JPH03869A - Mercerizing agent and mercerizing process using the same - Google Patents
Mercerizing agent and mercerizing process using the sameInfo
- Publication number
- JPH03869A JPH03869A JP13677289A JP13677289A JPH03869A JP H03869 A JPH03869 A JP H03869A JP 13677289 A JP13677289 A JP 13677289A JP 13677289 A JP13677289 A JP 13677289A JP H03869 A JPH03869 A JP H03869A
- Authority
- JP
- Japan
- Prior art keywords
- mercerizing
- aqueous solution
- fiber
- mercerizing agent
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- 229920002678 cellulose Polymers 0.000 claims abstract description 15
- 239000001913 cellulose Substances 0.000 claims abstract description 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000011282 treatment Methods 0.000 abstract description 16
- 238000005517 mercerization Methods 0.000 abstract description 9
- 239000003513 alkali Substances 0.000 abstract description 4
- 238000005470 impregnation Methods 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000004435 Oxo alcohol Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- -1 cetylalconyl Chemical compound 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003961 penetration enhancing agent Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はマーセライズ剤及びこれを用いるマーセル化方
法に関するものである。詳しくは、マーセル化工程にお
ける強アルカリ水溶液のセルロース含有繊維への浸透速
度に優れた新規なマーセライズ剤及びこれケ用いるマー
セル化方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a mercerizing agent and a mercerizing method using the same. Specifically, the present invention relates to a novel mercerizing agent that has an excellent rate of penetration of a strong alkaline aqueous solution into cellulose-containing fibers in a mercerizing process, and a mercerizing method using the same.
（従来技術）
例えば、コツトンなどのセルロース含有繊維の表面光沢
を改善するため、また、その染色性を向上させるために
、繊維類を強アルカリ水溶液中に浸漬させるマーセル化
処理は、別名シルケット加工とも呼ばれ古くから広〈実
施されている。この処理においては、アルカリ水溶液馨
短時間のうちに、繊維内部まで均一に浸透させることが
望ましい。そのため、従来よりアルカリ水溶液の処理浴
中に、繊維内へのアルカリ水溶液の浸透を促進するため
の浸透促進剤、すなわち、マーセライズ剤ン少量添加す
る方法が採用されている。このマーセライズ剤は、一般
にアニオン系界面活性剤ビ主体とするものであシ、種々
の市販品が販売されており実用に供されている。(Prior art) For example, in order to improve the surface gloss of cellulose-containing fibers such as cotton fibers and to improve their dyeability, mercerization treatment, which involves soaking fibers in a strong alkaline aqueous solution, is also known as mercerization treatment. It has been widely practiced since ancient times. In this treatment, it is desirable that the alkaline aqueous solution uniformly permeate into the interior of the fiber within a short period of time. Therefore, conventional methods have been adopted in which a small amount of a penetration enhancer, ie, a mercerizing agent, is added to the alkaline aqueous solution treatment bath to promote the penetration of the alkaline aqueous solution into the fibers. This mercerizing agent generally consists mainly of an anionic surfactant, and various commercially available products are commercially available and are in practical use.
しかしながら、従来品の場合、ある程度の浸透促進効果
は得られるもののまだ十分なものとは言えず、更に改良
の余地がある。また、従来品は、処理液の調製直後にお
いては比較的に優れた浸透効果が発揮されるが、処理時
間の経過とともにその効果が著しく低下すると言う問題
点もあった。However, in the case of conventional products, although a certain degree of penetration promotion effect can be obtained, it is still not sufficient, and there is still room for further improvement. In addition, conventional products exhibit a relatively excellent penetration effect immediately after the treatment liquid is prepared, but there is also a problem in that the effect deteriorates significantly as the treatment time progresses.
