CN105524542A - Antistatic floor paint - Google Patents
Antistatic floor paint Download PDFInfo
- Publication number
- CN105524542A CN105524542A CN201510485299.9A CN201510485299A CN105524542A CN 105524542 A CN105524542 A CN 105524542A CN 201510485299 A CN201510485299 A CN 201510485299A CN 105524542 A CN105524542 A CN 105524542A
- Authority
- CN
- China
- Prior art keywords
- parts
- floor paint
- dioxythiophene
- hard floor
- antistatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- -1 poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims abstract description 19
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 9
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 8
- 229920002050 silicone resin Polymers 0.000 claims abstract description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 12
- 230000004048 modification Effects 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 238000002834 transmittance Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 33
- 239000011248 coating agent Substances 0.000 description 32
- 239000011231 conductive filler Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 230000002045 lasting effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 206010009866 Cold sweat Diseases 0.000 description 3
- 238000004500 asepsis Methods 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- 238000009288 screen filtration Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
The invention relates to antistatic floor paint. The antistatic floor paint is prepared from modified poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), aromatic polyurethane acrylate, organic silicone resin, dimethylaminoethyl acrylate, a diluent, a leveling agent, graphene, magnesium chloride, nanometer aluminum powder and organic bentonite. After film formation and curing, the antistatic floor paint film has self-assembling characteristics and can be freely spread on a base so that a high efficiency conductive network is constructed. The antistatic floor paint film has high light transmittance, high conductivity and stability and has a wide application prospect.
Description
Technical field
The invention belongs to coating preparation field, be specifically related to a kind of hard floor paint possessing antistatic property.
Background technology
Electrostatic is a kind of phenomenon of the accumulation due to generations such as contact or frictions, in daily life, because weather, environment, physical influence can produce electrostatic, and the existence of electrostatic can bring harm to metal device, even cause stability to decline and occur the defects such as instrument failure, or there is the serious harms such as burning or blast in metallic oil pipeline etc.
Antistatic coating is the functional coating having conduction and get rid of accumulate static charge ability.Antistatic coating develops with modern science and technology, about has the developing history of over half a century so far.As far back as 1948, the U.S. discloses made the patent of conductive resin by silver and epoxy resin, this be the earliest disclosed in electrically conducting coating.The 1950's, Japan started the Antistatic Paint that production is master with silver system and carbon.The sixties in 20th century American and Britain, Deng state develops antistatic coating in succession.The eighties in 20th century external antistatic technique and electric-heating coatings technology obtain develop rapidly, China also begins one's study in the 1950's and applies antistatic coating.
Antistatic coating is divided into addition type and eigenmode two class, and eigenmode antistatic coating technology is still immature, and therefore a large amount of antistatic coating used is generally addition type coating at present.Addition type antistatic coating is in nonconducting binder resin, add the function that certain conductive filler material realizes static conductive, only has the volume fraction of conductive filler material to reach certain degree and could form conductive network or path, embody the character of conduction.Conventional conductive filler material has: carbonaceous material (carbon black, graphite etc.), metal-powder (silver powder, copper powder, nickel powder etc.), metal oxide semiconductor (stannic oxide, ferric oxide, zinc oxide), conducting nanoparticles and anti-electrostatic auxiliary agent etc.Wherein metal-powder density is large, and forming conductive path needs larger volume fraction, and top layer is oxidizable, can reduce and even lose electroconductibility, and corrosion-resistant, thus affect other performances of coating, therefore metal-powder is subject to a definite limitation as the application of conductive filler material; Static inhibitor temperature tolerance, water tolerance, oil-proofness, erosion resistance, poor durability, antistatic property is unstable; Early stage antistatic coating generally adopts carbonaceous material as conductive filler material, black conductive graphite and carbon black dispersion poor, goods color is black, is not easy to be modulated to other more shallow colors; Along with the development of science and technology, engender the novel conductive fillers such as metal oxide semiconductor and nanometer conductive powder, and applied in antistatic coating, this kind of material color is shallow, is easy to toning, has enriched the colour system of antistatic coating, but addition is large when this kind of material is used alone, dispersion stabilization is poor, can affect coating and and the performance of coating, therefore general and carbonaceous material with the use of.Occurred in recent years using electro-conductive fiber as the antistatic coating of conductive filler material, because electro-conductive fiber diameter is little, length-to-diameter ratio is large, only needs the electro-conductive fiber of seldom amount just can form the network of conduction in the coating, can reduce the impact on other performances of coating.
