CN105544186A - Dyeing method of green linen and green linen product dyed by same - Google Patents
Dyeing method of green linen and green linen product dyed by same Download PDFInfo
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- CN105544186A CN105544186A CN201610067185.7A CN201610067185A CN105544186A CN 105544186 A CN105544186 A CN 105544186A CN 201610067185 A CN201610067185 A CN 201610067185A CN 105544186 A CN105544186 A CN 105544186A
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- Prior art keywords
- mordant
- dyeing
- linen
- dyeing method
- green
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- 238000004043 dyeing Methods 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000003513 alkali Substances 0.000 claims abstract description 36
- XDVZNDLANFJOQR-UHFFFAOYSA-N Coptisine Natural products O=Cc1c2OCOc2ccc1C=C3/NCCc4cc5OCOc5cc34 XDVZNDLANFJOQR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229930003944 flavone Natural products 0.000 claims abstract description 18
- 150000002213 flavones Chemical class 0.000 claims abstract description 18
- 235000011949 flavones Nutrition 0.000 claims abstract description 18
- 238000003851 corona treatment Methods 0.000 claims abstract description 13
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical group [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 7
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 6
- XYHOBCMEDLZUMP-UHFFFAOYSA-N coptisine Chemical group C1=C2C=C(C3=C(C=C4OCOC4=C3)CC3)[N+]3=CC2=C2OCOC2=C1 XYHOBCMEDLZUMP-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000004744 fabric Substances 0.000 claims description 75
- 240000006995 Abutilon theophrasti Species 0.000 claims description 63
- 238000004140 cleaning Methods 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 239000012752 auxiliary agent Substances 0.000 claims description 18
- 239000003792 electrolyte Substances 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 11
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 7
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 7
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims description 4
- 238000003287 bathing Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- LUXPUVKJHVUJAV-UHFFFAOYSA-M coptisine, chloride Chemical group [Cl-].C1=C2C=C(C3=C(C=C4OCOC4=C3)CC3)[N+]3=CC2=C2OCOC2=C1 LUXPUVKJHVUJAV-UHFFFAOYSA-M 0.000 description 13
- 239000000835 fiber Substances 0.000 description 13
- 239000000975 dye Substances 0.000 description 11
- 229920000742 Cotton Polymers 0.000 description 5
- 241000208202 Linaceae Species 0.000 description 5
- 235000004431 Linum usitatissimum Nutrition 0.000 description 5
- 239000011487 hemp Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 3
- 244000247747 Coptis groenlandica Species 0.000 description 3
- 235000002991 Coptis groenlandica Nutrition 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 235000009120 camo Nutrition 0.000 description 3
- 235000005607 chanvre indien Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229940088598 enzyme Drugs 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000983 mordant dye Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Coloring (AREA)
Abstract
The invention relates to a dyeing method of green linen and a green linen product dyed by same. The dyeing method is characterized by comprising the following steps: a, alkali washing green linen raw materials, and then drying to obtain alkali washed green linen; b, performing co-bath mordant dyeing for the alkali washed green linen to obtain mordant-dyed green linen, wherein the mordant dyeing bath ratio is 1: (100 to 500), the mordant dyeing time is 20 to 100 minutes, the mordant is copper sulfate and/or ferrous sulfate, the consumption of the mordant is 1 to 10 percent owf, the mordant is coptisine and flavones, and the mass ratio of the mordant to the coptisine to the flavones is 1: (0.01 to 1): (0.03 to 1); c, performing corona treatment on the mordant-dyed green linen to obtain a green linen product. The dyeing method of the green linen is simple in dyeing method, easy to operate, and applicable to the industrialized operation, and used materials are low in price and easy to obtain.
Description
Technical field
The present invention relates to field of printing and dyeing, the dyeing method being specifically related to a kind of piemarker cloth and the piemarker cloth product of being printed and dyed by the method.
