CN105640826A - Three-layer anti-hair loss hair conditioner - Google Patents

Three-layer anti-hair loss hair conditioner Download PDF

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Publication number
CN105640826A
CN105640826A CN201511033283.0A CN201511033283A CN105640826A CN 105640826 A CN105640826 A CN 105640826A CN 201511033283 A CN201511033283 A CN 201511033283A CN 105640826 A CN105640826 A CN 105640826A
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hair
hair conditioner
silicon layer
layers
water layer
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CN201511033283.0A
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CN105640826B (en
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曹虎均
晏金
陈国祥
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Hangzhou Sincere Cosmetics Co Ltd
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Hangzhou Sincere Cosmetics Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03Liquid compositions with two or more distinct layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20Halogens; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645Proteins of vegetable origin; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q7/00Preparations for affecting hair growth

Abstract

The invention discloses a three-layer anti-hair loss hair conditioner. The three-layer anti-hair loss hair conditioner comprises a silicon oil layer, a water layer and a natural oil layer, wherein the silicon oil layer is prepared from the following ingredients in parts by weight: 0.5 to 5.5 parts of amodimethicone, 0.5 to 5.5 parts of bis(C13-15 alkoxyl)PG-amodimethicone, 3 to 8 parts of phenyl trimethicone, 10 to 20 parts of cyclomethicone and 10 to 20 parts of polydimethylsiloxane. The three-layer anti-hair loss hair conditioner disclosed by the invention has the beneficial effects that the glossiness of hairs can be remarkably increased, and the glossiness of the hairs still can be kept after the hairs get wet in the rain.

Description

Three layers of anti-depilation hair conditioner
Technical field
The present invention relates to a kind of washing product, in particular to a kind of three layers of anti-depilation hair conditioner.
Background technology
Hair conditioner uses in pairs also known as profit silk, general and shampoo. After hair washing, appropriate hair conditioner is evenly spread upon on hair, gently rub about one minute, therefore also have person to be rinsing conditioner, belong to hair cosmetic.
The Chinese patent that publication number is 105055209A discloses a kind of anti-de-hair conditioner and its preparation method. Although this anti-de-hair conditioner has good anti-de-effect, and the effect such as physiological well-being of promoting blood circulation and removing blood stasis, Cucumber Extract, repairing hair follicle, protection brain can be played, but the glossiness of hair quality is promoted limited and after drenching with rain the glossiness of hair quality cannot keep.
Summary of the invention
It is an object of the invention to provide a kind of three layers of anti-depilation hair conditioner. These three layers anti-depilation hair conditioner can significantly promote the glossiness of hair quality and the glossiness of hair quality still can be kept after drenching with rain.
The above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of three layers of anti-depilation hair conditioner, comprise silicon layer, water layer and natural oil reservoir, and described silicon layer comprises the component of following weight part number:
Described water layer comprises the material of following weight part number:
The thorn A Gan tree benevolence oil of described natural oil reservoir to be weight part be 10-25 part.
Described silicon layer also comprises the first additive that weight part is 0.2-1.5 part; Described first additive is made up of glucono-lactone and Sodium Benzoate, and the weight ratio of glucono-lactone and Sodium Benzoate is 1: 0.5-2.
Described water layer also comprises the Second addition that weight part is 0.85-1.35 part; Described Second addition is made up of oxalic acid tetraacethyl disodium and sodium-chlor, and the weight ratio of oxalic acid tetraacethyl disodium and sodium-chlor is 1: 40-65.
Described silicon layer, water layer and natural oil reservoir three layers under, be followed successively by natural oil reservoir, silicon layer, water layer.
A preparation method for three layers of anti-depilation hair conditioner, comprises the steps:
Step1: prepare silicon layer, water layer, natural oil reservoir respectively;
Silicon layer: according to weight part, weigh or measure ammonia end polydimethylsiloxane 0.5-5.5 part, two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane 0.5-5.5 part, phenyl poly-trimethylammonium siloxanes 3-8 part, ring polydimethylsiloxane 10-20 part, polydimethylsiloxane 10-20 part, first additive 0.2-1.5 part, then the component Homogeneous phase mixing that will obtain;
Water layer: according to weight part, weighs or measures water 35-45 part, hydrolysis lupin protein 0.5-3.5 part, Herba Houttuyniae extract 0.5-3.5 part, glycerine 0.5-5 part, Second addition 0.85-1.35 part, then the component Homogeneous phase mixing that will obtain;
Natural oil reservoir: according to weight part, measures thorn A Gan tree benevolence oil 10-25 part;
Step2: first add water layer, slowly adds silicon layer after leaving standstill again, adds natural oil reservoir again after again leaving standstill.
