CN105616175B - Self form restoring type facial mask hydrogel composition and its manufacture method - Google Patents

Self form restoring type facial mask hydrogel composition and its manufacture method Download PDF

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Publication number
CN105616175B
CN105616175B CN201510976952.1A CN201510976952A CN105616175B CN 105616175 B CN105616175 B CN 105616175B CN 201510976952 A CN201510976952 A CN 201510976952A CN 105616175 B CN105616175 B CN 105616175B
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weight
electrolyte
hydrogel composition
high molecular
skin
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CN105616175A (en
Inventor
金泰勋
李根秀
表亨培
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Ian hanbul Corporation
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Ian Hanbul Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties

Abstract

The present invention relates to self form restoring type facial mask hydrogel composition, more specifically, be related to it is a kind of be different from common hydrogel, containing there is the hydrogel composition of self form return function as double 20 ethers of decyl tetradecyl alcohol polyethers of associativity high molecular PEG 240/HDI copolymers.It is characterized in that, on the basis of composition total weight, containing as 20 ether of the double decyl tetradecyl alcohol polyethers of associativity high molecular PEG 240/HDI copolymers, 0.1 to 2.0 weight %, 0.4 to 5.0 weight % of natural polymer gelling agent, the weight of electrolyte 0.1 to 1.0 %, 1.0 to 60.0 weight % of skin effective ingredient, the weight of polyalcohol 10.0 to 30.0 % as plasticizer, preservative agent, pH adjusting agent and its outside the solvent for including water.

