CN105580804A - Insecticide for anopheles sinensis - Google Patents

Insecticide for anopheles sinensis Download PDF

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Publication number
CN105580804A
CN105580804A CN201610086327.4A CN201610086327A CN105580804A CN 105580804 A CN105580804 A CN 105580804A CN 201610086327 A CN201610086327 A CN 201610086327A CN 105580804 A CN105580804 A CN 105580804A
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parts
anopheles sinensis
trimethyl
dimethyl
dihydro
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梁立明
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Yantai Miluoka Chemical Technology Co Ltd
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Yantai Miluoka Chemical Technology Co Ltd
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Priority to CN201610086327.4A priority Critical patent/CN105580804A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring

Abstract

The invention relates to an insecticide and particularly relates to an insecticide for anopheles sinensis. The insecticide for the anopheles sinensis is prepared from the following raw materials: 2,2-dimethyl-1,3-propanediyl diacrylate, dihydro-3-methylene-2(3H)-furanone, (2E,6E)-3,7,11-trimethyl-2,6,10-dodecatriene-1-ol, diethyl allylmalonate and (E)-4-(2,6,6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-ketone and the like. The insecticide for the anopheles sinensis can be directly sprayed on animals or the anopheles sinensis at the periphery, and has a good insecticidal effect, so that the harms caused by the fact that the anopheles sinensis carries and transmits pathogenic bacteria are reduced and a healthy living environment is created; and the insecticide can be easily popularized and applied in the aspect of preventing and treating the anopheles sinensis by using the insecticide.

