KR20100134923A - Process of high fastness dyeing for dyeable polypropylene fabrics - Google Patents
Process of high fastness dyeing for dyeable polypropylene fabrics Download PDFInfo
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- KR20100134923A KR20100134923A KR1020090053287A KR20090053287A KR20100134923A KR 20100134923 A KR20100134923 A KR 20100134923A KR 1020090053287 A KR1020090053287 A KR 1020090053287A KR 20090053287 A KR20090053287 A KR 20090053287A KR 20100134923 A KR20100134923 A KR 20100134923A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/79—Polyolefins
- D06P3/794—Polyolefins using dispersed dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/004—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
Abstract
Description
본 발명은 가염성 폴리프로필렌 직물의 염색방법에 관한 것으로서 특히 견뢰도를 향상할 수 있는 염색방법에 관한 것이다.The present invention relates to a dyeing method of a chlorinated polypropylene fabric, and more particularly to a dyeing method that can improve the fastness.
일반적으로 폴리프로필렌 섬유는 염색이 되지 않기 때문에 방사시 안료를 첨가하여 제조하는데 이를 원착(또는 선염) 폴리프로필렌 섬유라고 한다. 이에 반하여 섬유제품 제조 후 염료에 의하여 염색이 가능하도록 한 폴리프로필렌 섬유를 가염성(可染性) 폴리프로필렌 섬유라고 한다. In general, polypropylene fibers are not dyed, and are produced by adding a pigment during spinning, which is called an original (or pre-dyed) polypropylene fiber. On the contrary, polypropylene fiber which can be dyed by dye after the manufacture of the fiber product is called salt polypropylene fiber.
폴리프로필렌 섬유가 다른 섬유보다 우수한 기능성은 경량성, 보온성, 발수성 등이다. 범용 소재인 PET나 나일론의 경우 이러한 기능성을 보완하기 위해 수십년 동안 섬유의 중공화, 축열 보온 첨가제의 첨가, 발수가공의 개발 등 수많은 노력이 이루어져 왔으며, 최근 스포츠 캐주얼 등의 기능성이 일반 의류에 접목되는 트렌드에 힘입어 이들의 기능성은 더욱 주목하고 있는 상태이다. 그러나 PET나 나일론의 기능성 개질이나 가공 등에 의한 효과는 폴리프로필렌 섬유가 근본적으로 가지고 있는 기능보다 못한 경우가 대부분이기 때문에 폴리프로필렌 섬유의 기능성 섬유로서의 성공 가능성이 매우 크다고 할 수 있다.Polypropylene fibers have superior functionality over other fibers in light weight, warmth, water repellency, and the like. In the case of general-purpose materials such as PET and nylon, many efforts have been made for decades to supplement such functionality, such as fiber hollowing, addition of heat storage additives, and development of water-repellent processing. Thanks to this trend, their functionality is getting more attention. However, the effects of the functional modification and processing of PET or nylon are often less than the functions that the polypropylene fibers have inherently. Therefore, the possibility of success as a functional fiber of the polypropylene fibers is very high.
그럼에도 불구하고 폴리프로필렌은 고결정성 범용수지로서 섬유로서의 전개는 일찍부터 요구되어 왔음에도 불구하고, 염색성이 결여되어 다양한 색상표현이 곤란하여 제한된 일부 용도에만 사용되어져 왔다. 폴리프로필렌 섬유의 가염화에 대한 노력은 1960년대 이후로 40년 이상 지속되어 왔으나, 연구수준을 벗어난 상업 생산 수준에서 우수한 염색성을 갖는 기술을 확보하지 못함으로써 상품화가 되지 못하였다. 그럼에도 불구하고, 여성 정장용으로 대표되던 기존 폴리에스터 직물산업에서 스포츠 캐주얼로 트렌드가 바뀌면서 다양한 기능성 섬유의 접목이 용이하게 되었고, 폴리프로필렌에 원착이란 개념의 착색 기술이 보급되면서 착실히 그 영역을 넓혀와 현재는 고기능성 섬유로서의 가치를 다시 확인하고 있는 상태이다. 그러나 여전히 색상 표현의 한계에 부딪혀 그 성장성이 주춤하고 있는 상태에 있다.Nevertheless, polypropylene is a highly crystalline general-purpose resin, although development as a fiber has been required early, but it has been used only for a limited use because it is difficult to express various colors due to lack of dyeability. Efforts to salt polypropylene fibers have continued for more than 40 years since the 1960s, but failed to commercialize them because they failed to secure technology with excellent dyeability at commercial production levels beyond the research level. Nevertheless, as the trend changed from the existing polyester fabric industry, which was represented for women's suits, to sports casual wear, various functional fibers were easily grafted. Is reaffirming its value as a highly functional fiber. However, it is still struggling to grow due to the limitations of color expression.