Summary of the invention
The object of the invention is the many defects solving antistatic coating in prior art, through a large amount of creative work, change its raw material composition and formula, a kind of formulation for coating material with antistatic property is provided, compared with prior art, high-effective conductive network can be built, antistatic film is made to have high transmission rate, high conductivity and stability, after also coating curing can being made, there is better mechanical property simultaneously, particularly there is the feature of activeness and quietness effect and high-wearing feature, make it have better antistatic wearing quality.
To achieve these goals, the hard floor paint that the present invention has an antistatic property is made up of the material of following weight parts:
Modification gathers (3,4-rthylene dioxythiophene)-polystyrolsulfon acid 5-8 part, aromatic urethane acrylate 15-20 part, silicone resin 10-13 part, dimethylaminoethyl acrylate 10-15 part, thinner 45-50 part, flow agent 0.5-0.8 part, Graphene 15-20 part, magnesium chloride 5-7 part, nano-silver powder 5-7 part, organobentonite 0.5-0.8 part.
The preparation method of poly-(the 3,4-rthylene dioxythiophene)-polystyrolsulfon acid of described modification is as follows:
Be under the condition of 35 DEG C in temperature, by sulfonated graphene, 3, 4-ethene dioxythiophene and polyoxyethylene glycol disperse in deionized water, the concentration making contained polyoxyethylene glycol in the mixed system of formation is 0.05wt%, and sulfonated graphene, 3, 4-ethene dioxythiophene, the mass ratio of polyoxyethylene glycol is 2:3:0.1, again the pH value of this mixed system is adjusted to 4.5, and be uniformly mixed with the speed of 500 turns/min, add oxygenant and catalyzer simultaneously, wherein oxygenant and 3, the mass ratio of 4-ethene dioxythiophene is 1:2, catalyzer and 3, the mass ratio 0.01:1 of 4-ethene dioxythiophene, the 10-72h of Keep agitation reaction subsequently, remove the foreign ion in reaction product mixture afterwards, obtain,
Described thinner is: water: Virahol: ethanol (volume ratio)=1:7:1;
Described flow agent is: polydimethylsiloxane
By modification poly-(3,4-ethene dioxythiophene)-polystyrolsulfon acid high speed dispersor high speed shear dispersion, rotating speed 1000 turns/min, stir 60min, successively aromatic urethane acrylate, silicone resin, dimethylaminoethyl acrylate, thinner, flow agent, Graphene, magnesium chloride, nano-silver powder, organobentonite are added and be wherein uniformly mixed, stir 15-60min, after 200 order filter screen filtration, to obtain final product.
The present invention adopts Graphene anticorrosion, has good acting in conjunction with photocuring system, and effect stability, action effective is long;
The present invention adopts nano-silver powder and nano silver antimicrobials combined action, has stronger antibacterial effect, and the time length is long, has good consistency with photocuring system;
Poly-(the 3,4-rthylene dioxythiophene)-polystyrolsulfon acid of modification prepared by the present invention can not only meet anlistatig requirement, and has good consistency with photocuring system, dilution oligopolymer, regulation system viscosity.
