CN102845416A - Aromatic insect-preventing vermifuge - Google Patents
Aromatic insect-preventing vermifuge Download PDFInfo
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Abstract
The invention provides an aromatic insect-preventing vermifuge used for preventing cloth injurious insects andor flying injurious insects. The aromatic insect-preventing vermifuge is a liquid-type aromatic insect-preventing vermifuge taking perfume element as the effective element. The aromatic insect-preventing vermifuge has good safety and has small volume. Even a container tilts down, the liquid of aromatic insect-preventing vermifuge does not leak. At the same time, the aromatic insect-preventing vermifuge can diffuse to space at an appropriate speed. The space preventing effect appears quickly and can last long. The aromatic insect-preventing vermifuge is characterized in that the perfume having insect-preventing and insect-expelling capacity and liquid perfume of diffusion-assisting agent containing at least one diol alcohol ether are diffused through a liquid perfume permeating film.
Description
Technical field
The present invention relates to the liquid-type aromaticity insecting driving insect agent for dress material insect and/or flying pest.
Background technology
In the past, be not subjected to the insect pest of the dress material insects such as casemaking clothes moth class, dermestids class, moth class in order to protect fibre, mainly proposed various insect-proof agents with the form that is used for wardrobe, drawer, closet or dress material containing box and with its practical application.As its active ingredient, use in the past the sublimability insect-proof agent compositions such as paracide or naphthalene, but it is pointed out to exist the problem of strong and stimulating and safety, in recent years, the normal temperature fluidization property pyrethroid insecticidal constituents such as Prallethrin, the third Flumethrin become main flow.Latter's pyrethroid insecticidal constituent is with trace the dress material insect to be demonstrated the active ingredient that high insecticidal effect, odorless and safety are good, serviceability is high, process the space but need cost number minutes fully to diffuse to, thereby expectation improves its initial effect.
In addition, guarantee comfortable life activity space for the flying pests such as mosquito class, midge class or fly class are driven away in the past from certain space, mainly proposed various flying pest vermifuges, insecticide with the form that is used for the life activity spaces such as living room, dining room, kitchen, entry, lavatory, balcony and with its practical application.In order to achieve the above object, practical application following several prods: insert liquid-sucking core in the liquid that is encased in the container and attract up, make it from the product (patent documentation 1) that a prose style free from parallelism is waved loose type of waving on top spices or the agent of fluidization property insecting driving insect, make spices etc. be solidified into gel and wave loose product (patent documentation 2) from its surface, perhaps, make liquid remain in the medicament absorber of pearl and make its product of waving loose form from the surface (patent documentation 3) etc.But for these products, there are the following problems: it is large and heavy that product size is generally large-scale, volume, can become obstacle in the place that these products are set.In addition, also there are the following problems: leakage occurs during overturning, and content is along with waving that loose composition reduces and deteriorated, granular wave a prose style free from parallelism through the time ground deteriorated, waves loose Speed Reduction in mid-term, latter stage after using beginning, it is indefinite etc. to wave loose terminal point.
On the other hand, be accompanied by the variation of nearest consumer demand, following tendency also occurred: compare with the insecticide in the past of the desinsection pest repellant that uses odorless, come to give fragrance to processing the space with the insecting driving insect agent with a little fragrance more energetically.
Take above-mentioned situation as background, proposed the natural essential oil that several usefulness have insecting driving insect effect and aromaticity concurrently and come derived components as the scheme of insecting driving insect composition.
For example, as dress material insect insect-proof agent, patent documentation 4 has proposed a kind of insect-proof agent, and its volatility insect-proof agent that will be selected from peppermint oil, lemon oil, orange oil, citronellol, the poppy seed oil combines with the low volatility insect-proof agent that is selected from pine needle oil, Japan cypress oil, camphor, the firpene.In addition, in the patent documentation 5, be conceived to the hatching inhibitor of dress material insect, consider as long as suppress and then can prevent from the insect pest that caused by the dress material insect from having proposed the multiple terpene compounds such as linalool, geraniol, citronellal, allyl heptanoate, neryl acetate are hatched inhibitor as ovum for larva from the ovum hatching.
In addition, as the flying pest pest repellant, proposed with bata-phenethyl alcohol in the patent documentation 6, the dihydroxy methyl jasmonate is as the culicifuge of active ingredient, proposed with orange oil in the patent documentation 7, cassia oil, grapefruit wet goods natural essential oil is as the flying pest pest repellant of active ingredient, proposed in the patent documentation 8 with by isomenthol, linalool, citronellol, citral, the composition that citronellol consists of is as the culicifuge of active ingredient, in addition, in patent documentation 9, proposed to use by lavender being carried out the flying pest expellent of the steam distillation water that steam distillation obtains.
But, come derived components or fragrance component as the aromaticity insecting driving insect agent of active ingredient with the natural essential oil that has insecting driving insect effect and aromaticity concurrently, effect to dress material insect and/or flying pest can not say sufficient, when it is developed, when selecting active ingredient, making up with other preparations or solvent, research is waved the loose high formulation of efficient and is absolutely necessary.
As the form of insect-proof agent, known to have with above-mentioned normal temperature sublimability solid be that camphor, naphthalene, paracide etc. are as the solid insect-proof agent of active ingredient.In addition, the insect-proof agent of this solid insect-proof agent as an alternative, the commercialization of following insect-proof agent: will be as normal temperature fluidization property pyrethroid insecticides organic solvent dissolutions such as the Prallethrin of active ingredient, the third Flumethrins, the liquid that obtains is contained in the hardboard of the paper pulp system of being dipped into or nonwoven film-making material etc. and the insect-proof agent that obtains or make the liquid gelling and gel insect-proof agent of obtaining etc.
Since the insect-proof agent of solid type when using through the time ground diminish, therefore, have the advantage of knowing easily the time of changing medicament, but then, it has unique foul smell and makes people have a mind to avoid.In addition, for the insect-proof agent of impregnation type, even insect-proof agent is waved loose and is consumed, the face shaping of impregnation carrier itself does not also change, thereby the shortcoming of the terminal point that existence can't clear and definite vermins-proof effect.On the other hand, for the gel insect-proof agent since when using through the time ground shrink, therefore, can judge the use process to a certain extent, but gel can complete obiteration, thereby still has the shortcoming of terminal point that can't clear and definite vermins-proof effect.In addition, the attractive in appearance of the gel after the contraction also has problems sometimes.
In order to overcome the problems referred to above, proposed take the aromatic that has insect protected function (patent documentation 10) of liquid fragrance as the basis.
Major part in them is following system: utilize the capillarity that is called as liquid-sucking core that is inserted in the bottle that liquid is housed to attract liquid, this liquid is exuded to and is positioned on the loose face of waving of top felt or paper pulp material, thereby makes medicine liquid ingredient loose from this face Back stroke.This system has can estimate easily that liquid reduces and the advantage of knowing easily the replacing time of medicament, but then, worry that liquid can spill into when the bottle overturning around.Based on above-mentioned situation, the agent of a kind of liquid-type aromaticity insecting driving insect of expectation exploitation, even it is formulation small-sized and that overturning also can not be overflowed, waving of space is loose can carry out with suitable speed medicament to preventing and kill off, the space preventive effect manifests fast and continues.
Patent documentation 1: TOHKEMY 2005-170914 communique
Patent documentation 2: TOHKEMY 2006-213640 communique
Patent documentation 3: TOHKEMY 2011-50684 communique
Patent documentation 4: Japanese kokai publication hei 09-278621 communique
Patent documentation 5: No. 4311773 communique of Japan Patent
Patent documentation 6: Japanese kokai publication hei 5-208902 communique
Patent documentation 7: TOHKEMY 2002-173407 communique
Patent documentation 8: TOHKEMY 2003-138290 communique
Patent documentation 9: TOHKEMY 2006-104075 communique
Patent documentation 10: Japanese kokai publication hei 11-196930 communique
Summary of the invention
The present invention relates to the liquid-type aromaticity insecting driving insect agent of natural or synthetic fragrance component as active ingredient, its purpose is to provide the agent of aromaticity insecting driving insect, it can bring into play high insecting driving insect effect, and it is good to the safety of people and pet, and slight aromaticity can be pointed out the beginning of effect, and, even have the structure that small-sized and overturning can leakage yet, and then also make the consumer use know latter stage easily time of changing medicament.