현재 생산되고 있는 원착폴리프로필렌 섬유의 경우 섬유 생산과 동시에 색상이 정해짐에 따라 로트 관리에 어려움이 많고 관리 비용이 많이 필요하다. 또한 색상에 따른 비용 차이가 있고, 단색 직편물 또는 패턴물만 생산이 가능하며 현재 수요가 증가하고 있는 날염물에는 적용이 불가능하다. In the case of the currently produced polypropylene fiber, the lot management is difficult and the management cost is high as the color is determined simultaneously with the fiber production. In addition, there is a difference in cost depending on the color, it is possible to produce only solid knitted fabrics or patterns, and it is not applicable to the printing materials that demand is increasing.
이러한 가염성 폴리프로필렌 섬유의 필요성에 부응하여 섬유업계에서는 여러종류의 가염성 폴리프로필렌섬유를 개발하고 있는데, 그 중 폴리에스테르성분과 폴리프로필렌을 블랜딩하여 방사한 가염성 폴리프로필렌 섬유의 경우 폴리에스테르 성분이 소량 함유되어 있으므로 분산염료의 의한 염색이 가능하였으나 폴리에스테르와 폴리프로필렌의 동색성의 실현이 어려웠으나 폴리프로필렌 원사의 세섬화로 인한 견뢰도 저하 및 염색불균일 현상이 초래되는 문제점을 안고 있었다.In response to the necessity of the chlorinated polypropylene fibers, the textile industry has developed various kinds of chlorinated polypropylene fibers. Among them, in the case of the chlorinated polypropylene fiber blended with polyester and polypropylene, the polyester component Although it contained small amount of dye, it was possible to dye by disperse dye, but it was difficult to realize the same color of polyester and polypropylene.
그러므로 본 발명에서는 기존의 가염성 폴리프로필렌 섬유를 이용한 직물의 염색에서 발생되는 문제점을 해결하여 견뢰도 저하 및 염색불균일을 해소하고 동색성을 확보하는 것을 기술적 과제로 한다.Therefore, in the present invention to solve the problems caused by the dyeing of the fabric using the conventional chlorinated polypropylene fiber to solve the lowering of color fastness and uneven dyeing and to secure the same color as a technical problem.
그러므로 본 발명에 의하면, 가염성 폴리프로필렌사로 제직된 폴리프로필렌직물을 NaOH 80~100g/ℓ, H2O2 10~20g/ℓ, 정련제 8.0~10g/ℓ, 과수안정제 3.0~5.0g/ℓ, 정수제 1.0~3.0g/ℓ 및 잔부로서 물을 함유하는 전처리액에 침지하여 상온에서 뱃치식정련한 후, 30~50℃에서 10~16시간동안 에이징하고 수세하는 전처리공정을 한 후,Therefore, according to the present invention, a polypropylene fabric woven with a chlorinated polypropylene yarn NaOH 80 ~ 100g / ℓ, H 2 O 2 10 ~ 20g / ℓ, Refiner 8.0 ~ 10g / ℓ, Fruit water stabilizer 3.0 ~ 5.0g / ℓ, After immersing in a pretreatment solution containing 1.0 to 3.0 g / l of water purifying agent and water as a remainder, and batch-refining at room temperature, the pretreatment step of aging and washing at 30 to 50 ° C. for 10 to 16 hours is performed.
