CN106065535A - A kind of degradable dye penetrant of novel environment friendly - Google Patents

A kind of degradable dye penetrant of novel environment friendly Download PDF

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Publication number
CN106065535A
CN106065535A CN201610607945.9A CN201610607945A CN106065535A CN 106065535 A CN106065535 A CN 106065535A CN 201610607945 A CN201610607945 A CN 201610607945A CN 106065535 A CN106065535 A CN 106065535A
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Prior art keywords
parts
dye penetrant
environment friendly
novel environment
degradable dye
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CN201610607945.9A
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Chinese (zh)
Inventor
刘慧宝
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Individual
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Priority to CN201610607945.9A priority Critical patent/CN106065535A/en
Publication of CN106065535A publication Critical patent/CN106065535A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65125Compounds containing ester groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/622Sulfonic acids or their salts
    • D06P1/623Aliphatic, aralophatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/622Sulfonic acids or their salts
    • D06P1/625Aromatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/645Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65131Compounds containing ether or acetal groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65168Sulfur-containing compounds
    • D06P1/65187Compounds containing sulfide or disulfide groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/655Compounds containing ammonium groups
    • D06P1/66Compounds containing ammonium groups containing quaternary ammonium groups

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of degradable dye penetrant of novel environment friendly, it comprises following parts by weight of component: fatty alcohol succinate 10 14 parts, epoxychloropropane 36 parts, dodecyl dihydroxy ethyl glycine betaine 36 parts, vinyl acetate 15 20 parts, disulfide group 2-ethyl hexyl ethanoate stannous methide 11 14 parts, deionized water 40 48 parts, dodecylbenzene sodium sulfonate 3 10 parts, aerosol-OT salt 26 parts, sucrose ester 12 16 parts, diethylaminoethyl methacrylate 4 12 parts, 48 parts of acrylic acid.Environmental protection of the present invention degradable dye penetrant levelling excellent performance, can substantially increase the absorbance of dyestuff, safe and harmless, environmental protection;The most also having good biological degradability, prepare this penetrating agent needed raw material cheap and easy to get, preparation technology is simple, produces equipment requirements low.

