CN105625094A - Mite prevention artificial decoration paper and preparing method thereof - Google Patents
Mite prevention artificial decoration paper and preparing method thereof Download PDFInfo
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- CN105625094A CN105625094A CN201511017250.7A CN201511017250A CN105625094A CN 105625094 A CN105625094 A CN 105625094A CN 201511017250 A CN201511017250 A CN 201511017250A CN 105625094 A CN105625094 A CN 105625094A
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- mite
- melamine resin
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
Abstract
The invention discloses mite prevention artificial decoration paper, comprising base paper (1) and melamine resin composite coating. The resin composite coating comprises smell mite prevention melamine resin layers (2) distributed at upper and lower surfaces of the base paper, a mite prevention melamine resin layer (3) with a porous structure located on the smell mite prevention melamine resin layer (2) at the upper surface of the base paper, and a common melamine resin layer (4) located on the smell mite prevention melamine resin layer (2) at the lower surface of the base paper. According to the mite prevention artificial decoration paper, a mite dispelling agent and a mite preventing agent are respectively added into the smell mite prevention melamine resin layers (2) and the mite prevention melamine resin layer (3), and the porous structure of the mite prevention melamine resin (3) are used, so that the mite dispelling agent releases aromatic odor and double mite dispelling actions are realized. The prevention further discloses a related preparing method, the process is simple and the prepared artificial decoration paper is obvious in mite prevention effect.
Description
Technical field
Patent of the present invention relates to wood-based plate decorative paper technical field, particularly relates to a kind of anti-mite artificial decoration paper and its preparation method.
Background technology
The mode of life of mite class is very complicated, herd with the life of the mankind in close relations with agricultural, doctor, endanger the tetranychid of farm-forestry crop, the flour mite of harm storage and cause person poultry disease trombiculid, leather mite, demodicid mite and dirt mite to affect life and the production of people, the health of harm humans. The disease that the dirt mite being distributed in people's living environment causes is studied by medical field, show that it is a kind of strong sensitinogen, the people in the whole world nearly 1/10 suffers from anaphylactic disease, and wherein the morbidity of asthma, allergic rhinitis and atopical dermatitis etc. is all closely bound up with existing of house dust mite.
Along with enriching of people's material life, indoor living environment has a very large change. The improvement of house airtight performance, makes indoor pollution assemble, and improper ventilation adds the growth that indoor humidity is also conducive to mould and house dust mite simultaneously, thus makes the allergen that dirt mite becomes the most general in living environment. The change of environment facilitates dirt mite and grows, and the prolongation of people in indoor residence time too increases the contact with dust mite allergen, and the sickness rate of the diseases such as dust mite allergy asthma increases thereupon. Therefore, the control of dirt mite receives the extensive concern of countries in the world researchist.
The control of mite worm is mainly for the harmful mite class in daily life, the chemical mite-proof agent of nearly 10 years each major companies of world exploitation is rich organic phosphates, amino formate, pyrethroid, benzoyl area kind, also has pyrazoles, pyridazine class, pyroles, pyridyl-methanamine class, triazole species, narrows pyridine class, bishydrazide, polynactin class etc. Develop the mite-proof agent being specifically designed to textiles at present, but at the also not relevant report of the mite-proof agent of furniture sector application.
Chinese patent CN103112208A discloses a kind of Environment-friendlyfiber/non-woven fiber/non-woven fabric composite board for home decoration and its preparation method, it is covered with non-woven fabrics at composition board substrate surface, add flaxen fiber in a substrate simultaneously, utilize flaxen fiber to have good sucting wet air permeability, make composition board have effect of antibiosis anti-acarien. But the over-all properties of its composition board declines, and flaxen fiber does not drive the effect of mite, in fact utilizes the effect of the anti-mite of flaxen fiber unsatisfactory. Therefore, strengthen the anti-mite performance in wood-based plate decorative paper surface with mite-proof agent, make wood-based plate decorative paper surface produce suppress or drive mite effect to harmful microorganism, have important practical significance.
Summary of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of anti-mite artificial decoration paper and its preparation method.
The technical solution used in the present invention is:
A kind of anti-mite artificial decoration paper, comprises base paper and melamine resin compound coating. Described resin compounded coating comprises the anti-mite melamine resin layer driving on mite melamine resin layer driving mite melamine resin layer, being positioned at base paper upper surface being distributed in base paper upper and lower surface, the common melamine resin layer driving on mite melamine resin layer being positioned at base paper lower surface.