Description

Self form restoring type facial mask hydrogel composition and its manufacture method
Technical field
The present invention relates to hydrogel, more specifically, is related to a kind of including having the function of voluntarily to recover form and obtaining The elastic characteristic of raising and the high molecular facial mask hydrogel composition of associativity for suppressing bleed characteristic.
Background technology
Hydrogel is as the material with High water cut characteristic containing large quantity of moisture, such as medicine, pharmacy, prosthese and stealthy eye Diversified trend is presented in mirror etc., its application field.Recently, wound dressing, drug delivery medium are not only, and is led in cosmetics Domain, is also act as moisturizing, nutrition supply, the facial mask for improving various efficiency purposes such as wrinkle, whitening.
In general, by the hydrogel that natural high molecular substance is formed by helping the working procedures such as liquid shaping, processing, packaging And produce, damaged after shaping due to external factor and gel itself bleed phenomenon, the configuration of surface there are gel such as accumulating, compressing Wound, or when using product, cause form may a part of the problem of deforming because of the application method of consumer.
Therefore, in order to overcome this problem, it is desirable to a kind of improved facial mask hydrogel composition, even in shaping Surface damage occurs during use for the production process of plurality of step and consumer afterwards, also can voluntarily recover form, be greatly improved Elastic force, suppresses bleed phenomenon.
The content of the invention
Technical problems to be solved by the inivention
Present invention seek to address that the problem of recording above, there is provided there is self form return function and the elasticity being improved The facial mask hydrogel composition and its manufacture method of characteristic.
For the technological means solved the problems, such as
To reach this purpose, the present invention, which provides, to be included as associativity high molecular PEG-240/HDI copolymers pair-last of the ten Heavenly stems The facial mask of -20 ether of base tetradecyl alchohol polyethers (PEG-240/HDI Copolymer Bis-Decetyltetradeceth-20Ether) Use hydrogel composition.
It is water-soluble polymeric as associativity high molecular PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers Thing, the characteristic of spring-like rebound after the gel being distributed in water shows high resiliency and deformed because of pressure, in addition, can Sprayer injection is carried out, the characteristic with salt resistance.Utilize this PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers Characteristic, can voluntarily recover the hydrogel that the production process of multiple steps and consumer occur during use after shaping Surface damage, and elastic force is greatly improved.
Containing as associativity high molecular PEG-240/HDI copolymers it is double--20 ether of decyl tetradecyl alcohol polyethers, so as to Enough temperature conditionss reduced when manufacturing, the advantages of being achieved in increasing production efficiency.In general, natural polymer hydrogel exists It is heated up in the state of 90~95 DEG C or so, realizes the mixing of multiple components, but contain the high molecular hydrogel of associativity Final warm temperature can be reduced to 80~85 DEG C or so and realize mixing, production efficiency can be improved.
In addition, in forming step, common hydrogel is often using such as non-woven fabrics, the support of mesh, net Layer, but the application high molecular hydrogel of associativity is due to elasticity and restoration increase, also can be into without using this supporting layer Type, so as to have the advantages that the production efficiency that can be greatly improved in processing and forming step.
What the present invention contained is used as associativity high molecular PEG-240/HDI copolymers pair-decyl tetradecyl alcohol polyethers -20 Ether, on the basis of hydrogel composition gross weight, can contain 0.1~2.0 weight %.If PEG-240/HDI copolymers pair- The content of -20 ether of decyl tetradecyl alcohol polyethers does not form gel then, moreover, recuperability or elasticity increase less than 0.1 weight % Effect can not be also expected.On the contrary, if the content of PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers is more than 2.0 Weight %, then gel viscosity is excessive, and there are the difficulty in manufacturing process, and the bleed power of extra-inhibitory end article, harms skin The skin of skin beauty composition absorbs.
In addition, the natural polymer gelling agent benchmark by weight comprising carragheen can contain 0.4~5.0 weight %.Institute State natural high molecular substance and mix two or more use, there is the effect for making gel strength increase, ratio more preferably forms 3:7 to 7:3 ratio.If the content of natural polymer gelling agent is below 0.4 weight %, then viscosity is too low, and the formation of gel is stranded Difficulty, can not show the characteristic of gel, on the contrary, if more than 5.0 weight %, then the excessive high hardness of gel, adhesive force decline, With the low characteristic of the use feeling as facial mask.In addition, when carragheen and other natural polymer gelling agents content ratio not Foot 3:When 7, the intensity of gel is excessively weak, the problem of being easily broken there are gel, if content ratio is more than 7:3, then the intensity of gel The problem of excessively increase, manufacturing process has difficulties, greatly reduces there are adhesive force.
In addition, in order to improve the tearing strength of natural high molecular substance, electrolyte can be used.This is because electrolyte with The natural high molecular substance forms crosslinking (Crosslinking).At this time, electrolyte can use potassium chloride, magnesium chloride, chlorine Change more than a kind in sodium, calcium chloride, particularly preferably using the potassium chloride of 0.1~0.5 weight %.When electrolyte content deficiency During 0.1 weight %, gel strength is too low, is torn there is a phenomenon where gel is tattered, if on the contrary, content more than 0.5 weight %, The excessive high hardness of gel, shows the tendency of the adhesion property decline as hydrogel.
In addition, as skin effective ingredient, can contain have the function of improvement wrinkle, whitening, moisturizing, nutrition supply into Part, such as adenosine, ursin, hyaluronic acid, glycerine, butanediol, collagen, purslane extract, tocopherol acetate, second More than a kind of the compositions such as edetate disodium, ethohexadiol, glycerol caprylate, but be not limited thereto.Skin effective ingredient Preferably comprise 1.0 to 60.0 weight %.If the content of skin effective ingredient is difficult to expect because of skin less than 1.0 weight % The cosmetic result and skin improvement effects for absorbing and producing, on the contrary, when in view of associativity macromolecule, natural polymer gel Agent, electrolyte, preservative agent and other compositions addition content when, add the content of skin effective ingredient more than 60.0 weight % Aspect is added to have difficulties.
The present invention relates to a kind of facial mask hydrogel composition, it is characterised in that containing high molecular as associativity PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers, natural polymer gelling agent, electrolyte, skin effective ingredient And solvent, it is few with self form return function when being deformed because of pressure and the elastic characteristic being improved, bleed phenomenon.
A kind of moreover, it relates to facial mask hydrogel composition, it is characterised in that by composition total weight benchmark, Containing as associativity high molecular PEG-240/HDI copolymers it is double -0.1 to 2.0 weight % of -20 ether of decyl tetradecyl alcohol polyethers, 0.4 to 5.0 weight % of natural polymer gelling agent, the weight of electrolyte 0.1 to 1.0 %, 1.0 to 60.0 weight of skin effective ingredient Measure %.
