CN105603732A - Mercerizing penetrant for cotton fabrics and preparation method thereof - Google Patents

Mercerizing penetrant for cotton fabrics and preparation method thereof Download PDF

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Publication number
CN105603732A
CN105603732A CN201610102033.6A CN201610102033A CN105603732A CN 105603732 A CN105603732 A CN 105603732A CN 201610102033 A CN201610102033 A CN 201610102033A CN 105603732 A CN105603732 A CN 105603732A
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China
Prior art keywords
penetrating agent
parts
fatty alcohol
silkete penetrating
bafta
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CN201610102033.6A
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Chinese (zh)
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CN105603732B (en
Inventor
魏天堂
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SUZHOU SANHE KAITAI YARN WEAVING Co Ltd
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SUZHOU SANHE KAITAI YARN WEAVING Co Ltd
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Priority to CN201610102033.6A priority Critical patent/CN105603732B/en
Publication of CN105603732A publication Critical patent/CN105603732A/en
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a mercerizing penetrant for cotton fabrics. The mercerizing penetrant comprises, by weight parts, 40-60 parts of fatty alcohol succinate, 10-20 parts of sodium laurate, 5-12 parts of acrylic acid, 10-25 parts of emulsifier, 8-15 parts of glycerin and 10-30 parts of deionized water. The mercerizing penetrant has the advantages of having low foam and being good in permeability, easy to degrade and free of harmful gas, is an excellent-performance, green and environment-friendly mercerizing penetrant, and is suitable for industrial large-scale production.

