CN105565848A - 活性炭紫砂陶及其制备方法 - Google Patents
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Abstract
本发明涉及一种活性炭紫砂陶及其制备方法。本发明中的活性炭紫砂陶,其制备原材料由以下重量百分比的组份混合而成:紫砂泥料50-90%,活性炭10-50%,其他陶土0-30%。本发明中的活性炭紫砂陶的制备方法,用常规的陶瓷制造工艺制备原材料和半成品,接着将所述半成品置于密闭容器中,用耗氧材料填充所述密闭容器中的空隙,然后经1100℃-1200℃烧制而成。所述耗氧材料中混入有易挥发性盐类。本发明采用密闭容器烧结法和耗氧保护法,可以保护制品烧结过程中活性炭不被氧化;本发明采用挥发施釉法,降低制品的气孔率,可以有效防止制品渗水。
Description
技术领域
本发明涉及紫砂陶,尤其涉及含炭紫砂陶,具体地说是一种活性炭紫砂陶及其制备方法。
背景技术
紫砂陶是陶器的一个分支。紫砂陶是指用质地细腻、含铁量较高的特种粘土制成的,呈色以赤褐为主,质地较坚硬而透气性能好的陶器。
活性炭紫砂陶是指在紫砂陶的原料中加入活性炭而制成的陶器。这种活性炭紫砂陶在保持了普通紫砂的特性外,还具备了活性炭的超强吸附和净化功能;并且由于保存了炭的特性,制品具有独特的黑色。活性炭紫砂陶可以广泛应用于茶具,餐具,以及代替一般日用陶瓷器皿。
活性炭紫砂陶虽然具有上述优点,但是也存在以下缺点:(1)活性炭紫砂陶制品在烧结过程中,活性炭易被氧化,制造工艺复杂;(2)活性炭紫砂陶制品的气孔率较普通紫砂陶制品的气孔率高,制品容易渗水。这些缺点的存在,制约了活性炭紫砂陶的广泛推广与应用。
申请号为201310419586.0,名称为“一种竹炭陶净水内胆及其制备方法”的中国发明专利申请公开了一种竹炭陶净水内胆的制备方法,其采用一定比例的竹炭颗粒、竹炭微粉、麦饭石、石英粉以及原矿紫砂泥混合成浆料,在模具中成型,经干燥后在全封闭的电炉设备中烧结而成。该方法采用全封闭的电炉,限制了其应用范围;另外,由于该方法是制造净水内胆,因而不需要解决渗水的问题。
申请号为201020271681.2,名称为“一种炭陶容器”的中国实用新型专利公开了一种含炭的炭陶容器,该专利的核心内容是“炭陶本体和其外表面上的隔水层构成”,即在炭陶本体的外侧加一层防水保护层;这种防水保护层可以是1000℃烧制的釉,或塑膜,或涂料,或金属外壳。这种防水层可以较好地解决炭陶容器的渗水问题,但是采用塑膜、涂料、金属外壳等措施不仅增加了工艺步骤,而且从使用角度上看也增加了局限性;并且1000℃左右的普通陶瓷釉在含碳的陶瓷本体上的实现也存在非常多的技术局限,难以广泛应用。
申请号为201310426997.2,名称为“一种高吸附性能的电气石竹炭陶瓷及制备方法”的中国发明专利申请公开了一种电气石竹炭陶瓷,该专利申请是将一定比例的竹炭粉与电气石粉,陶土混合,成型,在还原气氛缓慢升温至600~800℃煅烧,保温30~50分钟制成成品。该专利申请的制品用于吸附,不能用于制造有吸水率和强度要求的日用器皿等;同时该专利申请烧制方法采用气氛保护(还原气氛),限制条件多。
发明内容
本发明针对现有含炭紫砂陶或含碳陶瓷制造工艺复杂的问题,提供一种制造工艺简单的活性炭紫砂陶及其制备方法;另外,本发明还提供一种不易渗水的活性炭紫砂陶及其制备方法。
本发明的技术方案如下:
一种活性炭紫砂陶,所述活性炭紫砂陶的制备原材料由以下重量百分比的组份混合而成:紫砂泥料50-90%,活性炭10-50%,其他陶土0-30%。
进一步地,所述活性炭采用木炭、竹炭或者其它植物炭。
进一步地,所述其他陶土采用长石、木节土或者方解石。
进一步地,所述紫砂泥料的粒径为60目或者60目以上
进一步地,所述活性炭的粒径为80目-100目。
进一步地,所述其他陶土的粒径为200目-250目。
活性炭紫砂陶的制备方法,用常规的陶瓷制造工艺制备原材料和半成品,接着将所述半成品置于密闭容器中,用耗氧材料填充所述密闭容器中的空隙,然后经1100℃-1200℃烧制而成。
进一步地,所述密闭容器采用耐火材料匣钵、陶瓷容器或者耐高温合金容器。
进一步地,所述耗氧材料采用可燃性植物或者活性炭粉。
进一步地,所述耗氧材料中混入有易挥发性盐类。
本发明的技术效果在于:(1)采用密闭容器烧结法,这种密闭容器可以是陶瓷(耐火材料),耐高温金属,或者是窑炉。这种密闭容器可以解决在加热过程中不流入空气,以保护制品烧结过程中活性炭不被氧化;(2)采用耗氧保护法,即在密闭容器中装载制品后,用可燃性植物或活性炭粉填充,并覆盖制品。在加热过程中,由这部分可燃物消耗密闭容器中所含空气或漏入密闭容器的空气中的氧气,以达到保护制品中的炭不被氧化;(3)采用挥发施釉法,降低制品的气孔率,以达到制品可以储水。挥发施釉是在耗氧填充料中混入易挥发性盐类,如食盐,在加热到一定温度后,这此盐类升华为蒸汽,制品表面吸附蒸汽,形成类似传统陶瓷盐釉的表层,这种表层可以有较低的吸水性或不吸水,这样可以有效防止制品渗水。