Therefore, among the present invention, in order to make dress material insect and/or flying pest had the natural of insecting driving insect effect or the synthetic perfume composition is waved loose by liquid perfume agent permeability film with the suitable loose speed of waving, kind to fragrance component with vermins-proof effect is studied, and conducts in-depth research being used for regulating its combination of waving loose auxiliary agent of waving loose speed etc.
Result of study shows, do not use separately the fragrance component with insecting driving insect effect, suitable waves loose auxiliary agent but need to add with fragrance component has an intermiscibility.But its combination is very varied, thereby best being combined of exploration is not easy.The result who repeatedly studies in great detail shows, some specifically waved loose auxiliary agent wave loose with the suitable speed of faling apart of waving by liquid perfume agent permeability film with the liquid perfume agent that some specific insecting driving insect fragrance component combines.And find, utilize the waving of liquid perfume agent of this mode to fall apart and to bring into play good insecting driving insect effect to dress material insect and/or insect, can estimate clearly simultaneously liquid through the time reduce, and liquid wave loose after, the dirt that causes at container internal cause residue can not remain in the liquid container yet, thereby good.The present invention is based on above-mentioned opinion, further repeatedly improve and finish.
That is, the present invention relates to the aromaticity insecting driving insect agent of following formation.
[1] a kind of aromaticity insecting driving insect agent is characterized in that, makes the liquid perfume agent that comprises insecting driving insect spices and contain the loose auxiliary agent of waving of at least a glycol ethers wave loose by liquid perfume agent permeability film.
Such as above-mentioned [1] described aromaticity insecting driving insect agent, it is characterized in that [2] above-mentioned glycol ethers is to be selected from the group that is comprised of glycol ether, propylene glycol and dialkyl group glycol ethers more than one.
Such as above-mentioned [1] or the agent of [2] described aromaticity insecting driving insect, it is characterized in that [3] it is flavor compounds in 130 ~ 210 the scope that above-mentioned insecting driving insect spices comprises the molecular weight with ester group.
[4] such as above-mentioned [3] described aromaticity insecting driving insect agent, it is characterized in that, above-mentioned molecular weight is 130 ~ 210 the interior flavor compounds of scope, comprises to be selected from by methyl benzoate, acetic acid cis 3-hexene ester, benzyl acetate, allyl hexanoate, phenethyl acetate, allyl heptanoate, cinnamyl acetate, allyl octanoate, allyl amyl glycolate, cyclacet, allyl cyclohexyl propionate, acetic acid-2-tert-butyl group cyclohexyl, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, the tristane carboxylic acid, ethyl ester, phenyl ethyl formate, methyl phenyl carbinyl acetate, linalyl acetate, isobornyl acetate, the spices of more than one in the group that geranyl acetate and citronellyl acetate form.
Such as above-mentioned [1] or the agent of [2] described aromaticity insecting driving insect, it is characterized in that [5] above-mentioned insecting driving insect spices contains the spices of more than one the activity with breeding, motion and existence of suppressing insect.
[6] such as above-mentioned [1] or the agent of [2] described aromaticity insecting driving insect, it is characterized in that, the aforesaid liquid perfume agent is accommodated in the container of the open shape of part, described container is formed by the non-permeability material of liquid perfume agent, and paste liquid perfume agent permeability film in the opening portion of this container as the lid material, make this liquid perfume agent wave loose by this film.
Such as above-mentioned [6] described aromaticity insecting driving insect agent, it is characterized in that [7] aforesaid liquid perfume agent permeability film is for the film that formed by polythene material or contain polyethylene and film that vinyl-vinyl acetate copolymer forms.
[8] such as above-mentioned [6] described aromaticity insecting driving insect agent, it is characterized in that, above-mentioned lid material makes liquid perfume agent permeability film and the non-permeability film of liquid perfume agent form with the stacked shaping of strippable mode, before use, only peel off to remove and be positioned at the non-permeability film of outer field liquid perfume agent and liquid perfume agent permeability film is exposed, bring into use thus.
[9] such as above-mentioned [1] or the agent of [2] described aromaticity insecting driving insect, it is characterized in that, in the aforesaid liquid perfume agent, add colouring agent and painted its observability that improves.
The invention effect
The present invention relates to come derived components or synthetic perfume composition as the liquid-type aromaticity insecting driving insect agent of active ingredient with natural plant essential oils, the space insect repellant effect that its performance is high, and on the other hand, good to the safety of people and pet.And, slight aromaticity can be pointed out the beginning of effect, and improve and use sense, balancedly make in the liquid the insecting driving insect fragrance component with wave loose auxiliary agent and wave loose, therefore, even at also can be in container after the use not residual dirt that causes because of residue, using know latter stage, therefore can say that its practicality is high easily time of changing medicament.And liquor is by the non-permeability container of medicament with the non-permeability film sealing of removable liquid perfume agent that covers the film with Insecticide volatilizing device, therefore, do not worry in carrying fully or causes leakage because of overturning etc. when using.
For aromaticity insect-proof agent of the present invention and/or pest repellant (for example, comprise flying pest pest repellant etc.), the initial stage of loose speed when using of waving of its medicament begins until mid-term, latter stage all less than larger variation, thereby can realize stable dress material insect and/or the insecting driving insect effect of flying pest.For waving loose speed, consider that target prevents and kill off the area in space, can determine by the size and the quantity that are arranged on opening portion on the container of taking in liquor, that be pasted with the Insecticide volatilizing device film.In addition, it is small-sized preparation integral body can be finish-machined to light weight, therefore, can not become obstacle in use.
Description of drawings
Fig. 1 is expression sectional view basic comprising of the present invention, that contain the container of liquid perfume agent.
Fig. 2 is expression external view basic comprising of the present invention, that contain the container of liquid perfume agent.
Fig. 3 makes use-case as general embodiment example of the present invention in dustbin.
Fig. 4 is the external view of the configuration example of expression outer container of the present invention.
Fig. 5 is the external view that make use-case of expression when using outer container of the present invention to exist side by side use.
The external view that makes use-case when Fig. 6 is expression use outer container of the present invention and suspension use.
Fig. 7 is the skeleton diagram of the experimental rig that uses in the basic potency test of flying pest expelling parasite spices.
Label declaration
1 container
2 liquid perfume agent permeability films
The non-permeability film of 3 liquid perfume agent
4 adhesive layers
5 lid materials
6 liquid perfume agent
7 flange parts
11 outer containers
12 suspension parts
14 frame members
16 supports
Embodiment
General type as aromaticity insecting driving insect of the present invention agent, as shown in Figure 1, following formation: the liquid perfume agent 6 that will comprise insecting driving insect spices and wave loose auxiliary agent is packed in the suitable container 1, makes liquid perfume agent 6 wave loose from the liquid perfume agent permeability film 2 on the part that sticks on open container.
The in the past how known natural or synthetic perfume composition that the pest types such as insect, mite is demonstrated various active (activity that for example suppresses breeding, motion and the existence of insect).As the insecting driving insect spices that uses in the aromaticity insecting driving insect of the present invention agent, can use these known natural or synthetic perfume compositions.