Description

A kind of degradable dye penetrant of novel environment friendly
Technical field
The invention belongs to chemical field of weaving, be specifically related to a kind of degradable dye penetrant of novel environment friendly.
Background technology
Bafta, also known as cotton, is with cotton yarn for the woven fabric of raw material.Bafta becomes with excellent wearability One of conventional fabric, is widely used in garment material, drapery and TECHNICAL FABRIC.Cotton is most popular clothes and home textile Fabric.Multi-functional, soft, ventilative, moisture absorption, the comfortableness of annual dress, function admirable and endurable be only that cotton enjoys great popularity Numerous qualities in some.Along with textile printing and dyeing processing deep development, bafta kind becomes increasingly abundant, outward appearance and performance and Class also improves constantly.Due to the development of chemical fibre, occur in that cotton chemical fibre, the thing such as its length (generally 38 millimeter) Rationality shape meets cotton spinning requirement, pure on cotton spinning equipment spin or forms with cotton fiber blending, the fabric of this fibrid and Bafta is referred to as cotton fabric.Cotton fabric is cheap, widely applicable, and water absorption is strong, wear-resisting washable, soft comfortable, the winter Wearing warmth retention property season good, dress in summer is ventilative nice and cool, and bafta becomes the most frequently used children's garment material with its excellent wearability One of material, is the children's garment fabric popularized the most.Bafta color is the most bright-coloured, is used for child's summer clothing, and easy dress is interior Clothing, sportswear etc..Along with the raising of living standards of the people, people are more and more higher to the prescription of textile fabrics fabric. But owing to the grade of dyeing installation and raw cotton in recent years declines, often the most cotton containing some in grey cloth, cause and live using Property dyeing time, the flaws such as the spreadability of dyestuff is poor, and cloth cover often occurs dyeing uneven, dyeing horizontal stripe, affect knitted fabric cloth The quality in face.Solve above phenomenon, just need to add suitable auxiliary agent in dyeing course and improve because of textile fabrics grey cloth, set The dyeing speck that the reason such as standby causes.In dyeing course, the two of the dispersion of dyestuff and infiltration always puzzlement printing and dyeing enterprise ask greatly Topic, the poor dispersion of dyestuff, it is easy to cause cone yarn dyeing inequality, formed and inside and outside differ;And the infiltration of dyestuff is bad, Cheese is the best to the absorption rate of dyestuff, and dyestuff only rests on surface, it is impossible to dye is thoroughly.At present, on market, various dyeing are oozed Thoroughly agent is a lot, but biodegradability is poor, when recycle of alkali liquor processes volatile go out harmful gas, pollution environment, and endangering Victimize healthy, be unfavorable for environmental protection, and developing rapidly along with modern science and technology and production, properties of product proposed The highest requirement.Accordingly, it would be desirable to develop a kind of degradable dye penetrant of environmental protection that can overcome problem described above.
Summary of the invention
It is an object of the invention to provide a kind of degradable dye penetrant of novel environment friendly.
To achieve these goals, the invention provides a kind of degradable dye penetrant of novel environment friendly, comprise following heavy Amount part component: fatty alcohol succinate 10-14 part, epoxychloropropane 3-6 part, dodecyl dihydroxy ethyl glycine betaine 3-6 part, vinegar Acid ethylene 15-20 part, disulfide group 2-ethyl hexyl ethanoate stannous methide 11-14 part, deionized water 40-48 part, DBSA Sodium 3-10 part, aerosol-OT salt 2-6 part, sucrose ester 12-16 part, diethylaminoethyl methacrylate 4-12 Part, acrylic acid 4-8 part.
It also comprises polyvinyl alcohol 2-9 part.
It also comprises fatty alcohol-polyoxyethylene ether 1-7 part.
It also comprises APP 5-10 part.
The preparation technology of the present invention is common process, without technological improvement, skillfully grasps for those of ordinary skill in the art.
Beneficial effect: environmental protection of the present invention degradable dye penetrant levelling excellent performance, can substantially increase dyestuff Absorbance, safe and harmless, environmental protection;The most also there is good biological degradability, prepare this penetrating agent needed raw material honest and clean Valency is easy to get, and preparation technology is simple, produces equipment requirements low.
Detailed description of the invention
Embodiment 1
The degradable dye penetrant of environmental protection of the present embodiment, comprises following parts by weight of component: fatty alcohol succinate 10 parts, Epoxychloropropane 3 parts, dodecyl dihydroxy ethyl glycine betaine 3 parts, vinyl acetate 15 parts, disulfide group 2-ethyl hexyl ethanoate stannous methide 11 parts, deionized water 40 parts, dodecylbenzene sodium sulfonate 3 parts, aerosol-OT salt 2 parts, sucrose ester 12 parts, methyl Diethylaminoethyl acrylate 4 parts, 4 parts of acrylic acid.
Embodiment 2
The degradable dye penetrant of environmental protection of the present embodiment, comprises following parts by weight of component: fatty alcohol succinate 14 parts, Epoxychloropropane 6 parts, dodecyl dihydroxy ethyl glycine betaine 6 parts, vinyl acetate 20 parts, disulfide group 2-ethyl hexyl ethanoate stannous methide 14 parts, deionized water 48 parts, dodecylbenzene sodium sulfonate 10 parts, aerosol-OT salt 6 parts, sucrose ester 16 parts, first Base diethylaminoethyl acrylate 12 parts, 8 parts of acrylic acid, polyvinyl alcohol 9 parts.
Embodiment 3
The degradable dye penetrant of environmental protection of the present embodiment, comprises following parts by weight of component: fatty alcohol succinate 10 parts, Epoxychloropropane 3 parts, dodecyl dihydroxy ethyl glycine betaine 3 parts, vinyl acetate 15 parts, disulfide group 2-ethyl hexyl ethanoate stannous methide 11 parts, deionized water 40 parts, dodecylbenzene sodium sulfonate 3 parts, aerosol-OT salt 2 parts, sucrose ester 12 parts, methyl Diethylaminoethyl acrylate 4 parts, 4 parts of acrylic acid, polyvinyl alcohol 2 parts, fatty alcohol-polyoxyethylene ether 1 part.
Embodiment 4
The degradable dye penetrant of environmental protection of the present embodiment, comprises following parts by weight of component: fatty alcohol succinate 14 parts, Epoxychloropropane 6 parts, dodecyl dihydroxy ethyl glycine betaine 6 parts, vinyl acetate 20 parts, disulfide group 2-ethyl hexyl ethanoate stannous methide 14 parts, deionized water 48 parts, dodecylbenzene sodium sulfonate 10 parts, aerosol-OT salt 6 parts, sucrose ester 16 parts, first Base diethylaminoethyl acrylate 12 parts, 8 parts of acrylic acid, polyvinyl alcohol 9 parts, fatty alcohol-polyoxyethylene ether 7 parts, APP 10 Part.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.

