CN105525315A - Electroplating solution for obtaining ancient bronze plating - Google Patents
Electroplating solution for obtaining ancient bronze plating Download PDFInfo
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- CN105525315A CN105525315A CN201610029979.4A CN201610029979A CN105525315A CN 105525315 A CN105525315 A CN 105525315A CN 201610029979 A CN201610029979 A CN 201610029979A CN 105525315 A CN105525315 A CN 105525315A
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- parts
- electroplate liquid
- electroplating solution
- obtaining
- ancient bronze
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention discloses an electroplating solution for obtaining an ancient bronze plating. The electroplating solution comprises the following components in parts by mass: 12-15 parts of copper sulfate, 4-10 parts of ammonium persulfate, 0.7-1.2 parts of selenium dioxide, 60-80 parts of nitric acid, 20-30 parts of sulfuric acid, 0.2-0.4 part of sodium perborate and 100 parts of water. The components are mixed and stirred uniformly to obtain the electroplating solution. Through the mode, a plated part can obtain a protective layer through adoption of the electroplating solution, the corrosion resistance of the metal plated part is enhanced, the performance of the plated part is changed, the plated part achieves better toughness, the ancient bronze plating on the surface of the metal plated part has a long service left, cannot flake and discolor easily and is stable.
Description
Technical field
The present invention relates to plated item and technology field, particularly relating to a kind of for obtaining the electroplate liquid that coating is ancient bronze.
Background technology
Plating is containing in the solution of metallizing ion, with plated material or goods for negative electrode, by electrolytic action, matrix surface obtains the method for coating.The application of electroplating technology has had very long history, initial exploitation is for meeting the needs that people are anticorrosion and decorate, along with the continuous progress of science and technology, electroplating technology can also be used to the metal cladding producing special component and function, provides the characteristic of the aspects such as electricity, magnetic, light, heat.But the plating piece overlay coating after existing plating easily comes off and variable color, unstable.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of for obtaining the electroplate liquid that coating is ancient bronze, and the coating obtained is stablized and nondiscoloration.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of for obtaining the electroplate liquid that coating is ancient bronze, the component comprised has copper sulfate, ammonium persulphate, tin anhydride, nitric acid, sulfuric acid, sodium perborate and water, the component of described electroplate liquid is: in mass parts, copper sulfate 12-15 part, ammonium persulphate 4-10 part, tin anhydride 0.7-1.2 part, nitric acid 60-80, sulfuric acid 20-30 part, sodium perborate 0.2-0.4 part, 100 parts, water, mix each component and stir and obtain described electroplate liquid.
In a preferred embodiment of the present invention, the component of described electroplate liquid is: in mass parts, 14 parts, copper sulfate, ammonium persulphate 7 parts, tin anhydride 0.9 part, nitric acid 70,25 parts, sulfuric acid, sodium perborate 0.3 part, 100 parts, water.
In a preferred embodiment of the present invention, the granular size of described sodium perborate was that 10-50 mesh sieve obtains.
In a preferred embodiment of the present invention, the pH value of described electroplate liquid is 2-4.
The invention has the beneficial effects as follows: of the present invention for obtaining the electroplate liquid that coating is ancient bronze; adopt this electroplate liquid that plating piece can be made to obtain protective layer; increase the erosion resistance of metal plating piece; change the performance of metal plating piece; make it have better toughness; the ancient bronze plating on metal plating piece surface is long for duration of service, is not easy to come off and variable color, stable.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment one:
There is provided a kind of for obtaining the electroplate liquid that coating is ancient bronze, the component comprised has copper sulfate, ammonium persulphate, tin anhydride, nitric acid, sulfuric acid, sodium perborate and water, the component of described electroplate liquid is: in mass parts, 14 parts, copper sulfate, ammonium persulphate 7 parts, tin anhydride 0.9 part, nitric acid 70,25 parts, sulfuric acid, sodium perborate 0.3 part, 100 parts, water, mix each component and stir and obtain described electroplate liquid.The granular size of described sodium perborate was that 35 mesh sieves obtain.The pH value of described electroplate liquid is 3.
Embodiment two:
There is provided a kind of for obtaining the electroplate liquid that coating is ancient bronze, the component comprised has copper sulfate, ammonium persulphate, tin anhydride, nitric acid, sulfuric acid, sodium perborate and water, the component of described electroplate liquid is: in mass parts, 12 parts, copper sulfate, ammonium persulphate 4 parts, tin anhydride 0.7 part, nitric acid 80,30 parts, sulfuric acid, sodium perborate 0.4 part, 100 parts, water, mix each component and stir and obtain described electroplate liquid.The granular size of described sodium perborate was that 50 mesh sieves obtain.The pH value of described electroplate liquid is 4.
Embodiment three:
There is provided a kind of for obtaining the electroplate liquid that coating is ancient bronze, the component comprised has copper sulfate, ammonium persulphate, tin anhydride, nitric acid, sulfuric acid, sodium perborate and water, the component of described electroplate liquid is: in mass parts, 15 parts, copper sulfate, ammonium persulphate 10 parts, tin anhydride 1.2 parts, nitric acid 60,20 parts, sulfuric acid, sodium perborate 0.2 part, 100 parts, water, mix each component and stir and obtain described electroplate liquid.The granular size of described sodium perborate was that 10 mesh sieves obtain.The pH value of described electroplate liquid is 2.
