetate propionate with the average particle size of 45 microns, 10 g of mint essence and 1.1 kg of 7.8% hydroxypropyl methyl cellulose (HPMC) aqueous solution are respectively added into a laboratory wet granulator and are fully stirred and uniformly mixed to prepare wet materials. And (3) performing wet extrusion granulation on the prepared soft wet material on an E-50 wet extruder (the aperture of a distribution plate is 1.0mm) to obtain a cylindrical strip-shaped object. The extruder was fed at 23rpm and the extrusion speed was 26 rpm. And (3) rounding the cylindrical strip-shaped object on an S-250 rounding machine to obtain wet spherical particles. The rolling circle condition is as follows: the spheronizer was first run at 600rpm for 1.5 minutes and then at 500rpm for 3 minutes. The wet spherical pellets were freeze-dried to remove water, and dried pellets were obtained. Sieving with 14 mesh and 20 mesh sieve to obtain flavoring granule with desired particle size.
The prepared aroma-enhancing particles are directly added into cigarette filter sticks, and 40-60mg of aroma-enhancing particles are added into each cigarette filter stick. Specifically, the cigarette structure added with cigarette flavoring cellulose acetate particles is shown in figure 1.
According to the standard of smoking evaluation of the sensory technical requirements of GB5606.4-2005 cigarettes, a smoking evaluation group consisting of 8 smoking experts was organized to smoke cigarettes added with the flavor-enhancing particles for cigarettes, and the cigarettes with the same tobacco shreds and the conventional cellulose acetate filter cigarettes as reference samples were used, and the smoking evaluation results are shown in Table 1. The smoke temperature at the outlet end of each filter stick was also tested and the results are shown in table 2.
Table 1: results of flue gas chromatography
Table 2: flue gas temperature test results
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.
Claims (21)
1. The utility model provides a cigarette is with adding fragtant cooling granule which characterized in that: which comprises cellulose, derivatives and flavor substances.
2. The flavoring and cooling particle for cigarette according to claim 1, wherein: the cellulose, the derivatives and the fragrant substances are all powder, and the mass content of the natural fragrant powder is 20-100%; optionally, the cellulose and derivatives include: cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, methyl cellulose, ethyl cellulose, carboxymethyl cellulose.
3. The flavoring and cooling particle for cigarette according to claim 1, wherein: the particles have a particle size in the range of 150 microns to 2000 microns.
4. The flavoring and cooling particle for cigarette according to claim 1, wherein: the fragrant substance is a natural fragrant material, an extract or essence of the natural fragrant material;
optionally, the addition amount of the extract or essence of the natural fragrant material accounts for 0.02% -5% of the flavoring and cooling particles.
5. The flavoring and cooling particle for cigarette according to claim 2, wherein: the flavor substance powder has an average particle size of 75 μm or less.
6. The flavoring and cooling particle for cigarette according to claim 1, wherein: the fragrant substance is present in a coating covering the outside of the cellulose and derivative particles; the fragrance substance accounts for 0.2-0.6% of the whole coating.
7. The flavoring and cooling particle for cigarette according to claim 6, wherein: the thickness of the coating is 0.001-0.2 mm; optionally, the coating comprises hydroxypropyl methylcellulose, polyethylene glycol, and a flavoring; optionally, the fragrant substance is an extract or essence of a natural fragrant material.
8. The flavoring and cooling particle for cigarette according to claim 4 or 7, wherein: the extract or essence of the natural fragrant material comprises at least one of citrus type essence, fruit type essence, mint type essence, bean type essence, spicy type essence, milk type essence, meat type essence, coffee type essence, nut type essence, wine type essence and vegetable type essence;
optionally, the extract or essence of natural flavor material comprises rose essence, jasmine essence, mint essence, sandalwood essence, pineapple essence, lemon essence, licorice extract, tobacco extract;
optionally, the natural aroma material includes clove, tobacco, coffee beans, cocoa, cinnamon, mint, vanilla, tea, green tea, black tea, bay leaves, citrus peel, orange, lemon, lime, grapefruit, cumin, paprika, chili pepper, red pepper, eucalyptus, mint, curry, anise, dill, fennel, allspice, basil, rosemary, pepper, caraway seed, coriander leaves, garlic, mustard, nutmeg, thyme, turmeric, oregano, hops, sugar, other spices, other grains, and any combination therebetween.