Adding the time of repose after water layer is 10min, and adding the time of repose after silicon layer is 30min.
The present invention has following useful effect:
Using thorn A Gan tree benevolence oily in I natural oil reservoir, Ah's glycerine is rich in the unsaturated fatty acidss such as omega3 and omega9, so it can easily by dry absorption with repair impaired hair and hair follicle; Can well increase gloss hair; The hair oil being different from other, thorn A Gan tree benevolence is greasy, can stop curly headed and distribute arbituarily; Ci A dry tree benevolence oil does not stimulate, and can help softening hair; For tackling those hairs because using other chemical products impaired; Ci A dry tree benevolence oil can be absorbed by hair at once, recovers the moisture of hair; It also can as a harmful ultraviolet protective layer, and protection hair is not by environmental pollution; Because the high-content of vitamin-E of thorn A Gan tree benevolence oil, it also has in natural on-off cycles of hair growth and acts on very significantly; Help to suppress hair bifurcated and hair loss;
Containing multiple silicone oil composition in II silicon layer, silicone oil can fill up the gap of hair hair scale sheet, significantly improves the glossiness of hair quality. In addition, silicone oil is insoluble in water, thus silicone oil is adsorbed on hair, thus when people need sometimes in the rain, the hair quality of people still has good glossiness;
Ammonia end polydimethylsiloxane in III silicon layer and two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane are all containing cation group, and mostly contain anion surfactant in shampoo. Therefore, after people wash hair, it is possible to remain in the anionic group of hair surface with hair conditioner provided by the invention neutralization, thus form neutral film, cover hair surface, make hair submissive, be easy to combing, avoid hair crude;
IV glucono-lactone is made up of hydrophilic hydroxy group group. It can strengthen the adsorptive power to moisture in hair surface and glycerine acting in conjunction, and glucono-lactone strong adsorption moisture also produces a kind of natural substrates gel. The film of its uniqueness forms function and provides gratifying softness and smooth sensation. In addition glucono-lactone can catch free radical, thus plays when hair plays the provide protection to hair when uviolizing;
V water layer is hydrolyzed lupin protein and hair can be moistened by Herba Houttuyniae extract, to hair quality nutrition; Herba Houttuyniae taste is pungent, cold in nature cool, returns lung channel. Clearing heat and detoxicating, detumescence can treat sore, promoting urination and removing dampness, clearing away heat to cure dysentery, stomach strengthening and digestion promoting, with controlling real heat, lung carbuncle that heat poison, damp evil, disease heat are trouble, sore swollen toxin, hemorrhoidal hemorrhage, retention of heat in the spleen and stomach etc. Modern pharmacology experiment shows, this product has antibacterial, antiviral, the raising effect such as immunity of organisms, diuresis. Hydrolysis lupin protein has good antioxidant property, it is possible to strengthen the antioxidant property of hair fiber; Hydrolysis lupin protein and Herba Houttuyniae extract play synergy, promote the anti-alopecia performance of hair conditioner and glossiness performance and glossiness retention;
VI oxalic acid tetraacethyl disodium on the one hand can calcium ion in Bound moisture and magnesium ion, reduce because the poor water quality in some areas is to the deleterious effect of hair, on the other hand with Sodium Benzoate synergy, strengthen supporting antibacterial activity, especially Gram-negative bacteria can be produced better effect.And the enhancing of anti-microbial property can be reduced the use of Sodium Benzoate by oxalic acid tetraacethyl disodium, reduce the stimulation to human body and sensitization; Oxalic acid tetraacethyl disodium inherently can regulate the potential of hydrogen of hair conditioner, enables in the potential of hydrogen human body optimum range of hair conditioner, and reducing skin is stimulated;
VII is in water layer, and sodium-chlor can increase the viscosity effect of hair conditioner system, and the solubleness of sodium-chlor in water is easy to get more greatly and cheaply, it is possible to reduce production cost. In addition, sodium-chlor is human body picked-up every day, and therefore human body is stimulated less, also safer by sodium-chlor;
VIII natural oil reservoir is positioned at upper strata, silicon layer is positioned at middle level, water layer is positioned at lower floor, water layer is positioned at lower floor, fully and hair contact, the moisture that the material that the multiple water absorbing properties contained in water layer is good can firmly pin in hair, avoid hair quality dry, natural oil reservoir is positioned at upper strata, can play ultraviolet protection, and silicon layer is positioned at middle level, there is good water resistance, prevent moisture from entering silicon layer from water layer on the one hand, reduce moisture loss, prevent moisture from entering from outside on the other hand, hair conditioner also can be fitted with hair quality when drenching with rain, avoid departing from from hair quality at conditioner after marcelling of drenching with rain, cause the glossiness rapid decrease of hair quality.