As the natural perfume material composition, be not particularly limited, can enumerate such as alcohols spices, aldehydes spices, ethers spices, ester perfume, ketone fragrance etc.As alcohols spices, be not particularly limited, can enumerate such as cinnamyl alcohol, linalool, terpineol, citronellol, dihydro linalool, dihydromyrcenol, Ethyl linalool etc.As aldehydes spices, be not particularly limited, can enumerate such as benzaldehyde, cinnamic acid, piperonal, vanillin, citral, citronellal, capraldehyde etc.As ethers spices, be not particularly limited, can enumerate such as isoancthole, dl-rose oxide, phenylacetaldehyde dimethyl acetal, Linalool, oxide etc.As ester perfume, be not particularly limited, can enumerate such as propyl propionate, isoamyl acetate, acetic acid cis 3-hexene ester, methyl heptanoate, benzyl acetate, phenyl ethyl formate, allyl hexanoate, methyl phenyl carbinyl acetate, phenethyl acetate, allyl heptanoate, acetic acid fennel ester, allyl octanoate, allyl amyl glycolate, allyl cyclohexyl propionate, linalyl acetate, isobornyl acetate, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, Ergol, benzyl salicylate, phenylethyl phenylacetate etc.As ketone fragrance, be not particularly limited, known for example have: raspberry ketone, watermelon ketone, alpha, beta-lonone, α damascone, cashmeran, ambrotone.
Wherein, as the insecting driving insect fragrance component that uses among the present invention, can use the composition that is selected from above-mentioned natural perfume material composition and the above-mentioned synthetic perfume composition, has the activity (having the insecting driving insect effect) of the breeding, motion and the existence that suppress dress material insect (for example casemaking clothes moth, curtain casemaking clothes moth, black wool khapra beetle, roundlet khapra beetle, moth) and/or flying pest (for example mosquito class, fly, buffalo gnat class, midge class).
Alleged insecting driving insect effect not only refers to larvicidal activity, kills the adult activity among the present invention, also comprise following producing effect: the breeding stage insect is played fatal effect, even perhaps unlikely its death, but also to breeding, in the space existence or circle in the air and bring expelings, inhibition, thereby can prevent that dress material insect and/or flying pest class from approaching, the space is prevented and kill off in intrusion.
Particularly, can enumerate to the space of dress material insect and/or flying pest drive away active and contact drive away active, circle in the air suppress active, Behavioral interference is active, lay eggs and suppress active, ovum hatching and suppress that activity, ovicidal activity, larvicidal activity, larva food rcstriction are active, larva is built a nest and suppress active, larva and sprout wings and suppress active, larva and drive away active, adult expeling activity, extremely adult activity, adult interference in mating activity etc.
Comprise insect protected fragrance component and/or flying pest insect repellent fragrance composition in the above-mentioned insecting driving insect fragrance component, be not particularly limited, in above-mentioned most of fragrance component, particularly can enumerate: terpineol, citronellal, citral, aldehyde C-9, capraldehyde, citronellol, geraniol, nerol, borneol, decyl alcohol, linalool, the dihydro linalool, tetrahydrolialool, the dehydrogenation linalool, Ethyl linalool, dihydromyrcenol, rhodinol, menthol, to terpane-3, the 8-glycol, thymol, ebony alcohol, terpane, amphene, firpene, citrene, alpha, beta-lonone, cedrol methyl ether, anethole, isoancthole, cinnamic acid, cumal, phenylacetaldehyde dimethyl acetal, methyl benzoate, acetic acid cis 3-hexene ester, benzyl acetate, cognac oil, phenethyl acetate, butyl hexanoate, isobutyl hexanoate, cinnamyl acetate, acetic acid fennel ester, cyclacet, acetic acid-2-tert-butyl group cyclohexyl (verdox), acetic acid-4-tert-butyl group cyclohexyl (iris ester), the tristane carboxylic acid, ethyl ester, allyl hexanoate, allyl heptanoate, geranyl formate, citronellyl formate, phenyl ethyl formate, methyl phenyl carbinyl acetate, linalyl acetate, isobornyl acetate, geranyl acetate, citronellyl acetate, neryl acetate, gaultherolin, the isobutoxy allyl acetate, the n-pentyloxy allyl acetate, allyl amyl glycolate (the fluffy ester of lattice), dissident's ethoxyacetic acid allyl ester, 3-ethyl amoxy allyl acetate, the cyclopentyloxy acetic acid allyl ester, cyclohexyloxy allyl acetate (the fluffy ester of ring lattice), Allyl Phenoxyacetate, allyl octanoate, allyl cyclohexyl propionate, Ergol, benzyl salicylate, trimethyl citrate, cis-jasmone, watermelon ketone, cashmeran, ambrotone, the α damascone, the δ damascone, carvol, citronella oil, cinnamon oil, eucalyptus oil, lemon eucalyptus oil, Japan cypress oil, lavender oil, orange oil, oil of grapefruit, cedarwood oil, geranium oil, the thyme white oil, the peppermint wet goods can cooperate wherein more than one fragrance component.
Wherein, the molecular weight that preferably has ester group is 130 ~ 210 the interior compound of scope, be compound in 130 ~ 210 the scope as above-mentioned molecular weight, be not particularly limited, for example can enumerate: methyl benzoate, acetic acid cis 3-hexene ester, benzyl acetate, allyl hexanoate, phenethyl acetate, allyl heptanoate, cinnamyl acetate, allyl octanoate, allyl amyl glycolate, cyclacet, allyl cyclohexyl propionate, acetic acid-2-tert-butyl group cyclohexyl, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, the tristane carboxylic acid, ethyl ester, phenyl ethyl formate, methyl phenyl carbinyl acetate, linalyl acetate, isobornyl acetate, geranyl acetate and citronellyl acetate.These compositions can be used alone, and also can be use mixing two or more.
, can enumerate: methyl benzoate, acetic acid cis 3-hexene ester, benzyl acetate, allyl hexanoate, phenethyl acetate, allyl heptanoate, cinnamyl acetate, allyl octanoate, allyl amyl glycolate, cyclacet, allyl cyclohexyl propionate, acetic acid-2-tert-butyl group cyclohexyl, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, tristane carboxylic acid, ethyl ester the good insect pest preventing effectiveness of the larva of dress material insect performance or the spices of insecticidal effect as especially.These compositions can be used alone, and also can be use mixing two or more.
In addition, if make the ovum hatching inhibition of its performance dress material insect, then preferably cooperate disclosed tetrahydrolialool, citronellol, citral, geraniol, linalool, allyl hexanoate, allyl heptanoate, amphene, alpha, beta-lonone, cumal, damascone, citronella oil, cinnamon oil, eucalyptus oil, lemon eucalyptus oil, Japan cypress wet goods in No. the 4311773rd, Japan Patent and No. 4332301 communique of Japan Patent.And then, if give mating to the dress material insect, lay eggs, the inhibition of the reproductive behavior such as ovum hatching is active, then as No. 4148552 communique of Japan Patent is disclosed, preferably cooperates carvol, anethole, linalool etc.
And then,, can enumerate: benzyl acetate, allyl hexanoate, phenethyl acetate, allyl heptanoate, allyl octanoate, allyl amyl glycolate, allyl cyclohexyl propionate, acetic acid-2-tert-butyl group cyclohexyl, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, tristane carboxylic acid, ethyl ester, phenyl ethyl formate, methyl phenyl carbinyl acetate, linalyl acetate, isobornyl acetate, geranyl acetate and citronellyl acetate the spices of the good flying pest dispel effect of flying pest performance as especially.These compositions can be used alone, and also can be use mixing two or more.
