CN106192408A - A kind of high temperature resistant silkete penetrating agent of new cotton fabric - Google Patents

A kind of high temperature resistant silkete penetrating agent of new cotton fabric Download PDF

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Publication number
CN106192408A
CN106192408A CN201610611596.8A CN201610611596A CN106192408A CN 106192408 A CN106192408 A CN 106192408A CN 201610611596 A CN201610611596 A CN 201610611596A CN 106192408 A CN106192408 A CN 106192408A
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parts
high temperature
penetrating agent
temperature resistant
cotton fabric
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CN201610611596.8A
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Chinese (zh)
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刘慧宝
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Individual
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Priority to CN201610611596.8A priority Critical patent/CN106192408A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71Salts of phosphoric acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192Polycarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Abstract

The invention discloses a kind of high temperature resistant silkete penetrating agent of new cotton fabric, it comprises following parts by weight of component: 15 parts of acrylic acid, disodium hydrogen phosphate 47 parts, alkylphenol polyoxyethylene 8 10 parts, potassium oxalate 26 parts, fatty alcohol succinate 10 15 parts, sodium polyacrylate 13 20 parts, deionized water 40 50 parts, sodium citrate 8 11 parts, trioctyl phosphate 26 parts, 37 parts of the pure sodium sulfate of dodecane, 3 10 parts of lauryl alcohol ammonium sulfate, polyoxyethylene oleic acid ester 36 parts, citric acid 58 parts.Bafta of the present invention has good facilitation with high temperature resistant silkete penetrating agent for the mercerization finish of bafta, is very suitable for the industrialized production to scale;Having the thermostability of excellence, osmotic effect is more excellent, nontoxic, with low cost, non-corrosiveness simultaneously.