In sum, the effect that the present invention is total is as follows:
Inventive design is by water layer, silicon layer and natural oil reservoir three layers of hair conditioner formed, and the component and amount ranges to every layer explores the formula drawing hair conditioner, in preparation method, hair conditioner is optimized further, make to produce synergistic effect between each component of hair conditioner, promote the anti-depilation performance of hair conditioner, the glossiness of hair and glossiness retention, antibacterial and antioxidant property after drenching with rain.
Embodiment
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; the present embodiment can be made the amendment not having creative contribution as required by those skilled in the art after reading this specification sheets, but as long as being all subject to the protection of patent law in the right of the present invention.
If no special instructions, the reagent used in the embodiment of the present invention is all purchased from SigmaBiochemicalandOrganicCompoundsforResearchandDiagnos ticClinicalReagents company.
Table 1 embodiment 1-5 specifically forms table
Embodiment 1-5 is prepared in accordance with the following steps.
Step1: prepare silicon layer, water layer, natural oil reservoir respectively;
Silicon layer: according to weight part, weigh or measure ammonia end polydimethylsiloxane, two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane, phenyl poly-trimethylammonium siloxanes, ring polydimethylsiloxane, polydimethylsiloxane, the first additive, then the component Homogeneous phase mixing that will obtain;
Water layer: according to weight part, weighs or measures water, hydrolysis lupin protein, Herba Houttuyniae extract, glycerine, Second addition, then the component Homogeneous phase mixing that will obtain;
Natural oil reservoir: according to weight part, measures thorn A Gan tree benevolence oil;
Step2: first add water layer, slowly adds silicon layer after leaving standstill 10min again, adds natural oil reservoir again after again leaving standstill 30min.
1, anti-alopecia experiment
Choosing the age at one's mid-30s, alopecia rank is at three grades, and 30 woman of the voluntary participation experiment that other physical appearances are healthy and close, be divided into 6 groups at random, be numbered A-F.Wherein A-E group washes a hair in every two days, uses the hair conditioner prepared according to embodiment 1-5 after washing hair respectively every time. As a control group, F group washes a hair in every two days, is not suitable for hair conditioner after washing hair every time. Continue after 60 days, observe the hair loss conditions of 6 groups of men and do record.
The anti-alopecia experimental record table of table 2
Hair increases Hair reduces Hair is without considerable change
A Embodiment 1 ��
B Embodiment 2 �̡�
C Embodiment 3 �̡̡�
D Embodiment 4 ��
E Embodiment 5 ��
F Control group �̡̡�
Note: �� represents that situation exists, and �� number is more many, represents that situation is more obvious.
Observing table 2, find out from control group, for 3 grades of hair loss patients, if not carrying out therapeutic intervention, so its hair loss rate will be very fast. And three grades of hair loss patients can be played the help reducing alopecia by hair conditioner provided by the invention. Wherein, although the situation that hair reduces occurs in the E group adopting embodiment 5, but compared to control group trichomadesis speed, alleviate to some extent, show that embodiment 5 has the effect of anti-alopecia equally. And in 5 groups of embodiments, it is the most obvious that the hair in embodiment 3 increases situation, it is seen that embodiment 3 can obviously suppress alopecia, thus can grow the hair of trip under human body self metabolism.