Among the present invention, wave loose auxiliary agent and must contain at least a glycol ethers with above-mentioned insecting driving insect fragrance component together uses.As above-mentioned glycol ethers, be not particularly limited, can enumerate: glycol ether (for example, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, ethylene glycol monoallyl ether etc.), propylene glycol (such as dipropylene glycol monomethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether etc.) and dialkyl group glycol ethers (such as glycol dimethyl ether, diethylene glycol dimethyl ether, diethyl carbitol etc.), in addition, can also enumerate 3-methoxyl group-3-methyl butanol, 3-methoxyl group-2-methyl butanol etc.Among the present invention, the compound that has the structure of glycol ethers in the alcoholic compound is included in the glycol ethers of the present invention.Among the present invention, can be on the basis of above-mentioned glycol ethers and with the solvent of other kinds, for example, can suitably make water, alcohol (such as ethanol, isopropyl alcohol, n-hexyl alcohol etc.), glycol (such as propane diols etc.), the positive paraffin series hydrocarbon of various carbon numbers, different paraffin series hydrocarbon or aromatic hydrocarbon, surfactant, solubilizer, dispersant etc.
Found that of inventor's further investigation, the kind of waving loose auxiliary agent of using is also relevant with kind and the form of liquid perfume agent permeability film described later, for example, when the material of liquid perfume agent permeability film is polyethylene, the mixture of paraffin series hydrocarbon and glycol ethers has high adaptability, in addition, liquid perfume agent permeability film is that the mixture of two or more glycol ethers has higher adaptability when containing the film of polyethylene and vinyl-vinyl acetate copolymer.
Wave loose auxiliary agent as above-mentioned, two or more glycol ethers is being mixed in the situation about using, its combination is not particularly limited, and can use to be selected from two or more in the group that is comprised of glycol ether, propylene glycol and dialkyl group glycol ethers.For example, preferably use the combination of combination, propylene glycol monobutyl ether and the diethylene glycol monomethyl ether of propylene glycol monobutyl ether and dipropylene glycol dimethyl ether.
In addition, among the present invention, can also use the mixture of paraffin series hydrocarbon and glycol ethers.The paraffin series hydrocarbon is the positive paraffin series hydrocarbon of carbon number 12 ~ 14 more preferably.For carbon number is compound below 11, self wave loose too fast and be not suitable for this aromaticity insecting driving insect agent purposes.In addition, carbon number is 15 when above, and wax can occur, and therefore can not use in this purposes.In addition, for glycol ethers, be preferably propylene glycol monobutyl ether, diethylene glycol dimethyl ether, dipropylene glycol dimethyl ether, wherein, propylene glycol monobutyl ether more preferably.For the blending ratio of paraffin series hydrocarbon and glycol ethers, the mixing ratio of preferred paraffin series hydrocarbon and glycol ethers is in the scope of 1:3 ~ 1:5.When the ratio of glycol ethers is lower than this ratio, sometimes wave loose too fast or in preservation, be exuded on the film, otherwise when the ratio of glycol ethers was higher than this ratio, fluidization property was low and may be residual with the form of residue.
Prediction is waved loose auxiliary agent and is had self waving and also wave together loose effect with the insecting driving insect fragrance component when loose, waves the ratio of loose auxiliary agent when low, can not improve and wave loose efficient.For the match ratio of waving loose auxiliary agent, the ratio of preferably waving in the present invention loose auxiliary agent is high for insecting driving insect spices, and insecting driving insect spices is counted 2:3 ~ 2:5 with the ratio of waving loose auxiliary agent with weight ratio, wherein, and 1:2 more preferably.
For aromaticity insecting driving insect of the present invention agent, bring in the situation of adverse effect not giving to the insecting driving insect effect of insect and to the safety of people and pet, can cooperate various odor control agent composition, be used for regulating other fragrance ingredients, the fragrance component of fragrance.For example, can add the leaf alcohol that is called " green aroma " or leaf aldehyde etc., thereby give relaxation effect.
In addition, add pyrethroid insecticidal constituent, for example Prallethrin, 2 of normal temperature fluidization property, 3,5,6-ptfe benzyl-2,2-dimethyl-3-(2,2-dichloroethylene) cyclopropanecarboxylcompound [transfluthrin], 4-methyl-2,3,5,6-ptfe benzyl-2,2-dimethyl-3-(1-acrylic) cyclopropanecarboxylcompound [the third Flumethrin], 4-methoxyl methyl-2,3,5,6-ptfe benzyl-2 during 2-dimethyl-3-(1-acrylic) cyclopropanecarboxylcompound [methoxy benzyl Flumethrin] etc., can be realized the raising of insecting driving insect effect.
In addition, the composition as adding in aromaticity insecting driving insect of the present invention agent is not particularly limited, and can enumerate deodorant, mould inhibitor, antibacterial agent etc.As above-mentioned deodorant, can enumerate: the pyruvates such as volatile pine needle oil, Japan cypress oil, bamboo extract, biennial wormwood extract, Chinese parasol tree oil and ethyl pyruvate, pyruvic acid phenethyl ester etc.As above-mentioned mould inhibitor, can enumerate: 2-n-octyl-4-isothiazole woods-3-ketone, isopropyl methyl phenol, O-SyL etc.As above-mentioned antibacterial agent, can enumerate: chamenol, tetrahydrolialool, Eugenol, citronellal, allyl isothiocyanate etc.
Embodiment as aromaticity insecting driving insect of the present invention agent, can be listed below mode: as shown in Figure 1, the aforesaid liquid perfume agent is accommodated in the container 1 of the open shape of part, said vesse 1 is formed by the non-permeability material of liquid perfume agent, and paste liquid perfume agent permeability film 2 in the opening portion of this container 1 as the lid material, make this liquid perfume agent wave loose by this film.
As container 1, be not particularly limited, it is suitable using in actual applications plastic container.As the material of these plastics, the material that need to can't see through for the liquid perfume agent is considered anti-content physical property, and base material can use the non-permeability materials of liquid perfume agent such as polyethylene terephthalate, Merlon, polypropylene, polystyrene, polyamide.At this moment, if the material of the transparency or translucence, then know easily liquid because waving the loose minimizing that causes, thus preferred.
Aforesaid liquid perfume agent permeability film 2 (Fig. 1) refer to make liquid perfume agent 6 (Fig. 1) to wave loose film by this member.As this liquid perfume agent permeability film 2, so long as have resistance to chemical reagents, the liquid perfume agent is oozed out with the form of liquid and wave the loose outer film of container that penetrates into the form of gas, then be not particularly limited.
As the material of aforesaid liquid perfume agent permeability film, can enumerate such as: polyethylene (representational be low density polyethylene (LDPE), straight chain shape low density polyethylene (LDPE)), polypropylene, vinyl-vinyl acetate copolymer etc.In addition, above-mentioned film can contain two or more resins, for example, also can preferably use and contain film that vinyl-vinyl acetate copolymer (EVA) forms etc. in polyethylene.In this case, can be the film make each resin compound be shaped and obtain, also can be for example to use adhesive with the stacked film that forms more than two-layer of each resin bed.For example, in the situation of the film that obtains in that resin compound is formed, only otherwise the function of infringement aforesaid liquid perfume agent permeability, then the mixing ratio of each resin is not particularly limited.In addition, in the situation of the film that each resin bed is laminated, only otherwise the function of infringement aforesaid liquid perfume agent permeability, then stacked order and combination are not particularly limited, and for example, can enumerate the stacked film of polyethylene and EVA etc.In the situation of this stacked film, preferably take EVA as inboard (side that contact with the container 1 of Fig. 1), take polyethylene as outside (side that contacts with the non-permeability film 3 of the liquid perfume agent of Fig. 1) film of being laminated.
In addition, among the present invention, wave before use loose in order to prevent the liquid perfume agent, as the material of the lid material 5 (Fig. 1) of container, preferably the face that contacts with outside atmosphere with aforesaid liquid perfume agent permeability film 2 namely covers and the polylayer forest film of formation with the non-permeability film 3 of the liquid perfume agent of removable gas barrier property (Fig. 1) on the surface.