（発明が解決しようとする課題）
本発明は、マーセル化工程におけるセルロース含有繊維
内部へのアルカリ水溶液の浸透速度が速（、シかも処理
浴の経時的な性能低下も殆ど起こらないマーセライズ剤
及びマーセル化方法を提供するものである。(Problems to be Solved by the Invention) The present invention provides a mercerizing agent and a mercerizer that have a fast permeation rate of an aqueous alkaline solution into the interior of cellulose-containing fibers in the mercerization process, and hardly cause any deterioration in the performance of the treatment bath over time. This method provides a method for
（課題〉解決するための手段）
本発明の要旨は、アニオン系界面活性剤及び炭素数ｔ〜
／ｇの脂肪族アルコールのプロピレンオキサイド付加物
を含有することｔ特徴とするマーセライズ剤、及びアニ
オン系界面活性剤疎び炭素数ｇ〜ｌざの脂肪族アルコー
ルのプロピレンオキサイド付加物よりなるマーセライズ
剤の存在下、強アルカリ水溶液中に、セルロース含有繊
維を浸漬処理することｔ特徴とするマーセル化方法に存
する。(Means for solving the problem) The gist of the present invention is to provide an anionic surfactant and an anionic surfactant with a carbon number t~
A mercerizing agent characterized by containing a propylene oxide adduct of an aliphatic alcohol with a carbon number of 1 to 1 g, and an anionic surfactant, and a mercerizing agent comprising a propylene oxide adduct of an aliphatic alcohol with a carbon number of 1 to 1 g. The mercerization method is characterized by immersing cellulose-containing fibers in a strong alkaline aqueous solution in the presence of a mercerization method.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明のマーセライズ剤は、アニオン系界面活性剤及び
特定の脂肪族アルコールのプロピレンオキサイド付加物
を含有するものである。The mercerizing agent of the present invention contains an anionic surfactant and a propylene oxide adduct of a specific aliphatic alcohol.
アニオン系界面活性剤としては特に限定されず、従来か
らマーセライズ剤として使用されているものでよい。こ
れらの代表例としては、例えば、炭素数５〜ＩＯのアル
キル基をもつスルホン酸塩又は硫酸エステルよりなるア
ニオン系界面活性剤が挙げられる。The anionic surfactant is not particularly limited, and any one conventionally used as a mercerizing agent may be used. Representative examples of these include, for example, anionic surfactants made of sulfonates or sulfuric esters having an alkyl group having 5 to 10 carbon atoms.
一方、脂肪族アルコールのプロピレンオキサイド付加物
を構成する脂肪族アルコールは、直鎖状又は分岐状の炭
素数ざ〜ｉｔ、好ましくはｌＯ〜１５のアルコールであ
り、例えば、オクタツール、コーエチルヘキサノール、
ラウリルアルコール、セチルアルコニル、オレイルアル
コール、ステアリルアルコールなどが挙げられ、これら
は単独でも、あるいはこれらの混合物で用いてもよい。On the other hand, the aliphatic alcohol constituting the propylene oxide adduct of aliphatic alcohol is a linear or branched alcohol having a carbon number of ~it, preferably lO~15, such as octatool, coethylhexanol,
Examples include lauryl alcohol, cetylalconyl, oleyl alcohol, stearyl alcohol, and these may be used alone or in a mixture thereof.
なお、これらのアルコールとして、オキソアルコール、
改良オキソアルコール、セカンダリ−アルコールなどの
合成アルコールを用いることもできる。また、アルコー
ルへのプロピレンオキサイドの付加数は、通常９、ｌ〜
ｉｏ、好ましくは２〜６である。In addition, these alcohols include oxo alcohol,
Synthetic alcohols such as modified oxo alcohols and secondary alcohols can also be used. In addition, the number of propylene oxide added to alcohol is usually 9, l~
io, preferably 2-6.
本発明のマーセライズ剤において、脂肪族アルコールの
プロピレンオキサイド付加物の配合量は、通常、アニオ
ン系界面活性剤に対して、０．０２〜０．３重量倍、好
ましくは０．０２〜０．２重量倍である。この配合量が
あまり少ないとセルロース含有繊維へのアルカリ水溶液
の浸透速度を十分に改善することができず、また、あま
り多すぎても効果に変わりはないので経済的ではない。In the mercerizing agent of the present invention, the amount of the propylene oxide adduct of the aliphatic alcohol is usually 0.02 to 0.3 times the weight of the anionic surfactant, preferably 0.02 to 0.2 times the weight of the anionic surfactant. It is twice the weight. If this amount is too small, the permeation rate of the aqueous alkali solution into the cellulose-containing fibers cannot be sufficiently improved, and if it is too large, the effect remains the same, which is not economical.
更に、本発明のマーセライズ剤は、必要に応じて、水性
媒体で希釈されたものでもよく、また、例えば、メタノ
ール、ブチルエチルケトン、ブチルセロソルブなどの有
機溶剤等、公知の各種添加剤を配合することができる。Furthermore, the mercerizing agent of the present invention may be diluted with an aqueous medium if necessary, and various known additives may be added, such as organic solvents such as methanol, butyl ethyl ketone, and butyl cellosolve. I can do it.