Description

Silkete penetrating agent that a kind of bafta is used and preparation method thereof
Technical field:
The present invention relates to textile auxiliary field, silkete penetrating agent and preparation side thereof that particularly a kind of bafta is usedMethod.
Background technology:
Mercerization finish can improve glossiness and the absorption property of bafta, and can improve the chi of baftaVery little stability is very important cotton pretreatment link. But the concentration of lye using in mercerization finishHigher, can there is the problems such as viscosity is large, poor permeability, at the careless slightly bafta that will cause of operating processSurface mercerising phenomenon. Meanwhile, in mercerization finish process, due to poor permeability, can consume a large amount of alkaliLiquid, causes the waste of resource. Therefore in this processing procedure, add silkete penetrating agent, can greatly alleviate cotton and knitThe surperficial mercerising phenomenon of thing.
Silkete penetrating agent can make the surface tension of alkali lye reduce, and can also promote the infiltration of alkali lye simultaneously, not onlyCan make mercerization even, can also significantly shorten the time of mercerising. Common bleeding agent is because it is subject to turbidPoint and the large problem of foaming characteristic are difficult to application in mercerization. Meanwhile, silkete penetrating agent also need to be by forceIn aqueous slkali, can keep stable, and can not have influence on the recycling of strong base solution. Use comparatively at presentSilkete penetrating agent is generally to use cresols, fatty alcohol and ring ethanol widely, and the molecule of these compounds is less,Thereby vapour pressure is higher, can this class silkete penetrating agent in the time that recycle of alkali liquor is processed volatile go out harmful gas,Contaminated environment, and endanger the healthy of people.
Chinese patent 201510383102.0 discloses a kind of cellulose fibre mercerising and Alkali Weight Reduction Treatment of Polyester technique is usedSilkete penetrating agent and preparation method thereof, by weight percentage, this silkete penetrating agent comprises 30-50% trbasic zinc phosphateValue; 10-30%JFC phosphate; 10-30% amphoteric polymeric surfactant; 10-30% alkyl sugar acid anhydride. This silkThe alkaline-resisting 300gNaOH/L that reaches of light bleeding agent has fabulous in 180gNaOH/L-300gNaOH/L solutionPenetration. But this kind phosphate ester can produce accessory substance inorganic phosphate, this can produce corrosion, Er Qiehui to pipelineIrritant gaseous volatilization, affects the healthy of people.
Summary of the invention:
The present invention relates to the silkete penetrating agent that a kind of bafta is used, this silkete penetrating agent has low bubble, good penetrability,Easily degraded, without characteristics such as pernicious gases, is a kind of function admirable, and the silkete penetrating agent of environmental protection is applicable to workIndustry large-scale production.
Another object of the present invention is to provide the preparation method of this silkete penetrating agent.
For achieving the above object, the present invention is by the following technical solutions:
The silkete penetrating agent that bafta is used, is characterized in that, by weight, comprises following composition:
Fatty alcohol succinate 40-60 part, sodium laurate 10-20 part, acrylic acid 5-12 part, emulsifying agent 10-25Part, glycerine 8-15 part, deionized water 10-30 part.
Preferably, the silkete penetrating agent that a kind of bafta is used, is characterized in that, by weight, comprises followingComposition:
Fatty alcohol succinate 40-50 part, sodium laurate 12-16 part, acrylic acid 7-9 part, emulsifying agent 15-20Part, glycerine 10-14 part, deionized water 10-20 part.
Preferably, in wherein said fatty alcohol succinate, the carbon number of fatty alcohol is 4-10.
Preferably, in wherein said fatty alcohol succinate, the carbon number of fatty alcohol is 4-6.
Preferably, wherein said emulsifying agent is fatty glyceride, neopelex, sucrose ester or poly-One or more mixtures in sorb ester.
A preparation method for the silkete penetrating agent that bafta is used, is characterized in that, comprises the following steps:
(1), by fatty alcohol succinate, sodium laurate and acrylic acid, be dissolved in solvent, stir,Add emulsifying agent, high-speed stirred emulsification, after steaming desolventizes, adds glycerine and deionized water, stirs;
(2) to previous step produce mixed liquor in add NaOH solution, adjusting pH is 6-8, both cotton knittingThe silkete penetrating agent that thing is used.
Preferably, described in described step (1), solvent is ether, the one in ethanol or chloroform.
The present invention has following beneficial effect:
The silkete penetrating agent that bafta of the present invention is used does not comprise traditional phosphate composition, and penetration is good,Safe and harmless, environmental protection. And this silkete penetrating agent is in the time that recycle of alkali liquor is processed, and does not have irritative gasDischarge, the recycling of alkali lye is not impacted, do not affect the access times of alkali lye. This bafta is usedSilkete penetrating agent has good facilitation for the mercerization finish of bafta, the very applicable industrialization to scaleProduce.
Detailed description of the invention:
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment only usesIn explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
(1), by 60 parts of fatty alcohol succinates, 10 parts of sodium laurates and 5 parts of acrylic acid, be dissolved in solvent,Stir, add 25 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 10 parts of glycerine and 25Part deionized water, stirs;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Embodiment 2
(1), by 56 parts of fatty alcohol succinates, 18 parts of sodium laurates and 6 parts of acrylic acid, be dissolved in solvent,Stir, add 22 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 8 parts of glycerine and 30Part deionized water, stirs;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Embodiment 3
(1), by 53 parts of fatty alcohol succinates, 12 parts of sodium laurates and 10 parts of acrylic acid, be dissolved in solventIn, stir, add 20 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 9 parts of glycerineWith 15 parts of deionized waters, stir;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Embodiment 4
(1), by 47 parts of fatty alcohol succinates, 14 parts of sodium laurates and 7 parts of acrylic acid, be dissolved in solvent,Stir, add 17 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 10 parts of glycerine and 10Part deionized water, stirs;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Embodiment 5
(1), by 42 parts of fatty alcohol succinates, 16 parts of sodium laurates and 9 parts of acrylic acid, be dissolved in solvent,Stir, add 15 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 12 parts of glycerine and 15Part deionized water, stirs;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Embodiment 6
(1), by 40 parts of fatty alcohol succinates, 20 parts of sodium laurates and 12 parts of acrylic acid, be dissolved in solventIn, stir, add 10 parts of emulsifying agents, high-speed stirred emulsification, after steaming desolventizes, adds 14 parts of glycerineWith 20 parts of deionized waters, stir;
(2) in the mixed liquor producing to previous step, add NaOH solution, regulating pH is 7, has both obtained baftaWith silkete penetrating agent.
Above-described embodiment has all been carried out to alkaline-resisting permeance property test. Test operation method is: in 1000ml concentrationIn sodium hydroxide solution for 280g/L, add 5ml silkete penetrating agent, the circular standard that cut-off footpath is 3cmCanvas (18.2tex × 18.2tex) is put into sodium hydroxide solution. Under 20 DEG C of conditions, record standard sailThe wetting time of cloth, throws in standard canvas and starts the time till timing to canvas cloth cover all soaks. StandardThe wetting time of canvas is shorter, shows that the alkaline-resisting permeability of synthetic phosphoric acid ester sample is better, otherwise, alkaline-resisting infiltrationPerformance is poorer. Mean value result after test 5 is as shown in table 1, and unit is second.
Table 1

Claims (7)