A kind of moreover, it relates to facial mask hydrogel composition, it is characterised in that the natural polymer gelling agent Containing selected from cold by carragheen (Carrageenan Gum), xanthans (XanthanGum), cassia gum (Cassia Gum), knot Glue (Gellan Gum), locust bean gum, agar, algin, mannosan (Mannan), guar gum (Guar Gum), pool Lip river The group that husky nurse (Pluronic), pectin (Pectin) and cellulose are formed it is one kind or two or more.
Moreover, it relates to a kind of shaping manufacturing method using facial mask hydrogel composition, it is characterised in that Including：
A. mix as associativity high molecular PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers, naturally Polymeric gel agent, electrolyte, skin effective ingredient and solvent and the step of manufacture mixed liquor；
B. the mixed liquor of a is heated at 70 to 90 DEG C the step of dissolving and manufacturing gel mixture；And
C. the gel mixture of the heating is put into molding die at 60 to 65 DEG C and manufactures gelatinous hydrogel The step of formed body.
Invention effect
The present invention hydrogel composition as pre-production into facial mask or the hydrogel of piece form, by means of PEG-240/ HDI copolymers are double-self form return function of -20 ether of decyl tetradecyl alcohol polyethers, make to be manufactured or shape that when use deforms State is voluntarily recovered, and due to the elasticity being improved, without adding polymeric gel agent, also suppresses breakage and the bleed of gel Phenomenon, has the advantages that to keep facial mask form for a long time.
Brief description of the drawings
Fig. 1 is the form as associativity high molecular PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers Restore photo.
Fig. 2 is that the form of the hydrogel containing PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers is recovered to shine Piece.
Fig. 3 is the elasticity of the hydrogel under different PEG-240/HDI copolymers pair--20 ether content of decyl tetradecyl alcohol polyethers Chart.
Embodiment
The embodiment of the present invention is described in detail below.Following embodiments are used to illustrate to the present invention, the present invention Scope be not limited in the record scope of embodiment, this is that those skilled in the art are self-evident 's.
1 ＞ of ＜ embodiments
Using as associativity high molecular PEG-240/HDI copolymers it is double -0.1 weight % of -20 ether of decyl tetradecyl alcohol polyethers, 1.2 weight % of natural polymer gelling agent carragheen, 1.2 weight % of locust bean gum, 0.2 weight % of electrolyte, plasticizer 20.0 Weight %, skin useful 10.0 weight % of composition, preservative agent, solubilizer and spices etc. heat stirring at 80 DEG C, are compressed Shaping, has manufactured hydrogel composition.
2 ＞ of ＜ embodiments
Using as associativity high molecular PEG-240/HDI copolymers it is double -1.0 weight % of -20 ether of decyl tetradecyl alcohol polyethers, 1.2 weight % of natural polymer gelling agent carragheen, 1.2 weight % of locust bean gum, 0.2 weight % of electrolyte, plasticizer 20.0 Weight %, skin useful 10.0 weight % of composition, preservative agent, solubilizer and spices etc. heat stirring at 80 DEG C, are compressed Shaping, has manufactured hydrogel composition.
3 ＞ of ＜ embodiments
Using as associativity high molecular PEG-240/HDI copolymers it is double -2.0 weight % of -20 ether of decyl tetradecyl alcohol polyethers, 1.2 weight % of natural polymer gelling agent carragheen, 1.2 weight % of locust bean gum, 0.2 weight % of electrolyte, plasticizer 20.0 Weight %, skin useful 10.0 weight % of composition, preservative agent, solubilizer and spices etc. heat stirring at 80 DEG C, are compressed Shaping, has manufactured hydrogel composition.
1 ＞ of ＜ comparative examples
In addition to double--20 ether of decyl tetradecyl alcohol polyethers as associativity high molecular PEG-240/HDI copolymers, with The identical method of embodiment has manufactured hydrogel composition.
2 ＞ of ＜ comparative examples
Using as associativity high molecular PEG-240/HDI copolymers it is double -3.0 weight % of -20 ether of decyl tetradecyl alcohol polyethers, 1.2 weight % of natural polymer gelling agent carragheen, 1.2 weight % of locust bean gum, 0.2 weight % of electrolyte, plasticizer 20.0 Weight %, skin useful 10.0 weight % of composition, preservative agent, solubilizer and spices etc. heat stirring at 80 DEG C, are compressed Shaping, has manufactured hydrogel composition.
【Table 1】
1 ＞ of ＜ test examples
Confirm self form restoration characteristics of the hydrogel composition of the manufacture.
Self form restoration characteristics be to manufacture hydrogel apply physics power and cause deformation after, visually confirm through The degree recovered is crossed after given time.In order to confirm, test piece is measured by thickness 5.0mm, diameter 8cm manufacture sample. In Fig. 1, measurement result is shown with photo.
2 ＞ of ＜ test examples
Confirm the elastic characteristic of the hydrogel composition of the manufacture.
Gel elastomer is measured at normal temperatures using Instron 5569 (Instron co.USA).In order to measure, test piece Thickness is 5.0mm, a diameter of 10mm, and every kind of sample manufactures 3 test pieces and measures.During measurement, crosshead (Cross head) Speed is 10mm/min., it is thus identified that test piece returns to the measurement result value during original state when realizing and pressure is removed after 50% deformation.
On the basis of without the high molecular comparative example 1 of associativity, elastic characteristic value is compared, comparative example 2 is due to viscosity shape Into higher, occur problem in terms of water-setting gum forming, thus except.Confirm associativity macromolecule PEG-240/HDI copolymers The content of double--20 ether of decyl tetradecyl alcohol polyethers more increases, form restoration characteristics and elastic force also more increased tendency.Tied Fruit is shown in Fig. 2.
3 ＞ of ＜ test examples
Confirm the bleed rejection characteristic of the hydrogel composition of the manufacture.
After the hydrogel composition that comparative example 1 and embodiment 2 are manufactured takes care of 5 day time at normal temperatures respectively, by means of Measure the amount of bleed and observe bleed rejection characteristic.In order to confirm condensate rate, in transparent circular plastics test piece, by thickness After 5.0mm, diameter 8cm sizes are molded sample, gross weight after manufacturing is measured using electronic scale, in the shape to close the lid Taken care of under state 1~5 day time, wipe daily after the content of surface bleed, measure weight in the same way, thus measure Condensate rate.Its result understands that compared with the condensate rate in comparative example 1, the condensate rate in embodiment 2 is minimum, and in gel Configuration aspects, deformation are also small.Thus it is confirmed that hydrogel composition of the invention has suitable bleed, gel deformation It is small, there is the characteristic for being adapted to use for a long time.
【Table 2】
4 ＞ of ＜ test examples
Confirm the pH value and stability of the hydrogel of the manufacture.Measurement as a result, pH contains with associativity macromolecule The increase of amount and increase slightly, but meet common cosmetics pH scopes, stability shows good knot in whole samples Fruit value.Comparative example 2 due to viscosity is high, be difficult to water-setting gum forming and except.Estimation of stability the results show in table 3.
【Table 3】
○：Good ◇：Common X：It is weak
5 ＞ of ＜ test examples
Restored for by embodiment 1~3 and the use feeling of the hydrogel of the manufacture of comparative example 1~2 with the form of, towards 20 20 Common woman implements questionnaire survey within~40 years old, by its results show in table 4.Comparative example 2 is removed because of hydrogel difficult forming Outside.
【Table 4】
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1
Moisturizing power 4 5 5 4
Use feeling 4 5 5 3
Form recuperability 2 5 5 1
It is outstanding：5, it is slightly outstanding：4, commonly：3, it is slightly weak：2, it is faint：1