一方、本発明は上述のマーセライズ剤を用いて、セルロ
ース含有繊維なマーセル化する方法を提供するものであ
る。マーセル化の方法としては、強アルカリ水溶液中に
セルロース含有繊維を浸漬する通常の方法が採用し得る
。この際の強アルカリ水溶液としては、例えば、苛性ソ
ーダ又は苛性カリの水溶液が挙げられ、その濃度は、通
常１．２０〜３０重量％である。強アルカリ水溶液中へ
のマーセライズ剤の添加量としては、アニオン系界面活
性剤の存在量が、通常、０．０９〜Ｏ，Ｓ重量％であり
、しかも炭素数Ｓ〜／１の脂肪族アルコールのプロピレ
ンオキサイド付加物の存在量が０．００ ／ −０，２
重量％、好ましくは０．０ ／ −０，１重量％となる
ように調節される。要するに、強アルカリ水溶液及びマ
ーセライズ剤からなる処理浴中のアニオン系界面活性剤
及び脂肪族アルコールのプロピレンオキサイド付加物の
含有量が上記範囲内の場合に、セルロース含有繊維内部
への強アルカリ水溶液の浸透速度が特に良好となるので
ある。浸漬温度は、３〜３０℃程度であり、また、浸漬
時間は、通常、３０−９０秒程度である。セルロース含
有繊維は強アルカリ水溶液との接触により収縮するので
、通常、セルロース含有繊維が収縮しないように線維を
固定しつつ浸漬処理を行うか、又は、接触処理後、繊維
をマングルで絞りこれを展伸する方法が採られる。On the other hand, the present invention provides a method for mercerizing cellulose-containing fibers using the above-mentioned mercerizing agent. As a method for mercerization, a usual method of immersing cellulose-containing fibers in a strong alkaline aqueous solution can be adopted. Examples of the strong alkaline aqueous solution in this case include an aqueous solution of caustic soda or caustic potash, and the concentration thereof is usually 1.20 to 30% by weight. The amount of the mercerizing agent added to the strong alkaline aqueous solution is usually such that the amount of the anionic surfactant present is 0.09 to 0,S by weight, and the amount of the aliphatic alcohol having a carbon number of S to 1 is The amount of propylene oxide adduct is 0.00/-0.2
It is adjusted to % by weight, preferably 0.0/-0.1% by weight. In short, when the content of the anionic surfactant and propylene oxide adduct of aliphatic alcohol in the treatment bath consisting of a strong alkali aqueous solution and a mercerizing agent is within the above range, the strong alkali aqueous solution penetrates into the inside of the cellulose-containing fiber. The speed is particularly good. The immersion temperature is about 3 to 30°C, and the immersion time is usually about 30 to 90 seconds. Since cellulose-containing fibers shrink when they come into contact with a strong alkaline aqueous solution, the cellulose-containing fibers are usually soaked while being fixed to prevent them from shrinking, or after the contact treatment, the fibers are squeezed with a mangle and expanded. A method of stretching is adopted.
本発明で対象となるセルロース含有繊維としては、例え
ば、コツトン、レーヨン、麻など及びこれらとポリエス
テル、アクリル、ナイロンなどとの混合繊維が挙げられ
る。なお、繊維の形態は特に限定されず、繊維束状又は
歇物状のものでよい。Examples of cellulose-containing fibers targeted by the present invention include cotton, rayon, hemp, and mixed fibers of these with polyester, acrylic, nylon, and the like. Note that the form of the fibers is not particularly limited, and may be in the form of a fiber bundle or a fiber bundle.
マーセル化を終えたセルロース含有繊維は常法に従って
、水洗浄した後、その目的に応じて、種々の公知の後処
理を施し製品化される。After mercerization, the cellulose-containing fibers are washed with water according to a conventional method, and then subjected to various known post-treatments depending on the purpose, and then manufactured into products.
（実施例）
次に、本発明を実施例により更に詳細に説明するが、本
発明はその要旨を超えない限り以下の実施例に限定され
るものではない。(Examples) Next, the present invention will be explained in more detail by examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof.
実施例／〜Ｊ及び比較例／〜Ｊ
剤及び改良オキソアルコール（平均炭素数／、？）とプ
ロピレンオキサイド３個との付加物０．０３重量％を配
合した処理浴を調製した。Examples/~J and Comparative Examples/~J A treatment bath containing 0.03% by weight of an adduct of an agent and an improved oxo alcohol (average carbon number/?) and three propylene oxides was prepared.