Description

A kind of high temperature resistant silkete penetrating agent of new cotton fabric
Technical field
The invention belongs to chemical field of weaving, be specifically related to a kind of high temperature resistant silkete penetrating agent of new cotton fabric.
Background technology
Bafta, also known as cotton, is with cotton yarn for the woven fabric of raw material.Bafta becomes with excellent wearability One of conventional fabric, is widely used in garment material, drapery and TECHNICAL FABRIC.Cotton is most popular clothes and home textile Fabric.Multi-functional, soft, ventilative, moisture absorption, the comfortableness of annual dress, function admirable and endurable be only that cotton enjoys great popularity Numerous qualities in some.Along with textile printing and dyeing processing deep development, bafta kind becomes increasingly abundant, outward appearance and performance and Class also improves constantly.Due to the development of chemical fibre, occur in that cotton chemical fibre, the thing such as its length (generally 38 millimeter) Rationality shape meets cotton spinning requirement, pure on cotton spinning equipment spin or forms with cotton fiber blending, the fabric of this fibrid and Bafta is referred to as cotton fabric.Cotton fabric is cheap, widely applicable, and water absorption is strong, wear-resisting washable, soft comfortable, the winter Wearing warmth retention property season good, dress in summer is ventilative nice and cool, and bafta becomes the most frequently used children's garment material with its excellent wearability One of material, is the children's garment fabric popularized the most.Bafta color is the most bright-coloured, is used for child's summer clothing, and easy dress is interior Clothing, sportswear etc..Along with the raising of living standards of the people, people are more and more higher to the prescription of textile fabrics fabric. And a bafta or cotton blended fabric critically important operation in dyeing and printing process is mercerization finish.Cotton through mercerization finish Cloth, in physical characteristic, great changes will take place, makes fabric obtain significant gloss, clearly lines, well-pressed body bone, bright-coloured Color.During mercerising, cotton fiber, through the effect of Caustic soda, makes filament expansion, causes fabric count to certain contraction, makes Changing inside cellulose, as cellulose molecular structure changes the firmest, fabric strength increases;Changing of molecular structure Becoming, molecules align obtains the most neat, makes the column type that cotton fiber glazes from bandlet shape, and its gloss strengthens, fiber swollen Swollen, make dyestuff readily permeable, be evenly distributed in fiber, cotton increases with the affinity of dyestuff, easily colours, is not easy to take off Color, fabric is the most just greatly lowered through the contraction of broadwise, the washing shrinkage of finished product.Mercerization finish can improve the glossiness of bafta with And absorption property, and the stability of the size of bafta can be improved, it is very important cotton pretreatment link.But The concentration of lye used in mercerization finish is higher, can there is the problems such as big, the poor permeability of viscosity, careless slightly just in operating process The surface mercerising phenomenon of bafta can be caused.Meanwhile, during mercerization finish, due to poor permeability, can consume a large amount of Alkali liquor, cause the waste of resource.Add silkete penetrating agent the most in this place during reason, can significantly alleviate the table of bafta Face mercerising phenomenon.Silkete penetrating agent can make the surface tension of alkali liquor reduce, and can also promote the infiltration of alkali liquor simultaneously, can not only Make mercerization uniform, it is also possible to significantly to shorten the time of mercerising.Common penetrating agent is owing to it is by cloud point and foaming Property big problem, mercerization is difficult to application.Meanwhile, silkete penetrating agent also needs to keep steady in strong base solution Fixed, and do not interfere with the recycling of strong base solution.But existing silkete penetrating agent thermostability is the highest, heats volatile Go out harmful gas, pollute environment, and developing rapidly along with modern science and technology and production, properties of product are proposed increasingly High requirement.Accordingly, it would be desirable to develop a kind of high temperature resistant silkete penetrating agent of the bafta that can overcome problem described above.
Summary of the invention
It is an object of the invention to provide a kind of high temperature resistant silkete penetrating agent of new cotton fabric.
To achieve these goals, the invention provides a kind of high temperature resistant silkete penetrating agent of new cotton fabric, comprise with Lower parts by weight of component: acrylic acid 1-5 part, disodium hydrogen phosphate 4-7 part, alkylphenol polyoxyethylene 8-10 part, potassium oxalate 2-6 part, Fatty alcohol succinate 10-15 part, sodium polyacrylate 13-20 part, deionized water 40-50 part, sodium citrate 8-11 part, tricresyl phosphate Monooctyl ester 2-6 part, dodecane pure sodium sulfate 3-7 part, lauryl alcohol ammonium sulfate 3-10 part, polyoxyethylene oleic acid ester 3-6 part, citric acid 5-8 part.
It also comprises sal glauberi 2-6 part.
It also comprises aerosol-OT salt 12-16 part.
It also comprises sodium carbonate 1-5 part.
The preparation technology of the present invention is common process, without technological improvement, skillfully grasps for those of ordinary skill in the art.
Beneficial effect: bafta of the present invention has very for the mercerization finish of bafta with high temperature resistant silkete penetrating agent Good facilitation, is very suitable for the industrialized production to scale;Having the thermostability of excellence, osmotic effect is more excellent simultaneously Good, nontoxic, with low cost, non-corrosiveness.
Detailed description of the invention
Embodiment 1
The high temperature resistant silkete penetrating agent of the bafta of the present embodiment, comprises following parts by weight of component: 1 part of acrylic acid, phosphoric acid Disodium hydrogen 4 parts, alkylphenol polyoxyethylene 8 parts, potassium oxalate 2 parts, fatty alcohol succinate 10 parts, sodium polyacrylate 13 parts, go Ionized water 40 parts, sodium citrate 8 parts, trioctyl phosphate 2 parts, 3 parts of the pure sodium sulfate of dodecane, 3 parts of lauryl alcohol ammonium sulfate, oleic acid Polyoxyethylene ester 3 parts, citric acid 5 parts.
Embodiment 2
The high temperature resistant silkete penetrating agent of the bafta of the present embodiment, comprises following parts by weight of component: 5 parts of acrylic acid, phosphoric acid Disodium hydrogen 7 parts, alkylphenol polyoxyethylene 10 parts, potassium oxalate 6 parts, fatty alcohol succinate 15 parts, sodium polyacrylate 20 parts, go Ionized water 50 parts, sodium citrate 11 parts, trioctyl phosphate 6 parts, 7 parts of the pure sodium sulfate of dodecane, 10 parts of lauryl alcohol ammonium sulfate, oil Acid polyoxyethylene ester 6 parts, citric acid 8 parts, sal glauberi 6 parts.Embodiment 3
The high temperature resistant silkete penetrating agent of the bafta of the present embodiment, comprises following parts by weight of component: 1 part of acrylic acid, phosphoric acid Disodium hydrogen 4 parts, alkylphenol polyoxyethylene 8 parts, potassium oxalate 2 parts, fatty alcohol succinate 10 parts, sodium polyacrylate 13 parts, go Ionized water 40 parts, sodium citrate 8 parts, trioctyl phosphate 2 parts, 3 parts of the pure sodium sulfate of dodecane, 3 parts of lauryl alcohol ammonium sulfate, oleic acid Polyoxyethylene ester 3 parts, citric acid 5 parts, sal glauberi 2 parts, aerosol-OT salt 12 parts.
Embodiment 4
The high temperature resistant silkete penetrating agent of the bafta of the present embodiment, comprises following parts by weight of component: 5 parts of acrylic acid, phosphoric acid Disodium hydrogen 7 parts, alkylphenol polyoxyethylene 10 parts, potassium oxalate 6 parts, fatty alcohol succinate 15 parts, sodium polyacrylate 20 parts, go Ionized water 50 parts, sodium citrate 11 parts, trioctyl phosphate 6 parts, 7 parts of the pure sodium sulfate of dodecane, 10 parts of lauryl alcohol ammonium sulfate, oil Acid polyoxyethylene ester 6 parts, citric acid 8 parts, sal glauberi 6 parts, aerosol-OT salt 16 parts, sodium carbonate 5 parts.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.