具体实施方式
下面对本发明的具体实施方式作进一步的说明。
实施例1
取10%重量百分比的80目竹炭,90%重量白分比的70目紫砂泥;充分混合,采用一般陶瓷工艺可塑法泥料处理工艺,混合练泥,泥料含水率30%;陈腐一周后,用滚压成型制成杯子、罐子等制品,干燥后置于耐火材料匣钵中,空隙部位用稻壳填满,然后用耐火板压实;装载于密闭电炉中,加热4小时,到1100℃,保温30分钟,自然冷却。试样吸水率8%,表面灰黑色,表面吸水迅速。
实施例2
取20%重量百分比的100目木炭,80%重量百分比的60目紫砂泥;充分混合,采用一般陶瓷工艺可塑法泥料处理工艺,混合练泥,泥料含水率20.5%;陈腐一周后,用滚压成型制成杯子、罐子等制品,干燥后置于高于烧制温度的陶瓷容器中,空隙部位用锯木屑填满,然后用耐火板压实;装载于密闭电炉中,加热3.5小时,到1170℃,保温30分钟,自然冷却。试样吸水率11%,表面灰黑色,表面吸水迅速。
实施例3
取50%重量百分比的90目植物炭(用除竹、木外的其它植物经炭化形成的活性炭),50%重量百分比的80目紫砂泥;充分混合,采用一般陶瓷工艺可塑法泥料处理工艺,混合练泥,泥料含水率25%;陈腐一周后,用滚压成型制成杯子、罐子等制品,干燥后置于耐火材料匣钵中,空隙部位用谷糠填满,然后用耐火板压实;装载于密闭电炉中,加热6小时,到1200℃,保温30分钟,自然冷却。试样吸水率15%,表面灰黑色,表面吸水迅速。
实施例4
取25%重量百分比的100目竹炭,60%重量百分比的80目紫砂泥,10%重量百分比的250目长石,5%重量百分比的200目木节土;混合练泥,泥料含水率22%;陈腐一周后,用手工拉坯制成杯子、罐子等制品,干燥后置于用耐高温(高于1200℃)不锈钢(304)制成的圆筒状容器中,间隙用稻壳填满,上面用不锈钢板盖住,置于敞开式连续窑炉(推板窑,燃料为天然气)烧制,最高温度1150℃,保温50分钟,烧成周期14小时;出窑取出制品,制品黑色,吸水率8%;表面吸水迅速。
实施例5
取10%重量百分比的90目木炭,60%重量百分比的80目紫砂泥,15%重量百分比的200目长石,15%重量百分比的250目木节土;混合练泥,泥料含水率20%;陈腐一周后,用手工拉坯制成杯子、罐子等制品,干燥后置于用耐热温度高于1200℃的合金材料制成的容器中,间隙用活性炭粉填满,上面用不锈钢板盖住,置于敞开式连续窑炉(推板窑,燃料为天然气)烧制,最高温度1120℃,保温40分钟,烧成周期12小时;出窑取出制品,制品黑色,吸水率7%;表面吸水迅速。
实施例6
取30%重量百分比的100目竹炭,65%重量百分比的60目紫砂泥,5%重量百分比的200目方解石;加水,用球磨机球磨12小时,制成含水率35%的泥浆,细度250目筛余小于1%,用石膏模注浆成型制成杯子、罐子等制品,置于耐火材料匣钵中,匣钵间隙用浸泡过食盐的谷糠填充满,匣钵顶部用耐火板压实;置于1立方米梭式窑中烧制,燃料为液化气,最高温度1185℃,烧成周期8小时,保温1小时。制品表面不规则纹理,微光泽,深黑色,不吸水,制品吸水率12%。
实施例6中谷糠浸泡食盐的方式为:将谷糠置于容器中,然后用5%浓度的食盐水溶液淋透,并保持30分钟,晾干或烘干(温度一般不高于60℃)备用。
Claims (10)
1.一种活性炭紫砂陶,其特征是,所述活性炭紫砂陶的制备原材料由以下重量百分比的组份混合而成:紫砂泥料50-90%,活性炭10-50%,其他陶土0-30%。
2.按照权利要求1所述的活性炭紫砂陶,其特征是:所述活性炭采用木炭、竹炭或者其它植物炭。
3.按照权利要求1所述的活性炭紫砂陶,其特征是:所述其他陶土采用长石、木节土或者方解石。
4.按照权利要求1所述的活性炭紫砂陶,其特征是:所述紫砂泥料的粒径为60目或者60目以上。
5.按照权利要求1所述的活性炭紫砂陶,其特征是:所述活性炭的粒径为80目-100目。
6.按照权利要求1所述的活性炭紫砂陶,其特征是:所述其他陶土的粒径为200目-250目。
7.按照权利要求1-6中任一项所述的活性炭紫砂陶的制备方法,其特征是:用常规的陶瓷制造工艺制备原材料和半成品,接着将所述半成品置于密闭容器中,用耗氧材料填充所述密闭容器中的空隙,然后经1100℃-1200℃烧制而成。
8.按照权利要求7所述的活性炭紫砂陶的制备方法,其特征是:所述密闭容器采用耐火材料匣钵、陶瓷容器或者耐高温金属容器。
9.按照权利要求7所述的活性炭紫砂陶的制备方法,其特征是:所述耗氧材料采用可燃性植物或者活性炭粉。
10.按照权利要求7所述的活性炭紫砂陶的制备方法,其特征是:所述耗氧材料中混入有易挥发性盐类。
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