CN106401099B - A kind of anti-mite wallpaper and preparation method thereof - Google Patents
A kind of anti-mite wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106401099B CN106401099B CN201610955461.3A CN201610955461A CN106401099B CN 106401099 B CN106401099 B CN 106401099B CN 201610955461 A CN201610955461 A CN 201610955461A CN 106401099 B CN106401099 B CN 106401099B
- Authority
- CN
- China
- Prior art keywords
- mite
- layer
- parts
- agent
- wallpaper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0002—Wallpaper or wall covering on textile basis
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/04—Vegetal fibres
- D06N2201/042—Cellulose fibres, e.g. cotton
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/04—Vegetal fibres
- D06N2201/042—Cellulose fibres, e.g. cotton
- D06N2201/045—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/02—Dispersion
- D06N2205/023—Emulsion, aqueous dispersion, latex
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/06—Building materials
- D06N2211/063—Wall coverings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Life Sciences & Earth Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to wallpaper technical fields, and in particular to a kind of anti-mite wallpaper and preparation method thereof includes successively from bottom to up substrate layer, resin layer, ink layer and anti-mite layer, and the substrate layer bottom surface is provided with mould proof waterproof layer.Anti-mite wallpaper of the invention has good decoration function, while but also with anti-mite effect, the anti-mite time is lasting, and effect is good, and be arranged and substrate layer bottom surface is provided with mould proof waterproof layer, water percolation of wall is prevented, the growth of bacterium is inhibited, preparation process is simple, can be mass, at low cost.
Description
Technical field
The present invention relates to wallpaper technical fields, and in particular to a kind of anti-mite wallpaper and preparation method thereof.
Background technique
In the prior art, dust mite is the member of arachnid and spider family.They generally live in mattress,
The places such as blanket, curtain and soft decoration.Dust mite is food with the Skin Cell that the mankind leave, they also can leave disease in the place of process
Substance.Scientist confirms that the pathogen that dust mite is drained can cause allergic reaction to the mankind.It is millions of that dust mite is known as the whole world
Count one of the main triggering of allergic reaction patient.
Dust mite can caused by medical care problem include asthma, nose sensitivity, skin sensitivity, bronchitis, Hay Fever, eczema, sinus
Inflammation, pulmonary emphysema beat nose snore and other skins and respiratory disorder problem etc..The whole world about 1/4 people tormented by this, only Britain because
Allergy and the number influenced just up to ten thousand people of 2000-2500.
Wallpaper, a kind of decorative material for wall surface.It is with rich in color, myoplasm sense is strong, pattern is gorgeous, environmentally protective, construction
It the features such as convenient, affordable, decorative effect elegant, increasingly has been favored by people.Because it is suitable for the wall of large area
Face decoration has advantageous advantage for prevention and treatment acarid if anti-mite technology can be quoted.
Summary of the invention
The purpose of the present invention is being directed to above-mentioned deficiency in the prior art, a kind of anti-mite wallpaper is provided, there is dress well
Decorations effect, while but also with anti-mite effect, the anti-mite time is lasting, and effect is good, and setting be provided in substrate layer bottom surface it is mould proof
Waterproof layer prevents water percolation of wall, inhibits the growth of bacterium.
Another object of the present invention is to provide a kind of preparation side of anti-mite wallpaper for above-mentioned deficiency in the prior art
Method, the simple process of preparation, the anti-mite effect of the wallpaper prepared is good to inhibit bacterial growth again.
The purpose of the present invention is achieved through the following technical solutions:
A kind of anti-mite wallpaper successively includes substrate layer, resin layer, ink layer and anti-mite layer, the substrate layer from bottom to up
Bottom surface is provided with mould proof waterproof layer.
Wherein, the substrate layer is one of non-woven paper, coated paper or linen-cotton chemical & blended fabric.Substrate layer with a thickness of
0.01mm~0.2mm。
Wherein, the resin layer is 100:(0.1 ~ 2 by film forming matter, auxiliary agent, solvent score by weight): (1 ~ 10) mixes
It is made.Wherein film forming matter is made of water-soluble acrylic sap with polycarbodiimide crosslinkers, mass ratio be 1:(1/3 ~
1), auxiliary agent is silane coupling agent, and solvent is water, while resin layer can also be by PVC at 200-220 DEG C, and pressure is in 1.2-
It is coated with and is formed after being plasticized under 1.5MPa.The resin layer is that crosslinked acrylic resin coating plays wetting action to wallpaper substrate,
Have fine and close function to base simultaneously, to reduce substrate surface tension, resin layer with a thickness of 0.05mm ~ 0.50mm.The tree
The upper and lower surfaces of rouge layer are provided with the alternate groove of convex-concave.The alternate groove of resin layer setting convex-concave can increase resin layer
With the adhesiveness of substrate layer and ink layer, and the resin layer be crosslinked acrylic resin, have difunctional, functional group was both
It can increase the adhesiveness with substrate layer, wallpaper adhesive force increases, and stronger molecular force can be also formed with the one's share of expenses for a joint undertaking in resin, improves
The compactness of entire resin layer.