Claims (4)

1. the high temperature resistant silkete penetrating agent of new cotton fabric, it is characterised in that comprise following parts by weight of component: acrylic acid 1-5 Part, disodium hydrogen phosphate 4-7 part, alkylphenol polyoxyethylene 8-10 part, potassium oxalate 2-6 part, fatty alcohol succinate 10-15 part, Sodium polyacrylate 13-20 part, deionized water 40-50 part, sodium citrate 8-11 part, trioctyl phosphate 2-6 part, the acid of dodecane bright sulfur Sodium 3-7 part, lauryl alcohol ammonium sulfate 3-10 part, polyoxyethylene oleic acid ester 3-6 part, citric acid 5-8 part.
The high temperature resistant silkete penetrating agent of new cotton fabric the most according to claim 1, it is characterised in that: it also comprises ten water Sodium sulfate 2-6 part.
The high temperature resistant silkete penetrating agent of new cotton fabric the most according to claim 2, it is characterised in that: it also comprises sulfonation Dioctyl succinate sodium salt 12-16 part.
The high temperature resistant silkete penetrating agent of new cotton fabric the most according to claim 3, it is characterised in that: it also comprises carbonic acid Sodium 1-5 part.
CN201610611596.8A 2016-07-27 2016-07-27 A kind of high temperature resistant silkete penetrating agent of new cotton fabric Pending CN106192408A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794753A (en) * 2017-10-20 2018-03-13 江苏新瑞贝科技股份有限公司 A kind of high temperature resistant bleeding agent and preparation method thereof
CN109022632A (en) * 2018-08-13 2018-12-18 漳州香洲皮革有限公司 Soft mercerizing agent, the preparation method of soft mercerizing agent and the method for preparing flexible silk smooth bark with softness mercerizing agent

Citations (6)

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Publication number Priority date Publication date Assignee Title
JPH03869A (en) * 1989-05-30 1991-01-07 Mitsubishi Kasei Corp Mercerizing agent and mercerizing process using the same
CN102653921A (en) * 2012-04-26 2012-09-05 天津达一琦精细化工有限公司 Alkali-resisting penetrating agent for cotton fabric mercerization
CN103352366A (en) * 2013-06-08 2013-10-16 浙江大禾化工有限公司 Fast-permeation, low-form, and easy-degradation mercerizing penetrating agent, and preparation raw materials and preparation process thereof
CN104611923A (en) * 2015-01-23 2015-05-13 江苏金太阳纺织科技有限公司 Phosphate silkete penetrating agent and preparation method thereof
CN105017559A (en) * 2014-08-20 2015-11-04 太仓市璜泾太华化纤助剂厂 High-permeability chemical fiber pretreating agent
CN105040425A (en) * 2015-07-01 2015-11-11 广东灵捷制造化工有限公司 Mercerization penetrant and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03869A (en) * 1989-05-30 1991-01-07 Mitsubishi Kasei Corp Mercerizing agent and mercerizing process using the same
CN102653921A (en) * 2012-04-26 2012-09-05 天津达一琦精细化工有限公司 Alkali-resisting penetrating agent for cotton fabric mercerization
CN103352366A (en) * 2013-06-08 2013-10-16 浙江大禾化工有限公司 Fast-permeation, low-form, and easy-degradation mercerizing penetrating agent, and preparation raw materials and preparation process thereof
CN105017559A (en) * 2014-08-20 2015-11-04 太仓市璜泾太华化纤助剂厂 High-permeability chemical fiber pretreating agent
CN104611923A (en) * 2015-01-23 2015-05-13 江苏金太阳纺织科技有限公司 Phosphate silkete penetrating agent and preparation method thereof
CN105040425A (en) * 2015-07-01 2015-11-11 广东灵捷制造化工有限公司 Mercerization penetrant and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107794753A (en) * 2017-10-20 2018-03-13 江苏新瑞贝科技股份有限公司 A kind of high temperature resistant bleeding agent and preparation method thereof
CN109022632A (en) * 2018-08-13 2018-12-18 漳州香洲皮革有限公司 Soft mercerizing agent, the preparation method of soft mercerizing agent and the method for preparing flexible silk smooth bark with softness mercerizing agent
CN109022632B (en) * 2018-08-13 2021-04-27 漳州香洲皮革有限公司 Soft mercerizing agent, preparation method of soft mercerizing agent and method for preparing soft mercerizing leather by using soft mercerizing agent
CN113088586A (en) * 2018-08-13 2021-07-09 漳州香洲皮革有限公司 Preparation method of soft silky luster skin
CN113088586B (en) * 2018-08-13 2022-06-21 漳州香洲皮革有限公司 Preparation method of soft silky luster skin

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Application publication date: 20161207