CN102302003B - Interference repellent for leguminivora glycinivorella and preparation method of interference repellent - Google Patents
Interference repellent for leguminivora glycinivorella and preparation method of interference repellent Download PDFInfo
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- CN102302003B CN102302003B CN 201110163780 CN201110163780A CN102302003B CN 102302003 B CN102302003 B CN 102302003B CN 201110163780 CN201110163780 CN 201110163780 CN 201110163780 A CN201110163780 A CN 201110163780A CN 102302003 B CN102302003 B CN 102302003B
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- 241000981121 Leguminivora glycinivorella Species 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000005871 repellent Substances 0.000 title abstract description 8
- 230000002940 repellent Effects 0.000 title abstract description 8
- CXENHBSYCFFKJS-UHFFFAOYSA-N α-farnesene Chemical compound CC(C)=CCCC(C)=CCC=C(C)C=C CXENHBSYCFFKJS-UHFFFAOYSA-N 0.000 claims abstract description 26
- GEWDNTWNSAZUDX-WQMVXFAESA-N (-)-methyl jasmonate Chemical compound CC\C=C/C[C@@H]1[C@@H](CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-WQMVXFAESA-N 0.000 claims abstract description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- GEWDNTWNSAZUDX-UHFFFAOYSA-N methyl 7-epi-jasmonate Natural products CCC=CCC1C(CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-UHFFFAOYSA-N 0.000 claims abstract description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 14
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims abstract description 13
- JXBSHSBNOVLGHF-UHFFFAOYSA-N 10-cis-Dihydrofarnesen Natural products CC=C(C)CCC=C(C)CCC=C(C)C JXBSHSBNOVLGHF-UHFFFAOYSA-N 0.000 claims abstract description 13
- JSNRRGGBADWTMC-UHFFFAOYSA-N alpha-farnesene Natural products CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 ester n-valerate Chemical class 0.000 claims abstract description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000011521 glass Substances 0.000 claims description 22
- 238000007789 sealing Methods 0.000 claims description 12
- 229940005605 valeric acid Drugs 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 238000005303 weighing Methods 0.000 claims description 11
- 150000007823 ocimene derivatives Chemical class 0.000 claims description 7
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 6
- 229920000053 polysorbate 80 Polymers 0.000 claims description 6
- 241000238631 Hexapoda Species 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 2
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 abstract 1
- NPFVOOAXDOBMCE-PLNGDYQASA-N cis-3-Hexenyl acetate Natural products CC\C=C/CCOC(C)=O NPFVOOAXDOBMCE-PLNGDYQASA-N 0.000 abstract 1
- RRGOKSYVAZDNKR-ARJAWSKDSA-M cis-3-hexenylacetate Chemical compound CC\C=C/CCCC([O-])=O RRGOKSYVAZDNKR-ARJAWSKDSA-M 0.000 abstract 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 description 11
- 235000010469 Glycine max Nutrition 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 235000013305 food Nutrition 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 230000011664 signaling Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000008654 plant damage Effects 0.000 description 2
- 230000019491 signal transduction Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 231100000045 chemical toxicity Toxicity 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007758 mating behavior Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an interference repellent for leguminivora glycinivorella, and also discloses a preparation method for the interference repellent. The interference repellent is prepared from leaf alcohol, cis-3-hexenyl acetate, cis-3-hexenyl ester n-valerate, (E)-butyric acid-3-hexenyl ester, ocimenum, (Z)-propionic acid-3-hexenyl ester, alpha-farnesene, methyl jasmonate, n-hexane or dimethylbenzene and the like. The interference repellent has reasonable components, is an environment-friendly biological interference repellent, has a simple preparation method and a good prevention and control effect, is safe for crops and natural enemies, cannot make insects generate resistance, is environment-friendly and convenient to apply and popularize, and has a wide market prospect and obvious economic, ecological and social benefits.
Description
Technical field
The invention provides soybean pod borer and disturb repellant, also disclose its preparation method simultaneously, belong to pesticide production technology field.
