CN104911655A - Electroplating solution with excellent performance - Google Patents

Electroplating solution with excellent performance Download PDF

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Publication number
CN104911655A
CN104911655A CN201510333870.5A CN201510333870A CN104911655A CN 104911655 A CN104911655 A CN 104911655A CN 201510333870 A CN201510333870 A CN 201510333870A CN 104911655 A CN104911655 A CN 104911655A
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China
Prior art keywords
parts
sulfate
electroplating solution
citrates
sodium lauryl
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Pending
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CN201510333870.5A
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Chinese (zh)
Inventor
张慧玲
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Individual
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Individual
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Priority to CN201510333870.5A priority Critical patent/CN104911655A/en
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Abstract

The invention discloses an electroplating solution with excellent performance. The electroplating solution consists of the following raw material components: 20-25 parts of antimony trioxide, 150-200 parts of ferrous sulfate, 100-120 parts of copper sulfate, 130-150 parts of nickel sulfate, 100-120 parts of stannous chloride, 30-50 parts of aluminum sulfate, 30-40 parts of zinc carbonate, 8-10 parts of ammonium citrate, 6-8 parts of dipotassium hydrogen phosphate, 8-10 parts of potassium tartrate, 5-8 parts of potassium citrate, 8-10 parts of cocamidopropyl betaine, 6-8 parts of sodium lauryl sulfate, 3-5 parts of ipratropium bromide and 100-150 parts of deionized water. The electroplating solution with the excellent performance is strong in corrosion resistance, can reduce pollution, is an ideal plated layer, and can maintain the metal concentration of the plated layer used by the electroplating solution, and an obtained plated layer is high in brightness, strong in corrosion resistance, and capable of meeting use requirements of severe environments.

Description

A kind of electroplate liquid of superior performance
Technical field
The present invention relates to a kind of technical field of electroplate liquid, particularly relate to a kind of electroplate liquid of superior performance.
Background technology
Plating is exactly the process utilizing electrolysis principle to plate other metal or alloy of skim on some metallic surface, be utilize electrolytic action to make the technique of the surface attachment layer of metal film of metal or other materials making thus play to prevent corrosion, improve the effects such as wear resistance, electroconductibility, reflective and having improved aesthetic appearance.
At present, the plating system of the tin-zinc alloy of living has multiple: hydride systems, fluoroboric acid system, pyrophosphate salt system, gluconic acid salt system and citrate system.Domestic main application be prussiate, pyrophosphate salt system.Hydride systems is seriously polluted, and plating solution is unstable, causes quality of coating poor.This is mainly due to Bivalent Tin oxidizable one-tenth tetravalent tin in aqueous, causes coating muddy.Therefore, suitable stablizer and additive must be added, improve the overpotential of metal ion at cathodic discharge, to obtain the coating of excellent performance.
Summary of the invention
The object of the invention is to overcome the upper existing shortcoming stating prior art, a kind of electroplate liquid of superior performance is provided, the erosion resistance of the electroplate liquid of this superior performance is strong, can decreasing pollution, for desirable coating, can maintain the metal concentration of used coating, the brightness obtaining coating is high, erosion resistance is strong, can meet the service requirements of severe rugged environment.
The technical solution adopted for the present invention to solve the technical problems is: a kind of electroplate liquid of superior performance, be made up of the feed composition of following number: 20-25 part antimonous oxide, 150-200 part ferrous sulfate, 100-120 part copper sulfate, 130-150 part single nickel salt, 100-120 part tin protochloride, 30-50 part Tai-Ace S 150, 30-40 part zinc carbonate, 8-10 part ammonium citrate, 6-8 part dipotassium hydrogen phosphate, 8-10 part soluble tartrate, 5-8 part Tripotassium Citrate, 8-10 part AMONYL 380LC, 6-8 part sodium lauryl sulphate, 3-5 part ipratropium bromide, 100-150 part deionized water.
Further, the number of each feed composition is: 20 parts of antimonous oxides, 150 parts of ferrous sulfate, 100 parts of copper sulfate, 130 parts of single nickel salts, 100 parts of tin protochlorides, 30 parts of Tai-Ace S 150,30 parts of zinc carbonates, 8 parts of ammonium citrates, 6 parts of dipotassium hydrogen phosphates, 8 parts of soluble tartrates, 5 parts of Tripotassium Citrates, 8 parts of AMONYL 380LC, 6 parts of sodium lauryl sulphate, 3 parts of ipratropium bromides, 100 parts of deionized waters.
Or the number of each feed composition is: 25 parts of antimonous oxides, 200 parts of ferrous sulfate, 120 parts of copper sulfate, 150 parts of single nickel salts, 120 parts of tin protochlorides, 50 parts of Tai-Ace S 150,40 parts of zinc carbonates, 10 parts of ammonium citrates, 8 parts of dipotassium hydrogen phosphates, 10 parts of soluble tartrates, 8 parts of Tripotassium Citrates, 10 parts of AMONYL 380LC, 8 parts of sodium lauryl sulphate, 5 parts of ipratropium bromides, 150 parts of deionized waters.
In sum, the erosion resistance of the electroplate liquid of superior performance of the present invention is strong, can decreasing pollution, and be desirable coating, can maintain the metal concentration of used coating, the brightness obtaining coating is high, and erosion resistance is strong, can meet the service requirements of severe rugged environment.
Embodiment
Embodiment 1
The electroplate liquid of a kind of superior performance described by the present embodiment 1, is made up of the feed composition of following number: 20 parts of antimonous oxides, 150 parts of ferrous sulfate, 100 parts of copper sulfate, 130 parts of single nickel salts, 100 parts of tin protochlorides, 30 parts of Tai-Ace S 150,30 parts of zinc carbonates, 8 parts of ammonium citrates, 6 parts of dipotassium hydrogen phosphates, 8 parts of soluble tartrates, 5 parts of Tripotassium Citrates, 8 parts of AMONYL 380LC, 6 parts of sodium lauryl sulphate, 3 parts of ipratropium bromides, 100 parts of deionized waters.
Embodiment 2
The electroplate liquid of a kind of superior performance described by the present embodiment 2, is made up of the feed composition of following number: 25 parts of antimonous oxides, 200 parts of ferrous sulfate, 120 parts of copper sulfate, 150 parts of single nickel salts, 120 parts of tin protochlorides, 50 parts of Tai-Ace S 150,40 parts of zinc carbonates, 10 parts of ammonium citrates, 8 parts of dipotassium hydrogen phosphates, 10 parts of soluble tartrates, 8 parts of Tripotassium Citrates, 10 parts of AMONYL 380LC, 8 parts of sodium lauryl sulphate, 5 parts of ipratropium bromides, 150 parts of deionized waters.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to technical scheme of the present invention.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.