Particularly, lid material 5 is the duplexer that liquid perfume agent permeability film 2 and the non-permeability film 3 of liquid perfume agent form by adhesive layer 4 (Fig. 1), together peel off together with adhesive layer 4 and remove by being positioned at the non-permeability film 3 of outer field liquid perfume agent, liquid perfume agent permeability film 2 is exposed and bring into use.
As non-permeability film 3 members of aforesaid liquid perfume agent, suitably select according to the kind of the liquid perfume agent of using, can illustration: polyethylene terephthalate, nylon, aluminium foil etc.The non-permeability film 3 of aforesaid liquid perfume agent can be the monofilm that is made of a kind of member, the film that also can be laminated for two or more materials.
Need to prove, be not to use as mentioned above in the situation of the non-permeability film 3 Covering Liguid perfume agent permeability films 2 of removable liquid perfume agent, wave before use loosely for the liquid perfume agent that prevents aromaticity insecting driving insect of the present invention agent, preferably in advance container 1 integral body is accommodated with the state that is enclosed within the package body that is made of the non-permeability member of liquid perfume agent.
The shape of container 1 can be made by known habitual manufacturing process such as the method for hot forming such as vacuum forming method or gas pressure compacting method, injection molding methods so long as can take in liquid and shape that a part has an opening portion gets final product.
Opening portion periphery in this container 1 main body arranges smooth face and flange part 7 (Fig. 1), utilizes adhesive or ultrasonic bonding etc. that liquid perfume agent permeability film 2 is sealed, thereby the liquid perfume agent can be sealed in the container.At this moment, in order to confirm the minimizing of liquid itself, preferably the state of liquid perfume agent with liquid added in the container, and be not to make on its impregnation body that loads on absorbency etc.
For aromaticity insecting driving insect of the present invention agent, it is loose that the liquid perfume agent 6 that comprises insecting driving insect spices and wave loose auxiliary agent that is accommodated in the container 1 is waved by liquid perfume agent permeability film 2, and this is MIN formation.In this case, can install in the bottom surface of Fig. 1, container shown in Figure 2 and peel off paster or マ ジ Star Network テ-プ (registration mark) etc., use the inside etc. that directly sticks on the lid of wall, screen door, dustbin 10 shown in Figure 3.In addition, the hole 8 (Fig. 2) that also can be provided for hanging at the flange place of container, hook that hangs on wall etc. uses.
Perhaps, as other forms, container further is accommodated in the outer container 11 (Fig. 4) of air capacity of soils and uses, can expect thus the raising of setting property, interior decoration.
As a concrete example, as shown in Figure 4, but can be illustrated in the outer container 11 of the such structure of holding vessels between the frame member 14 with predetermined thickness of peristome 15 of the size with accommodating container 11.
Can be the member that separates between the frame member 14 (Figure 4 and 5), also can be for being provided with the integrally formed member of hinge part.Container 1 is accommodated in the frame member 14, by the book of opening as closing, will closes between the frame member 14, become thus the form (Fig. 5) of outer container 11.Can utilize the support 16 that arranges separately as shown in Figure 5 that this outer container 11 is erected on bed or the table uses, perhaps on the top of outer container 11 suspension part 12 is set as shown in Figure 6, be suspended on the places such as door handle 13 and use etc., can freely design as the form of outer container 11.
In order to observe easily the minimizing situation of liquid, can utilize as required dyestuff to carry out painted to liquid perfume agent 6.As long as dyestuff can be dissolved in the insecting driving insect spices that uses among the present invention and wave loose auxiliary agent and then be not particularly limited, can illustrate: orange No. 403 such azo dyess, green No. 202 such anthraquinone dyes and tar colorant, indigo class pigment etc.
The object insect of the present application is not particularly limited, and can enumerate: the dress material insects such as casemaking clothes moth, curtain casemaking clothes moth, black wool khapra beetle, roundlet khapra beetle, moth; The mosquito classes such as northern house, Culex molestus, aedes albopictus, Anopheles sinensis; The fly classes such as house fly, Fannia canicularis, Sarcophga fuscicauda, Aldrichina grahami, drosophila melanogaster, eye fly; The moth buffalo gnat classes such as hickie moth buffalo gnat, star spot moth buffalo gnat; The midge classes such as plumage midge, red midge; The flying pests such as moth class such as casemaking clothes moth, curtain casemaking clothes moth, Indian meal moth.In addition, as the field of employment, can use in various places in average family, warehouse, poultry hen house, factory, eating house, barracks, barbecue field etc.
Embodiment
Below, by embodiment and comparative example the present invention is described in more detail.The present invention is not subjected to the restriction of these embodiment, can suitably change in purport scope of the present invention.
Test example 1: insect protected spices basis potency test
On the filter paper of 10 * 10cm, inject respectively the solution that the various fragrance component 100mg with table 1 record of 1ml obtain with 10 times of ethanol dilutions, make its impregnation, ethanol is air-dry, as for examination filter paper.
To place the bottom of the about 6 liters vial of capacity for examination filter paper, 10 30 day age, average weights fixedly are housed is that 30 ~ 35mg/ casemaking clothes moth larva and wool tested cloth (2cm * 2cm, 40 ~ 45mg) cage at 5cm place above it.Then, with vial sealing, be 65% the indoor placement of constant temperature and humidity 7 days at 27 ℃, humidity, then, take out wool test cloth, measure insect pest rate (weight of insect pest amount/script * 100) and obtain dead worm rate.
Insect pest rate, dead worm rate and overall merit are shown in Table 1.
The following benchmark of overall merit utilization represents.◎: be 100% situation without insect pest and dead worm rate.Zero: be 50 ~ 99% situation without insect pest and dead worm rate.△: without insect pest but dead worm rate is 1 ~ 50% situation.*: damaged by vermin situation or without insect pest but dead worm rate is 0% situation.
Table 1
| The flavor compositions title | System | Molecular weight | Insect pest rate (%) | Dead worm rate (%) | Estimate |
| Hexylene glycol | Alcohol | 118 | 20 | 0 | × |
| Carbitol | Alcohol | 134 | 15 | 0 | × |
| Terpineol | Alcohol | 154 | 0 | 100 | ◎ |
| Dihydromyrcenol | Alcohol | 156 | 0 | 100 | ◎ |
| To terpane 3,8 glycol | Alcohol | 172 | 0 | 13 | △ |
| Ebony alcohol | Alcohol | 208 | 0 | 7 | △ |
| Cinnamic acid | Aldehyde | 132 | 0 | 90 | ○ |
| Cumal | Aldehyde | 148 | 0 | 100 | ◎ |
| Citronellal | Aldehyde | 154 | 0 | 100 | ◎ |
| Cedrol methyl ether | Ether | 236 | 0 | 23 | △ |
| Anethole | Ether | 148 | 0 | 7 | △ |
| The β naphthol ethyl ether | Ether | 172 | 15 | 0 | × |
| Dragon saliva furans (Ambrofix) | Ether | 236 | 0 | 0 | × |
| Methyl benzoate | Ester | 136 | 0 | 77 | ○ |
| Acetic acid cis 3-hexene ester | Ester | 142 | 0 | 5 | △ |
| Benzyl acetate | Ester | 150 | 0 | 24 | △ |
| Allyl hexanoate | Ester | 156 | 0 | 100 | ◎ |
| Cognac oil | Ester | 158 | 0 | 5 | △ |
| Phenethyl acetate | Ester | 164 | 0 | 57 | ○ |
| Allyl heptanoate | Ester | 170 | 0 | 100 | ◎ |
| Butyl hexanoate | Ester | 172 | 0 | 8 | △ |
| Isobutyl hexanoate | Ester | 172 | 0 | 7 | △ |
| Cinnamyl acetate | Ester | 176 | 0 | 79 | ○ |
| Acetic acid fennel ester | Ester | 180 | 0 | 5 | △ |
| Allyl octanoate | Ester | 184 | 0 | 100 | ◎ |
| Allyl amyl glycolate | Ester | 186 | 0 | 93 | ○ |
| Cyclacet | Ester | 192 | 0 | 62 | ○ |
| Allyl cyclohexyl propionate | Ester | 196 | 0 | 73 | ○ |
| Acetic acid-2-tert-butyl group cyclohexyl (verdox) | Ester | 198 | 0 | 65 | ○ |
| Acetic acid-4-tert-butyl group cyclohexyl (iris ester) | Ester | 198 | 0 | 85 | ○ |
| Cyclohexyloxy allyl acetate (the fluffy ester of ring lattice) | Ester | 198 | 0 | 100 | ◎ |
| The tristane carboxylic acid, ethyl ester | Ester | 207 | 0 | 63 | ○ |
| Ergol | Ester | 212 | 0 | 0 | × |
| Benzyl salicylate | Ester | 228 | 0 | 0 | × |
| Trimethyl citrate | Ester | 276 | 0 | 0 | × |
| Watermelon ketone | Ketone | 178 | 5 | 100 | × |
| Alpha, beta-lonone | Ketone | 192 | 10 | 100 | × |
| The δ damascone | Ketone | 192 | 0 | 100 | ◎ |
| Cashmeran | Ketone | 206 | 5 | 100 | × |
| Vertofix coeur (vertofix) | Ketone | 246 | 0 | 0 | × |
According to result of the test, select the fragrance component that confirms the validity as insect protected spices in the various fragrance components, carry out the test of film permeability.
