CN105594714A - Insecticide for preventing houseflies - Google Patents
Insecticide for preventing houseflies Download PDFInfo
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- CN105594714A CN105594714A CN201610086485.XA CN201610086485A CN105594714A CN 105594714 A CN105594714 A CN 105594714A CN 201610086485 A CN201610086485 A CN 201610086485A CN 105594714 A CN105594714 A CN 105594714A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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Abstract
The invention relates an insecticide, in particular to an insecticide for preventing houseflies. The insecticide is prepared from pyrrolidine-3-methanol, 3-(amino)-2-ethyl crotonate, butyl-2-pyrrolidone, 2-ethyl-2-adamantanol, cholesteryl N-decylate crystalline and the like. The insecticide is directly sprayed on places where houseflies frequently gather, can rapidly kill housefly eggs and larvae, is high in killing rate, saves insecticide cost and labor cost and is suitable for cleaning away houseflies.
Description
Technical field
The present invention relates to a kind of pesticide, be specifically related to a kind of control housefly pesticide.
Background technology
Housefly is the housefly class that distributes the most general. Piling as main taking soot and chicken manure of larva therefore in chicken farm or use chicken manure near the farm of compost, orchard, often has very huge group twinly, is CR Critical public health insect. On the foot of housefly with millions upon millions of germs. Rubbish, ight soil and the refuse of all housefly contacts spray with Grubicide.
At present, control housefly is mainly taked chemical prevention method, but due to long-term, high-dose use of insecticide, and between chemical insecticide, there is synergy, associating and antagonism, chemical insecticide interacts, make housefly there is the higher resistance to the action of a drug, and the resistance to the action of a drug strengthen day by day, therefore existing pesticide still has great room for improvement.
Summary of the invention
The object of the invention is to solve the housefly that above-mentioned prior art exists most pesticides are had to high drug-fast deficiency, provide a kind of housefly to there is responsive drug-fast control housefly pesticide to it.
A kind of control housefly pesticide, special character is to be prepared from by the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 11-17 part, 3-(methylamino)-2-butenoic acid ethyl 32-38 part, N-n-butylpyrrolioine ketone 16-22 part, 2-ethyl-2-adamantanol 23-27 part, cholesteryl decylate 6-14 part, 3-carboxymethyl-2-thioxo-4-thiazolidinone 25-31 part, 3, 3-diphenyl propyl alcohol 36-44 part, 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester 42-48 part, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 37-45 part.
Preferably, adopt control housefly pesticide prepared by the raw material of following weight portion proportioning to there is better insecticidal effect: 14 parts of pyrrolidines-3-methyl alcohol, 3-(methylamino)-32 parts of 2-butenoic acid ethyls, 22 parts of N-n-butylpyrrolioine ketone, 25 parts of 2-ethyl-2-adamantanols, 6 parts of cholesteryl decylates, 31 parts of 3-carboxymethyl-2-thioxo-4-thiazolidinones, 3, 40 parts of 3-diphenyl propyl alcohol, 2-acrylic acid-2, 2-dimethyl-1, 42 parts of 3-propylene diesters, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes] 45 parts of-3-ketone.
Further, better prevent and treat housefly pesticide in order to obtain insecticidal effect, described control housefly also comprises the raw material of following weight portion proportioning with pesticide: 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid 52-56 part, phosphoenolpyruvate list cyclohexylamine salt 3-9 part, 2,4,5-trimethoxy cinnamic acid 18-26 part.
Preferably, control housefly pesticide, its parts by weight of raw materials proportioning is: 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl] 54 parts of-5-heptenoic acids, 3 parts of phosphoenolpyruvate list cyclohexylamine salts, 26 parts of 2,4,5-trimethoxy cinnamic acids.
Preparation method of the present invention: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add pyrrolidines-3-methyl alcohol, 3-(methylamino)-2-butenoic acid ethyl, N-n-butylpyrrolioine ketone, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add 2-ethyl-2-adamantanol, cholesteryl decylate, 3-carboxymethyl-2-thioxo-4-thiazolidinone, 3, 3-diphenyl propyl alcohol, stir 30 minutes, be cooled to again 40 DEG C, add 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, continue to stir 30 minutes, obtain finished product.