2, glossiness test
2.1 smear test
Step one: choose 5 hair fibers that hair quality situation is close, thickness is close, smooth out with the fingers and stretch tight on specimen holder after putting down, identical light source is made to inject a branch of parallel light on hair fiber with 45 �� of input angles, normal reflection light is recorded by detector, electrical signal after opto-electronic conversion, through analog to digital conversion, gloss analog quantity is converted to digital quantity, it is shown that the numerical value of gloss;
Step 2: the variance calculating the gloss numerical value that 5 hair fibers draw, if variance value is less than 0.001, then the glossiness of these 5 hair fibers is considered as identical, and average the initial value glossiness as 5 hair fibers and using these 5 hair fibers as one group;
These 5 groups of hair fiber number consecutivelies, until selecting 5 groups of hair fibers, are F-J by step 3: repeating step one and two;
Step 4: the hair conditioner that 5 groups of hair fibers use embodiment 1-5 to prepare respectively is smeared, determine the numerical value of every root hair fiber gloss according to the method described in step one after 10min, and using the mean value of the glossiness of often organizing 5 hair fibers as the final value glossiness of this group hair fiber, compare with initial value glossiness and draw velocity of variation.
Glossiness calculation formula:
G C = C K m Σ j = 1 m ( 1 n Σ i = 1 n l i d j )
In formula: GcHair luster degree
CkThe Color correction factor
liAcquired original data
djThe diameter of-tested hair
2.2 drench with rain test
By smear 5 groups of hair fibers obtaining of test smooth out with the fingers flat after stretch tight on specimen holder, on 5 groups of hairs, evenly drench the rainwater spilling collection, drenching the volumetric flow rate spilt is 1 liter/min, after 3min, blot 5 groups of hair fiber surface rainwater, repeat to smear step one in test and test glossiness, and using the glossiness of the mean value of the glossiness often organizing 5 hair fibers after the drenching with rain of this group hair fiber, with smear test after obtain final value glossiness and compare and draw velocity of variation.
Table 3 is smeared and experimental record table of drenching with rain
Note: use after hair conditioner glossiness velocity of variation and after drenching with rain glossiness velocity of variation calculation formula as follows:
Glossiness velocity of variation=(final value glossiness-initial value glossiness)/initial value glossiness * 100% after use hair conditioner;
Glossiness velocity of variation after drenching with rain=(final value glossiness-drench with rain after glossiness)/final value glossiness * 100%.
As can be seen from Table 3, it may also be useful to after the hair conditioner that embodiment 1-5 provides, the glossiness of hair quality has lifting in various degree. After drenching with rain, although the glossiness of hair quality has decline in various degree, but fall is all less, so even after drenching with rain, it may also be useful to hair conditioner provided by the invention can make hair quality still can keep having good glossiness. From table 3, it can be seen that embodiment 3 glossiness and these two performances of glossiness maintenance degree are all better than other embodiments.
3, test is preserved
3.1 antibacterial experiment
Respectively get the hair conditioner 100ml for preparing according to embodiment 1-5 respectively evenly stand be coated in 100cm2Phase same specification clean open container on. It is 80cfu.mL by e. coli concentration-1Nutrient solution rock after evenly, scribble the container of hair conditioner evenly drips at 5 and add 5ml nutrient solution, 5 containers are placed in a 1m3Airtight cylinder body in, maintain in airtight cylinder body that oxygen concentration is in normal concentration, temperature maintains room temperature, measures intestinal bacteria number after 6h, and calculates intestinal bacteria number velocity of variation.
3.2 anti-oxidant experiments
Respectively get the hair conditioner 100ml for preparing according to embodiment 1-5 respectively evenly stand be coated in 100cm2Phase same specification clean open container on. 5 containers are placed in a 1m3Airtight cylinder body in, maintain in airtight cylinder body that oxygen concentration 3 is doubly to normal concentration, temperature maintains room temperature, observes color change.
Table 4 antibacterial experiment and anti-oxidant experimental record table
Note: intestinal bacteria number velocity of variation=(initial intestinal bacteria number-final value intestinal bacteria number)/initial intestinal bacteria number * 100%
As seen from Table 4, the intestinal bacteria decrement of embodiment 1-5 maintains 79%-90%, therefore can find out that intestinal bacteria are had good restraining effect by the present invention. And at 3 times under the oxygen concentration of normal concentration, the color change of embodiment 1-5 is less, it can be seen that the antioxidant property of the present invention is excellent. Embodiment 3 is all better than other embodiments on anti-microbial property and antioxidant property.