As the further improvement of such scheme, described anti-mite melamine resin layer surface has pinhole arrangement.
As the further improvement of such scheme, described in drive the feed composition of mite melamine resin layer as follows by weight:
Wherein said drive the GC-G019W that Hebei limited liability company of Ning Fang group is selected in mite agent.
As the further improvement of such scheme, the feed composition of described anti-mite melamine resin layer is as follows by weight:
As the further improvement of such scheme, at least one that described mite-proof agent is selected from 4-Aminobutanoicacid, clofentezine, hexythiazox, benzyl ether chrysanthemum ester, Buprofezin, Provado; It is wherein a kind of that described anion surfactant is selected from Sodium dodecylbenzene sulfonate, fatty alcohol-ether sodium sulfate, the sulfonate of ethoxylated fatty-acid methyl ester and a-sodium olefin sulfonate. Described anion surfactant is preferably Sodium dodecylbenzene sulfonate.
Wherein permeate agent is can fix hydrophilic and oleophilic group and can make the material that surface tension significantly declines, such as alkyl sodium sulfonate, sulfated castor oil, fatty alcohol-polyoxyethylene ether etc.; Releasing agent is the compound that paraffin, silicone oil etc. have infiltration and demoulding dual function; Defoamer is polysiloxane defoamers or polyether-modified silicon defoaming agent.
In addition, in the present invention resin curing agent adopt compound method be: by water, tosic acid and morpholine by weight ratio be 3:2:1 mix after stir and get final product.
As the further improvement of such scheme, in described melamine resin compound coating, melamine resin preparation method by weight is as follows: adding 37% formaldehyde solution 61 parts, 30 parts, tap water, glycol ether 5 parts first in a kettle., the sodium hydroxide solution adjust pH with 40% is to 9.0; Then add trimeric cyanamide 50 parts after being heated to 45 DEG C, it is warmed up to 90 DEG C from 45 DEG C, used time 45min; Question response solution adds 2.5 parts of caprolactams after becoming clarification, is incubated 120min at 90 DEG C, sampling and testing cloud point terminal; Finally cooling to 40 DEG C gradually, temperature fall time is probably 90min, obtains melamine resin.
A preparation method for anti-mite artificial decoration paper, it comprises following processing step:
1) leaching: be placed on impregnation equipment by base paper, takes out after driving mite melamine resin soaking, makes to drive mite melamine resin and be distributed in the positive and negative surface of base paper, oven for drying after floating roller is floating, must drive mite melamine resin layer;
2) upper it being coated with: 1) the mite melamine resin layer upper surface that drive that be prepared into be coated with mite melamine resin of deploying troops on garrison duty, and through the floating post-drying of floating roller, obtains anti-mite melamine resin layer;
3) back of the body is coated with: upper be coated with while be coated with common melamine resin driving mite melamine resin layer lower surface, through the floating post-drying of floating roller, obtain common melamine resin layer.
Wherein step 1) in the line speed of floating roller be 45.7m/min. Described oven dry is the Procuring by 4 joint baking ovens, and wherein oven temperature is respectively 135 DEG C, 160 DEG C, 145 DEG C and 125 DEG C.
In addition, above-mentioned steps 2) and step 3) carry out, wherein the linear velocity of floating roller is 38.4m/min. simultaneously
Specifically, step 3) preparation method of described common melamine resin is: it is the defoamer being added into the resin curing agent of 0.5 part, the releasing agent of 0.025 part, the dedusting agent of 0.5 part and 0.05 part in the melamine resin of 50 parts at weight part, dispersed with stirring.
As the further improvement of such scheme, the described preparation method driving mite melamine resin is as follows: at weight part be the melamine resin of 50 parts is added into the resin curing agent of 0.2��0.4 part, the permeate agent of 0.1��0.2 part, the dedusting agent of 0.3��0.5 part and 0.4��0.6 part drive mite agent, dispersed with stirring.
As the further improvement of such scheme, the preparation method of described anti-mite melamine resin is as follows: be the anion surfactant being added into the resin curing agent of 0.4��0.6 part, the releasing agent of 0.02��0.03 part, the dedusting agent of 0.3��0.5 part, the defoamer of 0.03��0.06 part, the mite-proof agent of 0.4��0.6 part and 0.0005 part in the melamine resin of 50 parts at weight part, dispersed with stirring.