Test example 2: the film permeability is waved loose test
To be of a size of the long limit doubling of the polyethylene film (thickness is 70 μ m) of 5 * 15cm, both sides, long limit are sealed, then, inject respectively the fragrance component of 1.5g (about 2ml) table 1 record, and then a remaining side also sealed, make the simple and easy film container that spices is housed.This simple and easy film container that spices is housed is hung in the thermostatic chamber that is arranged at 25 ℃, until the 30th day, the termly minimizing of gravimetry, and by obtaining the loose rate of waving with the difference of initial weight.The loose rate of waving of the 15th day and the 30th day and overall merit are shown in Table 2.
(overall merit is by following expression: ◎: the 30th day the loose rate of waving surpasses 75% situation.Zero: the 30 days the loose rate of waving is 30 ~ 75% situation.△: the 30th day the loose rate of waving is 10 ~ 30% situation.*: the 30th day the loose rate of waving is lower than 10% situation.)
Table 2
According to result of the test, compare with the spices of alcohols, ethers, ketone, ester class insect-proof agent spices wave the loose reasonable tendency that has.But when only adopting insect protected spices, it is slow to wave loose speed, therefore, and in order to improve the practicality as insect-proof agent, to promoting that waving the loose loose auxiliary agent of waving is studied.
Select in will be from the test example 2 better insect-proof agent spices and cooperate table 3 record of making insect protected spices, wave loose auxiliary agent and pigment mixes according to the prescription shown in the table 4, make various liquid perfume agent.
Test example 3: insect protected spices and the combination of waving loose auxiliary agent
The liquid 3g of this liquid perfume agent is injected into respectively in the predetermined container (the polyethylene terephthalate resin sheet that will form with polyethylene laminated so that length * wide * thickness be 30 * 30 * 6mm and be the container that plate-like obtains in the mode vacuum forming that has the flange of 8mm around the peristome), the peristome that will comprise flange portion covers with covering the material film, and seals.Stacked shaping obtains lid material film by pasting also as the polyethylene layer of the molten resin of adhesive layer by making liquid perfume agent permeability film and non-permeability film (polyethylene terephthalate film, aluminium film and polypropylene screen).
In this test, as liquid perfume agent permeability film, using (a) thickness is the straight chain shape low density polyethylene films of 70 μ m, perhaps (b) [laminate film of low density polyethylene (LDPE) (PE) and vinyl-vinyl acetate copolymer (EVA), PE is 18 μ m, EVA is 40 μ m, the thickness of laminate film integral body is 58 μ m, by take EVA as inboard (side that contact with the container 1 of Fig. 1) and take polyethylene as outside (side that contacts with the non-permeability film 3 of the liquid perfume agent of Fig. 1) film of being laminated] in any one.
In the time of will covering before use material and peel off from container, only peel off the non-permeability film of lower liquid perfume, the liquid perfume permeability film that remains in vessel side is exposed in the outside atmosphere, and the liquid perfume agent in the container begins to wave loose.Container after the non-permeability film of this liquid perfume peeled off leaves standstill in 25 ℃ of thermostatic chambers, until the 60th day, the termly minimizing of gravimetry, and by with the difference of initial weight, determine the loose rate of waving of liquid perfume agent.In addition, in order to investigate the stability that comprises the container that covers the material film, the container under the state of the non-permeability film of liquid perfume agent on the unstripped lid material is also left standstill to the 60th day in 25 ℃ of thermostatic chambers of the same terms.The loose rate of the 20th day, the 40th day, the 60th day respectively wave and overall merit are shown in Table 5.
Table 3
| Insect protected spices A composition | Insect protected spices B composition | Insect protected spices C composition |
| Methyl benzoate | Acetic acid cis 3-hexene ester | Propyl hexanoate |
| Phenethyl acetate | Benzyl acetate | Allyl hexanoate |
| Allyl octanoate | Allyl heptanoate | Cinnamyl acetate |
| Acetic acid-2-tert-butyl group cyclohexyl | Allyl amyl glycolate | Cyclacet |
| Cyclohexyloxy allyl acetate | Acetic acid-4-tert-butyl group cyclohexyl | Allyl cyclohexyl propionate |
| The tristane carboxylic acid, ethyl ester | The tristane carboxylic acid, ethyl ester | The tristane carboxylic acid, ethyl ester |
According to the result of this test, be in the poly situation at liquid perfume agent permeability film, contain among insect-proof agent spices and the embodiment 1 ~ 7 as the prescription of at least a glycol ethers of waving loose auxiliary agent, confirm from use beginning stable to the 60th day wave loose.Wherein, wave the mixture that loose auxiliary agent is preferably paraffin series hydrocarbon and glycol ethers, particularly, the ratio of paraffin series solvent and glycol ethers is the embodiment 2,4,5, the 6th in the scope of 1:3 ~ 1:5, and is effective.Outside this scope and the ratio of glycol ethers hour, waving loose speed has too fast tendency, and this scope outside and the ratio of glycol ethers when large, waving the speed of faling apart had slow tendency.In addition, embodiment 2 and 6 is compared, utilize colouring agent that liquid is implemented when painted, know easily by liquid and wave minimizing due to loose, thereby effectively.
Relative therewith, when waving loose auxiliary agent only for paraffin series hydrocarbon (comparative example 2) or only for glycol (comparative example 3), can't obtain good wave loose.
On the other hand, be to contain in the polyethylene in the situation of film of vinyl-vinyl acetate copolymer at liquid perfume agent permeability film, shown in embodiment 8,9,10, demonstrate the tendency of the two or more glycol ethers of preferred use.
Around being accommodated in, the insect-proof agent that will be made of liquid, container, the film identical with the material of use among the embodiment 2 has the polypropylene outer container processed of peristome (in 45 * 45 * 15mm).
2 above-mentioned aromaticity insect-proof agents are set between the gap of the clothes in the clothes chest of the long 50cm that takes in eighty per cant clothes of having an appointment * loose 40cm * high 25cm (about 50 liters), the result, through about two months, be not subject to the insect pest of the dress material insects such as casemaking clothes moth, curtain casemaking clothes moth, black wool khapra beetle, roundlet khapra beetle, but also have deodorizing effect, thereby be very practical.