Claims (4)

1. the degradable dye penetrant of novel environment friendly, it is characterised in that comprise following parts by weight of component: fatty alcohol succinic acid Ester 10-14 part, epoxychloropropane 3-6 part, dodecyl dihydroxy ethyl glycine betaine 3-6 part, vinyl acetate 15-20 part, disulfide group 2-ethyl hexyl ethanoate stannous methide 11-14 part, deionized water 40-48 part, dodecylbenzene sodium sulfonate 3-10 part, sulfosuccinate two Monooctyl ester sodium salt 2-6 part, sucrose ester 12-16 part, diethylaminoethyl methacrylate 4-12 part, acrylic acid 4-8 part.
The degradable dye penetrant of novel environment friendly the most according to claim 1, it is characterised in that: it also comprises polyvinyl alcohol 2-9 part.
The degradable dye penetrant of novel environment friendly the most according to claim 2, it is characterised in that: it also comprises poly alkyl alcohol Oxygen vinyl Ether 1-7 part.
The degradable dye penetrant of novel environment friendly the most according to claim 3, it is characterised in that: it also comprises APP 5-10 part.
CN201610607945.9A 2016-07-27 2016-07-27 A kind of degradable dye penetrant of novel environment friendly Pending CN106065535A (en)

Priority Applications (1)

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CN201610607945.9A CN106065535A (en) 2016-07-27 2016-07-27 A kind of degradable dye penetrant of novel environment friendly

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CN201610607945.9A CN106065535A (en) 2016-07-27 2016-07-27 A kind of degradable dye penetrant of novel environment friendly

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109252401A (en) * 2018-09-14 2019-01-22 桐乡市濮院毛针织技术服务中心 A kind of preparation method of the purple dye bleeding agent of high density acrylic fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313912A (en) * 2014-10-25 2015-01-28 合肥市安山涂层织物有限公司 Penetrating agent capable of purifying environment for leather and preparation method of penetrating agent
CN104805696A (en) * 2015-05-12 2015-07-29 湖州吉昌丝绸有限公司 Novel fabric penetrant composition
CN105040425A (en) * 2015-07-01 2015-11-11 广东灵捷制造化工有限公司 Mercerization penetrant and preparation method thereof
CN105603732A (en) * 2016-02-25 2016-05-25 苏州三和开泰花线织造有限公司 Mercerizing penetrant for cotton fabrics and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313912A (en) * 2014-10-25 2015-01-28 合肥市安山涂层织物有限公司 Penetrating agent capable of purifying environment for leather and preparation method of penetrating agent
CN104805696A (en) * 2015-05-12 2015-07-29 湖州吉昌丝绸有限公司 Novel fabric penetrant composition
CN105040425A (en) * 2015-07-01 2015-11-11 广东灵捷制造化工有限公司 Mercerization penetrant and preparation method thereof
CN105603732A (en) * 2016-02-25 2016-05-25 苏州三和开泰花线织造有限公司 Mercerizing penetrant for cotton fabrics and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109252401A (en) * 2018-09-14 2019-01-22 桐乡市濮院毛针织技术服务中心 A kind of preparation method of the purple dye bleeding agent of high density acrylic fabric

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