Intestinal bacteria, as conventional experimental bacteria, therefore select intestinal bacteria as the evaluation to embodiment 1-5 anti-microbial property. But, the anti-microbial property of embodiment 1-5 is not limited only to intestinal bacteria, it will be appreciated that for other bacteriums, and the bacterial classification especially belonging to Gram-negative bacteria with intestinal bacteria together all has good anti-microbial property.
From anti-alopecia experiment, glossiness experiment and preservation experiment three experiments, can find out, three layers of anti-depilation hair conditioner provided by the invention are strengthening the anti-depilation performance of hair, the glossiness of hair and glossiness retention after drenching with rain, antibacterial and antioxidant property have good effect, wherein embodiment 3 is all better than other embodiments at the glossiness of anti-depilation performance, hair and glossiness retention after drenching with rain, antibacterial and antioxidant property, shows optimum performance.
Comparative example 1
Publication number is adopted to be the embodiment 5 as a comparison case 1 in the documents of 105055209A.
Step one, with all Chinese medicinal materialss of the clean water of 20 DEG C;
Step 2, all Chinese medicinal materialss are carried out first respectively Mechanical Crushing, after broken, put into the infrared drying case that temperature is 60 DEG C, dry 1h, respectively the Chinese medicinal materials of above-mentioned oven dry is ground after Infrared Heating drying, it is get respectively again after 100 object filter screens filter by granularity: old ginger 11 parts, pseudo-ginseng 6 parts, 7 parts, almond, 11 parts, dried scallop, cassia twig 5 parts, Semen Sesami Nigrum 8 parts, rhizome of chuanxiong 4 parts, matrimony vine 3 parts, Rhizome of Grass leaf Sweelflag 2 parts, Root of Medicinal Cyathula 3 parts and 4 parts, sesame oil are A powder after mixing;
Step 3, adds 400 parts, water in the A powder described in step 2 kind, and the airtight Heating temperature that is heated to be is 75 DEG C, reflux 3 hours;
Step 4, the liquid obtained after being filtered by the mixture obtained in step 3 adds Trimethyllaurylammonium bromide 2 parts successively, is heated to 65 DEG C and stirs 1 hour, adds amino acid/11 part and 0.2 part, essence after being cooled to room temperature again, it is heated to 55 DEG C, stirs cooling after 2 hours and obtain anti-de-hair conditioner.
Comparative example 2 removes the hydrolysis lupin protein in water layer.
Comparative example 3 removes the Herba Houttuyniae extract in water layer.
Comparative example 4 removes the hydrolysis lupin protein in water layer and Herba Houttuyniae extract simultaneously.
Comparative example 5 and comparative example 6 are as shown in the table:
Table 5 comparative example 5 and comparative example 6 specifically form table
Comparative example 2-6 is prepared in accordance with the following steps.
Step1: prepare silicon layer, water layer, natural oil reservoir respectively;
Silicon layer: according to weight part, weigh or measure ammonia end polydimethylsiloxane, two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane, phenyl poly-trimethylammonium siloxanes, ring polydimethylsiloxane, polydimethylsiloxane, the first additive, then the component Homogeneous phase mixing that will obtain;
Water layer: according to weight part, weighs or measures water, hydrolysis lupin protein, Herba Houttuyniae extract, glycerine, Second addition, then the component Homogeneous phase mixing that will obtain;
Natural oil reservoir: according to weight part, measures thorn A Gan tree benevolence oil;
Step2: first add water layer, slowly adds silicon layer after leaving standstill 10min again, adds natural oil reservoir again after again leaving standstill 30min.
The working method tested according to anti-alopecia experiment, glossiness experiment and preservation, chooses embodiment 3 and comparative example 1-6 compares.