9. The flavoring and cooling particle for cigarette according to claim 1, wherein:
the particles are inactive particles or active particles or inactive particles of the outer coating layer;
optionally, the thickness of the outer coating layer of the inactive particles is 0-0.2mm, and the outer coating layer accounts for 0-50% of the mass of the whole particles; the thickness of the outer coating layer of the active particles is 0.001-0.2mm, and the outer coating layer accounts for 0.001-50% of the mass of the whole particles;
optionally, the inactive particles are less than 3.0mg/cm for nicotine adsorption in the smoke aerosol3The particles of (a);
optionally, the inactive particles comprise inorganic particles or organic particles;
optionally, the inorganic particles comprise one or more of alumina, zirconia, calcium carbonate spheres, glass beads, silica, iron, copper, aluminum, gold, platinum, magnesium silicate, or calcium sulfate;
optionally, the organic particulate comprises one or more of cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, sucrose powder, dextrin, lactose, powdered sugar, glucose, mannitol, starch, methyl cellulose, ethyl cellulose, polylactic acid, polyethylene, polypropylene, polyhydroxybutyrate, poly-epsilon-caprolactone, polyglycolic acid, polyhydroxyalkanoate, or a starch-based thermoplastic resin;
optionally, the active particles are capable of adsorbing nicotine in the smoke aerosol by more than or equal to 3.0mg/cm3The particles of (a);
optionally, the active particles comprise one or more of molecular sieves, activated carbon, diatomaceous earth, zeolite, perlite, ceramics, sepiolite, fuller's earth, ion exchange resins;
optionally, the outer coating layer is a film-forming material;
optionally, the film-forming material comprises one or more of cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylcellulose, ethylcellulose, polyvinylpyrrolidone, polyvinyl alcohol diethylamine acetate, styrene maleic acid copolymer, styrene-vinylpyridine copolymer, cellulose acetate phthalate, hydroxypropylmethylcellulose phthalate, cellulose acetate/polyethylene glycol, methylcellulose/polyethylene glycol, carboxymethylcellulose/polyethylene glycol, hydroxypropylmethylcellulose/polyethylene glycol, ethylcellulose/polyethylene glycol, acrylic resin/polyethylene glycol, or polylactic acid;
optionally, the outer coating contains a flavoring agent;
alternatively, the flavoring agent for the film coating comprises an edible flavor or tobacco extract;
optionally, the edible essence is at least one of a citrus type essence, a fruit type essence, a mint type essence, a bean type essence, a spice type essence, a milk type essence, a meat type essence, a coffee type essence, a nut type essence, an alcohol type essence, a vegetable type essence;
optionally, the particle shape comprises one or more of a sphere, a spheroid, a pie, a flake, a ribbon, an acicular, a polygonal shape, a faceted shape, or a random shape;
optionally, the particles have an average diameter in at least one dimension of from a lower limit of 50 microns, 100 microns, 150 microns, 200 microns, or 250 microns to an upper limit of 5000 microns, 2000 microns, 1000 microns, 900 microns, or 700 microns.
10. The preparation method of the flavor-enhancing and temperature-reducing particles for tobacco as claimed in claim 9, characterized by comprising the following steps:
(1) mixing active/inactive powder, flavoring agent and adhesive solution to prepare wet material;
(2) extruding and cutting the wet material obtained in the step (1) into smooth and compact cylindrical strips with the same diameter by adopting a wet extrusion granulation process, and carrying out rounding molding on the prepared cylindrical strips in a rounding machine to obtain initial wet granules;
(3) drying the initial wet granules, removing water to obtain active/inactive flavored granules.
