CN105586182B - The special stains removing soap of clothes leader - Google Patents
The special stains removing soap of clothes leader Download PDFInfo
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- CN105586182B CN105586182B CN201610153305.5A CN201610153305A CN105586182B CN 105586182 B CN105586182 B CN 105586182B CN 201610153305 A CN201610153305 A CN 201610153305A CN 105586182 B CN105586182 B CN 105586182B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/448—Brightening agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of special stains removing soap of clothes leader, the special stains removing soap of clothes leader is by including the raw materials of following mass percents：Sodium soap 90 95%, sodium metasilicate 2 5%, AEO 1 3%, CBS X 0.01 0.03%, essence 0.2 0.4%, EDTA 0.02 0.05%, surplus is water.The special stains removing soap of clothes leader of the present invention, the special detergent of strong osmotic containing multiple elements design, fabric fibre and dirt gap can quickly be penetrated into, disintegrate stain, the special stains removing soap of clothes leader is made of sodium soap and nonionic surfactant and specific active auxiliary agent, with superpower wetting penetrating power, for local intractable spot on clothing, it cleans and is applied at dirt before master washes after immersion, promote clean effect, give Normal Wash again, washing efficiency greatly improves, and is the excellent companion of liquid detergent.
Description
Technical field
The present invention relates to daily use chemicals cleaning product technical fields, and in particular to a kind of special stains removing soap of clothes leader.
Background technology
Root according to the statistics of State Statistics Bureau, " soap and synthetic detergent manufacturing industry " scale more than enterprise synthesis of detergent in 2014
Agent yield adds up to be 1228.68 ten thousand tons.Increase by 10.77% on a year-on-year basis；Wherein synthetic washing powder yield is 468.26 ten thousand tons, is increased on year-on-year basis
Long 2%；Liquid detergent yield is 760.42 ten thousand tons, increases by 16.96% on a year-on-year basis.Wherein increased with laundry liquid product the most fast
Speed, 155.8 ten thousand tons of enterprise's liquid detergent yield in scopes of statistics in 2014 increased by 33% than 2013.
According to the market analysis to liquid detergent, especially laundry liquid market, the concentration of laundry liquid green, ring
Protect sustainable, energy-saving and emission-reduction and the product development to segment market will become a kind of trend.But common liq liquid detergent is to clothes
Shortcomings are gone back in the cleaning of the local dirts such as stains removing (neck, sleeve), and present invention is generally directed to the local dirts such as clothes stains removing (neck, sleeve)
Feature strong osmotic containing multiple elements design detergent can quickly penetrate into fabric fibre and dirt gap, disintegrate stain.For clothing
Local intractable spot on object is cleaned before master washes after immersion and is applied at dirt, promotes clean effect, then give Normal Wash.
Washing efficiency greatly improves, and is the excellent companion of liquid detergent.
Invention content
For above-mentioned deficiency in the prior art, the technical problems to be solved by the invention are to provide a kind of clothes neck
Tuck inside the sleeve special stains removing soap, for part (collar and cuff) intractable spot on clothing, after immersion it is main wash before clean and being applied to dirt
Place promotes clean effect, then gives Normal Wash, and washing efficiency greatly improves, and is the excellent companion of liquid detergent, environmental protection can be held
It is continuous, energy-saving and emission-reduction and the product to segment market.
The present invention seeks to what is be achieved through the following technical solutions：
A kind of special stains removing soap of clothes leader, including following raw materials：Sodium soap, sodium metasilicate, AEO, CBS-X, essence,
EDTA and water.
A kind of special stains removing soap of clothes leader includes the raw material of following mass percents：
Preferably, the special stains removing soap of a kind of clothes leader includes the raw material of following mass percents：
A kind of special stains removing soap of clothes leader includes the raw material of following mass percents：
Preferably, the special stains removing soap of a kind of clothes leader includes the raw material of following mass percents：
Preferably, the sodium soap is sodium laurate, Sodium myristate, sodium palmitate, odium stearate, isostearic acid
One or more mixtures in sodium, enuatrol, sodium citrate.
