CN104911654A - Environment-friendly electroplating liquid - Google Patents
Environment-friendly electroplating liquid Download PDFInfo
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- CN104911654A CN104911654A CN201510333825.XA CN201510333825A CN104911654A CN 104911654 A CN104911654 A CN 104911654A CN 201510333825 A CN201510333825 A CN 201510333825A CN 104911654 A CN104911654 A CN 104911654A
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Abstract
The invention discloses environment-friendly electroplating liquid which consists of the following raw materials: 100-120 parts of nickel sulfate, 80-100 parts of zinc sulfate, 50-65 parts of sodium sulfate, 100-120 parts of copper sulfate, 80-100 parts of aluminum sulfate, 30-35 parts of potassium sulfate, 5-10 parts of ammonium carbamate, 6-8 parts of potassium biphthalate, 10-15 parts of ethyl o-aminobenzoate, 10-12 parts of sodium acetate, 5-10 parts of benzoic acid, 5-8 parts of sodium citrate, 10-12 parts of chloroacetic acid, 12-15 parts of phenoxyacetic acid, 12-20 parts of glycollic acid, 15-20 parts of ammonium dihydrogen phosphate, 10-15 parts of sodium perborate, 8-10 parts of sodium borohydride, 6-10 parts of sodium fluoborate, 10-15 parts of zinc borate and 60-100 parts of deionized water. The environment-friendly electroplating liquid has the characteristics of no toxicity, no harm, no corrosion, stable storage and the like as well as relatively good environmental protection property; and the surface covering power of the prepared electroplating layer on an electroplated product is enhanced.
Description
Technical field
The present invention relates to a kind of technical field of electroplate liquid, particularly relate to a kind of environmental protection electric plating solution.
Background technology
Plating is exactly the process utilizing electrolysis principle to plate other metal or alloy of skim on some metallic surface, be utilize electrolytic action to make the technique of the surface attachment layer of metal film of metal or other materials making thus play to prevent corrosion, improve the effects such as wear resistance, electroconductibility, reflective and having improved aesthetic appearance.
Chromium has excellent decorate properties, and hexavalent chromium plating, as most important, the most direct effective plated material, is widely used.But chromic pollution is very serious, very huge to the harm of human body and surrounding environment, a lot of countries have paid special attention to the harm of hexavalent chromium wastewater.Although someone replaces sexavalent chrome to use with trivalent chromium, effectiveness is little, does not have substitutability etc.
Summary of the invention
The object of the invention is to overcome the upper existing shortcoming stating prior art, a kind of environmental protection electric plating solution is provided, this environmental protection electric plating solution has the features such as nontoxic, harmless, corrosion-free, storage-stable, and the feature of environmental protection is better, and the electrolytic coating made strengthens the surface coverage ability of plated item.
The technical solution adopted for the present invention to solve the technical problems is: a kind of environmental protection electric plating solution, be made up of the feed composition of following number: 100-120 part single nickel salt, 80-100 part zinc sulfate, 50-65 part sodium sulfate, 100-120 part copper sulfate, 80-100 part Tai-Ace S 150, 30-35 part potassium sulfate, 5-10 part ammonium carbamate, 6-8 part potassium hydrogen phthalate, 10-15 part ethyl o-aminobenzoate, 10-12 part sodium acetate, 5-10 part phenylformic acid, 5-8 part Trisodium Citrate, 10-12 part Mono Chloro Acetic Acid, 12-15 part phenoxy acetic acid, 12-20 part oxyacetic acid, 15-20 part primary ammonium phosphate, 10-15 part Sodium peroxoborate, 8-10 part sodium borohydride, 6-10 part Sodium tetrafluoroborate, 10-15 part zinc borate, 60-100 part deionized water.