Claims (1)

  1. A kind of 1. facial mask hydrogel composition, it is characterised in that
    Containing as associativity high molecular PEG-240/HDI copolymers pair--20 ether of decyl tetradecyl alcohol polyethers, natural polymer Gelling agent, electrolyte, skin effective ingredient and solvent,
    By composition total weight benchmark, contain：
    As associativity high molecular PEG-240/HDI copolymers pair -0.1 to 2.0 weight % of -20 ether of decyl tetradecyl alcohol polyethers；
    By carragheen, xanthans, cassia gum, gellan gum, locust bean gum, agar, algin, mannosan, guar gum, In the group that pectin and cellulose are formed, two or more 0.4 to 5.0 weight of natural polymer gelling agent of selection including carragheen % is measured, wherein weight percentage of the carragheen in natural polymer gelling agent is 30%-70%；
    The weight of electrolyte 0.1 to 1.0 %, the electrolyte be selected from potassium chloride, magnesium chloride, sodium chloride, more than a kind of calcium chloride Electrolyte；
    With the beautifying skin work(including improving wrinkle, skin-whitening, moisture content supply, nutrition supply and improvement skin elasticity More than a kind of 1.0 to 60.0 weight % of skin effective ingredient of energy；And
    The solvent of surplus,
    The facial mask hydrogel composition is molded without using other support layer, being capable of self shape when being deformed because of pressure State is restored.
CN201510976952.1A 2014-12-31 2015-12-23 Self form restoring type facial mask hydrogel composition and its manufacture method Active CN105616175B (en)

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CN108066174B (en) * 2016-11-10 2020-09-08 上海家化联合股份有限公司 Stable composition easy to pick and self-level and application thereof
KR102002282B1 (en) 2017-09-08 2019-07-23 코스맥스 주식회사 Transparent Gel Cosmetic Composition
WO2019227275A1 (en) * 2018-05-28 2019-12-05 L'oreal Composition in the form of shape-memory gelly cream
CN111374907A (en) * 2018-12-29 2020-07-07 伽蓝（集团）股份有限公司 Skin moisturizer as well as preparation method and application thereof
CN113873984A (en) * 2019-05-31 2021-12-31 莱雅公司 Cosmetic composition in the form of a mouldable and stretchable gel
CN110711171A (en) * 2019-11-03 2020-01-21 上海悦目化妆品有限公司 Mirror cream with wrinkle removing and repairing effects
CN115813808A (en) * 2022-11-24 2023-03-21 上海家化联合股份有限公司 Cooling and itching relieving composition
CN115813809A (en) * 2022-11-24 2023-03-21 上海家化联合股份有限公司 Viscosity-controllable composition and use thereof

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