Wherein, the ink layer is by 100 parts of acrylic resin liquid, 20 ~ 50 parts of aqueous color paste, 10 ~ 30 parts of color masterbatch, mica powder
1 ~ 10 part, 2 ~ 5 parts of glitter powder are made.The solvent of acrylic resin liquid or polyurethane resin liquid as ink layer, acrylic resin
The relative molecular weight of film forming matter in liquid is larger, has good guarantor's light colour retention, water-fast chemical resistance, fast drying, construction
Convenient, being easy to construct recoats and does over again, and polyurethane rouge liquid is not due to dissolving in nonpolar base containing highly polar carbamate groups
Group, have good oil resistivity, toughness, wearability, resistance to ag(e)ing and adhesiveness, make the ink layer prepared be easy to it is mosquito-proof attached
Layer bonding, be not easy to be corroded；Both solvents can be mixed with various mill base color masterbatch and be mixed, and intersolubility is good, between various color masterbatch
It does not interfere, use is non-discolouring, and can bond well with resin layer, and adhesive force is good, and the pattern after decoration is not easy distortion and fades,
Good decorating effect.Ink layer with a thickness of 0.01mm~0.4mm.
Wherein, the anti-mite layer includes the raw material of following parts by weight: 30-100 parts of Hydroxylated acrylic resin, thickener 2-
10 parts, 0.5-5 parts of wetting dispersing agent, 1-2 parts of defoaming agent, 0.2-2 parts of auxiliary rheological agents, 0.5-6 parts of mite-proof agent, 1-10 parts of water.
The anti-mite layer is provided with anti-mite hole, and the pore size in anti-mite hole is 0.05-0.5mm.The body length of acarid is usually
0.1mm to 0.5mm, also has foot, a pair of of antenna and feeler, and whole polypide type is less than the body of acarid close to 1mm, anti-mite hole aperture
Type after so that acarid is entered wallpaper, is trapped in acarid in anti-mite hole, limits the activity of acarid to lethal.Anti-mite layer with a thickness of
0.6-1.2mm。
Hydroxylated acrylic resin can use water as external plasticizer, do not need to add any coalescing agent can preferably at
Film, the Hydroxylated acrylic resin are hydroxy acrylate copolymer, and solid part is 59-62%, specific gravity 0.95-1.05g/
cm3, can Quick cross-linking, fast in conjunction with mite-proof agent, crosslinking securely, avoids mite-proof agent from losing after wallpaper cleaning, weather-proof after film forming
It is property, heat-resist.
The thickener is sodium carboxymethylcellulose, propylene glycol alginate, sodium carboxymethyl starch, two starch phosphorus of acetyl group
One of acid esters, hydroxypropyl PASELLI EASYGEL, polyacrylic ester thickener or two kinds or more.Carboxymethyl fibre is preferably used
Plain sodium, propylene glycol alginate, sodium carboxymethyl starch are tieed up, sodium carboxymethylcellulose is the fibre that glucose polymerization degree is 100 ~ 2000
Plain derivative, relative molecular mass 242.16, white fibrous or particulate powder are tieed up, it is odorless, it is tasteless to have hygroscopicity, it does not dissolve in
Organic solvent；Propylene glycol alginate is made of alginic acid deep processing that extracting in natural seaweed, and appearance is white or faint yellow
Powder, it is water-soluble after at thick colloid.Sodium carboxymethyl starch (CMS-Na) is also known as carboxymethyl starch, is a kind of anionic starch
Ether is the electrolyte that can be dissolved in cold water.It is one kind of converted starch, belongs to ethers starch, be a kind of water soluble anion macromolecule
Type compound.It is tasteless, nontoxic, is not easy to go mouldy.
The wetting dispersing agent is octyl modified organic silicon oxygen silicon, naphthalene sulfonic acid condensate sodium salt, maleic acid/acrylic acid copolymer
It is any in object.The German BASF anionic dispersing agents Tamol NN 8906 of naphthalene sulfonic acid condensate sodium salt, energy is preferably used
The viscosity for efficiently reducing dense suspension makes dispersion be easy to topple over and mix, prevents product from agglomerating.