この処理浴表面に、コツトン生機糸２０本束（長さ７ｃ
ｒＩＬのものを中央で７回結んだもの）を浮遊させ、こ
の糸が全て処理液により濡れるまでの時間（全部部れる
と糸は沈降する）を測定し、その結果を第１表に示す。On the surface of this treatment bath, a bundle of 20 greige yarns (length 7cm) is placed on the surface of the treatment bath.
rIL tied 7 times in the center) was suspended, and the time until all of the threads were wetted by the treatment solution (the threads settled when all of the threads were wetted) was measured, and the results are shown in Table 1.
また、改良オキソアルコールとプロピレンオキサイドの
付加物を省略した処理浴についても、同様なテストを行
い、その結果を第１表に併せて示す。Similar tests were also conducted on a treatment bath in which the adduct of improved oxo alcohol and propylene oxide was omitted, and the results are also shown in Table 1.
第 ｌ 表
（発明の効果）
本発明のマーセライズ剤によれば公知のマーセライズ剤
に比べ、セルロース含有繊維内部へのアルカリ水溶液の
浸透速度がコルＳ倍程度も改善されるので、染色工場で
のマーセル化処理を短時間で効率的に行うことができ、
しかも、処理ムラのない均質な製品を得ることができる
。Table l (Effects of the Invention) The mercerizing agent of the present invention improves the permeation rate of an aqueous alkaline solution into the interior of cellulose-containing fibers by a factor of Col S compared to known mercerizing agents. The process can be carried out quickly and efficiently.
Furthermore, a homogeneous product without uneven processing can be obtained.
注１）市販マーセライズ剤の種類
Ａ：ヘキスト社製、商品名Ｌｅｏｎｉｌ ＧＡＪＢ＝バ
スフ社製、商品名ＬｅｏｐｈｅｎＢＮＣ＝ 日本染化社
製、商品名 七ンカＡＣ３注２）市販マーセライズ剤の
配合量
アニオン界面活性剤としての重量％を示す。Note 1) Type A of commercially available mercerizing agents: Manufactured by Hoechst, trade name Leonil GAJB = Manufactured by Basf, trade name LeophenBNC = Manufactured by Nippon Someka Co., Ltd., trade name Shichinka AC3 Note 2) Compounding amount of commercially available mercerizing agents Anionic surfactant % by weight as agent.
注３）浸透時間 測定を１０回繰り返し行りたときの平均値を示す。Note 3) Penetration time The average value obtained when the measurement was repeated 10 times is shown.
Claims (2)
族アルコールのプロピレンオキサイド付加物を含有する
ことを特徴とするマーセライズ剤。(1) A mercerizing agent characterized by containing an anionic surfactant and a propylene oxide adduct of an aliphatic alcohol having 8 to 18 carbon atoms.
族アルコールのプロピレンオキサイド付加物よりなるマ
ーセライズ剤の存在下、強アルカリ水溶液中に、セルロ
ース含有繊維を浸漬処理することを特徴とするマーセル
化方法。(2) Mercer characterized by immersing cellulose-containing fibers in a strong alkaline aqueous solution in the presence of a mercerizing agent consisting of an anionic surfactant and a propylene oxide adduct of an aliphatic alcohol having 8 to 18 carbon atoms. method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13677289A JPH03869A (en) | 1989-05-30 | 1989-05-30 | Mercerizing agent and mercerizing process using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13677289A JPH03869A (en) | 1989-05-30 | 1989-05-30 | Mercerizing agent and mercerizing process using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03869A true JPH03869A (en) | 1991-01-07 |
Family
ID=15183155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13677289A Pending JPH03869A (en) | 1989-05-30 | 1989-05-30 | Mercerizing agent and mercerizing process using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03869A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101979753A (en) * | 2010-09-28 | 2011-02-23 | 绍兴文理学院 | High-efficiency mercerization method of pure cotton woven fabrics |
| CN106192408A (en) * | 2016-07-27 | 2016-12-07 | 刘慧宝 | A kind of high temperature resistant silkete penetrating agent of new cotton fabric |
| JP2016204785A (en) * | 2015-04-23 | 2016-12-08 | サンノプコ株式会社 | Mercerizing promoter and viscose rayon manufacturing method |
-
1989
- 1989-05-30 JP JP13677289A patent/JPH03869A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101979753A (en) * | 2010-09-28 | 2011-02-23 | 绍兴文理学院 | High-efficiency mercerization method of pure cotton woven fabrics |
| JP2016204785A (en) * | 2015-04-23 | 2016-12-08 | サンノプコ株式会社 | Mercerizing promoter and viscose rayon manufacturing method |
| CN106192408A (en) * | 2016-07-27 | 2016-12-07 | 刘慧宝 | A kind of high temperature resistant silkete penetrating agent of new cotton fabric |
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