Further, the number of each feed composition is: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150,30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
Or the number of each feed composition is: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150,30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
In sum, environmental protection electric plating solution of the present invention has the features such as nontoxic, harmless, corrosion-free, storage-stable, and the feature of environmental protection is better, and the electrolytic coating made strengthens the surface coverage ability of plated item.
Embodiment
Embodiment 1
A kind of environmental protection electric plating solution described by the present embodiment 1, is made up of the feed composition of following number: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150,30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
Embodiment 2
A kind of environmental protection electric plating solution described by the present embodiment 2, is made up of the feed composition of following number: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150,30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to technical scheme of the present invention.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.
Claims (3)
1. an environmental protection electric plating solution, it is characterized in that, be made up of the feed composition of following number: 100-120 part single nickel salt, 80-100 part zinc sulfate, 50-65 part sodium sulfate, 100-120 part copper sulfate, 80-100 part Tai-Ace S 150, 30-35 part potassium sulfate, 5-10 part ammonium carbamate, 6-8 part potassium hydrogen phthalate, 10-15 part ethyl o-aminobenzoate, 10-12 part sodium acetate, 5-10 part phenylformic acid, 5-8 part Trisodium Citrate, 10-12 part Mono Chloro Acetic Acid, 12-15 part phenoxy acetic acid, 12-20 part oxyacetic acid, 15-20 part primary ammonium phosphate, 10-15 part Sodium peroxoborate, 8-10 part sodium borohydride, 6-10 part Sodium tetrafluoroborate, 10-15 part zinc borate, 60-100 part deionized water.
2. a kind of environmental protection electric plating solution according to claim 1, it is characterized in that, the number of each feed composition is: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150, 30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
3. a kind of environmental protection electric plating solution according to claim 1, it is characterized in that, the number of each feed composition is: 100 parts of single nickel salts, 80 parts of zinc sulfate, 50 parts of sodium sulfate, 100 parts of copper sulfate, 80 parts of Tai-Ace S 150, 30 parts of potassium sulfate, 5 parts of ammonium carbamates, 6 parts of potassium hydrogen phthalates, 10 parts of ethyl o-aminobenzoates, 10 parts of sodium acetates, 5 parts of phenylformic acid, 5 parts of Trisodium Citrates, 10 parts of Mono Chloro Acetic Acids, 12 parts of phenoxy acetic acids, 12 parts of oxyacetic acids, 15 parts of primary ammonium phosphates, 10 parts of Sodium peroxoborate, 8 parts of sodium borohydrides, 6 parts of Sodium tetrafluoroborates, 10 parts of zinc borates, 60 parts of deionized waters.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510333825.XA CN104911654A (en) | 2015-06-17 | 2015-06-17 | Environment-friendly electroplating liquid |
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| CN201510333825.XA CN104911654A (en) | 2015-06-17 | 2015-06-17 | Environment-friendly electroplating liquid |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105506687A (en) * | 2016-02-19 | 2016-04-20 | 苏州市华婷特种电镀有限公司 | Electroplating solution for obtaining coating of black nickel |
| CN105525315A (en) * | 2016-01-18 | 2016-04-27 | 苏州市华婷特种电镀有限公司 | Electroplating solution for obtaining ancient bronze plating |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532306A (en) * | 2014-12-22 | 2015-04-22 | 常熟市伟达电镀有限责任公司 | Environment-friendly electroplate liquid |
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2015
- 2015-06-17 CN CN201510333825.XA patent/CN104911654A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532306A (en) * | 2014-12-22 | 2015-04-22 | 常熟市伟达电镀有限责任公司 | Environment-friendly electroplate liquid |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105525315A (en) * | 2016-01-18 | 2016-04-27 | 苏州市华婷特种电镀有限公司 | Electroplating solution for obtaining ancient bronze plating |
| CN105506687A (en) * | 2016-02-19 | 2016-04-20 | 苏州市华婷特种电镀有限公司 | Electroplating solution for obtaining coating of black nickel |
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Application publication date: 20150916 |
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