It is highly preferred that the sodium soap is mixed by sodium laurate, odium stearate, isostearic acid sodium, the bay
Sour sodium, odium stearate, isostearic acid sodium mass ratio be (1-3)：(1-3)：(1-3).
Preferably, the sodium metasilicate is sodium metasilicate and/or sodium metasilicate.
Preferably, the AEO is fatty alcohol polyoxyethylene ether, one or more in AEO-6, AEO-9, AEO-12
Mixture.
Preferably, the CBS-X is bis- (the 2- sodium sulfonates styryl) biphenyl of 4,4'-.
Preferably, the complex enzyme is lipase, protease, amylase, cellulase, pectase, mannonase mistake
One or more mixtures in oxide enzyme.
Preferably, the essence using the industry often with essence, can be trans-cinnamic aldehyde, bergamio, limonene,
One or more mixtures in curcumin, squalene, β-carypohyllene.
It is highly preferred that the essence is mixed by limonene, curcumin, β-carypohyllene, the limonene, curcumin,
Squalene, β-carypohyllene mass ratio be (1-3)：(1-3)：(1-3).
Specifically, in the present invention：
Sodium metasilicate, No. CAS：6834-92-0, chemical formula Na2SiO3, molecular weight 122.00.
Sodium metasilicate, also known as sodium orthosilicate, No. CAS：13472-30-5, chemical formula Na4SiO4, molecular weight 184.04.
Sodium laurate, No. CAS：629-25-4.
Odium stearate, No. CAS：822-16-2.
Isostearic acid sodium, No. CAS：64248-79-9.
CBS-X is 4,4'- bis- (2- sodium sulfonates styryl) biphenyl, i.e. fluorescent whitening agent, No. CAS：27344-41-8.
Limonene, No. CAS：138-86-3.
Curcumin, No. CAS：458-37-7.
β-carypohyllene, No. CAS：87-44-5.
Hydroxy ethylene diphosphonic acid, abbreviation H501, No. CAS：2809-21-4, No. EINECS：220-552-8.
EDTA, i.e. ethylenediamine tetra-acetic acid, No. CAS：60-00-4.
AEO-9, No. CAS：68213-23-0, fatty alcohol polyoxyethylene ether are the chemistry that fatty alcohol addition of ethylene oxide obtains
Product, are a kind of nonionic surfactants, and performance indicator is shown in Table 1.
Table 1：AEO-9 performance indicator tables
| Appearance (30 DEG C) | Coloration Gardner's method | PH value | HLB value | Cloud point DEG C * | Solid content % |
| Weak yellow liquid | ＜ 3 | 5-8 | 11.6 | 76-82 | ≥99 |
Obviously, suitable pigment can also be freely added according to client's needs in the present invention, to adjust, improve this production
The color and luster of product.
The present invention may be used the general soapmaking of the industry and be prepared.For example, in mixing kettle, material body is heated to 40-
60 DEG C, under agitation, add in other each raw materials, stir evenly, by milling, vacuum duplex press strip, stripping and slicing, printing
Obtain the special stains removing soap of clothes leader of the present invention.Relative to the prior art, innovation of the invention is the preferred of formula,
Rather than preparation method is in itself.
The advantages of technical solution of the present invention, is mainly reflected in following several respects：Vegetable fatty acid sodium-salt in formula, washing
It is time saving and energy saving, and save money, it is environmentally protective；It is made of, has sodium soap and nonionic surfactant and specific active auxiliary agent
Superpower wetting penetrating power for local intractable spot on clothing, is cleaned before master washes after immersion and is applied at dirt, promote
Clean effect, then give Normal Wash.Washing efficiency greatly improves, and is the excellent companion of liquid detergent；Property does not hinder clothing mildly,
And make clothing it is relatively white, it is bright-coloured, prevent from turning to be yellow, change colour, simple and elegant fruity, pure and fresh fragrance.Obviously, clothes leader of the invention is special
It can also be used for the washing of general clothing with stains removing soap.
