CN105616175A - Shape-restoring hydrogel composition for mask pack and producing method thereof - Google Patents
Shape-restoring hydrogel composition for mask pack and producing method thereof Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
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Abstract
The present invention relates to a hydrogel composition for a mask pack capable of self-shape restoring, and a production method thereof. More specifically, the hydrogel composition contains PEG-240/HDI copolymer bis-decyltetraceth-20 ether which is an associative polymer, thereby having a function of self-shape restoring, unlike a general hydrogel. The hydrogel composition contains a solvent comprising, based on a total weight of the composition, 0.1-2.0 wt% of PEG-240/HDI copolymer bis-decyltetraceth-20 ether which is an associative polymer, 0.4-5.0 wt% of a natural polymer gelling agent, 0.1-1.0 wt% of an electrolyte, 1.0-60.0 wt% of a skin active ingredient, 10.0-30.0 wt% of a polyhydric alcohol as a plasticizer, a preservative, a pH adjusting agent, and water. The hydrogel composition according to the present invention is a hydrogel which is produced in advance in a form of a mask or patch, and whose transformed shape is restored by itself by a function of self-shape restoring of PEG-240/HDI copolymer bis-decyltetraceth-20 ether when produced, formed, or used. Also, damages to a gel and syneresis can be suppressed by improved elasticity without adding a polymer gelling agent, whereby a shape of a mask can be maintained for a long time.
Description
Technical field
The present invention relates to hydrogel, more specifically, relate to a kind of including and there is the function recovering form voluntarily and obtain the elastic characteristic improved and the high molecular facial film hydrogel composition of associativity suppressing bleed characteristic.
Background technology
Hydrogel is as the material with High water cut characteristic containing large quantity of moisture, and such as medical science, pharmacy, prosthese and contact lens etc., its application presents diversified trend. Recently, it is not only wound dressing, drug delivery medium, and at cosmetic field, is also act as moisturizing, nutrition supply, improves the facial film of various usefulness purposes such as wrinkle, whitening.
Generally speaking, the hydrogel being made up of natural high molecular substance produces by helping the working procedures such as liquid molding, processing, packaging, due to external factor and gel self bleed phenomenons such as accumulation, compressions after molding, the configuration of surface that there is gel is damaged, or when using goods, cause the problem that form is likely to part deformation because of the using method of consumer.
Therefore, in order to overcome this problem, it is desirable to a kind of improved facial film hydrogel composition, even if there is surface damage during using in the production process of plurality of step and consumer after formation, it also is able to recover voluntarily form, greatly improves elastic force, it is suppressed that bleed phenomenon.
Summary of the invention
Invention to solve the technical problem that
Present invention seek to address that the problem recorded above, it is provided that there is self-form return function and the facial film hydrogel composition of the elastic characteristic obtaining raising and manufacture method thereof.
The technological means of the problem for solving
For reaching this purpose, the present invention provides the facial film hydrogel composition included as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether (PEG-240/HDICopolymerBis-Decetyltetradeceth-20Ether).
It is water-soluble polymer as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether, the gel being distributed in water is the characteristic of spring-like resilience after showing high resiliency and deforming because of pressure, it addition, aerosol apparatus injection can be carried out, there is the characteristic of anti-salt. Utilize this PEG-240/HDI copolymer double; two-characteristic of decyl tetradecyl alcohol polyethers-20 ether, it is possible to recover the production process of multiple steps after molding voluntarily and consumer use during the surface damage of hydrogel that occurs, and greatly improve elastic force.
Containing as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether such that it is able to reduce temperature conditions when manufacturing, it is achieved in the advantage increasing production efficiency. Generally speaking, natural polymer hydrogel is when heating to about 90��95 DEG C, realize the mix and blend of multiple components, but final warm temperature can be reduced to about 80��85 DEG C containing the high molecular hydrogel of associativity and realize mix and blend, it is possible to improve production efficiency.
Additionally, even if in forming step, common hydrogel often uses the supporting layer of such as non-woven fabrics, net, net, but the application high molecular hydrogel of associativity increases due to elastic and restoration, without using this supporting layer also to be able to molding, thus the advantage with the production efficiency that can greatly improve in processing and forming step.