This control housefly pesticide, is directly sprayed on the common habitat of housefly, can eliminate fast Eggs of Musca Domestica Vicina and larva thereof, and elimination rate is high, has saved drug cost and human cost, is applicable to being applied in the removing work of housefly.
Detailed description of the invention
Below provide the specific embodiment of the present invention, be used for the present invention to be further described. In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
In following examples, raw material introduction:
Pyrrolidines-3-methyl alcohol, CAS accession number is: 5082-74-6;
3-(methylamino)-2-butenoic acid ethyl, CAS accession number is: 870-85-9;
N-n-butylpyrrolioine ketone, CAS accession number is: 3470-98-2;
2-ethyl-2-adamantanol, CAS accession number is: 14648-57-8;
Cholesteryl decylate, CAS accession number is: 1183-04-6;
3-carboxymethyl-2-thioxo-4-thiazolidinone, CAS accession number is: 5718-83-2;
3,3-diphenyl propyl alcohol, CAS accession number is: 20017-67-8;
2-acrylic acid-2,2-dimethyl-1,3-propylene diester, CAS accession number is: 2223-82-7;
The chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, CAS accession number is: 26567-23-7;
7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid, CAS accession number is: 363-24-6;
Phosphoenolpyruvate list cyclohexylamine salt, CAS accession number is: 10526-80-4;
2,4,5-trimethoxy cinnamic acid, CAS accession number is: 24160-53-0.
Embodiment 1
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 11g, 3-(methylamino)-2-butenoic acid ethyl 38g, N-n-butylpyrrolioine ketone 19g, 2-ethyl-2-adamantanol 23g, cholesteryl decylate 14g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 28g, 3,3-diphenyl propyl alcohol 36g, 2-acrylic acid-2,2-dimethyl-1,3-propylene diester 48g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 41g.
The present embodiment control housefly method for producing insecticide: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add pyrrolidines-3-methyl alcohol, 3-(methylamino)-2-butenoic acid ethyl, N-n-butylpyrrolioine ketone, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add 2-ethyl-2-adamantanol, cholesteryl decylate, 3-carboxymethyl-2-thioxo-4-thiazolidinone, 3, 3-diphenyl propyl alcohol, stir 30 minutes, be cooled to again 40 DEG C, add 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, continue to stir 30 minutes, obtain finished product.
Embodiment 2
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 14g, 3-(methylamino)-2-butenoic acid ethyl 32g, N-n-butylpyrrolioine ketone 22g, 2-ethyl-2-adamantanol 25g, cholesteryl decylate 6g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 31g, 3,3-diphenyl propyl alcohol 40g, 2-acrylic acid-2,2-dimethyl-1,3-propylene diester 42g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 45g.
The present embodiment control housefly with method for producing insecticide with embodiment 1.
Embodiment 3
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 17g, 3-(methylamino)-2-butenoic acid ethyl 35g, N-n-butylpyrrolioine ketone 16g, 2-ethyl-2-adamantanol 27g, cholesteryl decylate 10g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 25g, 3,3-diphenyl propyl alcohol 44g, 2-acrylic acid-2,2-dimethyl-1,3-propylene diester 45g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 37g.
The present embodiment control housefly with method for producing insecticide with embodiment 1.
Embodiment 4
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 14g, 3-(methylamino)-2-butenoic acid ethyl 32g, N-n-butylpyrrolioine ketone 22g, 2-ethyl-2-adamantanol 25g, cholesteryl decylate 6g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 31g, 3, 3-diphenyl propyl alcohol 40g, 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester 42g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 45g, 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid 52g, phosphoenolpyruvate list cyclohexylamine salt 9g, 2, 4, 5-trimethoxy cinnamic acid 22g.
The present embodiment control housefly method for producing insecticide: add in proportion distilled water in reaction pot, heating reaction kettle temperature rises to 65 DEG C--80 DEG C time, add pyrrolidines-3-methyl alcohol, 3-(methylamino)-2-butenoic acid ethyl, N-n-butylpyrrolioine ketone, and stirred through 1 hour, be cooled to subsequently 50 DEG C, add 2-ethyl-2-adamantanol, cholesteryl decylate, 3-carboxymethyl-2-thioxo-4-thiazolidinone, 3, 3-diphenyl propyl alcohol, stir 30 minutes, be cooled to again 40 DEG C, add 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone, 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid, phosphoenolpyruvate list cyclohexylamine salt, 2, 4, 5-trimethoxy cinnamic acid, continue to stir 30 minutes, obtain finished product.