Specific embodiment
In the present invention, unless otherwise instructed, all raw materials are in terms of substance content 100%.
Embodiment 5-11 cellulases, No. CAS：9012-54-8 is given birth to using the prebiotic hall bio tech ltd in Qingdao
The cellulase of 100,000 enzyme activities of production.
Protease in embodiment 5-11, No. CAS：9001-00-7, using the great day biology Engineering Co., Ltd production in Xi'an
The neutral proteinase of 100000 enzyme activities.
Embodiment 1-4
According to the corresponding embodiment 1-4 components and content specified by table 2, carry out raw material and weigh.
In mixing kettle, 50 DEG C are heated to, under agitation, each raw material is added in, stirs evenly, by milling, vacuum
Duplex press strip, stripping and slicing, printing can obtain the special stains removing soap of clothes leader of the invention.
Comparative example 1
According to 1 component of correspondence comparative example and content specified by table 2, carry out raw material and weigh, carry out as described in Example 1
It prepares.
Table 2：The special stains removing soap composition of raw materials list position of embodiment 1-4 clothes leaders：%
Remarks：% represents that the sum of mass percent, each embodiment each component is 100% in table 2.
Embodiment 5-11
According to the corresponding embodiment 5-8 components and content specified by table 3, according to the corresponding embodiment 9-11 specified by table 4
Component and content carry out raw material and weigh, and prepare embodiment 5-11 as follows.
In mixing kettle, 50 DEG C are heated to, at 300 revs/min, under stirring condition, each raw material is added in, stirs 30 minutes and mix
Uniformly, by milling, vacuum duplex press strip, stripping and slicing, printing can obtain the special stains removing soap of clothes leader of the invention.
Table 3：The special stains removing soap composition of raw materials list position of embodiment 5-8 clothes leaders：%
| Component | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 |
| Sodium laurate | 30.6 | 45.9 | 45.9 | / |
| Odium stearate | 30.6 | 45.9 | / | 45.9 |
| Isostearic acid sodium | 30.6 | / | 45.9 | 45.9 |
| Sodium metasilicate | 4 | 4 | 4 | 4 |
| AEO-9 | 2 | 2 | 2 | 2 |
| CBS-X | 0.02 | 0.02 | 0.02 | 0.02 |
| β-carypohyllene | 0.1 | 0.1 | 0.1 | 0.1 |
| Limonene | 0.1 | 0.1 | 0.1 | 0.1 |
| Curcumin | 0.1 | 0.1 | 0.1 | 0.1 |
| EDTA | 0.03 | 0.03 | 0.03 | 0.03 |
| Hydroxy ethylene diphosphonic acid | 0.03 | 0.03 | 0.03 | 0.03 |
| Cellulase | 0.5 | 0.5 | 0.5 | 0.5 |
| Protease | 0.5 | 0.5 | 0.5 | 0.5 |
| Water | Surplus | Surplus | Surplus | Surplus |
Remarks：% represents that the sum of mass percent, each embodiment each component is 100% in table 3.
Table 4：The special stains removing soap composition of raw materials list position of embodiment 9-11 clothes leaders：%
| Component | Embodiment 9 | Embodiment 10 | Embodiment 11 |
| Sodium laurate | 30.6 | 30.6 | 30.6 |
| Odium stearate | 30.6 | 30.6 | 30.6 |
| Isostearic acid sodium | 30.6 | 30.6 | 30.6 |
| Sodium metasilicate | 4 | 4 | 4 |
| AEO-9 | 2 | 2 | 2 |
| CBS-X | 0.02 | 0.02 | 0.02 |
| β-carypohyllene | 0.15 | 0.15 | / |
| Limonene | 0.15 | / | 0.15 |
| Curcumin | / | 0.15 | 0.15 |
| EDTA | 0.03 | 0.03 | 0.03 |
| Hydroxy ethylene diphosphonic acid | 0.03 | 0.03 | 0.03 |
| Cellulase | 0.5 | 0.5 | 0.5 |
| Protease | 0.5 | 0.5 | 0.5 |
| Water | Surplus | Surplus | Surplus |
Remarks：% represents that the sum of mass percent, each embodiment each component is 100% in table 4.