The present invention contain as the high molecular PEG-240/HDI copolymer of associativity double; two-decyl tetradecyl alcohol polyethers-20 ether, be benchmark by hydrogel composition gross weight, it is possible to containing 0.1��2.0 weight %. If the content of PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether is less than 0.1 weight %, then do not form gel, and, recuperability or the elastic effect that increases also cannot be expected. On the contrary, if the content of PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether is more than 2.0 weight %, then gel viscosity is too high, there is the difficulty in manufacturing process, the bleed power of extra-inhibitory end article, the skin absorption of beautifying skin composition is harmed.
It addition, the natural polymer gel benchmark by weight comprising carrageenan can contain 0.4��5.0 weight %. Described natural high molecular substance mixes two or more and uses, and has the effect making gel strength increase, and ratio more preferably constitutes the ratio of 3:7 to 7:3. If the content of natural polymer gel is below 0.4 weight %, then viscosity is too low, the formation difficulty of gel, the characteristic of gel cannot be shown, on the contrary, if being more than 5.0 weight %, then the much higher hard of gel, loss of adhesion, has the characteristic that the use sense as facial film is low. It addition, when the content of carrageenan and other natural polymer gel is than during less than 3:7, the intensity of gel is excessively weak, there is the problem that gel is easily broken, if content ratio is more than 7:3, then the intensity of gel excessively increases, manufacturing process has difficulties, and there is the problem that adhesive force greatly reduces.
It addition, for the tearing strength improving natural high molecular substance, it is possible to use electrolyte. This is because electrolyte forms crosslinking (Crosslinking) with described natural high molecular substance. Now, electrolyte can use more than a kind in potassium chloride, magnesium chloride, sodium chloride, calcium chloride, and the potassium chloride of 0.1��0.5 weight % is particularly preferably used. When electrolyte content is less than 0.1 weight %, gel strength is too low, and the phenomenon that gel junk is torn occurs, on the contrary, if content is more than 0.5 weight %, then and the much higher hard of gel, show the tendency that the adhesion property as hydrogel declines.
Additionally, as skin active ingredient, can contain and there is the composition improving wrinkle, whitening, moisturizing, nutrition supply function, the compositions more than a kind such as such as adenosine, arbutin, hyaluronic acid, glycerol, butanediol, collagen protein, Herba portulacae extract, tocopherol acetas, disodiumedetate, ethohexadiol, caprylin, but be not limited thereto. Skin active ingredient preferably comprises 1.0 to 60.0 weight %. If the content of skin active ingredient is less than 1.0 weight %, then it is difficult to cosmetic result and the skin improvement effects of expecting to produce because of skin absorption, on the contrary, when considering the interpolation content of associativity macromolecule, natural polymer gel, electrolyte, preservative agent and other composition, the content of skin active ingredient more than 60.0 weight % interpolations in have difficulties.
The present invention relates to a kind of facial film hydrogel composition, it is characterized in that, containing as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether, natural polymer gel, electrolyte, skin active ingredient and solvent, having oneself's form return function and the elastic characteristic obtaining raising when deforming because of pressure, bleed phenomenon is few.
Additionally, the present invention relates to a kind of facial film hydrogel composition, it is characterized in that, by composition total weight benchmark, containing as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether 0.1 to 2.0 weight %, natural polymer gel 0.4 to 5.0 weight %, electrolyte 0.1 to 1.0 weight %, skin active ingredient 1.0 to 60.0 weight %.
Additionally, the present invention relates to a kind of facial film hydrogel composition, it is characterized in that, described natural polymer gel contains the one kind or two or more of the group of the free carrageenan of choosing (CarrageenanGum), xanthan gum (XanthanGum), cassia gum (CassiaGum), gellan gum (GellanGum), locust bean gum, agar, Algin, mannan (Mannan), guar gum (GuarGum), poloxamer (Pluronic), pectin (Pectin) and cellulose composition.