Background technology
Soybean pod borer is taken place in China the Yellow River and Huai He River summer soybean district and northeast soybean producing region throughout the year, and harm is serious, and in the general time, worm food rate is 15-30%, underproduction 5-10%; Serious time worm food rate can reach 50-70%, underproduction 20-40%, and its harm is the one of the main reasons that causes soybean quality reduction and the underproduction.Therefore, the control of soybean pod borer also becomes one of important step of soybean production.
At present, the control of soybean pod borer namely taked blade face and beanpod to spray chrysanthemum ester class medicaments such as good fortune spirit and Belmark, control adult and newly hatched larvae at adult occurance peak and larva still based on chemical control before the incubation period.Make malicious rod or blind-your-eyes branch with DDT EC under the situation preferably on soybean envelope ridge, fumigate.Though chemical control has easy and simple to handle and the control efficiency outstanding feature, it has also caused significant damage when killing off the insect pests, the one, and the pesticide resistance of insect strengthens, and makes control difficulty day by day; The 2nd, the secondary insect outburst: the 3rd, chemical toxicity and biological magnification make chemical toxicant be enriched in human body by food chain, and the mankind are worked the mischief.Therefore, seek the ecological anti-controlling agent of soybean pod borer nuisanceless, environmental protection and have important economic implications.
Summary of the invention
The invention discloses a kind of soybean pod borer and disturb repellant, be used for inducing the similar reaction of insect's food-taking initiation, interference insect is selected the host, harm reduction.
The invention also discloses the preparation method of soybean pod borer interference repellant, establish for suitability for industrialized production.
Soybean pod borer of the present invention disturbs the solvent of repellant, it is characterized in that by following raw material by volume portion rate make:
Leaf-alcohol 10.0-15.0; Acetic acid leaf-alcohol ester 20.0-30.0; Positive valeric acid is suitable-3-hexene ester 2.0-3.0; (E)-butyric acid-3-hexene ester 3.0-5.0; α-farnesene 1.0-3.0; Methyl jasmonate 1.0-2.5; Solvent (n-hexane or dimethylbenzene) 40.0-50.0; Auxiliary agent (Tween 80 or agricultural newborn 500#) 1.0-2.0.
Soybean pod borer disturbs the optimization component of repellant,It is characterized in that by following raw material by volume portion rate make:
Leaf-alcohol 10.0-15.0; Acetic acid leaf-alcohol ester 20.0-30.0; Positive valeric acid is suitable-3-hexene ester 2.0-3.0; (E)-butyric acid-3-hexene ester 3.0-5.0; Ocimene 1.0-2.0; (Z)-propionic acid-3-hexene ester 1.0-2.5; α-farnesene 1.0-3.0; Methyl jasmonate 1.0-2.5;
Solvent (n-hexane or dimethylbenzene) 40.0-50.0; Auxiliary agent (Tween 80 or agricultural newborn 500#) 1.0-2.0.
Described soybean pod borer disturbs the preparation method of repellant, may further comprise the steps:
Ratio in above-mentioned prescription takes by weighing each raw material mixing back with the Brown Glass Brown glass bottles and jars only sealing namely, preserves in-4 ℃ ~-20 ℃ low temperature.
Prevent and treat mechanism:
Can inducing plant behind the insect's food-taking host plant produce defense reaction, discharge the specificity volatile compound, influence that getting of insect eaten and behavior such as lay eggs.Discover that jasmonic (JA) and methyl jasmonate (MeJA) they are the signaling molecules in the plant injury signal pathway, use this class signaling molecule and handle plant, the similar reaction that can induce insect's food-taking to cause, and interference insect is selected the host, harm reduction.It is to make principle mutually according to insect and plant that soybean pod borer disturbs repellant, utilize host plant to the regulating and controlling effect mechanism of insect behavior, with the methyl jasmonate treatment soybean plant strain, the soybean volatile compound is carried out activity analysis and biologicall test, and the biological species of the environmental protection that filters out is disturbed repellant.The medicament volatile matter influences the host location of soybean pod borer, mating behavior and the selection of laying eggs, thereby the ovum amount that falls of reduction field beanpod.In addition, because the soybean pod borer adult stage is short, it is neat to sprout wings, and occurs behind soybean envelope ridge, the soybean field of envelope ridge closing can form the microclimate space of sealing, is convenient to the medicament slowly-releasing, and the lasting period is long, therefore, but this biologic product single dispenser is difficult for scattering and disappearing, and control efficiency is good.