1. the silkete penetrating agent that bafta is used, is characterized in that, by weight, comprises following composition:Fatty alcohol succinate 40-60 part, sodium laurate 10-20 part, acrylic acid 5-12 part, emulsifying agent 10-25Part, glycerine 8-15 part, deionized water 10-30 part.
2. the silkete penetrating agent that bafta according to claim 1 is used, is characterized in that, by weightMeter, comprises following composition: fatty alcohol succinate 40-50 part, sodium laurate 12-16 part, acrylic acid 7-9Part, emulsifying agent 15-20 part, glycerine 10-14 part, deionized water 10-20 part.
3. the silkete penetrating agent that bafta according to claim 1 and 2 is used, is characterized in that, described inIn fatty alcohol succinate, the carbon number of fatty alcohol is 4-10.
4. the silkete penetrating agent that bafta according to claim 1 and 2 is used, is characterized in that, described inIn fatty alcohol succinate, the carbon number of fatty alcohol is 4-6.
5. the silkete penetrating agent that bafta according to claim 1 and 2 is used, is characterized in that, described inEmulsifying agent is fatty glyceride, neopelex, one or more in sucrose ester or polysorbateMixture.
6. a preparation method for the silkete penetrating agent that bafta is used, is characterized in that, comprises the following steps:
(1), by fatty alcohol succinate, sodium laurate and acrylic acid, be dissolved in solvent, stir,Add emulsifying agent, high-speed stirred emulsification, after steaming desolventizes, adds glycerine and deionized water, stirs;
(2) to previous step produce mixed liquor in add NaOH solution, adjusting pH is 6-8, both cotton knittingThe silkete penetrating agent that thing is used.
7. the preparation method of the silkete penetrating agent that bafta according to claim 6 is used, is characterized in that,Described in described step (1), solvent is ether, the one in ethanol or chloroform.
CN201610102033.6A 2016-02-25 2016-02-25 A kind of silkete penetrating agent of cotton fabric and preparation method thereof Active CN105603732B (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106012603A (en) * 2016-07-27 2016-10-12 董荣琴 Novel high-temperature-resisting penetrant for leather
CN106065535A (en) * 2016-07-27 2016-11-02 刘慧宝 A kind of degradable dye penetrant of novel environment friendly
CN106222331A (en) * 2016-07-27 2016-12-14 董荣琴 A kind of degradable penetrating agent of New-type leather
CN106521936A (en) * 2016-10-14 2017-03-22 无锡市华诚印染剂厂 Quick penetrating agent for fabric
CN106676914A (en) * 2016-07-27 2017-05-17 董荣琴 Novel alkali-resistant penetrant for leather

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101703044A (en) * 2009-09-22 2010-05-12 成都绿金高新技术股份有限公司 Compound penetrating agent of neopelex and phosphoric acid
CN103643496A (en) * 2013-11-21 2014-03-19 湖州申祥丝织有限责任公司 Novel fabric mercerizing penetrating agent
CN104358149A (en) * 2014-10-25 2015-02-18 合肥市安山涂层织物有限公司 Rapid moistening and diffusing synthetic leather penetrant and preparing method thereof
CN104358150A (en) * 2014-10-29 2015-02-18 合肥市安山涂层织物有限公司 Strong-alkali-resistant high-permeability penetrant for leather
CN104644537A (en) * 2015-01-22 2015-05-27 韦爱琴 Hair and body wash

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101703044A (en) * 2009-09-22 2010-05-12 成都绿金高新技术股份有限公司 Compound penetrating agent of neopelex and phosphoric acid
CN103643496A (en) * 2013-11-21 2014-03-19 湖州申祥丝织有限责任公司 Novel fabric mercerizing penetrating agent
CN104358149A (en) * 2014-10-25 2015-02-18 合肥市安山涂层织物有限公司 Rapid moistening and diffusing synthetic leather penetrant and preparing method thereof
CN104358150A (en) * 2014-10-29 2015-02-18 合肥市安山涂层织物有限公司 Strong-alkali-resistant high-permeability penetrant for leather
CN104644537A (en) * 2015-01-22 2015-05-27 韦爱琴 Hair and body wash

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106012603A (en) * 2016-07-27 2016-10-12 董荣琴 Novel high-temperature-resisting penetrant for leather
CN106065535A (en) * 2016-07-27 2016-11-02 刘慧宝 A kind of degradable dye penetrant of novel environment friendly
CN106222331A (en) * 2016-07-27 2016-12-14 董荣琴 A kind of degradable penetrating agent of New-type leather
CN106676914A (en) * 2016-07-27 2017-05-17 董荣琴 Novel alkali-resistant penetrant for leather
CN106521936A (en) * 2016-10-14 2017-03-22 无锡市华诚印染剂厂 Quick penetrating agent for fabric

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