11. The preparation method of the flavor enhancing and temperature reducing granule for tobacco as claimed in claim 10, characterized in that: the adhesive in the step (1) comprises more than one of hydroxypropyl methylcellulose aqueous solution, pregelatinized starch aqueous solution or sodium carboxymethyl cellulose;
optionally, the concentration of the hydroxypropyl methylcellulose aqueous solution or the pregelatinized starch aqueous solution is 8-12%;
optionally, the mass ratio of the binder to the powder in the step (1) is (1.0-1.2): 1; the mass ratio of the natural fragrant powder to the total powder is as follows: 0.2-1.0;
optionally, the flavoring agent powder in step (1) is a natural flavoring material including clove, tobacco, coffee bean, cocoa, cinnamon, mint, vanilla, tea, green tea, black tea, bay leaves, citrus peel, orange, lemon, lime, grapefruit, cumin, paprika, chili pepper, red pepper, eucalyptus, mint, curry, anise, dill, fennel, allspice, basil, rosemary, pepper, caraway seed, coriander leaf, garlic, mustard, nutmeg, thyme, turmeric, oregano, other spices, hops, other grains, sugar and any combination thereof; the average grain diameter of the ground powder is less than or equal to 75 microns;
optionally, the rotary extrusion granulator in step (2) is fed at a speed of 23-25rpm and extruded at a speed of 25-30 rpm;
optionally, the spheronizer in step (2) works at 600-;
optionally, the preparation method of the particles for flavoring and cooling the outer coating layer for the cigarette comprises the following steps:
(1) coating the surface of the particles with a coating solution by a fluidized bed coating method to form a solid-solid composite phase-change aroma-enhancing coating film layer to obtain initial wet particles;
(2) heating and drying to remove the solvent on the surfaces of the initial wet particles to obtain initial particles;
(3) screening to obtain coated particles;
optionally, the coating solution in the step (1) is more than one of water-soluble coating solution, ethanol coating solution or acetone coating solution;
optionally, the water-soluble coating solution comprises more than one of hydroxypropyl methylcellulose/polyethylene glycol aqueous solution, carboxymethyl cellulose/polyethylene glycol aqueous solution or acrylic resin/polyethylene glycol aqueous solution; the solvent is water; the molecular weight of the polyethylene glycol is 1000-;
optionally, the mass concentration of the water-soluble coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass; the essence and spice accounts for 0.1-2% of the total coating liquid;
optionally, the ethanol coating solution comprises an ethyl cellulose/polyethylene glycol ethanol solution; the solvent is 95% ethanol; the molecular weight of the polyethylene glycol is 1000-;
optionally, the mass concentration of the ethanol coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass. The essence and spice accounts for 0.1-2% of the total coating liquid;
optionally, the acetone coating solution comprises more than one of a cellulose diacetate/polyethylene glycol acetone solution or a cellulose acetate butyrate/polyethylene glycol acetone solution; the solvent is acetone; the molecular weight of the polyethylene glycol is 1000-;
optionally, the mass concentration of the acetone coating solution is 3.5-6.5%; the polyethylene glycol accounts for 20-50% of the coating liquid by mass. The essence and spice accounts for 0.1-2% of the total coating liquid;
optionally, the coating film layer in the step (1) accounts for 0-50% of the mass of the whole granule;
optionally, the inlet air temperature of the fluidized bed in the step (1) is 40-60 ℃; the material temperature is 30-45 ℃; the diameter of the spray nozzle of the spray gun is 1.0 mm; the atomization pressure is 0.15-0.20 MPa; the flow rate of the pump liquid of the peristaltic pump is 5-15 r/min.
12. The preparation method of the flavoring and cooling particles for cigarettes according to claim 2, characterized by comprising the following steps: mixing the fragrant substance powder with cellulose and derivative powder, and preparing the aroma-enhancing and cooling granules by a wet extrusion spheronization process.
13. The preparation method of the flavoring and cooling particles for cigarettes according to claim 12, wherein the preparation method comprises the following steps:
wet grinding cellulose and derivatives into powder with average particle size of 75 μm or less; grinding the flavor substance into powder with average particle size of 75 μm or less by pulverizing and dry grinding; respectively weighing the cellulose, the derivative powder and the fragrant substance powder, adding a hydroxypropyl methyl cellulose aqueous solution, and fully and uniformly stirring on a laboratory wet mixer to obtain wet materials; carrying out wet extrusion granulation on the prepared soft wet material on a wet extruder to obtain a cylindrical strip-shaped object; rounding the cylindrical strip-shaped object on a rounding machine to obtain wet spherical particles; freeze-drying the wet spherical particles to remove water to obtain dried particles; sieving to obtain the flavoring granule with required particle size.
14. The preparation method of the flavoring and cooling particles for cigarettes according to claim 13, wherein the preparation method comprises the following steps: wherein: the dosage ratio of the cellulose and derivative powder, the flavor substance powder and the hydroxypropyl methylcellulose is as follows: (0-0.72): (0.20-0.92): 0.08.
15. the preparation method of the flavoring and cooling particles for cigarettes of claim 6, which is characterized by comprising the following steps: preparing cellulose and derivative particles by using cellulose and derivative powder as materials through a wet extrusion spheronization process; then coating a layer containing the flavor substances on the surfaces of the cellulose and derivative particles by a fluidized film coating mode.