Claims (3)

1. the electroplate liquid of a superior performance, it is characterized in that, be made up of the feed composition of following number: 20-25 part antimonous oxide, 150-200 part ferrous sulfate, 100-120 part copper sulfate, 130-150 part single nickel salt, 100-120 part tin protochloride, 30-50 part Tai-Ace S 150,30-40 part zinc carbonate, 8-10 part ammonium citrate, 6-8 part dipotassium hydrogen phosphate, 8-10 part soluble tartrate, 5-8 part Tripotassium Citrate, 8-10 part AMONYL 380LC, 6-8 part sodium lauryl sulphate, 3-5 part ipratropium bromide, 100-150 part deionized water.
2. the electroplate liquid of a kind of superior performance according to claim 1, it is characterized in that, the number of each feed composition is: 20 parts of antimonous oxides, 150 parts of ferrous sulfate, 100 parts of copper sulfate, 130 parts of single nickel salts, 100 parts of tin protochlorides, 30 parts of Tai-Ace S 150,30 parts of zinc carbonates, 8 parts of ammonium citrates, 6 parts of dipotassium hydrogen phosphates, 8 parts of soluble tartrates, 5 parts of Tripotassium Citrates, 8 parts of AMONYL 380LC, 6 parts of sodium lauryl sulphate, 3 parts of ipratropium bromides, 100 parts of deionized waters.
3. the electroplate liquid of a kind of superior performance according to claim 1, it is characterized in that, the number of each feed composition is: 25 parts of antimonous oxides, 200 parts of ferrous sulfate, 120 parts of copper sulfate, 150 parts of single nickel salts, 120 parts of tin protochlorides, 50 parts of Tai-Ace S 150,40 parts of zinc carbonates, 10 parts of ammonium citrates, 8 parts of dipotassium hydrogen phosphates, 10 parts of soluble tartrates, 8 parts of Tripotassium Citrates, 10 parts of AMONYL 380LC, 8 parts of sodium lauryl sulphate, 5 parts of ipratropium bromides, 150 parts of deionized waters.
CN201510333870.5A 2015-06-17 2015-06-17 Electroplating solution with excellent performance Pending CN104911655A (en)

Priority Applications (1)

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CN201510333870.5A CN104911655A (en) 2015-06-17 2015-06-17 Electroplating solution with excellent performance

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Application Number Priority Date Filing Date Title
CN201510333870.5A CN104911655A (en) 2015-06-17 2015-06-17 Electroplating solution with excellent performance

Publications (1)

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CN104911655A true CN104911655A (en) 2015-09-16

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929889A (en) * 2017-05-09 2017-07-07 句容市博远电子有限公司 A kind of cyanideless electro-plating liquid and preparation method thereof
CN107687011A (en) * 2017-07-14 2018-02-13 成都联利达五金制品有限公司 A kind of sulphite electroplate liquid
CN114108041A (en) * 2021-12-20 2022-03-01 太仓市惠得利弹簧有限公司 Spring surface oxidation resistance treatment process

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929889A (en) * 2017-05-09 2017-07-07 句容市博远电子有限公司 A kind of cyanideless electro-plating liquid and preparation method thereof
CN107687011A (en) * 2017-07-14 2018-02-13 成都联利达五金制品有限公司 A kind of sulphite electroplate liquid
CN114108041A (en) * 2021-12-20 2022-03-01 太仓市惠得利弹簧有限公司 Spring surface oxidation resistance treatment process

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Application publication date: 20150916