Wherein in anti-mite melamine resin preparation process, with the addition of anion surfactant, the anti-mite melamine resin layer that preparation is gone out has pinhole arrangement after overlaying into plate, this kind of pinhole arrangement should be avoided in the artificial decoration paper of routine, but the present invention make use of the pinhole arrangement of anti-mite melamine resin layer just, make to drive and mite melamine resin layer drives the effect that mite agent can play release aromatic odour. Utilize simultaneously and it is added into different anion surfactants, it is possible to the effectively size of control pin hole, thus the speed of mite agent release is driven in control.
The invention has the beneficial effects as follows:
The anti-mite artificial decoration paper of the present invention drives mite agent and mite-proof agent by adding in melamine resin compound coating, formed and it is positioned at driving mite melamine resin layer and being positioned at the anti-mite melamine resin layer of the base paper upper surface second layer of base paper upper and lower surface, utilize the pinhole arrangement of anti-mite melamine resin layer simultaneously, make to drive mite agent and can discharge aromatic odour, reach dual and drive mite effect.
The anti-mite artificial decoration Preparation Method technique made of paper of the present invention is simple, and prepare the artificial decoration paper that anti-mite effect is remarkable after testing simultaneously.
Accompanying drawing explanation
Fig. 1 is the structural representation of the anti-mite artificial decoration paper of the present invention.
Embodiment
In order to make the object of the application, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated. For thorough understanding the present invention, ensuing description can relate to some specific detail. And when not having these specific detail, the present invention then may still can realize, namely the technician in art uses the work that these describe and statement effectively introduces them to the others skilled in the art in art herein essential. It is to be understood that specific embodiment described herein is only in order to explain the application, and it is not used in and limits real protection scope. And be the object of the present invention of avoiding confusion, owing to other technology such as composition, processing units known has been readily appreciated that, therefore they are not described in detail.
With reference to Fig. 1, a kind of anti-mite artificial decoration paper, comprise base paper 1 and melamine resin compound coating, it is characterised in that: described resin compounded coating comprises the anti-mite melamine resin layer 3 driving on mite melamine resin layer 2 driving mite melamine resin layer 2, being positioned at base paper upper surface being distributed in base paper upper and lower surface, the common melamine resin layer 4 driving on mite melamine resin layer 2 being positioned at base paper lower surface. Wherein anti-mite melamine resin layer 3 surface has pinhole arrangement.
Prepare melamine resin needed for melamine resin compound coating: preparation method is as follows by weight: adding 37% formaldehyde solution 61 parts, 30 parts, tap water, glycol ether 5 parts first in a kettle., the sodium hydroxide solution adjust pH with 40% is to 9.0; Then add trimeric cyanamide 50 parts after being heated to 45 DEG C, it is warmed up to 90 DEG C from 45 DEG C, used time 45min; Question response solution adds 2.5 parts of caprolactams after becoming clarification, is incubated 120min at 90 DEG C, sampling and testing cloud point terminal; Finally cooling to 40 DEG C gradually, temperature fall time is probably 90min, obtains melamine resin.
Embodiment 1
Mite melamine resin (a) is driven in preparation: be the GC-G019W being added into the resin curing agent of 0.2 part, the permeate agent of 0.1 part, the dedusting agent of 0.5 part and 0.4 part in the melamine resin of 50 parts at weight part, and dispersed with stirring is stand-by.
Prepare anti-mite melamine resin (a): be the Sodium dodecylbenzene sulfonate being added into the resin curing agent of 0.4 part, the releasing agent of 0.02 part, the dedusting agent of 0.5 part, the defoamer of 0.03 part, the 4-Aminobutanoicacid of 0.4 part and 0.0005 part in the melamine resin of 50 parts at weight part, dispersed with stirring, stand-by.
Prepare common melamine resin: be the defoamer being added into the resin curing agent of 0.5 part, the releasing agent of 0.025 part, the dedusting agent of 0.5 part and 0.05 part in the melamine resin of 50 parts at weight part, dispersed with stirring, stand-by.
A preparation method for anti-mite artificial decoration paper, it comprises following processing step:
1) leaching: base paper 1 is placed on impregnation equipment, take out after driving mite melamine resin (a) soaking, make to drive mite melamine resin (a) and it is distributed in the positive and negative surface of base paper 1, oven for drying after floating roller is floating, mite melamine resin layer 2 must be driven;
2) upper it being coated with: 1) mite melamine resin layer 2 upper surface that drives that is prepared into is coated with mite melamine resin (a) of deploying troops on garrison duty, and through the floating post-drying of floating roller, obtains anti-mite melamine resin layer 3;
3) back of the body is coated with: upper be coated with while be coated with common melamine resin driving mite melamine resin layer 2 lower surface, through the floating post-drying of floating roller, obtain common melamine resin layer 4.