The auxiliary rheological agents are levelling agent, and the levelling agent is polyacrylate, Dimethicone Copolyol body, gathers
It is any in methyl alkyl and polyethylene glycol ether copolymer.Levelability can be improved by being added in wallpaper of the invention, reduce shrinkage cavity,
Make anti-mite layer that there is good flexibility, good adhesive force, glossiness and gloss retention.
The defoaming agent is polyethers-silicone copolymers, silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxy third
It is any in alkene glycerin ether.The oil content of the defoaming agent be 15-40%, pH value 6-8, stability of emulsion be 3000r/min not
Less than 15min.Ply adhesion is improved, the arrangement of Hydroxylated acrylic resin material, the preferred silicone emulsion of defoaming agent or poly- are improved
Oxypropylene glycerin ether.
Wherein, the mite-proof agent is norbornene derivative, carboxylic acid derivative, cinerins, aromatic carboxylic acid esters, boron
The mixture of one of acid compounds or two kinds or more.It is by composite family Blumea balsamifera cauline leaf that these types of mite-proof agent, which all has borneol,
Or lauraceae plant borneol camphor tree branches and leaves through steam distillation and are recrystallized and are obtained, and have swelling and pain relieving, heat-clearing dissipates poison dissipates fire removing toxic substances
Effect；Carboxylic acid derivative is connected with carboxyl the derivative of the organic acid constituted, including carboxylic acid halides, acid anhydrides, ester, amide by alkyl
It is easy hydrolysis Deng, acyl chlorides and acid anhydrides, the pH after hydrolysis presents acid, makes acarid be difficult to survive and lethal；Cinerins are one
Class can prevent and treat the broad spectrum pesticide of various pests, and insecticidal toxicity is than older generation insecticide such as organochlorine, organic phosphorus, carbamic acid
Esters improve 10~100 times.Pyrethroid has strong action of contace poison to insect, some kinds have both stomach toxicity or stifling
Effect, but all without systemic action.Its mechanism of action is to upset the normal physiological of insect nerve, is allowed to by excited, spasm to fiber crops
Numbness and it is dead.Pyrethroid is therefore safer to people and animals because dosage is small, low using concentration, to the pollution very little of environment；It is preferred that
Carboxylic acid derivative, cinerins；Further, it is preferable that Clariant Corporation, Actigard AM-21-16 mite-proof agent；Boric acid class
Compound is dissolved in water in acidity, and majority is used for the insecticide of cockroach and insects, fine to the effect of acarid, can wave together with water
Hair has and drives mite effect well.Acarid is mainly distributed on carpet, sofa, down toy, bedding, cushion, mattress and pillow etc.
Place is multiplied, and is food with sweat, secretion, the exuviae bits of people, reproduction speed is exceedingly fast, and the air humidity 60% or more can be fast
Speed is bred, and there is the palmula of tool long handle in the end of 2 pairs of foots before male and female mite, is the part that is quick of perception, dye is easy under acidic environment
Disease has good effect from dead, of the invention anti-mite layer slant acidity, energy anti-mite.
Wherein, proportion of the mould proof waterproof layer by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight
100:(20-30): (1-5) is made.The acrylic compounds performed polymer is formed by polymerizable acrylic monomer, is added curing agent and is prevented
It mould dose, is able to achieve rapid curing and polymerize to form solidifying film layer, the mould inhibitor is Clariant Corporation SANITIZED TH22-27
Mould inhibitor, mould inhibitor act on cell, destroy the metabolism of microorganism, therefore have ceased them and act on, grow and breed
Ability.Mould inhibitor is pyrithione derivative, and being used cooperatively with hydrophobicity auxiliary agent can get corrosion-resistant effect.Wherein, described
Curing agent is amino resins, pyridine, the mixture with two or more in epoxy group resin, curing agent and mould inhibitor
Can be similar, it does not react, associativity is good, and mould inhibitor is Clariant Corporation SANITIZED TH22-27 mould inhibitor.It is described mould proof anti-
Water layer is provided with anti-water hole, anti-water hole be it is horn-like, the aperture at loudspeaker osculum end is 1-100nm, and the aperture of loudspeaker big opening end is
20-600mm.Horn-like osculum end is set on the outside of wallpaper, the aperture very little at osculum end, less than the volume of bacterium and moisture content, from
And the entrance of bacterium and moisture content is avoided, while horn-like big opening end is set to anti-mite layer side, it can be convenient for the evaporation of moisture content in wallpaper
It goes out, keeps dry and comfortable inside wallpaper, relative humidity is made to be less than the living environment that acarid adapts to；If the loudspeaker big opening end is provided with
Dry wadding item, wadding item can limit the movement of acarid in wallpaper, to inhibit the existence of acarid.The mould proof waterproof layer with a thickness of
0.05mm~0.1mm.