Description

A kind of Anopheles sinensis pesticide
Technical field
The present invention relates to a kind of pesticide, be specifically related to a kind of Anopheles sinensis pesticide.
Background technology
Anopheles sinensis, in China, except Qinghai and Xinjiang, Provinces (regions) are all on the books. Female mosquito is held concurrently and inhales people, animal blood, but the large animal bloods such as deflection ox, horse, donkey. Rice field is the main breeding site of this anopheles normally, but also in the environment such as marsh, reed field, lakeside, irrigation canals and ditches, pond, depression ponding, grows widely.
Anopheles sinensis appearance is distinguished a little with general mosquito, on the moving wing of anopheles, has the alternate spot of grey black, likes to inhale animal blood, generally common in suburb, cowshed. Expert says, anopheles is easy to identification, and its health in the time of flight is 30～45 with object plane and spends oblique angles. Anopheles likes dividing at cockcrow attacks, and the cunning degree of anopheles is not as good as yellow-fever mosquito, while waiting people to feel, it be not also drawn onto blood but end opening stung, at this moment kill its skin and can play bag. Anopheles is the important medium that malaria is propagated in Chinese vast plains region, is also one of important medium of wuchereria malayi filariasis. Some area was also once separated to epidemic encephalitis B virus from this anopheles. Thereby very necessary to the cleaning of this kind of mosquito, correspondingly, be suitable for pesticide that Anopheles sinensis uses also for market is needed badly.
Summary of the invention
The object of the invention is to solve that above-mentioned prior art exists to the poor deficiency of Anopheles sinensis eradicating efficacy, a kind of effective Anopheles sinensis pesticide of Anopheles sinensis of eliminating is provided.
A kind of Anopheles sinensis pesticide, special character is to be prepared from by the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 14-20 parts, dihydro-3-methylene-2 (3H)-furanone 21-29 part, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 33-39 parts, allyl diethyl malonate 37-43 part, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25-31 part, 2-ethyleneoxy ethanol 40-46 part, dimethacrylate tetraethylene-glycol ester 16-22 part, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28-36 part, 2, 6-dimethyl-7-octen-2-ol 19-27 part.
Preferably, adopt Anopheles sinensis pesticide prepared by the raw material of following weight portion proportioning to there is better insecticidal effect: 2, 2-dimethyl-1, 17 parts of 3-propane two base diacrylates, dihydro-3-methylene-2 (3H)-21 parts of furanones, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 39 parts of 10-12 carbon triolefin-1-alcohol, 40 parts of allyl diethyl malonates, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl) 25 parts of-3-butene-2-one, 46 parts of 2-ethyleneoxy ethanol, 19 parts of dimethacrylate tetraethylene-glycol esters, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base] 28 parts of-5alpha-androstane-1-alkene-3-ketone, 2, 27 parts of 6-dimethyl-7-octen-2-ols.
Further, in order to obtain the better Anopheles sinensis pesticide of insecticidal effect, described Anopheles sinensis also comprises the raw material of following weight portion proportioning with pesticide: 7-methyl isophthalic acid-ethyl-4-oxo-1,4-dihydro-1,8-naphthyridines-3-carboxylic acid 7-11 part, 3-methyl-2-Oxobutyric acid sodium 4-10 part, 4-methyl-2-oxopentanoic acid 12-16 part.
Preferably, Anopheles sinensis pesticide, its parts by weight of raw materials proportioning is: 7-methyl isophthalic acid-ethyl-4-oxo-Isosorbide-5-Nitrae-dihydro-1,9 parts of 8-naphthyridines-3-carboxylic acids, 4 parts, 3-methyl-2-Oxobutyric acid sodium, 16 parts of 4-methyl-2-oxopentanoic acids.
Preparation method of the present invention: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add 2, 2-dimethyl-1, 3-propane two base diacrylates, dihydro-3-methylene-2 (3H)-furanone, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add allyl diethyl malonate, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one, 2-ethyleneoxy ethanol, dimethacrylate tetraethylene-glycol ester, stir 30 minutes, be cooled to again 40 DEG C, add 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone, 2, 6-dimethyl-7-octen-2-ol, continue to stir 30 minutes, obtain finished product.
This Anopheles sinensis pesticide, can directly spray animal Anopheles sinensis with it and around, and good disinsection effect, the harm that Anopheles sinensis is carried pathogen transmission reduced, create healthy living environment, be beneficial to and applying aspect control Anopheles sinensis pesticide.
Detailed description of the invention
Below provide the specific embodiment of the present invention, be used for the present invention to be further described. In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
In following examples, raw material introduction:
2,2-dimethyl-1,3-propane two base diacrylates, CAS accession number is: 2223-82-7;
Dihydro-3-methylene-2 (3H)-furanone, CAS accession number is: 547-65-9;
(2E, 6E)-3,7,11-trimethyl-2,6,10-, 12 carbon triolefin-1-alcohol, CAS accession number is: 106-28-5;
Allyl diethyl malonate, CAS accession number is: 2049-80-1;
(E)-4-(2,6,6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one, CAS accession number is: 79-77-6;
2-ethyleneoxy ethanol, CAS accession number is: 764-48-7;
Dimethacrylate tetraethylene-glycol ester, CAS accession number is: 109-17-1;
17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone, CAS accession number is: 1247-69-4;
2,6-dimethyl-7-octen-2-ol, CAS accession number is: 18479-58-8;
7-methyl isophthalic acid-ethyl-4-oxo-Isosorbide-5-Nitrae-dihydro-1,8-naphthyridines-3-carboxylic acid, CAS accession number is: 389-08-2;
3-methyl-2-Oxobutyric acid sodium, CAS accession number is: 3715-29-5;
4-methyl-2-oxopentanoic acid, CAS accession number is: 816-66-0.
Embodiment 1
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 14g, dihydro-3-methylene-2 (3H)-furanone 29g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 36g, allyl diethyl malonate 37g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 31g, 2-ethyleneoxy ethanol 43g, dimethacrylate tetraethylene-glycol ester 16g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 36g, 2, 6-dimethyl-7-octen-2-ol 23g.
The present embodiment Anopheles sinensis method for producing insecticide: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add 2, 2-dimethyl-1, 3-propane two base diacrylates, dihydro-3-methylene-2 (3H)-furanone, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add allyl diethyl malonate, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one, 2-ethyleneoxy ethanol, dimethacrylate tetraethylene-glycol ester, stir 30 minutes, be cooled to again 40 DEG C, add 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone, 2, 6-dimethyl-7-octen-2-ol, continue to stir 30 minutes, obtain finished product.