Background technology
The origin of clothes, existing thousands of years history.From warming with animal skin, leaf, weave cotton cloth to breeding silkworms to reel off raw silk from cocoons consciously, experienced by very long process.Ancients have learned to extract fiber from fiber crops, cotton, spin cotton and weave cloth.Today, people learned chemically middle refinement synthetic fiber.Weave gimmick also increasingly exquisite, from simple plain weave, twill, satin weave, to complicated alternative construction, double-layered structure and figured texture weave.But along with the development of society, the progress of technology, people no longer meet its thermal property and outward appearance, pay attention to its wearability gradually.According to parameters such as different fabric, different tissues structure, fabric different-thickness, density, tightnesses, the wearability of research fabric.And bast-fibre and fabric thereof are with its moisture absorption, ventilative, uvioresistant, the premium properties such as antistatic, be subject to consumers, become a kind of fashion, particularly at Japan, European & American Market, the symbol of the noble quality of the specific wrinkle of the linen fabrics is also the symbol of identity.China is one of linen leading exporter in the world, has certain advantage in the international market, and major product has blue fiber crops, flax, hemp, jute etc., but because linen elastic recovery is poor, wear no resistance, dress has prodding and itching feeling, and the exploitation of pure linen is subject to certain restrictions.Current clothing linen is to multifunctional direction development, and numb blending or numb intertexture had both remained the advantage of flax fibre, embodied again the strong point of other textile fabrics, improved wearability and the style of fabric, were the trend of product development.
Because china-hemp fibers supramolecular structure and cotton fiber have larger difference, its content of cellulose is far below cotton fiber, and degree of crystallinity, the degree of orientation and content of lignin are all higher, therefore hemp fabric pre-treatment and dyeing is made to there is certain difficulty, cause Hemp textile exploitation to be restricted, added value of product is not high.
Chinese patent CN104631132A discloses a kind of Chinese fiber crops natural dyeing technique, specifically comprise: (1) Chinese bast-fibre biological enzyme degumming: pretreating process: process conditions are: H<sub>2</subGrea tT.GreaT.GTS0<sub>4LEssT.LTss T.LT/sub> concentration 3g/L, temperature 60 C, time 1.5h, bath raio 1:14; Come unstuck with the two kinds of enzyme mixing of pectase, cellulase and different proportion, pectase degumming best results; Step is: raw ramie → leaching enzyme → kiering → bleach → copy fiber crops → drift pickling → oil supply → dehydration → oven dry; (2) boiling-off oxygen bleaching: be under the condition of 1:12 in bath raio, drift end solution is warming up to 98 DEG C with the speed of 2 DEG C/min, floats 30 minutes, the end at such a temperature, then is cooled to 25 DEG C of washings 20 minutes with the speed of 2 DEG C/min; (3) natural dye dying: vegetable colour is main, animal dye is auxiliary; (4) dyeing; (5) control of Value in Dyeing Process.This invention technology can carry out dyeing process for Chinese fiber crops effectively, and technique environmental protection, application is convenient.
Chinese patent CN104278542A discloses one and to grow flax the dyeing after time brightness electric discharge graft modification.Described technique, by carrying out time brightness electric discharge graft modification to flax, drastically increases dye-uptake and the firmness of flax dyeing.What dye-uptake did not carry out processing improves more than 20%; Dry fastness reaches 5 grades, fastness to wet rubbing reaches 4-5 level, washing fastness reaches 4-5 level.
Conventional linen dyeing method is printed and dyed, and the linen dye-uptake obtained is low, tinctorial yield is low, and the linen after dyeing seems that color is more shallow.
Summary of the invention
In order to solve the problems referred to above that prior art exists, the dyeing method dyeing method of the present invention that the invention provides a kind of piemarker cloth print and dye that the piemarker cloth product dye-uptake obtained increases substantially, tinctorial yield be improved significantly, dye after piemarker cloth product colour full.
The technical solution adopted in the present invention is:
A dyeing method for piemarker cloth, the method comprises: a, piemarker cloth raw material carried out post-drying after alkali cleaning, obtains alkali cleaning piemarker cloth; B, described alkali cleaning piemarker cloth carried out, with bathing mordant dyeing, obtain mordant dyeing piemarker cloth; Wherein, mordant dyeing bath raio is 1:(100-500), the mordant dyeing time is 20-100 minute, mordant is copper sulphate and/or ferrous sulfate, mordant consumption is 1-10%owf, mordanting assistant is coptisine and flavones, and the mass ratio of mordant, coptisine and flavones is 1:(0.01-1): (0.03-1); C, gained mordant dyeing piemarker cloth is carried out corona treatment, obtain piemarker cloth product.
Preferably, the alkali that described alkali cleaning is used is NaOH and/or potassium hydroxide.
Preferably, the condition of described alkali cleaning is: temperature is 100-120 degree Celsius, and the time is 20-60 minute, and alkali cleaning bath raio is 1:(100-300), concentration of lye is 5-50 grams per liter.