A kind of preparation method of anti-mite wallpaper includes the following steps:
Step A: the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight are stirred under the speed of 200r/min ~ 500r/min
It mixes and is mixed to prepare cold coating；
Step B: being added aqueous color paste, color masterbatch, mica powder and the glitter powder of above-mentioned parts by weight in acrylic resin liquid,
Obtained decorative paint is stirred under the speed of 500r/min ~ 800r/min；
Step C: being coated on substrate layer or prints upper cold coating forms resin layer, be coated with or print on the resin layer on
Decorative paint forms ink layer, then is finally applied in substrate layer bottom surface in ink layer surface by impregnating, printing or be coated with anti-mite layer
Anti-mite wallpaper is made in the mould proof waterproof layer of cloth.
Wherein, anti-mite layer has mite-proof agent, and mite-proof agent has good anti-mite effect, can individually be directly coated at ink
On layer, while anti-mite layer coating can be prepared with binding resin or is printed in ink layer surface, it is preferable that the system of the anti-mite layer
Preparation Method includes the following steps:
1) Hydroxylated acrylic resin is weighed by calculation amount, is successively slowly added to 1/3-1/2 parts of water, wetting and dispersings while stirring
Agent, defoaming agent, auxiliary rheological agents stir 20-30min under the speed of 200r/min ~ 500r/min；
2) mite-proof agent is added, stirs 20-30min under the speed of 500r/min-800r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 800Pas ~ 8000Pas, with 1000r/min ~
The speed of 1500r/min, which stirs evenly, to be republished or is coated on ink layer up to anti-mite layer.
The anti-mite layer entirety slant acidity that the present invention prepares, and there is band anti-mite function active group, energy and resin
Hydroxyl in film forms covalent bond, is firmly fixed on resin film, contacts when acarid is fallen on wallpaper with wallpaper, mite-proof agent
In active constituent by destroying the nervous function of acarid, epidermis, inhibiting growth, development and breed to achieve the purpose that mite killing；
Driving mite agent simultaneously can prevent acarid close or inhibit its breeding under the action of the sense of taste, smell and pheromones.Wherein, it dries
Temperature is 60-120 DEG C.The anti-mite layer is provided with anti-mite hole, and the pore size in anti-mite hole is 0.05-0.5mm.The body of acarid is long
Usually 0.1mm to 0.5mm, also has foot, a pair of of antenna and feeler, and whole polypide type is less than acarid close to 1mm, anti-mite hole aperture
Figure, after so that acarid is entered wallpaper, be trapped in acarid in anti-mite hole, limit the activity of acarid to lethal.
Beneficial effects of the present invention: a kind of anti-mite wallpaper of the invention is provided with mould proof waterproof layer in substrate layer bottom surface, when
When wallpaper is bonded with metope, wallpaper has waterproofness well to metope, avoids the infiltration of metope water, and wallpaper is made to keep dry shape
State makes acarid and bacterium lose the environment of existence, not only anti-mite but also mould proof；Resin layer is arranged on substrate layer soaks substrate, more
Have flexibility, and have compaction to substrate layer, fills and leads up substrate layer, increase the planarization of wallpaper；Setting oil on the resin layer
Layer of ink, ink layer is similar to the material of resin layer, and the degree of adhesion of the two is high, and stickiness is more preferable；Anti-mite layer is set on ink layer,
Mite-proof agent forms covalent bond with the hydroxyl in anti-mite function active group and resin film in anti-mite layer, is firmly fixed in tree
On membrane of lipoprotein, the drug effect for avoiding anti-mite function reduces due to the scouring to wallpaper surface, extends the persistence for driving mite function.Together
When selected materials have the advantages that nontoxic, biodegradable, have excellent environmental-protecting performance, mould proof waterproof layer is able to suppress bacterium
Deng breeding, guarantee cleaning, the beauty of wallpaper, while protecting wallpaper not to be influenced by water percolation of wall, extends wallpaper and use the time.