The insect-proof agent that will be made of liquid, container, the film identical with the material that uses among the embodiment 3 is accommodated in and is accompanied with the suspension part and has around peristome and can confirm that the polypropylene outer container processed of the openning that liquid reduces (in 100 * 50 * 15mm), takes in 2 insect-proof agents in each outer container.2 these outer containers are namely amounted to 4 aromaticity insect-proof agents be suspended in the western-style clothes cabinet that volume is about 500 liters, used two months.As a result, can protect clothes not to be subjected to the insect pest of dress material insect fully in during this period, in addition, in the time after two months, the surplus of utilizing the liquid after painted to confirm is few, confirms that it has the End point indication function.In addition, except the liquid of surplus, in container, do not observe the dirt of pigment or oil content residue, thereby be very practical.
Test example 4: flying pest expelling parasite spices basis potency test
Make experimental rig shown in Figure 7.
The various fragrance components of 0.5g table 6 record are contained be dipped on the filter paper that diameter is 10cm, as for examination filter paper 17.It is that 10cm, length are in the acrylic resin rounding cylinder 18 of 100cm that above-mentioned confession examination filter paper is horizontally placed on internal diameter, in the part that apart from its two ends is 15cm gauze is housed, as filter 19, further the central portion at distance cylinder two ends arranges the movable dividing plate 20 of plastic plate.At one end the part of the barrel 18 of A side has be used to the hole section 21 of packing into for the examination insect, puts into 25 northern house female insects by this hole section to cylinder interior, closes close pore part 21.At one end arrange between A and the gauze filter 19 for examination filter paper 17, then, remove the dividing plate 20 of cylinder 17 central portions, through the time observe the quantity for the examination insect that the direction from partition position to an end B moves.
And after observation, calculate mobility (mobile borer population/confession examination borer population), 50% traveling time (for the semimobile time of examination worm) and 90% traveling time (for 90% time of moving of examination worm).The overall merit of projects of calculating is shown in Table 6.
Overall merit is represented by following benchmark.
◎: 90% traveling time is the situation below 10 minutes.
Zero: 90% traveling time is the situation below 20 minutes.
△: 90% traveling time is the situation below 30 minutes.
*: 90% traveling time was greater than 30 minutes situation.
Table 6
According to result of the test, select the fragrance component that confirms flying pest insect repellent fragrance effect in the various fragrance components, carry out the test of film permeability.
Test example 5: the film permeability is waved loose test
To be of a size of the long limit doubling of the polyethylene film (thickness is 70 μ m) of 5 * 15cm, both sides, long limit are sealed, then, inject respectively the fragrance component of 1.5g (about 2ml) table 6 record, and then a remaining side also sealed, make the simple and easy film container that spices is housed.This simple and easy film container that spices is housed is hung in the thermostatic chamber that is arranged at 25 ℃, until the 30th day, the termly minimizing of gravimetry, and by obtaining the loose rate of waving with the difference of initial weight.The loose rate of waving of the 15th day and the 30th day and overall merit are shown in Table 7.
(overall merit is by following expression: ◎: the 30th day the loose rate of waving surpasses 75% situation.Zero: the 30 days the loose rate of waving is 30 ~ 75% situation.△: the 30th day the loose rate of waving is 10 ~ 30% situation.*: the 30th day the loose rate of waving is lower than 10% situation.)
Table 7
According to result of the test, compare with the spices of alcohols, ethers, ketone, the spices of ester class wave the loose reasonable tendency that has.But when only adopting fragrance component, it is slow to wave loose speed, therefore, and in order to improve the practicality as aromaticity flying pest pest repellant, to promoting that waving the loose loose auxiliary agent of waving is studied.
Select in will be from the test example 5 better flying pest insect repellent fragrance and cooperate table 8 record of making the flying pest insect repellent fragrance, wave loose auxiliary agent and pigment mixes according to the prescription shown in the table 9, make various liquid perfume agent.
Table 8
| Flying pest insect repellent fragrance A composition | Flying pest insect repellent fragrance B composition | Flying pest insect repellent fragrance C composition |
| Phenethyl acetate | Allyl octanoate | Allyl heptanoate |
| Citronellyl acetate | Benzyl acetate | Allyl hexanoate |
| Allyl octanoate | Allyl heptanoate | Methyl phenyl carbinyl acetate |
| Acetic acid-2-tert-butyl group cyclohexyl | Linalyl acetate | Phenethyl acetate |
| Cyclohexyloxy allyl acetate | Acetic acid-4-tert-butyl group cyclohexyl | Allyl cyclohexyl propionate |
| The tristane carboxylic acid, ethyl ester | The tristane carboxylic acid, ethyl ester | The tristane carboxylic acid, ethyl ester |
Test example 6: flying pest insect repellent fragrance and the combination of waving loose auxiliary agent
The liquid 10g of this liquid perfume agent is injected into respectively in the predetermined container (the PET resin sheet that will form with polyethylene laminated so that length * wide * thickness be 50 * 50 * 8mm and be the container that plate-like obtains in the mode vacuum forming that has the flange of 8mm around the opening portion), the opening portion that will comprise flange portion covers with covering the material film, and seals.
Stacked shaping obtains lid material film by pasting also as the polyethylene layer of the molten resin of adhesive layer by making liquid perfume agent permeability film and non-permeability film (polyethylene terephthalate film, aluminium film and polypropylene screen).
In this test, as liquid perfume agent permeability film, using (a) thickness is the straight chain shape low density polyethylene films of 70 μ m, perhaps (b) [laminate film of low density polyethylene (LDPE) (PE) and vinyl-vinyl acetate copolymer (EVA): PE is 25 μ m, EVA is 30 μ m, the thickness of laminate film integral body is 55 μ m, by take EVA as inboard (side that contact with the container 1 of Fig. 1) and take polyethylene as outside (side that contacts with the non-permeability film 3 of the liquid perfume agent of Fig. 1) be laminated] in any one.
In the time of will covering before use material and peel off from container, only peel off the non-permeability film of lower liquid perfume, the liquid perfume permeability film that remains in vessel side is exposed in the outside atmosphere, and the liquid perfume agent in the container begins to wave loose.Container after the non-permeability film of this liquid perfume peeled off leaves standstill in 25 ℃ of thermostatic chambers, until the 60th day, the termly minimizing of gravimetry, and by with the difference of initial weight, determine the loose rate of waving of liquid perfume agent.In addition, in order to investigate the stability that comprises the container that covers the material film, the container under the state of the non-permeability film of liquid perfume agent on the unstripped lid material is also left standstill to the 60th day in 25 ℃ of thermostatic chambers of the same terms.The loose rate of the 20th day, the 40th day, the 60th day respectively wave and overall merit are shown in Table 10.
Result according to this test, be in the poly situation at liquid perfume agent permeability film, contain among flying pest insect repellent fragrance and the embodiment 13 ~ 19 as the prescription of at least a glycol ethers of waving loose auxiliary agent, from use beginning all observed to the 60th day stable wave loose.Wherein, wave the mixture that loose auxiliary agent is preferably paraffin series hydrocarbon and glycol ethers, particularly, the ratio of paraffin series solvent and glycol ethers is the embodiment 14,16,17, the 18th in the scope of 1:3 ~ 1:5, and is effective.Outside this scope and the ratio of glycol ethers hour, waving loose speed has too fast tendency, and this scope outside and the ratio of glycol ethers when large, waving the speed of faling apart had slow tendency.In addition, embodiment 14 and 18 is compared, utilize colouring agent that liquid is implemented when painted, know easily by liquid and wave minimizing due to loose, thereby effectively.
Relative therewith, when waving loose auxiliary agent only for paraffin series hydrocarbon (comparative example 5), have since the initial stage and excessively to wave loose tendency, particularly in the Sample storage before test, produce the problem that the permeability film that covers in the material and non-permeability film are peeled off.In addition, when only being glycol (comparative example 6), wave loose slack-off and can't obtain good result.In addition, using alcohols (n-hexyl alcohol) to replace in the situation of glycol ethers waving of can't obtaining expecting loose (comparative example 4).