Embodiment 2
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 17g, dihydro-3-methylene-2 (3H)-furanone 21g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 39g, allyl diethyl malonate 40g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25g, 2-ethyleneoxy ethanol 46g, dimethacrylate tetraethylene-glycol ester 19g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28g, 2, 6-dimethyl-7-octen-2-ol 27g.
The present embodiment Anopheles sinensis with method for producing insecticide with embodiment 1.
Embodiment 3
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 20g, dihydro-3-methylene-2 (3H)-furanone 25g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 33g, allyl diethyl malonate 43g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 28g, 2-ethyleneoxy ethanol 40g, dimethacrylate tetraethylene-glycol ester 22g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 32g, 2, 6-dimethyl-7-octen-2-ol 19g.
The present embodiment Anopheles sinensis with method for producing insecticide with embodiment 1.
Embodiment 4
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 17g, dihydro-3-methylene-2 (3H)-furanone 21g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 39g, allyl diethyl malonate 40g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25g, 2-ethyleneoxy ethanol 46g, dimethacrylate tetraethylene-glycol ester 19g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28g, 2, 6-dimethyl-7-octen-2-ol 27g, 7-methyl isophthalic acid-ethyl-4-oxo-1, 4-dihydro-1, 8-naphthyridines-3-carboxylic acid 7g, 3-methyl-2-Oxobutyric acid sodium 10g, 4-methyl-2-oxopentanoic acid 14g.
The present embodiment Anopheles sinensis method for producing insecticide: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add 2, 2-dimethyl-1, 3-propane two base diacrylates, dihydro-3-methylene-2 (3H)-furanone, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add allyl diethyl malonate, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one, 2-ethyleneoxy ethanol, dimethacrylate tetraethylene-glycol ester, stir 30 minutes, be cooled to again 40 DEG C, add 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone, 2, 6-dimethyl-7-octen-2-ol, 7-methyl isophthalic acid-ethyl-4-oxo-1, 4-dihydro-1, 8-naphthyridines-3-carboxylic acid, 3-methyl-2-Oxobutyric acid sodium, 4-methyl-2-oxopentanoic acid, continue to stir 30 minutes, obtain finished product.
Embodiment 5
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 17g, dihydro-3-methylene-2 (3H)-furanone 21g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 39g, allyl diethyl malonate 40g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25g, 2-ethyleneoxy ethanol 46g, dimethacrylate tetraethylene-glycol ester 19g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28g, 2, 6-dimethyl-7-octen-2-ol 27g, 7-methyl isophthalic acid-ethyl-4-oxo-1, 4-dihydro-1, 8-naphthyridines-3-carboxylic acid 9g, 3-methyl-2-Oxobutyric acid sodium 4g, 4-methyl-2-oxopentanoic acid 16g.
The present embodiment Anopheles sinensis with method for producing insecticide with embodiment 4.
Embodiment 6
Weigh the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 17g, dihydro-3-methylene-2 (3H)-furanone 21g, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 39g, allyl diethyl malonate 40g, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25g, 2-ethyleneoxy ethanol 46g, dimethacrylate tetraethylene-glycol ester 19g, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28g, 2, 6-dimethyl-7-octen-2-ol 27g, 7-methyl isophthalic acid-ethyl-4-oxo-1, 4-dihydro-1, 8-naphthyridines-3-carboxylic acid 11g, 3-methyl-2-Oxobutyric acid sodium 7g, 4-methyl-2-oxopentanoic acid 12g.
The present embodiment Anopheles sinensis with method for producing insecticide with embodiment 4.
Carry out the test of the Anopheles sinensis resistance to the action of a drug with embodiment 1-6 gained finished product
1. medicament: embodiment 1-6 gained control Anopheles sinensis pesticide; Acetone is pure for analyzing.
2. examination worm: Anopheles sinensis Wild population gathers in pond, fringe area, takes to laboratory rearing to F1 generation and tests.
3. concrete testing procedure:
Taking III age Mo IV primary larva in age as subjects, former medicine is diluted with acetone, by 5～7 series concentration of medicament configuration to be measured, in the beaker of 250mL (or ceramic whiteware bowl etc.), add the liquid of 200mL dechlorination running water and 0.5mL respective concentration, add a people 2O～30 examination worm, after 24h, check result and record the death toll under each processing concentration dose. Taking 200mI dechlorination water as contrast, each concentration gradient repeats 3 times, the contrast death rate should < 2O, otherwise that test is considered as is invalid. Laboratory and recovery room temperature for (25 ± 1) DEG C, relative humidity be 60～70.
4. dead criterion: touch the respiratory siphon of Anopheles Sinensis Larvae in Paddy Fields by sharp instrument, active or tremble and be considered as death.
5. statistical method: utilize DPS software to calculate the LC of bioassay results50Value, and calculate resistance coefficient. Resistance to the action of a drug grade is judged: resistance coefficient≤2 are sensitivity; 2<resistance coefficient≤1O is the low resistance to the action of a drug; 1O<resistance coefficient≤2O is the moderate resistance to the action of a drug; Resistance coefficient>20, be the high resistance property of medicine.
Field acquisition Anopheles sinensis is the LC with pesticide to embodiment 1-6 gained control Anopheles sinensis50Be respectively 11.7,21.3,8.5,9.1,1.6,0.9 μ g/L, resistance coefficient is respectively 0.31,0.26,0.29,0.24,0.18,0.22. Anopheles sinensis is all responsive with pesticide to embodiment 1-6 gained control Anopheles sinensis. Specifically see the following form.
Anopheles sinensis is the resistance to the action of a drug measurement result with pesticide to embodiment 1-6 gained control Anopheles sinensis
Pesticide LC50（μg／L） Resistance coefficient
Embodiment 1 11.7 0.31
Embodiment 2 21.3 0.26
Embodiment 3 8.5 0.29
Embodiment 4 9.1 0.24
Embodiment 5 1.6 0.18
Embodiment 6 0.9 0.22
From upper table contrast, it is lower that the present invention prevents and treats Anopheles sinensis resistance to insecticides coefficient, and be all less than 0.35, it is worth much smaller than 2, therefore Anopheles sinensis has higher sensitiveness to pesticide of the present invention, be beneficial to and efficiently kill Anopheles sinensis, Anopheles sinensis eradicating efficacy is good.