The anti-alopecia performance comparison recorder of table 6 embodiment 3 and comparative example 1-6
Hair increases Hair reduces Hair is without considerable change
Embodiment 3 �̡̡�
Comparative example 1 �̡� 8 -->
Comparative example 2 ��
Comparative example 3 ��
Comparative example 4 �̡�
Comparative example 5 �̡̡�
Comparative example 6 �̡�
The glossiness performance of table 7 embodiment 3 and comparative example 1-6 and glossiness retention contrast recorder
The anti-microbial property of table 8 embodiment 3 and comparative example 1-6 and antioxidant property contrast recorder
Can draw to draw a conclusion according in table 6,7,8:
Comparing embodiment 3 and comparative example 1:
In anti-alopecia performance, although embodiment 3 and comparative example 1 all have anti-alopecia performance, but the anti-alopecia performance of embodiment 3 is better than comparative example 1; In glossiness performance and glossiness retention, embodiment 3 is to the lifting of the glossiness performance of hair quality obviously due to comparative example 1, and embodiment 3 is also obviously better than comparative example 1 in the retention of hair quality glossiness performance after drenching with rain; On anti-microbial property and antioxidant property, comparative example 1 is also obviously be weaker than embodiment 3. It thus is seen that the anti-depilation hair conditioner of the present invention three layers is all better than, at anti-alopecia performance, glossiness performance and glossiness retention and anti-microbial property and antioxidant property, the hair conditioner that the documents that publication number is 105055209A mentions.
Comparing embodiment 3, comparative example 2-4:
At anti-alopecia performance, glossiness performance and glossiness retention and anti-microbial property and antioxidant property, the performance of comparative example 2-4 is weaker than embodiment 3. but it is all poorer than comparative example 2 and 3 in the anti-alopecia performance of comparative example 4, it is seen that hydrolysis lupin protein and Herba Houttuyniae extract play synergy, promote the anti-alopecia performance of the present invention, in glossiness performance and glossiness retention, hydrolysis lupin protein and Herba Houttuyniae extract show synergy equally, and the performance of the hair conditioner simultaneously removing hydrolysis lupin protein and Herba Houttuyniae extract is poorer than the hair conditioner removing separately hydrolysis lupin protein or Herba Houttuyniae extract, on anti-microbial property and antioxidant property, remove simultaneously the hydrolysis hair conditioner of lupin protein with Herba Houttuyniae extract anti-microbial property identical with the hair conditioner of separately removal Herba Houttuyniae extract, but it is better than removing separately the hair conditioner of hydrolysis lupin protein, and simultaneously remove hydrolysis the hair conditioner of lupin protein with Herba Houttuyniae extract anti-oxidant and independent remove hydrolysis lupin protein hair conditioner identical, but it is better than removing separately the hair conditioner of Herba Houttuyniae extract, visible Herba Houttuyniae extract has good antimicrobial property, and be hydrolyzed lupin protein and show good antioxidant property.
Comparing embodiment 3, comparative example 5 and 6:
At anti-alopecia performance, glossiness performance and glossiness retention and anti-microbial property and antioxidant property, comparative example 5 and 6 is all obviously poor than embodiment 3, and gap is bigger, it is seen that the amount ranges of each component that the present invention adopts is through what constantly exploration drew.When the consumption of each composition is not in the amount ranges of the present invention, even if identical with the component that the present invention adopts, but performance also there will be bigger deviation, especially when consumption is less than the amount ranges of the present invention, deviation is bigger.
What deserves to be explained is, when using hair conditioner of the present invention, should first rock, after making water layer, silicon layer and natural oil reservoir carry out fully mixing, then smear on hair. When hair conditioner smears on hair, owing to water layer and hair quality bonding force are more firm, therefore water layer and hair quality are close to, and the bonding strength of silicon layer and water layer is better than the bonding strength of natural oil reservoir and water layer, and therefore silicon layer is between water layer and natural oil reservoir.

Claims (8)

1. three layers of anti-depilation hair conditioner, is characterized in that: comprise silicon layer, water layer and natural oil reservoir, and described silicon layer comprises the component of following weight part number:
Ammonia end polydimethylsiloxane 0.5-5.5 part
Two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane 0.5-5.5 part
Phenyl gathers trimethylammonium siloxanes 3-8 part
Ring polydimethylsiloxane 10-20 part
Polydimethylsiloxane 10-20 part.
2. three layers of anti-depilation hair conditioner according to claim 1, is characterized in that: described water layer comprises the material of following weight part number:
Water 35-45 part
Hydrolysis lupin protein 0.5-3.5 part
Herba Houttuyniae extract 0.5-3.5 part
Glycerine 0.5-5 part.
3. three layers of anti-depilation hair conditioner according to claim 2, is characterized in that: the thorn A Gan tree benevolence oil of described natural oil reservoir to be weight part be 10-25 part.