On the other hand, liquid perfume agent permeability film for the situation that in polyethylene, contains the film that vinyl-vinyl acetate copolymer forms under, shown in embodiment 20,21,22, demonstrate the tendency of the two or more glycol ethers of preferred use.
With 1 by with before test example 6 under embodiment 14 in the aromaticity flying pest pest repellant that consists of of identical liquid, container, the film of the material that uses have the polypropylene outer container processed of opening portion (in 65 * 65 * 15mm) around being accommodated in.Use on the window limit that this aromaticity flying pest pest repellant is arranged on Domestic toilet (area is about 1 tatami), after the use, through about two months, do not observe the intrusion of the flying pests such as mosquito, midge, moth buffalo gnat, and given suitable fragrance effect to toilet space, thereby be very practical.
With 1 by with before test example 6 in embodiment 21 in the aromaticity flying pest pest repellant that consists of of identical liquid, container, the film of the material that uses be accommodated in the polypropylene that is accompanied with suspension part outer container processed (in 80 * 65 * 15mm).This outer container is suspended on the inboard of gateway door, used two months.As a result, do not confirm the intrusion of the flying pests such as mosquito, midge, moth buffalo gnat in during this period, and given fragrance effect, thereby be very practical.In addition, few in the surplus that the moment after two months utilizes the liquid after painted to observe, confirm that it has the End point indication function.In addition, except the liquid of surplus, the dirt to pigment or oil content residue unconfirmed in container, thereby be very practical.
Utilizability on the industry
The present invention all can be used widely in the insecting driving insect agent of dress material insect and/or flying pest and the insecting driving insect field of other various insects, thereby is extremely useful.
Claims (9)
1. aromaticity insecting driving insect agent is characterized in that, makes the liquid perfume agent that comprises insecting driving insect spices and contain the loose auxiliary agent of waving of at least a glycol ethers wave loose by liquid perfume agent permeability film.
2. aromaticity insecting driving insect as claimed in claim 1 agent is characterized in that, described glycol ethers is to be selected from the group that is comprised of glycol ether, propylene glycol and dialkyl group glycol ethers more than one.
3. aromaticity insecting driving insect as claimed in claim 1 or 2 agent is characterized in that, it is flavor compounds in 130 ~ 210 the scope that described insecting driving insect spices comprises the molecular weight with ester group.
4. aromaticity insecting driving insect as claimed in claim 3 agent, it is characterized in that, described molecular weight is 130 ~ 210 the interior flavor compounds of scope, comprises to be selected from by methyl benzoate, acetic acid cis 3-hexene ester, benzyl acetate, allyl hexanoate, phenethyl acetate, allyl heptanoate, cinnamyl acetate, allyl octanoate, allyl amyl glycolate, cyclacet, allyl cyclohexyl propionate, acetic acid-2-tert-butyl group cyclohexyl, acetic acid-4-tert-butyl group cyclohexyl, cyclohexyloxy allyl acetate, the tristane carboxylic acid, ethyl ester, phenyl ethyl formate, methyl phenyl carbinyl acetate, linalyl acetate, isobornyl acetate, the spices of more than one in the group that geranyl acetate and citronellyl acetate form.
5. aromaticity insecting driving insect as claimed in claim 1 or 2 agent is characterized in that, described insecting driving insect spices contains the spices of more than one the activity with breeding, motion and existence of suppressing insect.
6. aromaticity insecting driving insect as claimed in claim 1 or 2 agent, it is characterized in that, described liquid perfume agent is accommodated in the container of the open shape of part, described container is formed by the non-permeability material of liquid perfume agent, and be pasted with liquid perfume agent permeability film in the opening portion of this container as the lid material, make this liquid perfume agent wave loose by this film.
7. aromaticity insecting driving insect as claimed in claim 6 agent is characterized in that, described liquid perfume agent permeability film is for the film that formed by polythene material or contain polyethylene and film that vinyl-vinyl acetate copolymer forms.
8. aromaticity insecting driving insect as claimed in claim 6 agent, it is characterized in that, described lid material makes liquid perfume agent permeability film and the non-permeability film of liquid perfume agent form with the stacked shaping of strippable mode, before use, only peel off to remove and be positioned at the non-permeability film of outer field liquid perfume agent and liquid perfume agent permeability film is exposed, bring into use thus.
9. aromaticity insecting driving insect as claimed in claim 1 or 2 agent is characterized in that, adds colouring agent and painted its observability that improves in described liquid perfume agent.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-147028 | 2011-07-01 | ||
| JP2011147028A JP5858663B2 (en) | 2011-07-01 | 2011-07-01 | Aromatic insect repellent |
| JP2011-287503 | 2011-12-28 | ||
| JP2011287503A JP5939794B2 (en) | 2011-12-28 | 2011-12-28 | Aromatic flying pest repellent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102845416A true CN102845416A (en) | 2013-01-02 |
| CN102845416B CN102845416B (en) | 2016-08-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210228425.9A Active CN102845416B (en) | 2011-07-01 | 2012-07-02 | Armaticity insecting driving insect agent |
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| Country | Link |
|---|---|
| CN (1) | CN102845416B (en) |
| HK (1) | HK1175368A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105580804A (en) * | 2016-02-16 | 2016-05-18 | 烟台米罗卡化工科技有限公司 | Insecticide for anopheles sinensis |
| CN106719616A (en) * | 2016-11-29 | 2017-05-31 | 李志旭 | A kind of mango insect-repelling method |
| CN107035106A (en) * | 2017-06-22 | 2017-08-11 | 合肥聪亨新型建材科技有限公司 | A kind of multi-functional ground heating floor |
| CN107343861A (en) * | 2017-07-28 | 2017-11-14 | 厦门琥珀日化科技股份有限公司 | Long-acting mosquito-driving and antimicrobial spray containing natural plant essential oils and preparation method thereof |
| CN109463378A (en) * | 2018-12-28 | 2019-03-15 | 朱虹斐 | Mosquito expelling plaster |
| CN111202099A (en) * | 2020-01-18 | 2020-05-29 | 华南农业大学 | Insect repellent water for solenopsis invicta and preparation method thereof |
| CN113226030A (en) * | 2018-12-28 | 2021-08-06 | 花王株式会社 | Pest repellent composition |
| CN114208826A (en) * | 2018-09-19 | 2022-03-22 | 大日本除虫菊株式会社 | Absorption enhancer, composition containing flying pest repellent fragrance, and flying pest repellent article |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105580804A (en) * | 2016-02-16 | 2016-05-18 | 烟台米罗卡化工科技有限公司 | Insecticide for anopheles sinensis |
| CN106719616A (en) * | 2016-11-29 | 2017-05-31 | 李志旭 | A kind of mango insect-repelling method |
| CN107035106A (en) * | 2017-06-22 | 2017-08-11 | 合肥聪亨新型建材科技有限公司 | A kind of multi-functional ground heating floor |
| CN107343861A (en) * | 2017-07-28 | 2017-11-14 | 厦门琥珀日化科技股份有限公司 | Long-acting mosquito-driving and antimicrobial spray containing natural plant essential oils and preparation method thereof |
| CN114208826A (en) * | 2018-09-19 | 2022-03-22 | 大日本除虫菊株式会社 | Absorption enhancer, composition containing flying pest repellent fragrance, and flying pest repellent article |
| CN109463378A (en) * | 2018-12-28 | 2019-03-15 | 朱虹斐 | Mosquito expelling plaster |
| CN113226030A (en) * | 2018-12-28 | 2021-08-06 | 花王株式会社 | Pest repellent composition |
| CN111202099A (en) * | 2020-01-18 | 2020-05-29 | 华南农业大学 | Insect repellent water for solenopsis invicta and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102845416B (en) | 2016-08-03 |
| HK1175368A1 (en) | 2013-07-05 |
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