Preferably, described mordant dyeing bath raio is 1:(200-300), the mordant dyeing time is 40-60 minute, and mordant is copper sulphate, and mordant consumption is 2-5%owf.
Preferably, the mass ratio of described mordant, coptisine and flavones is 1:(0.03-0.5): (0.1-0.7).
Preferably, the condition of described corona treatment is: corona voltage is 100-2000 volt, and the time is 2-50 minute.
Preferably, the condition of described corona treatment is: corona voltage is 1200-1500 volt, and the time is 12-20 minute.
Preferably, electrolyte auxiliary agent is also added with in bath mordant dyeing described in step b; Described electrolyte auxiliary agent is sodium chloride, sodium dihydrogen phosphate or natrium citricum, and the addition of described electrolyte auxiliary agent is 0.1-3 times of mordant.
Preferably, described electrolyte auxiliary agent is sodium chloride or sodium dihydrogen phosphate, and the addition of described electrolyte auxiliary agent is 1-2 times of mordant.
The piemarker cloth product that preparation method of the present invention prints and dyes.
Beneficial effect of the present invention, by: the dyeing method of piemarker cloth provided by the invention is simple to operation, used raw material cheap and easy to get, is applicable to industrial operation; Use dyeing method of the present invention to print and dye the piemarker cloth product dye-uptake obtained increases substantially, tinctorial yield be improved significantly, dyeing after piemarker cloth product colour full; After coptis dyeing, piemarker cloth fabric is provided with certain antibiotic health-care function.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearly, will be described in detail technical scheme of the present invention below.Obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, other embodiments all that those of ordinary skill in the art obtain under the prerequisite not making creative work, all belong to the scope that the present invention protects.
The invention provides a kind of dyeing method of piemarker cloth, the method comprises: a, piemarker cloth raw material carried out post-drying after alkali cleaning, obtains alkali cleaning piemarker cloth; B, described alkali cleaning piemarker cloth carried out, with bathing mordant dyeing, obtain mordant dyeing piemarker cloth; Wherein, mordant dyeing bath raio is 1:(100-500), the mordant dyeing time is 20-100 minute, mordant is copper sulphate and/or ferrous sulfate, mordant consumption is 1-10%owf, mordanting assistant is coptisine and flavones, and the mass ratio of mordant, coptisine and flavones is 1:(0.01-1): (0.03-1); C, gained mordant dyeing piemarker cloth is carried out corona treatment, obtain piemarker cloth product.
Mordant dyeing utilizes carrier to make do not have the coloring matter of affinity to catch the method for fiber to fiber, this carrier claims mordant, mordant is metallic salt mainly, as (for acid mordant dyes) such as aluminium salt, chromic salts, mantoquita, molysite, also have some organic compounds as tannic acid (for alkaline mordant dye).The Color of linen can not only be promoted for coptisine and flavones as mordanting assistant and there is certain antibacterial action.
According to the present invention, described alkali cleaning alkali used can be NaOH and/or potassium hydroxide.
According to the present invention, the condition of described alkali cleaning is: temperature can be 100-120 degree Celsius, and the time can be 20-60 minute, and alkali cleaning bath raio can be 1:(100-300), concentration of lye can be 5-50 grams per liter.
According to the present invention, described mordant dyeing bath raio can be 1:(200-300), the mordant dyeing time can be 40-60 minute, and mordant can be copper sulphate, and mordant consumption can be 2-5%owf.
According to the present invention, the mass ratio of described mordant, coptisine and flavones can be 1:(0.03-0.5): (0.1-0.7).
According to the present invention, the condition of described corona treatment is: corona voltage can lie prostrate for 100-2000, and the time can be 2-50 minute.
In the electric substation and circuit of more than 110kV, often can hear the discharging sound of " flight of steps leading to a palace hall mile " and nattier blue ring of light, Here it is corona.Corona is specific electron avalanche---the stable discharging of-streamer form in severe non-uniform electric field.Corona can improve wool surfaces activity and surface energy, increases absorption property, improves the adsorbance of the fiber sheath coptis and adsorbing stability.
According to the present invention, the condition of described corona treatment is: corona voltage can lie prostrate for 1200-1500, and the time can be 12-20 minute.
According to the present invention, described in step b, also add electrolyte auxiliary agent with in bath mordant dyeing; Described electrolyte auxiliary agent can be sodium chloride, sodium dihydrogen phosphate or natrium citricum, and the addition of described electrolyte auxiliary agent can be 0.1-3 times of mordant.