Mutually coordinate between each component material of the present invention, for the applicant is through large change of variable condition, parameter, through single factor experiment, factorial experiment obtains, the application's operating parameters is that contriver obtains through creative work operation, after its antistatic coating film forming solidification prepared, there is self-assembly characteristic, can freely spread in substrate, and build high-effective conductive network, antistatic film is made to have high transmission rate, high conductivity and stability, after also coating curing can being made, there is better mechanical property simultaneously, particularly there is the feature of activeness and quietness effect and high-wearing feature, make it have better antistatic wearing quality.
Embodiment
Embodiment 1
Have a hard floor paint for antistatic property, it is made up of the material of following weight parts:
Modification gathers (3,4-rthylene dioxythiophene)-polystyrolsulfon acid 5 parts, aromatic urethane acrylate 15 parts, silicone resin 10 parts, dimethylaminoethyl acrylate 10 parts, thinner 45 parts, flow agent 0.5 part, Graphene 15 parts, 5 parts, magnesium chloride, nano-silver powder 5 parts, organobentonite 0.5 part.
The preparation method of poly-(the 3,4-rthylene dioxythiophene)-polystyrolsulfon acid of described modification is as follows:
Be under the condition of 35 DEG C in temperature, by sulfonated graphene, 3, 4-ethene dioxythiophene and polyoxyethylene glycol disperse in deionized water, the concentration making contained polyoxyethylene glycol in the mixed system of formation is 0.05wt%, and sulfonated graphene, 3, 4-ethene dioxythiophene, the mass ratio of polyoxyethylene glycol is 2:3:0.1, again the pH value of this mixed system is adjusted to 4.5, and be uniformly mixed with the speed of 500 turns/min, add oxygenant and catalyzer simultaneously, wherein oxygenant and 3, the mass ratio of 4-ethene dioxythiophene is 1:2, catalyzer and 3, the mass ratio 0.01:1 of 4-ethene dioxythiophene, the 60h of Keep agitation reaction subsequently, remove the foreign ion in reaction product mixture afterwards, obtain, described oxygenant is Sodium Persulfate, described catalyzer is iron trichloride.
Described thinner is: water: Virahol: ethanol (volume ratio)=1:7:1;
Described flow agent is: polydimethylsiloxane;
By modification poly-(3,4-ethene dioxythiophene)-polystyrolsulfon acid high speed dispersor high speed shear dispersion, rotating speed 1000 turns/min, stir 60min, successively aromatic urethane acrylate, silicone resin, dimethylaminoethyl acrylate, thinner, flow agent, Graphene, magnesium chloride, nano-silver powder, organobentonite are added and be wherein uniformly mixed, stir 15min, after 200 filter screen filtration, to obtain final product.
Correlated performance after test coating and film forming, fast setting is dry, environment-protecting asepsis, and be not clamminess, do not return sticky, scratch resistance is wear-resisting; Excellent and the lasting stability of antistatic property, coating surface resistance is 7.2 × 10
5Ω/sq, places coatingsurface resistance 7.5 × 10 after 1 year
5Ω/sq, antistatic property is lasting.Resistance to elevated temperatures 800 DEG C, 6h is intact, coating hardness 5H, adhesion 1 grade, snappiness 1mm, shock strength 50kg.cm.
Embodiment 2
Possess a hard floor paint for antistatic property, it is made up of the material of following weight parts:
Modification gathers (3,4-rthylene dioxythiophene)-polystyrolsulfon acid 8 parts, aromatic urethane acrylate 20 parts, silicone resin 13 parts, dimethylaminoethyl acrylate 15 parts, thinner 50 parts, flow agent 0.8 part, Graphene 20 parts, 7 parts, magnesium chloride, nano-silver powder 7 parts, organobentonite 0.8 part.