4. three layers of anti-depilation hair conditioner according to claim 1, is characterized in that: described silicon layer also comprises the first additive that weight part is 0.2-1.5 part; Described first additive is made up of glucono-lactone and Sodium Benzoate, and the weight ratio of glucono-lactone and Sodium Benzoate is 1:0.5-2.
5. three layers of anti-depilation hair conditioner according to claim 2, is characterized in that: described water layer also comprises the Second addition that weight part is 0.85-1.35 part; Described Second addition is made up of oxalic acid tetraacethyl disodium and sodium-chlor, and the weight ratio of oxalic acid tetraacethyl disodium and sodium-chlor is 1:40-65.
6. three layers of anti-depilation hair conditioner according to claim 3, is characterized in that: described silicon layer, water layer and natural oil reservoir three layers under, be followed successively by natural oil reservoir, silicon layer, water layer.
7. a preparation method for three layers of anti-depilation hair conditioner, is characterized in that: comprise the steps:
Step1: prepare silicon layer, water layer, natural oil reservoir respectively;
Silicon layer: according to weight part, weigh or measure ammonia end polydimethylsiloxane 0.5-5.5 part, two (C13-15 alkoxyl group) PG-ammonia end polydimethylsiloxane 0.5-5.5 part, phenyl poly-trimethylammonium siloxanes 3-8 part, ring polydimethylsiloxane 10-20 part, polydimethylsiloxane 10-20 part, first additive 0.2-1.5 part, then the component Homogeneous phase mixing that will obtain;
Water layer: according to weight part, weighs or measures water 35-45 part, hydrolysis lupin protein 0.5-3.5 part, Herba Houttuyniae extract 0.5-3.5 part, glycerine 0.5-5 part, Second addition 0.85-1.35 part, then the component Homogeneous phase mixing that will obtain;
Natural oil reservoir: according to weight part, measures thorn A Gan tree benevolence oil 10-25 part;
Step2: first add water layer, slowly adds silicon layer after leaving standstill again, adds natural oil reservoir again after again leaving standstill.
8. the preparation method of three layers of anti-depilation hair conditioner according to claim 7, is characterized in that: adding the time of repose after water layer is 10min, adding the time of repose after silicon layer is 30min.
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CN107929103A (en) * 2017-12-18 2018-04-20 珠海伊斯佳科技股份有限公司 A kind of three layers of hair/scalp care spraying
CN108309836A (en) * 2018-04-27 2018-07-24 广州环亚化妆品科技有限公司 A kind of compound plant essential oil and its preparation method and application
CN110812252A (en) * 2019-12-06 2020-02-21 广州环亚化妆品科技有限公司 Three-layer hair care composition and preparation method and application thereof
CN111449991A (en) * 2020-04-03 2020-07-28 上海美浮特生物科技有限公司 Hair repair composition, preparation method and application thereof
CN115006289A (en) * 2021-07-31 2022-09-06 苏州绿叶日用品有限公司 Anti-fouling hair care composition and preparation method thereof

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CN107929103A (en) * 2017-12-18 2018-04-20 珠海伊斯佳科技股份有限公司 A kind of three layers of hair/scalp care spraying
CN108309836A (en) * 2018-04-27 2018-07-24 广州环亚化妆品科技有限公司 A kind of compound plant essential oil and its preparation method and application
CN110812252A (en) * 2019-12-06 2020-02-21 广州环亚化妆品科技有限公司 Three-layer hair care composition and preparation method and application thereof
WO2021110134A1 (en) * 2019-12-06 2021-06-10 广州环亚化妆品科技有限公司 Three-layer hair care composition, preparation method therefor, and application thereof
CN110812252B (en) * 2019-12-06 2022-04-01 广州环亚化妆品科技有限公司 Three-layer hair care composition and preparation method and application thereof
CN111449991A (en) * 2020-04-03 2020-07-28 上海美浮特生物科技有限公司 Hair repair composition, preparation method and application thereof
CN111449991B (en) * 2020-04-03 2022-05-10 上海美浮特生物科技有限公司 Hair repair composition, preparation method and application thereof
CN115006289A (en) * 2021-07-31 2022-09-06 苏州绿叶日用品有限公司 Anti-fouling hair care composition and preparation method thereof

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