It is of the invention another advantage is that: a kind of preparation method of anti-mite wallpaper sets gradually tree on substrate layer
Rouge layer, ink layer and anti-mite layer, then the mould proof waterproof layer on substrate layer bottom-surface coated, preparation process is simple, can be mass, at
This is low.
Detailed description of the invention
Invention is described further using attached drawing, but the embodiments in the accompanying drawings do not constitute any limitation to the present invention,
For those of ordinary skill in the art, without creative efforts, it can also be obtained according to the following drawings
Its attached drawing.
Fig. 1 is a kind of structural schematic diagram of anti-mite wallpaper of the invention.
Appended drawing reference includes: 1 substrate layer, 2 resin layers, 3 ink layers, 4 anti-mite layers, 5 mould proof waterproof layers.
Specific embodiment
With the following Examples and attached drawing the invention will be further described.
Embodiment 1
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:0.1:1.
The ink layer 3 is by 100 parts of acrylic resin liquid, 20 parts of aqueous color paste, 12 parts of color masterbatch, and 3 parts of mica powder, glitter powder
2.5 parts are made.
The anti-mite layer 4 includes 6 parts of 35 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
0.8 part of powder, 1.2 parts of defoaming agent, 0.5 part of auxiliary rheological agents, 0.8 part of mite-proof agent, 2 parts of water.
The mite-proof agent is that norbornene derivative, carboxylic acid derivative and cinerins are 1:2:0.5 by ratio of weight and the number of copies
Composition.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/3 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 20min under the speed of 200r/min；
2) mite-proof agent is added, stirs 20min under the speed of 500r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 900Pas, stirred evenly with the speed of 1100r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:25 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent is that amino resins, pyridine are 2:3.5 composition in parts by weight.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 200r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 500r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 2
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is coated paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:0.5:3.
The ink layer 3 is by 100 parts of acrylic resin liquid, 30 parts of aqueous color paste, 25 parts of color masterbatch, and 4 parts of mica powder, glitter powder
4 parts are made.
The anti-mite layer 4 includes 8 parts of 45 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
2.4 parts of powder, 1.8 parts of defoaming agent, 0.4 part of auxiliary rheological agents, 2.5 parts of mite-proof agent, 6 parts of water.
The mite-proof agent is cinerins, aromatic carboxylic acid esters, boric acid compound are 7:2 by ratio of weight and the number of copies:
0.5 composition.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/2 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 25min under the speed of 300r/min；
2) mite-proof agent is added, stirs 25min under the speed of 600r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 900Pas, stirred evenly with the speed of 1200r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:30 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
5 are made.
The curing agent is pyridine, band epoxy group resin is 0.5:3 composition in parts by weight.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 200r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 700r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 3
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:1.2:6.
The ink layer 3 is by 100 parts of acrylic resin liquid, 30 parts of aqueous color paste, 20 parts of color masterbatch, and 7 parts of mica powder, glitter powder
5 parts are made.
The anti-mite layer 4 includes 8 parts of 50 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
2.5 parts of powder, 2 parts of defoaming agent, 1.8 parts of auxiliary rheological agents, 3.5 parts of mite-proof agent, 4 parts of water.
The mite-proof agent is that cinerins, aromatic carboxylic acid esters are 1:2.5 composition by ratio of weight and the number of copies.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/2 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 28min under the speed of 400r/min；
2) mite-proof agent is added, stirs 30min under the speed of 600r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 1200Pas, stirred evenly with the speed of 1300r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:20 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent be amino resins and conmmand be in parts by weight 1:1 composition.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 200r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 600r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 4
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is linen-cotton chemical & blended fabric；The resin layer 2 by film forming matter, help
Agent, solvent score by weight are mixed for 100:2:10.
The ink layer 3 is by 100 parts of acrylic resin liquid, 40 parts of aqueous color paste, 30 parts of color masterbatch, and 9 parts of mica powder, glitter powder
2 parts are made.
The anti-mite layer 4 includes 2 parts of 100 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
0.5 part of powder, 1 part of defoaming agent, 0.2 part of auxiliary rheological agents, 1.5 parts of mite-proof agent, 2.5 parts of water.
The mite-proof agent is the Actigard AM-21-16 mite-proof agent of Clariant Corporation.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/3 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 28min under the speed of 500r/min；
2) mite-proof agent is added, stirs 28min under the speed of 700r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 6000Pas, stirred evenly with the speed of 1000r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:24 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent is amino resins, pyridine, is in parts by weight 1:1:1 composition with epoxy group resin.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 400r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 500r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 5
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:0.5:2.