Usage and dosage:
Every day was investigated soybean pod borer adult moth amount in beginning in the afternoon before sunset July 20, measured when the field moth and increased suddenly, and the group's of beating phenomenon occurring namely is that adult is contained the phase of sending out, and carries out dispenser this moment.Get the 6-10ml medicament for every mu, convert water and be made into the spraying of 3000-5000 times of liquid, in spraying, upper blade, but do not spray at integral shroud topmost, prevent rapid evaporation, influence control efficiency.
Good effect of the present invention is:Be signaling molecule in the plant injury signal pathway according to jasmonic (JA) and methyl jasmonate (MeJA), use this class signaling molecule and handle plant, the similar reaction that can induce insect's food-taking to cause, interference insect is selected the host, harm reduction.Disturb the repellant component reasonable, the biological species that is environmental protection is disturbed repellant, preparation method is simple, control efficiency is good, and crop and natural enemy are had safety, can not make insect produce resistance, free from environmental pollution, be convenient to application, market prospects are wide, economic benefit, ecological benefits and obvious social benefit.
Embodiment
By following examples the present invention is described for example further, and do not limit the present invention in any way, under the prerequisite that does not deviate from technical solution of the present invention, any change or change that those of ordinary skills that the present invention is done realize easily all will fall within the claim scope of the present invention.
Embodiment 1:
Take by weighing leaf-alcohol 13.0g, acetic acid leaf-alcohol ester 28.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 4.0g, α-farnesene 3.0g, methyl jasmonate 2.0g, dimethylbenzene 45.0g, Tween 80 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely, preserve in-4 ℃ ~-20 ℃ low temperature.
Embodiment 2:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 22.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 5.0g, α-farnesene 2.0g, methyl jasmonate 1.0g, dimethylbenzene 50.0g, Tween 80 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely, preserve in-4 ℃ ~-20 ℃ low temperature.
Embodiment 3:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 22.0g, positive valeric acid suitable-3-hexene ester 2.0g, (E)-butyric acid-3-hexene ester 5.0g, ocimene 2.0g, (Z)-propionic acid-3-hexene ester 1.0g, α-farnesene 3.0g, methyl jasmonate 2.0g, dimethylbenzene 46.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely, preserve in-4 ℃ ~-20 ℃ low temperature.
Embodiment 4:
Take by weighing leaf-alcohol 13.0g, acetic acid leaf-alcohol ester 23.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 4.0g, ocimene 2.0g, (Z)-propionic acid-3-hexene ester 1.5g, α-farnesene 2.0g, methyl jasmonate 1.5g, n-hexane 48.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely, preserve in-4 ℃ ~-20 ℃ low temperature.
Embodiment 5:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 21.0g, positive valeric acid suitable-3-hexene ester 2.0g, (E)-butyric acid-3-hexene ester 5.0g, ocimene 1.0g, (Z)-propionic acid-3-hexene ester 1.0g, α-farnesene 2.0g, methyl jasmonate 1.0g, n-hexane 50.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely, preserve in-4 ℃ ~-20 ℃ low temperature.
Below test shows interference repellent effect of the present invention:
Test material and method:
Test in 2009 and the soybean Tanaka in Jilin Agriculture University in 2010 and carry out, 6 processing are established in test altogether, i.e. contrast (spraying auxiliary agent and solvent) and 5 soybean pod borer disturb the processing of repellant example formulations.Each processing arranges 3 repetitions, and the residential quarter area of each processing is 100m
2, the residential quarter randomized arrangement.15 d investigation drug effect after the dispenser, 5 samplings are all adopted in each residential quarter, and 400 of the pods of shelling beans check larva quantity, calculate hundred pods live borer population and average control efficiency.The beanpod maturing stage carries out list to the soybean of different disposal and receives singles' threshing, investigation worm food rate.