Test case 1
To the clothes leader of embodiment 1-11, the detergency of special stains removing soap matching standard liquid detergent is tested.
The special stains removing soap (1.0wt%) of clothes leader is according to method as defined in QB/T 1224-2012, in standard liquid detergent
The detergency of (0.2wt%).
Specific detection data refers to table 5.
Table 5：With the use of detergency test table
By 5 test data of table as it can be seen that the special stains removing soap of clothes leader of the present invention has good detergency ability.Especially
, the data of embodiment 3 are substantially better than embodiment 1 and embodiment 2, it is seen then that using AEO nonionic surfactants, fatty alcohol
Polyoxyethylene ether is compounded with sodium metasilicate, and detergency ability is synergistic.
Comparing embodiment 5 and embodiment 6-8, embodiment 5 (sodium laurate, odium stearate, isostearic acid sodium compounding) cooperation
Liquid detergent detergency ability is substantially better than embodiment 6-8 (both arbitrary compounding in sodium laurate, odium stearate, isostearic acid sodium)；
Comparing embodiment 5 and embodiment 9-11, embodiment 5 (limonene, curcumin, β-carypohyllene compounding) cooperation liquid detergent detergency ability
It is substantially better than embodiment 9-11 (both arbitrary compounding in limonene, curcumin, β-carypohyllene).
(2) stains removing (leader) special-purpose soap detergency test is used alone：
According to method as defined in QB/T 1224-2012, dispel, the detergency of stain (leader) special-purpose soap (0.2wt%).Specifically
Detection data refers to table 6.
Table 6：Detergency test table is used alone
By 6 test data of table as it can be seen that comparing embodiment 3 and embodiment 1-2, the data of embodiment 3 are substantially better than embodiment 1
With embodiment 2, it is seen then that AEO nonionic surfactants, fatty alcohol polyoxyethylene ether are synergistic with sodium metasilicate compound property.
Comparing embodiment 5 and embodiment 6-8, embodiment 5 (sodium laurate, odium stearate, isostearic acid sodium compounding) is individually
Embodiment 6-8 (both arbitrary compounding in sodium laurate, odium stearate, isostearic acid sodium) is substantially better than using detergency ability；Than
Compared with embodiment 5 and embodiment 9-11, it is apparent that detergency ability is used alone in embodiment 5 (limonene, curcumin, β-carypohyllene compounding)
Better than embodiment 9-11 (both arbitrary compounding in limonene, curcumin, β-carypohyllene).
(3) basic physical and chemical index test：
The clothes of the embodiment of the present invention 4 is led by I type laundry soap of QB/T2486-2008 according to its physical and chemical index of professional standard
Special stains removing soap of tucking inside the sleeve is tested, as a result such as table 7.
Table 7：The special stains removing soap base of clothes leader this physicochemical data test table
Test case 2
Bacteriostasis property test is carried out to embodiment 5-11, respectively to Escherichia coli (ATYCC 25922), Staphylococcus aureus
Bacterium (ATCC 6538) is tested, and tests and is carried out at room temperature at 20 DEG C, first by the strain suspensions and clothing of above two strain
The special stains removing soap of leader heated at constant temperature in test tube is taken, 1mL is then added in sterile test tube using bovine serum albumin as training
The bacteria suspension of base and the special stains removing soap of 1g clothes leaders are supported, after mixing fully shaking 5 minutes, then calculate sterilizing rate and (survey
Average colony number in bacteria suspension before and after fixed experiment).Concrete outcome is shown in Table 8.