Finally overlaying into plate must anti-mite artificial decoration paper product.
Embodiment 2
Mite melamine resin (b) is driven in preparation: be the GC-G019W being added into the resin curing agent of 0.4 part, the permeate agent of 0.2 part, the dedusting agent of 0.4 part and 0.5 part in the melamine resin of 50 parts at weight part, and dispersed with stirring is stand-by.
Prepare anti-mite melamine resin (b): be the Sodium dodecylbenzene sulfonate being added into the resin curing agent of 0.6 part, the releasing agent of 0.03 part, the dedusting agent of 0.4 part, the defoamer of 0.06 part, the hexythiazox of 0.3 part, 0.3 part of Provado and 0.0005 part in the melamine resin of 50 parts at weight part, dispersed with stirring, stand-by.
Prepare common melamine resin: with implementing 1.
A preparation method for anti-mite artificial decoration paper, it comprises following processing step:
1) leaching: base paper 1 is placed on impregnation equipment, take out after driving mite melamine resin (b) soaking, make to drive mite melamine resin (b) and it is distributed in the positive and negative surface of base paper 1, oven for drying after floating roller is floating, mite melamine resin layer 2 must be driven;
2) upper it being coated with: 1) mite melamine resin layer 2 upper surface that drives that is prepared into is coated with mite melamine resin (b) of deploying troops on garrison duty, and through the floating post-drying of floating roller, obtains anti-mite melamine resin layer 3;
3) back of the body is coated with: upper be coated with while be coated with common melamine resin driving mite melamine resin layer 2 lower surface, through the floating post-drying of floating roller, obtain common melamine resin layer 4.
Finally overlaying into plate must anti-mite artificial decoration paper product.
Embodiment 3
Mite melamine resin (c) is driven in preparation: be the GC-G019W being added into the resin curing agent of 0.2 part, the permeate agent of 0.2 part, the dedusting agent of 0.4 part and 0.6 part in the melamine resin of 50 parts at weight part, and dispersed with stirring is stand-by.
Prepare anti-mite melamine resin (c): be the fatty alcohol-ether sodium sulfate being added into the resin curing agent of 0.5 part, the releasing agent of 0.02 part, the dedusting agent of 0.3 part, the defoamer of 0.03 part, the benzyl ether chrysanthemum ester of 0.5 part and 0.0005 part in the melamine resin of 50 parts at weight part, dispersed with stirring, stand-by.
Prepare common melamine resin: with implementing 1.
A preparation method for anti-mite artificial decoration paper, it comprises following processing step:
1) leaching: base paper 1 is placed on impregnation equipment, take out after driving mite melamine resin (c) soaking, make to drive mite melamine resin (c) and it is distributed in the positive and negative surface of base paper 1, oven for drying after floating roller is floating, mite melamine resin layer 2 must be driven;
2) upper it being coated with: 1) mite melamine resin layer 2 upper surface that drives that is prepared into is coated with mite melamine resin (c) of deploying troops on garrison duty, and through the floating post-drying of floating roller, obtains anti-mite melamine resin layer 3;
3) back of the body is coated with: upper be coated with while be coated with common melamine resin driving mite melamine resin layer 2 lower surface, through the floating post-drying of floating roller, obtain common melamine resin layer 4.
Finally overlaying into plate must anti-mite artificial decoration paper product.
Embodiment 1��3 being prepared the anti-mite artificial decoration paper product and carries out anti-mite performance test, testing method adopts GB/T24253-20099.2 to suppress method. Its test result is such as following table:
Wherein control sample is common trimeric cyanamide artificial decoration plate. Having the data in upper table to obtain, the present invention prepares the anti-mite artificial decoration plate and has obvious anti-mite effect.
Claims (9)
1. an anti-mite artificial decoration paper, comprise base paper (1) and melamine resin compound coating, it is characterised in that: described resin compounded coating comprises anti-mite melamine resin layer (3) driven mite melamine resin layer (2), be positioned at the smell of base paper upper surface and drive on mite melamine resin layer (2) being distributed in base paper upper and lower surface, the common melamine resin layer (4) driving on mite melamine resin layer (2) being positioned at base paper lower surface.
2. the anti-mite artificial decoration paper of one according to claim 1, it is characterised in that, described anti-mite melamine resin layer (3) surface has pinhole arrangement.