Control efficiency=(check plot hundred pods borer population-treatment region hundred pods alive borer population alive)/check plot hundred pods borer population alive * 100%
Result of the test:
Result of the test shows, uses the prevention and control field that soybean pod borer disturbs repellant, and big bean worm food rate obviously descends, and the interference repellant control efficiency of optimization of C can reach more than 75.0%.See Table 1, table 2:
The field control effect of table one soybean pod borer interference in 2009 repellant
The field control effect of table two soybean pod borer interference in 2010 repellant
Claims (3)
1. a soybean pod borer disturbs repellant, it is characterized in that making by the following method:
Take by weighing leaf-alcohol 13.0g, acetic acid leaf-alcohol ester 28.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 4.0g, α-farnesene 3.0g, methyl jasmonate 2.0g, dimethylbenzene 45.0g, Tween 80 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely.
2. a soybean pod borer disturbs repellant, it is characterized in that making by the following method:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 22.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 5.0g, α-farnesene 2.0g, methyl jasmonate 1.0g, dimethylbenzene 50.0g, Tween 80 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely.
3. a soybean pod borer disturbs repellant, it is characterized in that making by the following method:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 22.0g, positive valeric acid suitable-3-hexene ester 2.0g, (E)-butyric acid-3-hexene ester 5.0g, ocimene 2.0g, (Z)-propionic acid-3-hexene ester 1.0g, α-farnesene 3.0g, methyl jasmonate 2.0g, dimethylbenzene 46.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely.
4. a soybean pod borer disturbs repellant, it is characterized in that making by the following method:
Take by weighing leaf-alcohol 13.0g, acetic acid leaf-alcohol ester 23.0g, positive valeric acid suitable-3-hexene ester 3.0g, (E)-butyric acid-3-hexene ester 4.0g, ocimene 2.0g, (Z)-propionic acid-3-hexene ester 1.5g, α-farnesene 2.0g, methyl jasmonate 1.5g, n-hexane 48.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely.
5. a soybean pod borer disturbs repellant, it is characterized in that making by the following method:
Take by weighing leaf-alcohol 15.0g, acetic acid leaf-alcohol ester 21.0g, positive valeric acid suitable-3-hexene ester 2.0g, (E)-butyric acid-3-hexene ester 5.0g, ocimene 1.0g, (Z)-propionic acid-3-hexene ester 1.0g, α-farnesene 2.0g, methyl jasmonate 1.0g, n-hexane 50.0g, agricultural newborn 500# 2.0g, each material is mixed the back with the Brown Glass Brown glass bottles and jars only sealing namely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110163780 CN102302003B (en) | 2011-06-17 | 2011-06-17 | Interference repellent for leguminivora glycinivorella and preparation method of interference repellent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110163780 CN102302003B (en) | 2011-06-17 | 2011-06-17 | Interference repellent for leguminivora glycinivorella and preparation method of interference repellent |
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| CN102302003B true CN102302003B (en) | 2013-08-14 |
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| CN108293993B (en) * | 2018-02-02 | 2020-07-03 | 吉林农业大学 | Cladosporium spinulosum repellent and preparation method thereof |
| CN108719282B (en) * | 2018-06-04 | 2021-10-15 | 山西农业大学植物保护学院(山西省农业科学院植物保护研究所) | Special attractant for preventing and controlling oriental fruit moth and preventing and controlling method |
| CN110745243B (en) * | 2019-11-13 | 2023-03-28 | 吉林省农业科学院 | Method for preventing and treating soybean pod borers by using unmanned aerial vehicle |
| CN115968882B (en) * | 2023-02-02 | 2024-06-14 | 四川省新兰月生物科技有限公司 | Pharmaceutical composition for promoting color conversion of citrus and preparation method thereof |
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| IL102846A (en) * | 1992-08-18 | 2001-08-08 | Israel State | Arthropod control composition for plant protection |
| JP2005075753A (en) * | 2003-08-29 | 2005-03-24 | Soda Aromatic Co Ltd | Noxious insect-controlling agent for plant |
| EP2274409B1 (en) * | 2008-04-07 | 2011-10-12 | Symrise AG | Use of carboxylic acid esters as a fragrance substance |
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