The ink layer 3 is by 100 parts of acrylic resin liquid, 30 parts of aqueous color paste, 36 parts of color masterbatch, and 7 parts of mica powder, glitter powder
2 parts are made.
The anti-mite layer 4 includes 6 parts of 50 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
2.5 parts of powder, 2 parts of defoaming agent, 2 parts of auxiliary rheological agents, 4 parts of mite-proof agent, 4 parts of water.
The mite-proof agent is that cinerins, aromatic carboxylic acid esters are 1:2.5 composition by ratio of weight and the number of copies.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/3 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 28min under the speed of 400r/min；
2) mite-proof agent is added, stirs 24min under the speed of 600r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 7000Pas, stirred evenly with the speed of 1500r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:25 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
2 are made.
The curing agent be amino resins and conmmand be in parts by weight 2.5:1 composition.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 200r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 600r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 6
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:1.5:3.
The ink layer 3 is by 100 parts of acrylic resin liquid, 38 parts of aqueous color paste, 20 parts of color masterbatch, and 4 parts of mica powder, glitter powder
4 parts are made.
The anti-mite layer 4 includes 2 parts of 60 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
3 parts of powder, 2 parts of defoaming agent, 1.8 parts of auxiliary rheological agents, 3.5 parts of mite-proof agent, 4 parts of water.
The mite-proof agent is that cinerins, aromatic carboxylic acid esters are 0.5:2 composition by ratio of weight and the number of copies.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/2 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 28min under the speed of 480r/min；
2) mite-proof agent is added, stirs 20min under the speed of 800r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 3000Pas, stirred evenly with the speed of 1400r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4
Proportion 100:20 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent be amino resins and conmmand be in parts by weight 0.4:1 composition.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 500r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 800r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 7
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:2:4.
The ink layer 3 is by 100 parts of acrylic resin liquid, 50 parts of aqueous color paste, 20 parts of color masterbatch, and 6 parts of mica powder, glitter powder
2 parts are made.
The anti-mite layer 4 includes 2 parts of 80 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
3 parts of powder, 1.8 parts of defoaming agent, 2 parts of auxiliary rheological agents, 5 parts of mite-proof agent, 4 parts of water.
The mite-proof agent be norbornene derivative, carboxylic acid derivative, aromatic carboxylic acid esters, boric acid compound by weight
Portion rate is 0.5:2:4:1 composition.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/2 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 20min under the speed of 450r/min；
2) mite-proof agent is added, stirs 20min under the speed of 650r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 4000Pas, stirred evenly with the speed of 1400r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:30 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent be amino resins and conmmand be in parts by weight 1:5 composition.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 500r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 700r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Embodiment 8
A kind of anti-mite wallpaper successively includes substrate layer 1, resin layer 2, ink layer 3 and anti-mite layer 4, the base from bottom to up
1 bottom surface of material layer is provided with mould proof waterproof layer 5.The substrate layer 1 is non-woven paper；The resin layer 2 is by film forming matter, auxiliary agent, molten
Agent score by weight is mixed for 100:0.2:2.
The ink layer 3 is by 100 parts of acrylic resin liquid, 20 parts of aqueous color paste, 20 parts of color masterbatch, and 4 parts of mica powder, glitter powder
4 parts are made.
The anti-mite layer 4 includes 8 parts of 80 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting point
3 parts of powder, 1.2 parts of defoaming agent, 0.4 part of auxiliary rheological agents, 3.5 parts of mite-proof agent, 4 parts of water.
The mite-proof agent is that cinerins, aromatic carboxylic acid esters are 0.5:2 composition by ratio of weight and the number of copies.
The preparation method of the anti-mite layer 4 includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/3 part of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 25min under the speed of 200r/min；
2) mite-proof agent is added, stirs 25min under the speed of 660r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity be 7500Pas, stirred evenly with the speed of 1200r/min
It republishes or is coated on ink layer 3 up to anti-mite layer 4.
Proportion 100:20 of the mould proof waterproof layer 5 by acrylic compounds performed polymer, curing agent and mould inhibitor in parts by weight:
4 are made.
The curing agent be amino resins and conmmand be in parts by weight 0.4:1 composition.