3. the anti-mite artificial decoration paper of one according to claim 1, it is characterised in that, described in drive the feed composition of mite melamine resin layer (2) as follows by weight:
Melamine resin 50 parts;
Resin curing agent 0.2 ~ 0.4 part;
Permeate agent 0.1 ~ 0.2 part;
Dedusting agent 0.3 ~ 0.5 part;
Drive mite agent 0.4 ~ 0.6 part.
4. the anti-mite artificial decoration paper of one according to claim 1, it is characterised in that, the feed composition of described anti-mite melamine resin layer (3) is as follows by weight:
Melamine resin 50 parts;
Resin curing agent 0.4 ~ 0.6 part;
Releasing agent 0.02 ~ 0.03 part;
Dedusting agent 0.3 ~ 0.5 part;
Defoamer 0.03 ~ 0.06 part;
Mite-proof agent 0.4 ~ 0.6 part;
Anion surfactant 0.0005 part.
5. the anti-mite artificial decoration paper of one according to claim 4, it is characterised in that, at least one that described mite-proof agent is selected from 4-Aminobutanoicacid, clofentezine, hexythiazox, benzyl ether chrysanthemum ester, Buprofezin, Provado; It is wherein a kind of that described anion surfactant is selected from Sodium dodecylbenzene sulfonate, fatty alcohol-ether sodium sulfate, the sulfonate of ethoxylated fatty-acid methyl ester and a-sodium olefin sulfonate.
6. the anti-mite artificial decoration paper of one according to claim 1, it is characterized in that, in described melamine resin compound coating, melamine resin preparation method by weight is as follows: adding 37% formaldehyde solution 61 parts, 30 parts, tap water, glycol ether 5 parts first in a kettle., the sodium hydroxide solution adjust pH with 40% is to 9.0; Then add trimeric cyanamide 50 parts after being heated to 45 DEG C, it is warmed up to 90 DEG C from 45 DEG C, used time 45min; Question response solution adds 2.5 parts of caprolactams after becoming clarification, is incubated 120min at 90 DEG C, sampling and testing cloud point terminal; Finally cooling to 40 DEG C gradually, temperature fall time is probably 90min, obtains melamine resin.
7. the preparation method of an anti-mite artificial decoration paper, it is characterised in that comprise following processing step:
1) leaching: base paper (1) is placed on impregnation equipment, take out after driving mite melamine resin soaking, make to drive mite melamine resin and it is distributed in base paper (1) positive and negative surface, oven for drying after floating roller is floating, mite melamine resin layer (2) must be driven;
2) upper it being coated with: 1) mite melamine resin layer (2) upper surface that drives that is prepared into is coated with mite melamine resin of deploying troops on garrison duty, and through the floating post-drying of floating roller, obtains anti-mite melamine resin layer (3);
3) back of the body is coated with: upper be coated with while be coated with common melamine resin driving mite melamine resin layer (2) lower surface, through the floating post-drying of floating roller, obtain common melamine resin layer (4).
8. the anti-mite artificial decoration paper of one according to claim 7, it is characterized in that, the described preparation method driving mite melamine resin is as follows: at weight part be the melamine resin of 50 parts is added into the resin curing agent of 0.2 ~ 0.4 part, the permeate agent of 0.1 ~ 0.2 part, the dedusting agent of 0.3 ~ 0.5 part and 0.4 ~ 0.6 part drive mite agent, dispersed with stirring.
9. the anti-mite artificial decoration paper of one according to claim 7, it is characterized in that, the preparation method of described anti-mite melamine resin is as follows: be the anion surfactant being added into the resin curing agent of 0.4 ~ 0.6 part, the releasing agent of 0.02 ~ 0.03 part, the dedusting agent of 0.3 ~ 0.5 part, the defoamer of 0.03 ~ 0.06 part, the mite-proof agent of 0.4 ~ 0.6 part and 0.0005 part in the melamine resin of 50 parts at weight part, dispersed with stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017250.7A CN105625094A (en) | 2015-12-28 | 2015-12-28 | Mite prevention artificial decoration paper and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106401099A (en) * | 2016-10-27 | 2017-02-15 | 广东玉兰集团股份有限公司 | Anti-acarid wallpaper and preparation method thereof |
| CN114134753A (en) * | 2021-10-26 | 2022-03-04 | 苏州吉谷新材料有限公司 | Coating material for newsprint paper, preparation method thereof and transfer paper production process |
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| CN114134753A (en) * | 2021-10-26 | 2022-03-04 | 苏州吉谷新材料有限公司 | Coating material for newsprint paper, preparation method thereof and transfer paper production process |
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Application publication date: 20160601 |