시작온도 30~40℃, 승온속도 0.5~1.0℃/분으로 승온하여 최종온도 110~130℃로 분산염료를 함유한 염욕내에 상기 폴리프로필렌직물을 염색한 후,After dyeing the polypropylene fabric in a salt bath containing a disperse dye at a starting temperature of 30 to 40 ° C., a heating rate of 0.5 to 1.0 ° C./min, and a final temperature of 110 to 130 ° C.,
산성환원세정을 하고 수세 및 건조하는 것을 특징으로 하는 가염성 폴리프로필렌 직물의 고견뢰염색방법이 제공된다.Provided is a method for high color fastening of a chlorinated polypropylene fabric which is characterized by acid reduction washing, washing with water and drying.
이하 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명은 가염성 폴리프로필렌직물의 염색방법에 관한 것으로서 가염성 폴리프로필렌직물을 전처리하여 제직시 발생한 잔유물을 제거한 후 분산염료를 사용 하여 염색하고 산성환원세정을 하여 균염효과 및 견뢰도 향상을 도모할 수 있는 가염성 폴리프로필렌직물의 염색방법에 관한 것이다.The present invention relates to a dyeing method of a chlorinated polypropylene fabric, and after removing the residue generated during weaving by pretreatment of the chlorinated polypropylene fabric, it is dyed using a disperse dye, and acid reduction reduction to improve the leveling effect and color fastness. The present invention relates to a method of dyeing a chlorinated polypropylene fabric.
본 발명에서 염색의 대상이 되는 가염성 폴리프로필렌직물은 섬유형성 후 염료에 의하여 염색이 가능하도록 한 가염성 폴리프로필렌사를 이용한 것이다. 가염성 폴리프로필렌사는 그 종류가 다양하게 연구되고 현재 직물용으로 적용되고 있는데, 특히, 본 발명에서는 폴리프로필렌 폴리머와 폴리에틸렌테레프탈레이트 폴리머가 블랜딩되어 방사된 가염성 폴리프로필렌사를 사용하여 분산염료에 의해 염색이 가능한 것을 사용하는 것이 바람직하다.In the present invention, the chlorinated polypropylene fabric, which is the object of dyeing, uses a chlorinated polypropylene yarn that enables dyeing by dye after fiber formation. The polychlorinated polypropylene yarn has been studied variously and is currently applied for textiles. In particular, in the present invention, the polypropylene polymer and the polyethylene terephthalate polymer are blended and spun with a dispersible dye using the salted polypropylene yarn. It is preferable to use what can be dyed.
우선, 본 발명에서는 상기 가염성 폴리프로필렌사로 제직된 폴리프로필렌직물을 전처리공정을 하게 되는데, 전처리액은 NaOH 80~100g/ℓ, H2O2 10~20g/ℓ, 정련제 8.0~10g/ℓ, 과수안정제 3.0~5.0g/ℓ, 정수제 1.0~3.0g/ℓ 및 잔부로서 물을 함유하도록 하여 가염성 폴리프로필렌직물을 정련표백한다. First, in the present invention, the polypropylene fabric woven with the saltable polypropylene yarn is subjected to a pretreatment process, and the pretreatment solution is NaOH 80 to 100 g / l, H 2 O 2 10 to 20 g / l, refining agent 8.0 to 10 g / l, The salted polypropylene fabric is refined and bleached to contain 3.0 to 5.0 g / l of permeable stabilizer, 1.0 to 3.0 g / l of purified water and remainder to contain water.