Embodiment 5
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 14g, 3-(methylamino)-2-butenoic acid ethyl 32g, N-n-butylpyrrolioine ketone 22g, 2-ethyl-2-adamantanol 25g, cholesteryl decylate 6g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 31g, 3, 3-diphenyl propyl alcohol 40g, 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester 42g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 45g, 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid 54g, phosphoenolpyruvate list cyclohexylamine salt 3g, 2, 4, 5-trimethoxy cinnamic acid 26g.
The present embodiment control housefly with method for producing insecticide with embodiment 4.
Embodiment 6
Weigh the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 14g, 3-(methylamino)-2-butenoic acid ethyl 32g, N-n-butylpyrrolioine ketone 22g, 2-ethyl-2-adamantanol 25g, cholesteryl decylate 6g, 3-carboxymethyl-2-thioxo-4-thiazolidinone 31g, 3, 3-diphenyl propyl alcohol 40g, 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester 42g, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 45g, 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid 56g, phosphoenolpyruvate list cyclohexylamine salt 6g, 2, 4, 5-trimethoxy cinnamic acid 18g.
The present embodiment control housefly with method for producing insecticide with embodiment 4.
Carry out the test of the housefly resistance to the action of a drug with embodiment 1-6 gained finished product
1. medicament: embodiment 1-6 gained control housefly pesticide; Acetone, ether are that analysis is pure.
2. examination worm: housefly Wild population gathers in the market of farm produce, takes to laboratory rearing to F1 generation and tests.
3. concrete testing procedure:
Former medicine is diluted with acetone, by 5～7 series concentration of medicament configuration to be measured. Choose 25 female worms of the healthy housefly of 3～5 ages in days, carrying out slight anesthesia with ether is placed in plate, utilize micro intravenous drip instrument that 0.3I medicament is dripped in female adult housefly mesonotum, complete by concentration order from low to high, after drop finishes, every group of examination worm is transferred in 200mL disposable transparent cup, with gauze sealing, raise with the rayon balls that is soaked with G/W, after 24h, check result and record the death toll under each processing concentration dose. Taking acetone stoste as contrast, every group test repeat 3 times, the control group death rate should < 2O, otherwise test be considered as invalid. Laboratory and recovery room temperature for (25 ± 1) DEG C, relative humidity be 60～70.
4. dead criterion: turn on housefly belly, six foots are twitched, and touch and can not initiatively stand up to creep and be considered as death with probe.
5. statistical method: utilize DPS software to calculate the LC of bioassay results50Value, and calculate resistance coefficient. Resistance to the action of a drug grade is judged: resistance coefficient≤2 are sensitivity; 2<resistance coefficient≤1O is the low resistance to the action of a drug; 1O<resistance coefficient≤2O is the moderate resistance to the action of a drug; Resistance coefficient>20, be the high resistance property of medicine.
Field acquisition housefly is the LC with pesticide to embodiment 1-6 gained control housefly50Be respectively 4.8,4.2,4.4,3.0,2.7,2.9 μ g/L, resistance coefficient is respectively 0.25,0.22,0.23,0.18,0.12,0.15. Housefly is all responsive with pesticide to embodiment 1-6 gained control housefly. Specifically see the following form.
Housefly is the resistance to the action of a drug measurement result with pesticide to embodiment 1-6 gained control housefly
| Pesticide | LC50（μg／L） | Resistance coefficient |
| Embodiment 1 | 4.8 | 0.25 |
| Embodiment 2 | 4.2 | 0.22 |
| Embodiment 3 | 4.4 | 0.23 |
| Embodiment 4 | 3.0 | 0.18 |
| Embodiment 5 | 2.7 | 0.12 |
| Embodiment 6 | 2.9 | 0.15 |
From upper table contrast, it is lower that the present invention prevents and treats housefly resistance to insecticides coefficient, and be all not more than 0.25, and it is worth much smaller than 2, and old family fly has higher sensitiveness to pesticide of the present invention, is beneficial to and efficiently kills housefly, and housefly eradicating efficacy is good.