16. The preparation method of the flavoring and cooling particles for cigarettes according to claim 12, wherein the preparation method comprises the following steps:
wet grinding cellulose and derivatives into powder with average particle size of 75 μm or less; weighing the cellulose and derivative powder, adding hydroxypropyl methylcellulose aqueous solution, and fully and uniformly stirring on a laboratory wet mixer to obtain a wet material; carrying out wet extrusion granulation on the prepared soft wet material on a wet extruder to obtain a cylindrical strip-shaped object; rounding the cylindrical strip-shaped object on a rounding machine to obtain wet spherical particles; removing moisture from the wet spherical particles to obtain dry primary particles; performing film coating on the primary particles by using a bottom jet fluidized bed; after coating, drying the water on the surface of the particles; taking out, sieving to obtain the aroma-enhancing and temperature-reducing granules with the required particle size.
17. The preparation method of the flavoring and cooling particles for cigarettes according to claim 16, wherein the preparation method comprises the following steps: the dosage of the coating liquid is controlled, so that the coating film accounts for 5 to 15 percent of the mass of the final particles.
18. The preparation method of the flavoring and cooling particles for cigarettes according to claim 16, wherein the preparation method comprises the following steps: the particle bulk density of the cooling particles is 0.50g/mL-0.52 g/mL.
19. The preparation method of the flavoring and cooling particles for cigarettes according to claim 16, wherein the preparation method comprises the following steps: the concentration of the coating liquid is 5.0 percent; the main components are hydroxypropyl methylcellulose and polyethylene glycol 6000, and the solvent is water; wherein the proportion of polyethylene glycol in the main component is 30%, and the proportion of the fragrance substance in the main component is 0.2% -0.6%.
20. Use of the flavored cooling particles for cigarettes according to any one of claims 1 to 9 in cigarettes.
21. The use of the flavoring and cooling particles for cigarettes according to claim 20, wherein the flavoring and cooling particles comprise: 40-60mg of the aroma-enhancing and temperature-reducing particles are added into each cigarette filter stick.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011189272.2A CN112273717A (en) | 2020-10-30 | 2020-10-30 | Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011189272.2A CN112273717A (en) | 2020-10-30 | 2020-10-30 | Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112273717A true CN112273717A (en) | 2021-01-29 |
Family
ID=74354244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011189272.2A Pending CN112273717A (en) | 2020-10-30 | 2020-10-30 | Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112273717A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112890270A (en) * | 2021-03-31 | 2021-06-04 | 云南巴菰生物科技有限公司 | Sweetening granule for heating non-burning cigarette and preparation method thereof |
| CN113303492A (en) * | 2021-06-16 | 2021-08-27 | 云南养瑞科技集团有限公司 | Spherical aroma-enhancing tobacco particles and preparation method thereof |
| CN113679101A (en) * | 2021-09-09 | 2021-11-23 | 云南长宜科技有限公司 | Dual-cooling particle |
| CN114027541A (en) * | 2021-11-02 | 2022-02-11 | 江苏大亚滤嘴材料有限公司 | Preparation method of tobacco fragrant granules |
| CN115644491A (en) * | 2022-10-20 | 2023-01-31 | 云南中烟新材料科技有限公司 | Tea flavor particle for cigarette filter stick and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101707899A (en) * | 2007-06-07 | 2010-05-12 | 韩国烟草人参公社 | The cigarette filters comprising natural herb material and its cigarette |
| CN102835736A (en) * | 2012-10-12 | 2012-12-26 | 云南绅博源生物科技有限公司 | Granular material for cigarette filter stick and preparation method of granular material |
| CN102892316A (en) * | 2010-03-26 | 2013-01-23 | 菲利普莫里斯生产公司 | Plug space plug filter with flavor bead |
| CN103932394A (en) * | 2013-01-23 | 2014-07-23 | 湖南中烟工业有限责任公司 | Multi-section composite cigarette filtering stick, preparation method thereof and application of turgid plant granules |
| CN104705785A (en) * | 2015-01-23 | 2015-06-17 | 南通醋酸纤维有限公司 | Cellulose acetate particle aggregation body and preparing method and application thereof |
| CN109700070A (en) * | 2019-03-01 | 2019-05-03 | 南通醋酸纤维有限公司 | A kind of particle and its preparation method and application that can reduce cigarette smoke temperature |
| CN110250565A (en) * | 2019-06-10 | 2019-09-20 | 江西中烟工业有限责任公司 | A kind of plant granule perfume (or spice) pearl and the preparation method and application thereof |
-
2020