A kind of preparation method of anti-mite wallpaper, including the following steps:
Step A: prepare resin layer 2: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 300r/min speed
Under be stirred obtained cold coating, republish or be coated on 1 surface of substrate layer up to resin layer 2；
Step B: preparing and ink layer 3 is arranged: aqueous color paste, the color of above-mentioned parts by weight is added in acrylic resin liquid
Female, mica powder and glitter powder, obtained printing ink paint is stirred under the speed of 500r/min, republishes or be coated on resin layer
2 surfaces are up to ink layer 3；
Step C: the dipping of 3 surface of ink layer made from step B prints or is coated with anti-mite layer 4, finally at 1 bottom of substrate layer
Face is coated with mould proof waterproof layer 5 and anti-mite wallpaper is made.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (7)
1. a kind of anti-mite wallpaper, it is characterised in that: from bottom to up successively include substrate layer, resin layer, ink layer and anti-mite layer, institute
It states substrate layer bottom surface and is provided with mould proof waterproof layer；The resin layer is 100 by film forming matter, auxiliary agent, solvent score by weight:
(0.1 ~ 2): (1 ~ 10) is mixed；Prevent that stating anti-mite layer is provided with anti-mite hole, the pore size in anti-mite hole is 0.05-0.5mm；Institute
The upper and lower surfaces for stating resin layer are provided with the alternate groove of convex-concave；
The anti-mite layer includes 2-10 parts of 30-100 parts of raw material hydroxyl acrylic resin, the thickener of following parts by weight, wetting
0.5-5 parts of dispersing agent, 1-2 parts of defoaming agent, 0.2-2 parts of auxiliary rheological agents, 0.5-6 parts of mite-proof agent, 1-10 parts of water；
The preparation method of the anti-mite layer includes the following steps:
1) weigh Hydroxylated acrylic resin by calculation amount, be successively slowly added to while stirring 1/3-1/2 parts of water, wetting dispersing agent,
Defoaming agent, auxiliary rheological agents stir 20-30min under the speed of 200r/min ~ 500r/min；
2) mite-proof agent is added, stirs 20-30min under the speed of 500r/min-800r/min, it is made to be uniformly dispersed；
3) be added thickener, then plus remaining water, adjustment viscosity is 800Pas ~ 8000Pas, with 1000r/min ~ 1500r/
The speed of min, which stirs evenly, to be republished or is coated on ink layer up to anti-mite layer.
2. a kind of anti-mite wallpaper according to claim 1, it is characterised in that: the substrate layer be non-woven paper, coated paper or
One of linen-cotton chemical & blended fabric.
3. a kind of anti-mite wallpaper according to claim 1, it is characterised in that: the ink layer is by acrylic resin liquid 100
Part, 20 ~ 50 parts of aqueous color paste, 10 ~ 30 parts of color masterbatch, 1 ~ 10 part of mica powder, 2 ~ 5 parts of glitter powder are made.
4. a kind of anti-mite wallpaper according to claim 1, it is characterised in that: the mite-proof agent is norbornene derivative, carboxylic acid
The mixture of one of analog derivative, cinerins, aromatic carboxylic acid esters, boric acid compound or two kinds or more.
5. a kind of anti-mite wallpaper according to claim 1, it is characterised in that: the mould proof waterproof layer is by acrylic compounds pre-polymerization
Body, the proportion 100:(20-30 of curing agent and mould inhibitor in parts by weight): (1-5) is made.
6. a kind of anti-mite wallpaper according to claim 5, it is characterised in that: the curing agent is amino resins, pyridine, band
Two or more mixture in epoxy group resin.