가염성 폴리프로필렌직물을 상기 전처리액에 침지하여 상온에서 뱃치식정련한 후, 30~40℃에서 10~16시간동안 에이징하고 수세하는 전처리공정을 하게 되는데, 본 발명의 피염물인 가염성 폴리프로필렌은 가염성을 부여하였다고는 하나 초소수성특성을 가지는 폴리프로필렌 특유의 성질상 필라멘트 사이로 물을 기반으로 하는 각종 조제의 침투가 원활하지 않을 수 있으며, 또한 필라멘트자체의 열적특성이 상대적으로 낮으므로 이러한 특성을 고려하여 상기 전처리공정상의 수세공정중 수세기 수조 온도를 70~90℃로 고정하고 및 실린더를 통과하지 않고 습식(WET)상태로 수세를 끝내어 후작업인 염색작업에 의한 직물의 질감(TOUCH)을 향상시킬 수 있 다.After immersing the salted polypropylene fabric in the pretreatment solution and batch-refining at room temperature, the pre-treatment process is carried out at 30 to 40 ° C. for 10 to 16 hours and then washed with water. Although it imparts flammability, due to the peculiarity of polypropylene having super hydrophobic properties, the penetration of various preparations based on water between the filaments may not be smooth, and the thermal properties of the filaments themselves are relatively low. In consideration of fixing the centrifugal water tank temperature at 70 ~ 90 ℃ during the water washing process in the pretreatment process and finishing the water washing in the wet (WET) state without passing through the cylinder, It can be improved.
상기 전처리공정 후, 시작온도 30~40℃, 승온속도 0.5~1.0℃/분으로 승온하여 최종온도 110~130℃로 조절한 분산염료를 함유한 염욕내에 상기 폴리프로필렌직물을 염색하게 되는데, 130℃를 초과한 온도에서 염색하는 경우에는 염착률이 우수하게 될 수가 있겠지만, 폴리프로필렌 직물의 질감(touch)이 딱딱(hard)해 질 수 있어 130℃를 넘기지 않는 것이 좋다.After the pretreatment step, the polypropylene fabric is dyed in a salt bath containing a dispersion dye adjusted to a final temperature of 110 to 130 ° C. by heating at a starting temperature of 30 to 40 ° C. and a heating rate of 0.5 to 1.0 ° C./min. When the dyeing at a temperature exceeding the dyeing rate may be excellent, but the touch of the polypropylene fabric (hard) can be (hard) it is good not to exceed 130 ℃.
염색공정이 끝난 후, 산성환원세정을 하고 수세 및 건조하여 본 발명의 가염성 폴리프로필렌 직물의 염색을 완료하게 되는데, 상기 산성환원세정은 조제로서 산성 환원세정제 3.0~5.0g/ℓ 및 잔부로서 물을 함유하는 세정욕에 욕비 20:1~30:1(O.W.F)로 70~90℃에서 20~30분간 행하는 것이 좋다. After the dyeing process is completed, the acid reduction washing, washing and drying to complete the dyeing of the salt-containing polypropylene fabric of the present invention, the acid reduction washing is prepared as an acid reducing detergent 3.0 ~ 5.0g / L and the balance as water It is good to perform 20-30 minutes at 70-90 degreeC with a bath ratio 20: 1-30: 1 (OWF) to the washing bath containing these.
기존에는 알카리 환원세정을 주로 하였으나, 이 방법은 견뢰도 향상에는 많은 도움을 주었지만 색상의 변색으로 인해 색상의 안정성 및 재현성이 현저히 떨어지는 영향이 있다. 따라서 본 발명에서는 상기와 같이 산성 환원세정제를 사용하여 폴리프로필렌직물에 대한 염착성을 향상시켜 색상의 안정성 및 재현성을 높일 수 있다. In the past, alkali reduction was mainly performed, but this method helped to improve fastness, but the color stability and reproducibility were remarkably inferior due to color discoloration. Therefore, in the present invention, by using an acidic reducing detergent as described above, it is possible to improve the color stability and reproducibility of the dye by improving the polypropylene fabric.