According to the present invention, described electrolyte auxiliary agent can be sodium chloride or sodium dihydrogen phosphate, and the addition of described electrolyte auxiliary agent can be 1-2 times of mordant.
The piemarker cloth product that the present invention also provides preparation in accordance with the present invention to print and dye.
To further illustrate the present invention by embodiment below, but the present invention is not therefore subject to any restriction.
If no special instructions, instrument of the present invention and reagent are and are purchased, and the commodity of different brands do not affect concrete use.
The dye-uptake assay method of embodiment of the present invention piemarker cloth product:
According to lambert----Beer law, measures the absorbance A b of coloured differently stage dye liquor respectively
s, with dye-uptake=(1-Ab
si/ Ab
so× Ki/Ko) × 100% calculating dye-uptake, in formula: Ab
sifor absorbance measured after dyeing residual liquid dilution; Ki is dyeing residual liquid extension rate; Ab
so isabsorbance measured after dye liquor dilution; Ko is dye liquor extension rate.
The tinctorial yield of embodiment of the present invention piemarker cloth product: calculated by tinctorial yield=dye-uptake × dye dosage grams/skin sample weight grams.
Embodiment 1
A, at 100 degrees Celsius, alkali cleaning bath raio is under 1:100, and piemarker cloth raw material is put into the sodium hydroxide solution that concentration of lye is 5 grams per liters, and alkali cleaning 20 minutes post-dryings, obtain alkali cleaning piemarker cloth;
B, be 1:100 according to mordant dyeing bath raio, add 1%owf copper sulphate as mordant, be that 1:0.01:0.03 adds coptisine and flavones as mordanting assistant according to the mass ratio of mordant, coptisine and flavones, the same bath mordant dyeing that described alkali cleaning piemarker cloth carries out 20 minutes, as electrolyte auxiliary agent, is obtained mordant dyeing piemarker cloth by the sodium chloride adding 1/10 mordant quality;
C, under corona voltage is 100 volts, gained mordant dyeing piemarker cloth is carried out corona treatment 2 minutes, obtains piemarker cloth product 1.After tested, the dye-uptake that calculates piemarker cloth product 1 is 95.2%, and tinctorial yield is 1.82%, full color.
Embodiment 2
A, at 120 degrees Celsius, alkali cleaning bath raio is under 1:300, and piemarker cloth raw material is put into the potassium hydroxide solution that concentration of lye is 50 grams per liters, and alkali cleaning 60 minutes post-dryings, obtain alkali cleaning piemarker cloth;
B, be 1:300 according to mordant dyeing bath raio, add 10%owf ferrous sulfate as mordant, be that 1:1:1 adds coptisine and flavones as mordanting assistant according to the mass ratio of mordant, coptisine and flavones, the same bath mordant dyeing that described alkali cleaning piemarker cloth carries out 100 minutes, as electrolyte auxiliary agent, is obtained mordant dyeing piemarker cloth by the sodium dihydrogen phosphate adding 3 times of mordant quality;
C, under corona voltage is 2000 volts, gained mordant dyeing piemarker cloth is carried out corona treatment 50 minutes, obtains piemarker cloth product 2.After tested, the dye-uptake that calculates piemarker cloth product 2 is 94.5%, and tinctorial yield is 1.86%, full color.
Embodiment 3
A, at 110 degrees Celsius, alkali cleaning bath raio is under 1:200, and piemarker cloth raw material is put into the NaOH and potassium hydroxide solution that concentration of lye is 30 grams per liters, and alkali cleaning 40 minutes post-dryings, obtain alkali cleaning piemarker cloth;
B, be 1:250 according to mordant dyeing bath raio, add 5%owf copper sulphate and ferrous sulfate as mordant, be that 1:0.5:0.5 adds coptisine and flavones as mordanting assistant according to the mass ratio of mordant, coptisine and flavones, the same bath mordant dyeing that described alkali cleaning piemarker cloth carries out 60 minutes, as electrolyte auxiliary agent, is obtained mordant dyeing piemarker cloth by the natrium citricum adding 1.5 times of mordant quality;
C, under corona voltage is 1000 volts, gained mordant dyeing piemarker cloth is carried out corona treatment 25 minutes, obtains piemarker cloth product 3.After tested, the dye-uptake that calculates piemarker cloth product 3 is 96.0%, and tinctorial yield is 1.88%, full color.