The invention has the beneficial effects as follows:
One, adopt this electroplate liquid that plating piece can be made to obtain protective layer, increase the erosion resistance of metal plating piece;
Two, change the performance of metal plating piece, make it have better toughness;
Three, the ancient bronze plating on metal plating piece surface is long for duration of service, is not easy to come off and variable color, stable.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (4)
1. one kind is ancient bronze electroplate liquid for obtaining coating, it is characterized in that, the component comprised has copper sulfate, ammonium persulphate, tin anhydride, nitric acid, sulfuric acid, sodium perborate and water, the component of described electroplate liquid is: in mass parts, copper sulfate 12-15 part, ammonium persulphate 4-10 part, tin anhydride 0.7-1.2 part, nitric acid 60-80, sulfuric acid 20-30 part, sodium perborate 0.2-0.4 part, 100 parts, water, mix each component and stir and obtain described electroplate liquid.
2. according to claim 1 for obtaining the electroplate liquid that coating is ancient bronze, it is characterized in that, the component of described electroplate liquid is: in mass parts, 14 parts, copper sulfate, ammonium persulphate 7 parts, tin anhydride 0.9 part, nitric acid 70,25 parts, sulfuric acid, sodium perborate 0.3 part, 100 parts, water.
3. according to claim 1 for obtaining the electroplate liquid that coating is ancient bronze, it is characterized in that, the granular size of described sodium perborate was that 10-50 mesh sieve obtains.
4. according to claim 1 for obtaining the electroplate liquid that coating is ancient bronze, it is characterized in that, the pH value of described electroplate liquid is 2-4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610029979.4A CN105525315A (en) | 2016-01-18 | 2016-01-18 | Electroplating solution for obtaining ancient bronze plating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610029979.4A CN105525315A (en) | 2016-01-18 | 2016-01-18 | Electroplating solution for obtaining ancient bronze plating |
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| Publication Number | Publication Date |
|---|---|
| CN105525315A true CN105525315A (en) | 2016-04-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610029979.4A Pending CN105525315A (en) | 2016-01-18 | 2016-01-18 | Electroplating solution for obtaining ancient bronze plating |
Country Status (1)
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| CN (1) | CN105525315A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774367A (en) * | 2021-09-09 | 2021-12-10 | 浙江伟星实业发展股份有限公司 | Coloring liquid and application thereof |
Citations (9)
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| EP0258202A1 (en) * | 1986-08-11 | 1988-03-02 | Mitchell Bradford International Corp. | Room temperature blackening solution and method for forming a black coating on a ferrous metal substrate |
| CN101275255A (en) * | 2007-12-20 | 2008-10-01 | 广州市二轻工业科学技术研究所 | Maintenance method for alkaline non-cyanide plating copper |
| CN101316500A (en) * | 2007-06-01 | 2008-12-03 | 哈尔滨工业大学 | Production method of wire netting transparent electromagnetic shielding layer material |
| CN102363884A (en) * | 2011-10-24 | 2012-02-29 | 江门市瑞期精细化学工程有限公司 | Surface treatment process for zinc alloy die casting |
| CN102899650A (en) * | 2012-10-23 | 2013-01-30 | 自贡勃生表面技术推广有限公司 | Steel normal-temperature blackening solution composite film-forming accelerator, steel normal-temperature blackening solution and preparation method of steel normal-temperature blackening solution |
| CN104278299A (en) * | 2014-09-23 | 2015-01-14 | 明光旭升科技有限公司 | Electroplating process for copper wires |
| CN104651824A (en) * | 2014-04-28 | 2015-05-27 | 严振 | Method for coloring copper and copper alloy with gun color |
| CN104661502A (en) * | 2014-12-09 | 2015-05-27 | 邹仕放 | Preparation method of wire mesh transparent electromagnetic shielding layer material |
| CN104911654A (en) * | 2015-06-17 | 2015-09-16 | 陈新棠 | Environment-friendly electroplating liquid |
-
2016
- 2016-01-18 CN CN201610029979.4A patent/CN105525315A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0258202A1 (en) * | 1986-08-11 | 1988-03-02 | Mitchell Bradford International Corp. | Room temperature blackening solution and method for forming a black coating on a ferrous metal substrate |
| CN101316500A (en) * | 2007-06-01 | 2008-12-03 | 哈尔滨工业大学 | Production method of wire netting transparent electromagnetic shielding layer material |
| CN101275255A (en) * | 2007-12-20 | 2008-10-01 | 广州市二轻工业科学技术研究所 | Maintenance method for alkaline non-cyanide plating copper |
| CN102363884A (en) * | 2011-10-24 | 2012-02-29 | 江门市瑞期精细化学工程有限公司 | Surface treatment process for zinc alloy die casting |
| CN102899650A (en) * | 2012-10-23 | 2013-01-30 | 自贡勃生表面技术推广有限公司 | Steel normal-temperature blackening solution composite film-forming accelerator, steel normal-temperature blackening solution and preparation method of steel normal-temperature blackening solution |
| CN104651824A (en) * | 2014-04-28 | 2015-05-27 | 严振 | Method for coloring copper and copper alloy with gun color |
| CN104278299A (en) * | 2014-09-23 | 2015-01-14 | 明光旭升科技有限公司 | Electroplating process for copper wires |
| CN104661502A (en) * | 2014-12-09 | 2015-05-27 | 邹仕放 | Preparation method of wire mesh transparent electromagnetic shielding layer material |
| CN104911654A (en) * | 2015-06-17 | 2015-09-16 | 陈新棠 | Environment-friendly electroplating liquid |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774367A (en) * | 2021-09-09 | 2021-12-10 | 浙江伟星实业发展股份有限公司 | Coloring liquid and application thereof |
| CN113774367B (en) * | 2021-09-09 | 2024-03-26 | 浙江伟星实业发展股份有限公司 | Coloring liquid and application thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160427 |