따라서 본 발명에 의하여 경량성, 발수성, 속건성, 위생성 및 방오성등의 다양한 기능성을 가진 폴리프로필렌의 다양한 색상으로의 염색을 함과 동시에 균염성 및 견뢰도를 향상시키고 동색성을 확보할 수 있었다.Therefore, according to the present invention, the polypropylene having various functionalities such as light weight, water repellency, quick drying, hygiene and antifouling property can be dyed to various colors, and the homogeneity and color fastness can be improved and the same color can be secured.
이하 다음의 실시 예에서는 본 발명의 가염성 폴리프로필렌 직물의 고견뢰염색방법에 대한 비한정적인 예시를 하고 있다.The following examples are given as non-limiting examples of the high color fastness dyeing method of the salted polypropylene fabric of the present invention.
[실시예 1]Example 1
1.5데니아급의 가염성 폴리프로필렌사(휴비스산)로 제직된 폴리프로필렌직물을 NaOH 80g/ℓ, H2O2 10g/ℓ, 정련제 8.0g/ℓ, 과수안정제 3.0g/ℓ, 정수제 1.0g/ℓ 및 잔부로서 물을 함유하도록 한 전처리액에 침지하여 상온에서 뱃치식 정련을 하고, 30℃에서 10시간동안 에이징하고 수세하여 전처리공정을 한 후, 시작온도 40℃, 승온속도 0.5℃/분으로 승온하여 최종온도 120℃로 분산염료(Dianix Yellow AC-E new, Dianix Red AC-E 01 , Dianix Blue AC-E)를 함유한 염욕내에 상기 폴리프로필렌직물을 염색한 후, 산성 환원세정제 3g/ℓ 및 잔부로서 물을 함유하는 환원세정욕에 욕비 20:1(O.W.F)로 80℃에서 15분간 환원세정한 후 수세 및 건조하였다.A polypropylene fabric woven from 1.5 denier-type salt-containing polypropylene yarn (Hubis acid) was used for NaOH 80g / l, H 2 O 2 10g / l, Refiner 8.0g / l, Fruit water stabilizer 3.0g / l, Water purification 1.0g Batch refining at room temperature by immersing in a pretreatment liquid containing / L and water as remainder, aging at 30 ° C for 10 hours, washing with pretreatment step, starting temperature 40 ° C, heating rate 0.5 ° C / min The polypropylene fabric was dyed in a salt bath containing dispersed dyes (Dianix Yellow AC-E new , Dianix Red AC-E 01, Dianix Blue AC-E) at a final temperature of 120 ° C., and then 3 g / After a reduced wash at 80 ° C. for 15 minutes with a bath ratio of 20: 1 (OWF) in a reducing wash bath containing 1 liter and water as a remainder, washed with water and dried.
염색가공이 완료된 직물의 견뢰도를 측정하여 도 1 내지 도 3에 첨부하였다. 견뢰도측정결과 세탁견뢰도, 마찰견뢰도, 땀견뢰도 및 해수견뢰도가 4~5급으로 우수하였으며, 염소처리수 견뢰도 및 일광견뢰도 또한 양호하였다. The fastness of the dyeing is completed fabric is measured and attached to FIGS. Color fastness, washing fastness, friction fastness, sweat fastness and seawater fastness were excellent in grades 4-5, and chlorine treated water fastness and daylight fastness were also good.
도 1 내지 도 3은 본 발명에 의해 염색가공된 직물의 시험성적서이다.1 to 3 is a test report of the fabric dyed by the present invention.
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KR101230098B1 (en) * | 2011-04-26 | 2013-02-05 | 박재홍 | The printing method of polypropylene fiber material and the product thereby |
KR101520790B1 (en) | 2013-05-08 | 2015-05-15 | 주식회사 이주 | Polypropylene textile wallpapaer and manufacturing process thereof |
KR101485712B1 (en) | 2013-12-19 | 2015-01-22 | 주식회사 신흥 | Method Of Digital Textile Printing For Polypropylene Textiles |
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KR100539424B1 (en) * | 2004-01-03 | 2005-12-27 | 주식회사 휴비스 | Easy-dyeable Polyolefinic Fiber and Process of producing thereof |
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