Moreover, it relates to a kind of molded body manufacture method utilizing facial film hydrogel composition, it is characterised in that including:
A. the step manufacturing mixed liquor as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether, natural polymer gel, electrolyte, skin active ingredient and solvent is mixed;
B. the mixed liquor of described a is heated at 70 to 90 DEG C and dissolve and manufacture the step of gel mixture; And
C. the gel mixture of described heating is put into mould at 60 to 65 DEG C and manufacture the step of gelatinous hydrogel molded body.
Invention effect
The hydrogel composition of the present invention is as being fabricated to facial film or the hydrogel of sheet form in advance, self-form return function by means of PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether, when making manufacture molding or use, the form of deformation is recovered voluntarily, and owing to obtaining the elasticity improved, without adding polymeric gel agent, also suppress breakage and the bleed phenomenon of gel, there is the advantage keeping facial film form for a long time.
Accompanying drawing explanation
Fig. 1 is that the form as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether restores photo.
The form that Fig. 2 is the hydrogel containing PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether recovers photo.
Fig. 3 is the elastic chart of the hydrogel under different PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether content.
Detailed description of the invention
Embodiments of the invention are described in detail below. Following embodiment is for illustrating to the present invention, and the scope of the present invention is not limited within the scope of the record of embodiment, and this is that those skilled in the art are self-evident.
<embodiment 1>
Using as associativity high molecular PEG-240/HDI copolymer double; two-decyl tetradecyl alcohol polyethers-20 ether 0.1 weight %, natural polymer gel carrageenan 1.2 weight %, locust bean gum 1.2 weight %, electrolyte 0.2 weight %, plasticizer 20.0 weight %, skin useful composition 10.0 weight %, preservative agent, the stirring of heating at 80 DEG C such as solubilizing agent and spice, it is compressed molding, manufactures hydrogel composition.
<embodiment 2>
Using as associativity high molecular PEG-240/HDI copolymer double; two-decyl tetradecyl alcohol polyethers-20 ether 1.0 weight %, natural polymer gel carrageenan 1.2 weight %, locust bean gum 1.2 weight %, electrolyte 0.2 weight %, plasticizer 20.0 weight %, skin useful composition 10.0 weight %, preservative agent, the stirring of heating at 80 DEG C such as solubilizing agent and spice, it is compressed molding, manufactures hydrogel composition.
<embodiment 3>
Using as associativity high molecular PEG-240/HDI copolymer double; two-decyl tetradecyl alcohol polyethers-20 ether 2.0 weight %, natural polymer gel carrageenan 1.2 weight %, locust bean gum 1.2 weight %, electrolyte 0.2 weight %, plasticizer 20.0 weight %, skin useful composition 10.0 weight %, preservative agent, the stirring of heating at 80 DEG C such as solubilizing agent and spice, it is compressed molding, manufactures hydrogel composition.
<comparative example 1>
Except as except the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether, manufacture hydrogel composition with the method identical with embodiment.
<comparative example 2>
Using as associativity high molecular PEG-240/HDI copolymer double; two-decyl tetradecyl alcohol polyethers-20 ether 3.0 weight %, natural polymer gel carrageenan 1.2 weight %, locust bean gum 1.2 weight %, electrolyte 0.2 weight %, plasticizer 20.0 weight %, skin useful composition 10.0 weight %, preservative agent, the stirring of heating at 80 DEG C such as solubilizing agent and spice, it is compressed molding, manufactures hydrogel composition.
[table 1]
<test example 1>
Confirm the self-form restoration characteristics of the hydrogel composition of described manufacture.
Oneself's form restoration characteristics is, after making deformation to the power of the hydrogel applying physics manufactured, to be visually confirmed to be the degree recovered after given time. In order to confirm, test piece manufactures test portion by thickness 5.0mm, diameter 8cm and has measured. In FIG, measurement result is shown with photo.
<test example 2>
Confirm the elastic characteristic of the hydrogel composition of described manufacture.
Gel elastomer utilizes Instron5569 (Instronco.USA) to measure at normal temperatures. In order to measure, the thickness of test piece is 5.0mm, and diameter is 10mm, and every kind of test portion manufactures 3 test piece measurements. During measurement, crosshead (Crosshead) speed is 10mm/min., it is thus identified that test piece returns to the measurement result value during original state when removing pressure after realizing 50% deformation.