Claims (4)

1. an Anopheles sinensis pesticide, it is characterized in that being prepared from by the raw material of following weight portion proportioning: 2, 2-dimethyl-1, 3-propane two base diacrylate 14-20 parts, dihydro-3-methylene-2 (3H)-furanone 21-29 part, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 10-12 carbon triolefin-1-alcohol 33-39 parts, allyl diethyl malonate 37-43 part, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl)-3-butene-2-one 25-31 part, 2-ethyleneoxy ethanol 40-46 part, dimethacrylate tetraethylene-glycol ester 16-22 part, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base]-5alpha-androstane-1-alkene-3-ketone 28-36 part, 2, 6-dimethyl-7-octen-2-ol 19-27 part.
2. Anopheles sinensis pesticide as claimed in claim 1, it is characterized in that parts by weight of raw materials proportioning is: 2, 2-dimethyl-1, 17 parts of 3-propane two base diacrylates, dihydro-3-methylene-2 (3H)-21 parts of furanones, (2E, 6E)-3, 7, 11-trimethyl-2, 6, 39 parts of 10-12 carbon triolefin-1-alcohol, 40 parts of allyl diethyl malonates, (E)-4-(2, 6, 6-trimethyl-1-cyclohexene-1-yl) 25 parts of-3-butene-2-one, 46 parts of 2-ethyleneoxy ethanol, 19 parts of dimethacrylate tetraethylene-glycol esters, 17beta-[(tetrahydrochysene-2H-pyrans-2-yl) oxygen base] 28 parts of-5alpha-androstane-1-alkene-3-ketone, 2, 27 parts of 6-dimethyl-7-octen-2-ols.
3. Anopheles sinensis pesticide as claimed in claim 1 or 2, characterized by further comprising the raw material of following weight portion proportioning: 7-methyl isophthalic acid-ethyl-4-oxo-Isosorbide-5-Nitrae-dihydro-1,8-naphthyridines-3-carboxylic acid 7-11 part, 3-methyl-2-Oxobutyric acid sodium 4-10 part, 4-methyl-2-oxopentanoic acid 12-16 part.
4. Anopheles sinensis pesticide as claimed in claim 3, is characterized in that parts by weight of raw materials proportioning is: 7-methyl isophthalic acid-ethyl-4-oxo-Isosorbide-5-Nitrae-dihydro-1,9 parts of 8-naphthyridines-3-carboxylic acids, 4 parts, 3-methyl-2-Oxobutyric acid sodium, 16 parts of 4-methyl-2-oxopentanoic acids.
CN201610086327.4A 2016-02-16 2016-02-16 Insecticide for anopheles sinensis Pending CN105580804A (en)

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Application publication date: 20160518