The preparation method of poly-(the 3,4-rthylene dioxythiophene)-polystyrolsulfon acid of described modification is as follows:
Be under the condition of 35 DEG C in temperature, by sulfonated graphene, 3, 4-ethene dioxythiophene and polyoxyethylene glycol disperse in deionized water, the concentration making contained polyoxyethylene glycol in the mixed system of formation is 0.05wt%, and sulfonated graphene, 3, 4-ethene dioxythiophene, the mass ratio of polyoxyethylene glycol is 2:3:0.1, again the pH value of this mixed system is adjusted to 4.5, and be uniformly mixed with the speed of 500 turns/min, add oxygenant and catalyzer simultaneously, wherein oxygenant and 3, the mass ratio of 4-ethene dioxythiophene is 1:2, catalyzer and 3, the mass ratio 0.01:1 of 4-ethene dioxythiophene, the 72h of Keep agitation reaction subsequently, remove the foreign ion in reaction product mixture afterwards, obtain, described oxygenant is Sodium Persulfate, described catalyzer is iron trichloride.
Described thinner is: water: Virahol: ethanol (volume ratio)=1:7:1;
Described flow agent is: polydimethylsiloxane
By modification poly-(3,4-ethene dioxythiophene)-polystyrolsulfon acid high speed dispersor high speed shear dispersion, rotating speed 1000 turns/min, stir 60min, successively aromatic urethane acrylate, silicone resin, dimethylaminoethyl acrylate, thinner, flow agent, Graphene, magnesium chloride, nano-silver powder, organobentonite are added and be wherein uniformly mixed, stir 60min, after 200 filter screen filtration, to obtain final product.
Correlated performance after test coating and film forming, fast setting is dry, environment-protecting asepsis, and be not clamminess, do not return sticky, scratch resistance is wear-resisting; Excellent and the lasting stability of antistatic property, coating surface resistance is 6.9 × 10
5Ω/sq, places coatingsurface resistance 7.3 × 10 after 1 year
5Ω/sq, antistatic property is lasting.Resistance to elevated temperatures 800 DEG C, 6h is intact, coating hardness 5H, adhesion 1 grade, snappiness 1mm, shock strength 50kg.cm.
Through the inventive method antistatic floor paint, its antistatic property is lasting, high temperature resistant, and fast setting is dry, environment-protecting asepsis, and be not clamminess, do not return sticky, scratch resistance is wear-resisting, has broad application prospects.
Claims (4)
1. possess a hard floor paint for antistatic property, it is characterized in that, described hard floor paint is made up of the material of following weight parts:
Modification gathers (3,4-rthylene dioxythiophene)-polystyrolsulfon acid 8 parts, aromatic urethane acrylate 20 parts, silicone resin 13 parts, dimethylaminoethyl acrylate 15 parts, thinner 50 parts, flow agent 0.8 part, Graphene 20 parts, 7 parts, magnesium chloride, nano-silver powder 7 parts, organobentonite 0.8 part.
2. hard floor paint according to claim 1, is characterized in that:
The preparation method of poly-(the 3,4-rthylene dioxythiophene)-polystyrolsulfon acid of described modification comprises the steps:
Be under the condition of 35 DEG C in temperature, by sulfonated graphene, 3, 4-ethene dioxythiophene and polyoxyethylene glycol disperse in deionized water, the concentration making contained polyoxyethylene glycol in the mixed system of formation is 0.05wt%, and sulfonated graphene, 3, 4-ethene dioxythiophene, the mass ratio of polyoxyethylene glycol is 2:3:0.1, again the pH value of this mixed system is adjusted to 4.5, and be uniformly mixed with the speed of 500 turns/min, add oxygenant and catalyzer simultaneously, wherein oxygenant and 3, the mass ratio of 4-ethene dioxythiophene is 1:2, catalyzer and 3, the mass ratio 0.01:1 of 4-ethene dioxythiophene, the 10-72h of Keep agitation reaction subsequently, obtain.
3. the hard floor paint according to claim 1-2, is characterized in that, the preferred Sodium Persulfate of described oxygenant, the preferred iron trichloride of described catalyzer.