With without the high molecular comparative example 1 of associativity for benchmark, compare elastic characteristic value, comparative example 2 due to viscosity formed higher, generation problem in hydrogel molding, thus except. The content confirming associativity macromolecule PEG-240/HDI copolymer pair-decyl tetradecyl alcohol polyethers-20 ether more increases, the tendency that form restoration characteristics and elastic force also more increase. Its result is shown in Fig. 2.
<test example 3>
Confirm the bleed rejection characteristic of the hydrogel composition of described manufacture.
After the hydrogel composition that comparative example 1 and embodiment 2 are manufactured takes care of 5 day time respectively at normal temperatures, observe bleed rejection characteristic by means of the amount measuring bleed. In order to confirm condensate rate, in transparent circular plastics test piece, after test portion being shaped by thickness 5.0mm, diameter 8cm size, electronic scale is utilized to measure gross weight after manufacture, 1��5 day time of keeping when cover lid, wiping every day, after the content of surface bleed, measures weight in the same way, thus measures condensate rate. Its result is it can be seen that compared with the condensate rate in comparative example 1, the condensate rate in embodiment 2 is minimum, and in gel structure, deforms also little. Thus it is confirmed that, the hydrogel composition of the present invention has suitable bleed, and gel deformation is little, has and is suitable for the long-time characteristic used.
[table 2]
<test example 4>
Confirm pH value and the stability of the hydrogel of described manufacture. The result measured, pH increases slightly along with the increase of associativity macromolecule content, but meets common cosmetics pH scope, and stability shows good end value in whole test portions. Comparative example 2 owing to viscosity is high, be difficult to hydrogel molding and except. Estimation of stability result is shown in table 3.
[table 3]
Zero: good ��: common X: weak
<test example 5>
Use sense for the hydrogel manufactured with embodiment 1��3 and comparative example 1��2 is restored with form, implements questionnaire survey towards 20 20��40 years old common womans, its result is shown in table 4. Comparative example 2 because of hydrogel difficult forming except.
[table 4]
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| Moisturizing power | 4 | 5 | 5 | 4 |
| Use sense | 4 | 5 | 5 | 3 |
| Form recuperability | 2 | 5 | 5 | 1 |
Outstanding: 5, slightly outstanding: 4, common: 3, slightly weak: 2, faint: 1
Claims (2)
1. a facial film hydrogel composition, it is characterised in that
Contain as the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether, natural polymer gel, electrolyte, skin active ingredient and solvent,
By composition total weight benchmark, contain:
As the high molecular PEG-240/HDI copolymer of associativity pair-decyl tetradecyl alcohol polyethers-20 ether 0.1 to 2.0 weight %;
In the group being made up of carrageenan xanthan gum, cassia gum, gellan gum, locust bean gum, agar, Algin, mannan, guar gum, poloxamer, pectin and cellulose, include one kind or two or more natural polymer gel 0.4 to the 5.0 weight % of carrageenan selection;
Electrolyte 0.1 to 1.0 weight %;
Have and include improving wrinkle, skin-whitening, moisture content supply, nutrition supply and improve skin active ingredient 1.0 to the 60.0 weight % of more than a kind of beautifying skin function of skin elasticity; And
The solvent of surplus,
Described facial film hydrogel composition does not use other support layer and molding, can oneself's form restore when deforming because of pressure.