From embodiment 1-3, the dyeing method of piemarker cloth provided by the invention is simple to operation, use raw material cheap and easy to get, be applicable to industrial operation; Use dyeing method of the present invention to print and dye the piemarker cloth product dye-uptake obtained increases substantially, tinctorial yield be improved significantly, dyeing after piemarker cloth product colour full; After coptis dyeing, piemarker cloth fabric is provided with certain antibiotic health-care function.
Claims (10)
1. a dyeing method for piemarker cloth, is characterized in that, the method comprises:
A, piemarker cloth raw material carried out post-drying after alkali cleaning, obtain alkali cleaning piemarker cloth;
B, described alkali cleaning piemarker cloth carried out, with bathing mordant dyeing, obtain mordant dyeing piemarker cloth; Wherein, mordant dyeing bath raio is 1:(100-500), the mordant dyeing time is 20-100 minute, mordant is copper sulphate and/or ferrous sulfate, mordant consumption is 1-10%owf, mordanting assistant is coptisine and flavones, and the mass ratio of mordant, coptisine and flavones is 1:(0.01-1): (0.03-1);
C, gained mordant dyeing piemarker cloth is carried out corona treatment, obtain piemarker cloth product.
2. dyeing method according to claim 1, is characterized in that, described alkali cleaning alkali used is NaOH and/or potassium hydroxide.
3. dyeing method according to claim 1, is characterized in that, the condition of described alkali cleaning is: temperature is 100-120 degree Celsius, and the time is 20-60 minute, and alkali cleaning bath raio is 1:(100-300), concentration of lye is 5-50 grams per liter.
4. dyeing method according to claim 1, is characterized in that, described mordant dyeing bath raio is 1:(200-300), the mordant dyeing time is 40-60 minute, and mordant is copper sulphate, and mordant consumption is 2-5%owf.
5. dyeing method according to claim 1, is characterized in that, the mass ratio of described mordant, coptisine and flavones is 1:(0.03-0.5): (0.1-0.7).
6. dyeing method according to claim 1, is characterized in that, the condition of described corona treatment is: corona voltage is 100-2000 volt, and the time is 2-50 minute.
7. dyeing method according to claim 1, is characterized in that, the condition of described corona treatment is: corona voltage is 1200-1500 volt, and the time is 12-20 minute.
8. dyeing method according to claim 1, is characterized in that, also adds electrolyte auxiliary agent described in step b with in bath mordant dyeing; Described electrolyte auxiliary agent is sodium chloride, sodium dihydrogen phosphate or natrium citricum, and the addition of described electrolyte auxiliary agent is 0.1-3 times of mordant.
9. dyeing method according to claim 1, is characterized in that, described electrolyte auxiliary agent is sodium chloride or sodium dihydrogen phosphate, and the addition of described electrolyte auxiliary agent is 1-2 times of mordant.
10. the piemarker cloth product that the dyeing method of the piemarker cloth in claim 1-9 described in any one is printed and dyed.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1093131A (en) * | 1993-11-19 | 1994-10-05 | 蒙阴恒昌染纱有限公司 | Dyeing process for sulphurized china jute and cotton hank yarn |
| CN1865580A (en) * | 2006-06-20 | 2006-11-22 | 大连轻工业学院 | Method for mordant printing on fabric dyed by natural vegetable dye |
| JP2010222722A (en) * | 2009-03-23 | 2010-10-07 | Tsuyakin Kogyo Kk | Method for dyeing cellulose fiber with natural dye |
| CN105063998A (en) * | 2015-08-14 | 2015-11-18 | 太仓天龙化纤有限公司 | Dyeing and finishing process for linen and cotton blended fiber fabric |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093131A (en) * | 1993-11-19 | 1994-10-05 | 蒙阴恒昌染纱有限公司 | Dyeing process for sulphurized china jute and cotton hank yarn |
| CN1865580A (en) * | 2006-06-20 | 2006-11-22 | 大连轻工业学院 | Method for mordant printing on fabric dyed by natural vegetable dye |
| JP2010222722A (en) * | 2009-03-23 | 2010-10-07 | Tsuyakin Kogyo Kk | Method for dyeing cellulose fiber with natural dye |
| CN105063998A (en) * | 2015-08-14 | 2015-11-18 | 太仓天龙化纤有限公司 | Dyeing and finishing process for linen and cotton blended fiber fabric |
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