Table 8：Bacteriostasis property test result table
| Sample | Escherichia coli sterilizing rate, % | Staphylococcus aureus sterilizing rate, % |
| Embodiment 5 | 95.5 | 96.6 |
| Embodiment 6 | 94.1 | 93.8 |
| Embodiment 7 | 93.4 | 93.5 |
| Embodiment 8 | 93.7 | 94.0 |
| Embodiment 9 | 92.1 | 93.2 |
| Embodiment 10 | 93.1 | 93.5 |
| Embodiment 11 | 92.7 | 92.9 |
Comparing embodiment 5 and embodiment 6-8, embodiment 5 (sodium laurate, odium stearate, isostearic acid sodium compounding) sterilization
Rate is apparently higher than embodiment 6-8 (both arbitrary compounding in sodium laurate, odium stearate, isostearic acid sodium)；Comparing embodiment 5 with
Embodiment 9-11, embodiment 5 (limonene, curcumin, β-carypohyllene compounding) sterilizing rate are apparently higher than embodiment 9-11 (lemons
Both arbitrary compounding in alkene, curcumin, β-carypohyllene).
Unquestionably, it is of the invention, can also have a variety of transformation and remodeling, however it is not limited to the specific reality of the above embodiment
Apply example.In short, protection scope of the present invention should include those obvious transformation to those skilled in the art
Or it substitutes and retrofits.
Claims (5)
1. a kind of special stains removing soap of clothes leader, which is characterized in that include the raw material of following mass percents：
The sodium soap is mixed by sodium laurate, odium stearate, isostearic acid sodium, the sodium laurate, odium stearate,
The mass ratio of isostearic acid sodium is (1-3)：(1-3)：(1-3).
2. the special stains removing soap of clothes leader as described in claim 1, it is characterised in that：The sodium metasilicate for sodium metasilicate and/
Or sodium metasilicate.
3. the special stains removing soap of clothes leader as described in claim 1, it is characterised in that：The AEO is aliphatic alcohol polyethenoxy
Ether, one or more mixtures in AEO-6, AEO-9, AEO-12.
4. the special stains removing soap of clothes leader as described in claim 1, it is characterised in that：The complex enzyme is lipase, without flower
Fruit protease, pepsin, trypsase, papain, subtilopeptidase A, amylase, cellulase, pectase,
One or more mixtures in mannonase peroxidase.
5. the special stains removing soap of clothes leader as described in claim 1, it is characterised in that：The essence by limonene, curcumin,
β-carypohyllene mixes, the limonene, curcumin, squalene, β-carypohyllene mass ratio be (1-3)：(1-3)：(1-
3)。
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188794A (en) * | 1997-01-22 | 1998-07-29 | 何选明 | Phosphorus free and aluminium free soap powder |
| CN102888301A (en) * | 2012-09-26 | 2013-01-23 | 上海群乐船舶附件启东有限公司 | Washing soap |
| CN103013722A (en) * | 2012-12-12 | 2013-04-03 | 合肥豪豪日化有限公司 | High water content compound laundry bar soap and preparation method thereof |
| CN104371860A (en) * | 2013-08-13 | 2015-02-25 | 杨林贵 | Safe composite washing soap powder |
| CN104560455A (en) * | 2013-10-16 | 2015-04-29 | 戴留庆 | Efficient stain-removing laundry soap |
-
2016
- 2016-03-17 CN CN201610153305.5A patent/CN105586182B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188794A (en) * | 1997-01-22 | 1998-07-29 | 何选明 | Phosphorus free and aluminium free soap powder |
| CN102888301A (en) * | 2012-09-26 | 2013-01-23 | 上海群乐船舶附件启东有限公司 | Washing soap |
| CN103013722A (en) * | 2012-12-12 | 2013-04-03 | 合肥豪豪日化有限公司 | High water content compound laundry bar soap and preparation method thereof |
| CN104371860A (en) * | 2013-08-13 | 2015-02-25 | 杨林贵 | Safe composite washing soap powder |
| CN104560455A (en) * | 2013-10-16 | 2015-04-29 | 戴留庆 | Efficient stain-removing laundry soap |
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|---|---|
| CN105586182A (en) | 2016-05-18 |
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Effective date of registration: 20221205 Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090 Patentee after: Shanghai Soap Factory Co.,Ltd. Address before: 200431 building 35, No. 1001, Changjiang West Road, Baoshan District, Shanghai Patentee before: Shanghai Soap Co.,Ltd. |