- 2020-10-30 CN CN202011189272.2A patent/CN112273717A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101707899A (en) * | 2007-06-07 | 2010-05-12 | 韩国烟草人参公社 | The cigarette filters comprising natural herb material and its cigarette |
| CN102892316A (en) * | 2010-03-26 | 2013-01-23 | 菲利普莫里斯生产公司 | Plug space plug filter with flavor bead |
| CN102835736A (en) * | 2012-10-12 | 2012-12-26 | 云南绅博源生物科技有限公司 | Granular material for cigarette filter stick and preparation method of granular material |
| CN103932394A (en) * | 2013-01-23 | 2014-07-23 | 湖南中烟工业有限责任公司 | Multi-section composite cigarette filtering stick, preparation method thereof and application of turgid plant granules |
| CN104705785A (en) * | 2015-01-23 | 2015-06-17 | 南通醋酸纤维有限公司 | Cellulose acetate particle aggregation body and preparing method and application thereof |
| CN109700070A (en) * | 2019-03-01 | 2019-05-03 | 南通醋酸纤维有限公司 | A kind of particle and its preparation method and application that can reduce cigarette smoke temperature |
| CN110250565A (en) * | 2019-06-10 | 2019-09-20 | 江西中烟工业有限责任公司 | A kind of plant granule perfume (or spice) pearl and the preparation method and application thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112890270A (en) * | 2021-03-31 | 2021-06-04 | 云南巴菰生物科技有限公司 | Sweetening granule for heating non-burning cigarette and preparation method thereof |
| CN113303492A (en) * | 2021-06-16 | 2021-08-27 | 云南养瑞科技集团有限公司 | Spherical aroma-enhancing tobacco particles and preparation method thereof |
| CN113679101A (en) * | 2021-09-09 | 2021-11-23 | 云南长宜科技有限公司 | Dual-cooling particle |
| CN113679101B (en) * | 2021-09-09 | 2023-10-13 | 云南长宜科技有限公司 | Dual cooling granule |
| CN114027541A (en) * | 2021-11-02 | 2022-02-11 | 江苏大亚滤嘴材料有限公司 | Preparation method of tobacco fragrant granules |
| CN115644491A (en) * | 2022-10-20 | 2023-01-31 | 云南中烟新材料科技有限公司 | Tea flavor particle for cigarette filter stick and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112273717A (en) | Aroma-enhancing and cooling particles for cigarettes, and preparation method and application thereof | |
| JP5323064B2 (en) | Tobacco filters made from natural herb plants and tobacco using the same | |
| CN112273718A (en) | Structure capable of enhancing aroma and reducing cigarette smoke temperature, preparation method and application | |
| CN109700070B (en) | Particle capable of reducing cigarette smoke temperature and preparation method and application thereof | |
| CN110250565A (en) | A kind of plant granule perfume (or spice) pearl and the preparation method and application thereof | |
| CN109123775B (en) | Heating non-combustion cigarette containing herbal fragrance type solid aromatic beads and preparation method thereof | |
| CN110013806B (en) | Graphene-plant porous composite microsphere and preparation method and application thereof | |
| JP7164097B2 (en) | Functional cigarette filter containing natural plant material, tobacco, and method for producing the same | |
| CN107156903B (en) | Cigarette filter tip particle material with double-layer structure and manufacturing method thereof | |
| CN109198721A (en) | A kind of middle branch cigarette filter tip and preparation method thereof containing bulky grain solid-state perfume (or spice) pearl | |
| CN108936788A (en) | A kind of tobacco particle with cooling flavouring function | |
| CN101108027A (en) | Application of expanded cabo particle in cigarette filter tip | |
| CN109730355B (en) | Preparation method of aroma-enhancing particles for cigarette filter stick | |
| KR100984681B1 (en) | The cigarette filters added natural herb granules | |
| CN114766718A (en) | Cigarette aroma-carrying particle, preparation method and application thereof | |
| CN110226774B (en) | Dry cigarette bead tip rod capable of improving sweet feeling of cigarettes | |
| CN103689796B (en) | Lemon grass porous particle and application thereof to cigarettes | |
| CN103704882B (en) | Cocoa shell porous particles and application thereof in cigarettes | |
| CN103689795B (en) | Peony porous particle and application thereof to cigarettes | |
| CN109875114A (en) | A kind of cigarette functional microsphere and the preparation method and application thereof with nucleocapsid interlayer structure | |
| CN111084417B (en) | Preparation method and application of cigarette filter stick aroma-enhancing ball | |
| JPH0230261B2 (en) | ||
| CN103689794A (en) | Pelargonium graveolens porous particle and application thereof to cigarette | |
| CN115039911A (en) | Natural plant essence carrier for cigarette, cigarette filter stick and cigarette cartridge | |
| CN110946325B (en) | Filter stick flavoring particle with natural substance as carrier and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210129 |
|
| RJ01 | Rejection of invention patent application after publication |