7. a kind of preparation method of anti-mite wallpaper according to claim 1-6, it is characterised in that: including following step
It is rapid:
Step A: resin layer is prepared: by the film forming matter, auxiliary agent, solvent of above-mentioned parts by weight 200r/min ~ 500r/min's
It is stirred obtained cold coating under speed, republishes or be coated on substrate layer surface up to resin layer；
Step B: preparing and ink layer is arranged: aqueous color paste, color masterbatch, the mica of above-mentioned parts by weight is added in acrylic resin liquid
Powder and glitter powder are stirred obtained printing ink paint under the speed of 500r/min ~ 800r/min, republish or be coated on resin
Layer surface is up to ink layer；
Step C: the dipping of the ink layer surface made from step B prints or is coated with anti-mite layer, finally anti-in substrate layer bottom-surface coated
Anti-mite wallpaper is made in mould waterproof layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955461.3A CN106401099B (en) | 2016-10-27 | 2016-10-27 | A kind of anti-mite wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955461.3A CN106401099B (en) | 2016-10-27 | 2016-10-27 | A kind of anti-mite wallpaper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106401099A CN106401099A (en) | 2017-02-15 |
| CN106401099B true CN106401099B (en) | 2019-07-19 |
Family
ID=58013974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610955461.3A Active CN106401099B (en) | 2016-10-27 | 2016-10-27 | A kind of anti-mite wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106401099B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107386009B (en) * | 2017-07-28 | 2020-02-04 | 广东玉兰集团股份有限公司 | Humidity-sensitive color-changing wallpaper and preparation method thereof |
| CN109135369A (en) * | 2018-07-11 | 2019-01-04 | 浙江荣禾新材料股份有限公司 | A kind of summer sleeping mat acrylate paint |
| CN109156449B (en) * | 2018-09-28 | 2023-07-25 | 生标（上海）医疗器械科技有限公司 | Painting and calligraphy cultural relic protection device and protection method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07309701A (en) * | 1994-05-19 | 1995-11-28 | Yuaale Sangyo Kk | Pest-repellent material |
| CN103694789B (en) * | 2013-11-28 | 2015-10-28 | 福建省格林春天科技有限公司 | A kind of wallpaper use ink with repelling effect and preparation method thereof |
| CN204551957U (en) * | 2015-03-12 | 2015-08-12 | 江苏北台壁纸实业有限公司 | The Environment-friendlywallpaper wallpaper that a kind of separable anti-mite is degerming |
| CN205077330U (en) * | 2015-10-08 | 2016-03-09 | 浙江江山百艺装饰材料有限公司 | Antibiotic expelling parasite wall paper of anti -hemming |
| CN205259524U (en) * | 2015-12-09 | 2016-05-25 | 广东玉兰集团股份有限公司 | Embroidery effect wall paper |
| CN105625094A (en) * | 2015-12-28 | 2016-06-01 | 佛山市天元汇邦装饰材料有限公司 | Mite prevention artificial decoration paper and preparing method thereof |
| CN106013642A (en) * | 2016-06-21 | 2016-10-12 | 钱学东 | Aramid 1313 fiber wallpaper |
-
2016
- 2016-10-27 CN CN201610955461.3A patent/CN106401099B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106401099A (en) | 2017-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106401099B (en) | A kind of anti-mite wallpaper and preparation method thereof | |
| CN106368397B (en) | A kind of mosquito-proof wallpaper and preparation method thereof | |
| WO2018056551A1 (en) | Eco-friendly biodegradable mulching material with improved tensile strength | |
| JP2016199551A (en) | Cosmetic adhesive composition | |
| CN103113039A (en) | Diatom-ooze indoor-wall decoration material | |
| CN106047280A (en) | Artificial veneer composite formaldehyde-free adhesive and preparation method thereof | |
| CN102499236B (en) | Solid microemulsion comprising pyrethroid pesticide and preparation method of solid microemulsion | |
| CN108294058A (en) | A kind of safety and environmental protection effective, harmless slow-release pesticidal particle and preparation method thereof | |
| AU2003244384A1 (en) | Method of controlling acarian and device for use in the same | |
| CN105419192A (en) | Nontoxic elastic plasticine and preparation method thereof | |
| KR20120021904A (en) | Furniture manufacturing method using eco-friendly flame retardant | |
| CN105287667A (en) | Traditional Chinese medicine liquid patch for treating arthritis and rheumatism | |
| JPH10500676A (en) | Novel pestiside composition of "oil-in-water emulsion" | |
| CN206205312U (en) | A kind of mosquito-proof wallpaper | |
| CN106035394A (en) | Preparation method of microcapsule mosquito-repellent incense liquid on basis of wormwood oil | |
| KR102022194B1 (en) | Whitening mask pack composition having enhenced adhesive property | |
| CN1926990A (en) | Environmental protection cockroach eradication tablet(agent) | |
| JP4627970B2 (en) | MICROCAPSULE FOR FIBER TREATMENT AND FIBER STRUCTURE HAVING THE SAME | |
| CN105625094A (en) | Mite prevention artificial decoration paper and preparing method thereof | |
| CN113891654A (en) | Compositions and methods for parasite control | |
| CN101233859A (en) | Method for preparing antibacterial agent for shoes | |
| CN107780293A (en) | A kind of insect prevention antibacterial honeycomb paper and preparation method thereof | |
| CN108184857A (en) | A kind of miticide composition containing second azoles mite nitrile with single carbonamidine | |
| CN108077273A (en) | A kind of miticide composition containing second azoles mite nitrile and Amitraz | |
| EP2249637A1 (en) | Adhesive compositions capable of completely removing acari, bacteria, moths, ticks, fleas from fabrics and animal's hair |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |