CN105670760A - High-performance cutting fluid - Google Patents
High-performance cutting fluid Download PDFInfo
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- CN105670760A CN105670760A CN201610113075.XA CN201610113075A CN105670760A CN 105670760 A CN105670760 A CN 105670760A CN 201610113075 A CN201610113075 A CN 201610113075A CN 105670760 A CN105670760 A CN 105670760A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses high-performance cutting fluid. The high-performance cutting fluid is prepared from a mixture of sodium carbonate and sodium bicarbonate, acetic acid, borax, sodium silicate, trimethyl borate, dimethicone, pentaerythrityl, sodium diphenylaminesulfonate, sodium dodecyl benzene sulfonate and water. The cutting fluid has high lubricating and anti-friction performance, and the difficulty in entering kerfs is lowered for the cutting fluid. By means of adding the mixture of sodium carbonate and sodium bicarbonate into the cutting fluid, the cutting fluid has high redispersibility, and is easy for cleaning and subsequent treatment. Through coordination of sodium diphenylaminesulfonate and sodium dodecyl benzene sulfonate, the inhibition rate of the cutting fluid is increased greatly. Through pretreatment of the dimethicone, the anti-foaming property of the cutting fluid can be increased, the smoothness of a machined part is high, the machining accuracy is increased greatly, the tool life is prolonged, the production cost is lowered greatly, and the economic benefit is increased.
Description
Technical field
The present invention relates to coolant technical field, particularly relate to a kind of high-performance cutting fluid.
Background technology
Cutting fluid is that one is used in metal cutting, the mill course of processing, it is used for cooling down and lubricating the industrial type fluid of cutter and workpiece, cutting fluid is formed with science compound from multiple super strong functional auxiliary agent, is provided simultaneously with good cooling performance, greasy property, rustless property, fuel-displaced cleaning function, anti-corrosion function easily dilutable feature. But, present most enterprises, take a fancy to the action effect of cutting fluid by all means, and do not go the feature of environmental protection considering to use cutting fluid, after cutting fluid lost efficacy, the cutting fluid that arbitrarily discharge is discarded, causes substantial amounts of pollution to environment. Additionally, many cutting fluids, under the environment of high speed or heavy duty cutting, can produce high-temperature chemical reaction, form harmful vapors and mist of oil, not only contaminated environment also causes damage to processing staff is healthy.
Summary of the invention
It is an object of the invention to provide a kind of high-performance cutting fluid.
The present invention is achieved through the following technical solutions:
A kind of high-performance cutting fluid, it is made up of following component by weight, sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water.
Further, described sodium carbonate is 3:1 with the mixed proportion of sodium bicarbonate.
Further, described Borax processes through forging in advance at 350 DEG C, and the time is 20 minutes.
Further, described dimethicone is through pretreatment: is mixed with dimethicone with the mixture of octamethylcy-clotetrasiloxane by the MTES that total weight parts is 1 part, is at 75 DEG C in temperature, reacts 1-2 hour; Described MTES mixes in 1:4 ratio with octamethylcy-clotetrasiloxane.
Further, the Borax after forging and sodium silicate are carried out premixing, add the water that weight portion is 15 parts, heat 55-65 DEG C, continue 15 minutes.
The preparation method of a kind of high-performance cutting fluid, comprises the following steps:
1) weigh by weight: sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water;
2) first adding water in reactor, then add diphenylamine sulfonic acid sodium salt and dodecylbenzene sodium sulfonate, heating is to 55 DEG C;
3) to 2) in add sodium carbonate and sodium bicarbonate mixture, through the dimethicone of pretreatment, sodium acetate, methyl borate. and four seasons amylalcohol, heating is to 75 DEG C;
4) to 3) in add Borax and sodium silicate aqueous mixtures through premix, heating is to 110 DEG C, and after stirring 1 hour with 200 revs/min of speed, is cooled to room temperature.
The invention has the beneficial effects as follows, compared with prior art:
Cutting fluid of the present invention has good lubrication, good cooling and splendid anti-wear performance, greatly reduces cutting fluid and enters the difficulty in joint-cutting. Make cutting fluid have good redispersion characteristic by adding sodium carbonate in cutting fluid with sodium bicarbonate mixture, be readily cleaned and subsequent treatment. Synergism by diphenylamine sulfonic acid sodium salt and dodecylbenzene sodium sulfonate so that the corrosion inhibition rate of cutting fluid is greatly improved. By the Borax after forging and sodium silicate are carried out premixing process so that cutting fluid antibiotic property is good, not easily goes mouldy, and life cycle is long, will not stink within the long time, human body is harmless. By the pretreatment of methyl-silicone oil can improve the anti-foaming property of cutting fluid, workpiece fineness is good, and machining accuracy is greatly improved, and extends cutter life, very big reduces production cost, improves economic benefit.
Detailed description of the invention
A kind of high-performance cutting fluid, it is made up of following component by weight, sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water.
Further, described sodium carbonate is 3:1 with the mixed proportion of sodium bicarbonate.
Further, described Borax processes through forging in advance at 350 DEG C, and the time is 20 minutes.
Further, described dimethicone is through pretreatment: is mixed with dimethicone with the mixture of octamethylcy-clotetrasiloxane by the MTES that total weight parts is 1 part, is at 75 DEG C in temperature, reacts 1-2 hour; Described MTES mixes in 1:4 ratio with octamethylcy-clotetrasiloxane.
Further, the Borax after forging and sodium silicate are carried out premixing, add the water that weight portion is 15 parts, heat 55-65 DEG C, continue 15 minutes.
The preparation method of a kind of high-performance cutting fluid, comprises the following steps:
1) weigh by weight: sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water;
2) first adding water in reactor, then add diphenylamine sulfonic acid sodium salt and dodecylbenzene sodium sulfonate, heating is to 55 DEG C;
3) to 2) in add sodium carbonate and sodium bicarbonate mixture, through the dimethicone of pretreatment, sodium acetate, methyl borate. and four seasons amylalcohol, heating is to 75 DEG C;
4) to 3) in add Borax and sodium silicate aqueous mixtures through premix, heating is to 110 DEG C, and after stirring 1 hour with 200 revs/min of speed, is cooled to room temperature.
Cutting fluid highly versatile of the present invention, can be suitable for processing technique such as the turning of the non-ferrous metals such as the ferrous metal such as various carbon steels, steel alloy, cast iron and aluminium alloy, kirsite, titanium alloy, milling, boring, bore hole, grindings. Cutting fluid of the present invention is best to the corrosion mitigating effect of carbon steel, up to 98.34%.
Claims (6)
1. a high-performance cutting fluid, it is characterized in that, it is made up of following component by weight, sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water.
2. a kind of high-performance cutting fluid according to claim 1, it is characterised in that the mixed proportion of described sodium carbonate and sodium bicarbonate is 3:1.
3. a kind of high-performance cutting fluid according to claim 1, it is characterised in that described Borax processes through forging in advance at 350 DEG C, and the time is 20 minutes.
4. a kind of high-performance cutting fluid according to claim 1, it is characterized in that, described dimethicone is through pretreatment: is mixed with dimethicone with the mixture of octamethylcy-clotetrasiloxane by the MTES that total weight parts is 1 part, is at 75 DEG C in temperature, reacts 1-2 hour; Described MTES mixes in 1:4 ratio with octamethylcy-clotetrasiloxane.
5. a kind of high-performance cutting fluid according to claim 1, it is characterised in that the Borax after forging and sodium silicate are carried out premixing, adds the water that weight portion is 15 parts, heat 55-65 DEG C, continue 15 minutes.
6. the preparation method of a high-performance cutting fluid, it is characterised in that comprise the following steps:
1) weigh by weight: sodium carbonate and sodium bicarbonate mixture 30 parts, sodium acetate 3 parts, Borax 5 parts, sodium silicate 10 parts, methyl borate. 4 parts, dimethicone 50 parts, tetramethylolmethane 8 parts, diphenylamine sulfonic acid sodium salt 8 parts, dodecylbenzene sodium sulfonate 10 parts, 100 parts of water;
2) first adding water in reactor, then add diphenylamine sulfonic acid sodium salt and dodecylbenzene sodium sulfonate, heating is to 55 DEG C;
3) to 2) in add sodium carbonate and sodium bicarbonate mixture, through the dimethicone of pretreatment, sodium acetate, methyl borate. and four seasons amylalcohol, heating is to 75 DEG C;
4) to 3) in add Borax and sodium silicate aqueous mixtures through premix, heating is to 110 DEG C, and after stirring 1 hour with 200 revs/min of speed, is cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610113075.XA CN105670760A (en) | 2016-03-01 | 2016-03-01 | High-performance cutting fluid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610113075.XA CN105670760A (en) | 2016-03-01 | 2016-03-01 | High-performance cutting fluid |
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| CN105670760A true CN105670760A (en) | 2016-06-15 |
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| CN201610113075.XA Pending CN105670760A (en) | 2016-03-01 | 2016-03-01 | High-performance cutting fluid |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106978244A (en) * | 2017-03-28 | 2017-07-25 | 常州大学 | A kind of preparation method of Environment-friendlycorrosion-resistant corrosion-resistant type cutting fluid |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1548505A (en) * | 2003-05-24 | 2004-11-24 | 启东尤希路化学工业有限公司 | Water soluble cutting fluid |
| CN103409221A (en) * | 2013-07-02 | 2013-11-27 | 昌利锻造有限公司 | Metal machining liquid and preparation method thereof |
| CN103695144A (en) * | 2013-12-07 | 2014-04-02 | 马鞍山市力鑫机械制造有限公司 | Semi-synthetic metal cutting liquid and preparation method thereof |
| CN104403772A (en) * | 2014-10-13 | 2015-03-11 | 巢湖广丰金属制品有限公司 | High-performance metal cutting fluid |
| CN104450139A (en) * | 2014-11-20 | 2015-03-25 | 无锡鸿声铝业有限公司 | Water-based aluminum alloy cutting fluid |
-
2016
- 2016-03-01 CN CN201610113075.XA patent/CN105670760A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1548505A (en) * | 2003-05-24 | 2004-11-24 | 启东尤希路化学工业有限公司 | Water soluble cutting fluid |
| CN103409221A (en) * | 2013-07-02 | 2013-11-27 | 昌利锻造有限公司 | Metal machining liquid and preparation method thereof |
| CN103695144A (en) * | 2013-12-07 | 2014-04-02 | 马鞍山市力鑫机械制造有限公司 | Semi-synthetic metal cutting liquid and preparation method thereof |
| CN104403772A (en) * | 2014-10-13 | 2015-03-11 | 巢湖广丰金属制品有限公司 | High-performance metal cutting fluid |
| CN104450139A (en) * | 2014-11-20 | 2015-03-25 | 无锡鸿声铝业有限公司 | Water-based aluminum alloy cutting fluid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106978244A (en) * | 2017-03-28 | 2017-07-25 | 常州大学 | A kind of preparation method of Environment-friendlycorrosion-resistant corrosion-resistant type cutting fluid |
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Application publication date: 20160615 |