2. facial film hydrogel composition according to claim 1, it is characterised in that
Described electrolyte is selected from potassium chloride, magnesium chloride, sodium chloride, the electrolyte of more than a kind of calcium chloride.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0194596 | 2014-12-31 | ||
| KR1020140194596A KR101525403B1 (en) | 2014-12-31 | 2014-12-31 | Shape-restoring hydrogel composition for mask pack and producing method thereof |
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| Publication Number | Publication Date |
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| CN105616175A true CN105616175A (en) | 2016-06-01 |
| CN105616175B CN105616175B (en) | 2018-05-04 |
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| CN201510976952.1A Active CN105616175B (en) | 2014-12-31 | 2015-12-23 | Self form restoring type facial mask hydrogel composition and its manufacture method |
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| CN (1) | CN105616175B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108066174A (en) * | 2016-11-10 | 2018-05-25 | 上海家化联合股份有限公司 | A kind of easy picking, the stabilization composition of Self-leveling and its application |
| CN111374907A (en) * | 2018-12-29 | 2020-07-07 | 伽蓝（集团）股份有限公司 | Skin moisturizer as well as preparation method and application thereof |
| WO2020237670A1 (en) * | 2019-05-31 | 2020-12-03 | L'oreal | Cosmetic composition in the form of moldable and stretchable gel |
| CN112654343A (en) * | 2018-05-28 | 2021-04-13 | 欧莱雅 | Composition in the form of a shape memory gel cream |
| CN115813808A (en) * | 2022-11-24 | 2023-03-21 | 上海家化联合股份有限公司 | Cooling and itching relieving composition |
| CN115813809A (en) * | 2022-11-24 | 2023-03-21 | 上海家化联合股份有限公司 | Viscosity-controllable composition and use thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102002282B1 (en) | 2017-09-08 | 2019-07-23 | 코스맥스 주식회사 | Transparent Gel Cosmetic Composition |
| CN110711171A (en) * | 2019-11-03 | 2020-01-21 | 上海悦目化妆品有限公司 | Mirror cream with wrinkle removing and repairing effects |
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| CN102836089A (en) * | 2012-09-20 | 2012-12-26 | 上海进瑞实业有限公司 | Spraying skin-protecting cosmetic composition and application thereof |
| CN102869725A (en) * | 2010-04-28 | 2013-01-09 | 株式会社资生堂 | Thickening composition and cosmetics containing same |
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| JP5462465B2 (en) * | 2008-10-15 | 2014-04-02 | 小川香料株式会社 | Method for producing aqueous gel fragrance composition |
| JP5539769B2 (en) * | 2010-03-29 | 2014-07-02 | 株式会社コーセー | Hydrous gel sheet |
| KR101301378B1 (en) * | 2011-01-03 | 2013-08-29 | 한국콜마주식회사 | Manufacturing Method of Oil-in-Water Type Foundation Composition Showing Shape-Memory Phenomenon |
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| CN102869725A (en) * | 2010-04-28 | 2013-01-09 | 株式会社资生堂 | Thickening composition and cosmetics containing same |
| CN102836089A (en) * | 2012-09-20 | 2012-12-26 | 上海进瑞实业有限公司 | Spraying skin-protecting cosmetic composition and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108066174A (en) * | 2016-11-10 | 2018-05-25 | 上海家化联合股份有限公司 | A kind of easy picking, the stabilization composition of Self-leveling and its application |
| CN108066174B (en) * | 2016-11-10 | 2020-09-08 | 上海家化联合股份有限公司 | Stable composition easy to pick and self-level and application thereof |
| CN112654343A (en) * | 2018-05-28 | 2021-04-13 | 欧莱雅 | Composition in the form of a shape memory gel cream |
| CN112654343B (en) * | 2018-05-28 | 2023-05-16 | 欧莱雅 | Composition in the form of a shape memory gel-like cream |
| CN111374907A (en) * | 2018-12-29 | 2020-07-07 | 伽蓝（集团）股份有限公司 | Skin moisturizer as well as preparation method and application thereof |
| WO2020237670A1 (en) * | 2019-05-31 | 2020-12-03 | L'oreal | Cosmetic composition in the form of moldable and stretchable gel |
| CN113873984A (en) * | 2019-05-31 | 2021-12-31 | 莱雅公司 | Cosmetic composition in the form of a mouldable and stretchable gel |
| CN115813808A (en) * | 2022-11-24 | 2023-03-21 | 上海家化联合股份有限公司 | Cooling and itching relieving composition |
| CN115813809A (en) * | 2022-11-24 | 2023-03-21 | 上海家化联合股份有限公司 | Viscosity-controllable composition and use thereof |
| WO2024109460A1 (en) * | 2022-11-24 | 2024-05-30 | 上海家化联合股份有限公司 | Viscosity-controllable composition and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101525403B1 (en) | 2015-06-03 |
| CN105616175B (en) | 2018-05-04 |
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