Claims (4)
1. a control housefly pesticide, it is characterized in that being prepared from by the raw material of following weight portion proportioning: pyrrolidines-3-methyl alcohol 11-17 part, 3-(methylamino)-2-butenoic acid ethyl 32-38 part, N-n-butylpyrrolioine ketone 16-22 part, 2-ethyl-2-adamantanol 23-27 part, cholesteryl decylate 6-14 part, 3-carboxymethyl-2-thioxo-4-thiazolidinone 25-31 part, 3, 3-diphenyl propyl alcohol 36-44 part, 2-acrylic acid-2, 2-dimethyl-1, 3-propylene diester 42-48 part, the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone 37-45 part.
2. prevent and treat as claimed in claim 1 housefly pesticide, it is characterized in that parts by weight of raw materials proportioning is: 14 parts of pyrrolidines-3-methyl alcohol, 3-(methylamino)-32 parts of 2-butenoic acid ethyls, 22 parts of N-n-butylpyrrolioine ketone, 25 parts of 2-ethyl-2-adamantanols, 6 parts of cholesteryl decylates, 31 parts of 3-carboxymethyl-2-thioxo-4-thiazolidinones, 40 parts of 3,3-diphenyl propyl alcohol, 2-acrylic acid-2,2-dimethyl-1,42 parts of 3-propylene diesters, 45 parts of the chloro-6'-of 2'-(lignocaine) spiral shell [isobenzofuran-1 (3H), 9'-(9H) xanthenes]-3-ketone.
3. prevent and treat as claimed in claim 1 or 2 housefly pesticide, characterized by further comprising the raw material of following weight portion proportioning: 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl]-5-heptenoic acid 52-56 part, phosphoenolpyruvate list cyclohexylamine salt 3-9 part, 2,4,5-trimethoxy cinnamic acid 18-26 part.
4. prevent and treat as claimed in claim 3 housefly pesticide, it is characterized in that parts by weight of raw materials proportioning is: 7-[3-hydroxyl-2-(3-hydroxyl-1-octenyl)-5-oxocyclopentyl] 54 parts of-5-heptenoic acids, 3 parts of phosphoenolpyruvate list cyclohexylamine salts, 2,26 parts of 4,5-trimethoxy cinnamic acids.
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| CN201610086485.XA CN105594714A (en) | 2016-02-16 | 2016-02-16 | Insecticide for preventing houseflies |
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| CN201610086485.XA CN105594714A (en) | 2016-02-16 | 2016-02-16 | Insecticide for preventing houseflies |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884227A (en) * | 2006-07-03 | 2006-12-27 | 华南农业大学 | Method for preparation of coated release-controlled granular fertilizer |
| CN101348398A (en) * | 2008-08-26 | 2009-01-21 | 华南农业大学 | Long-acting coated compound fertilizer and preparation thereof |
| WO2010023198A1 (en) * | 2008-08-29 | 2010-03-04 | Rhodia Operations | Herbicidal composition comprising an aminophosphate or aminophosphonate salt and an n-alkyl- pyrrolidone solvent |
| CN101880262A (en) * | 2010-06-23 | 2010-11-10 | 山东理工大学 | Preparation method of 2-thiazolidine ketone |
| CN101445491B (en) * | 2008-12-26 | 2011-08-17 | 山东师范大学 | Thiazolinone derivative and preparation method and application thereof |
-
2016
- 2016-02-16 CN CN201610086485.XA patent/CN105594714A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884227A (en) * | 2006-07-03 | 2006-12-27 | 华南农业大学 | Method for preparation of coated release-controlled granular fertilizer |
| CN101348398A (en) * | 2008-08-26 | 2009-01-21 | 华南农业大学 | Long-acting coated compound fertilizer and preparation thereof |
| WO2010023198A1 (en) * | 2008-08-29 | 2010-03-04 | Rhodia Operations | Herbicidal composition comprising an aminophosphate or aminophosphonate salt and an n-alkyl- pyrrolidone solvent |
| CN101445491B (en) * | 2008-12-26 | 2011-08-17 | 山东师范大学 | Thiazolinone derivative and preparation method and application thereof |
| CN101880262A (en) * | 2010-06-23 | 2010-11-10 | 山东理工大学 | Preparation method of 2-thiazolidine ketone |
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Application publication date: 20160525 |