4. the hard floor paint according to claim 1-3, is characterized in that:
Described thinner is: water: Virahol: ethanol=1:7:1(volume ratio);
Described flow agent is: polydimethylsiloxane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510485299.9A CN105524542B (en) | 2015-08-10 | 2015-08-10 | A kind of floor paint for possessing antistatic property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510485299.9A CN105524542B (en) | 2015-08-10 | 2015-08-10 | A kind of floor paint for possessing antistatic property |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105524542A true CN105524542A (en) | 2016-04-27 |
| CN105524542B CN105524542B (en) | 2018-02-23 |
Family
ID=55767079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510485299.9A Active CN105524542B (en) | 2015-08-10 | 2015-08-10 | A kind of floor paint for possessing antistatic property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105524542B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479276A (en) * | 2016-09-30 | 2017-03-08 | 天津宝兴威科技有限公司 | A kind of nano-silver conductive coating |
| CN107163830A (en) * | 2017-07-19 | 2017-09-15 | 安徽三品技术服务有限公司 | A kind of wear-resisting sterilization floor paint |
| CN108676347A (en) * | 2018-05-18 | 2018-10-19 | 许水仙 | A kind of preparation method of the special antistatic agent of polyurethane plastics |
| CN109694640A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of wear-resisting floor wearing floor |
| CN109694598A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of antistatic floor paint |
| CN111171552A (en) * | 2020-02-20 | 2020-05-19 | 上海超碳石墨烯产业技术有限公司 | Graphene flexible conductive composite film and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1996657A1 (en) * | 2006-03-14 | 2008-12-03 | Suh, Kwang Suck | Antistatic coating composition for polarizer films and antistatic polarizer film using the same |
| CN102558772A (en) * | 2011-12-15 | 2012-07-11 | 河海大学 | Poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel and preparation method thereof |
| CN103173108A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Environment-friendly washing-resistant antistatic coating and preparation method thereof |
| CN103788859A (en) * | 2014-01-08 | 2014-05-14 | 华东理工大学 | Antistatic coating for ultraviolet curing and preparation method thereof |
-
2015
- 2015-08-10 CN CN201510485299.9A patent/CN105524542B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1996657A1 (en) * | 2006-03-14 | 2008-12-03 | Suh, Kwang Suck | Antistatic coating composition for polarizer films and antistatic polarizer film using the same |
| CN102558772A (en) * | 2011-12-15 | 2012-07-11 | 河海大学 | Poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel and preparation method thereof |
| CN103173108A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Environment-friendly washing-resistant antistatic coating and preparation method thereof |
| CN103788859A (en) * | 2014-01-08 | 2014-05-14 | 华东理工大学 | Antistatic coating for ultraviolet curing and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479276A (en) * | 2016-09-30 | 2017-03-08 | 天津宝兴威科技有限公司 | A kind of nano-silver conductive coating |
| CN107163830A (en) * | 2017-07-19 | 2017-09-15 | 安徽三品技术服务有限公司 | A kind of wear-resisting sterilization floor paint |
| CN107163830B (en) * | 2017-07-19 | 2019-04-02 | 安徽三品技术服务有限公司 | A kind of wear-resisting sterilization floor paint |
| CN109694640A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of wear-resisting floor wearing floor |
| CN109694598A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of antistatic floor paint |
| CN108676347A (en) * | 2018-05-18 | 2018-10-19 | 许水仙 | A kind of preparation method of the special antistatic agent of polyurethane plastics |
| CN111171552A (en) * | 2020-02-20 | 2020-05-19 | 上海超碳石墨烯产业技术有限公司 | Graphene flexible conductive composite film and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105524542B (en) | 2018-02-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105524542A (en) | Antistatic floor paint | |
| US10138382B2 (en) | Formulations comprising metal nanowires and PEDOT | |
| JP2013035966A (en) | Electroconductive coating | |
| TWI712661B (en) | Conductive paste and conductive film formed by using it | |
| CN105505186A (en) | Antistatic paint | |
| JP2011124029A (en) | Transparent conductive film and its manufacturing method | |
| CN111548708A (en) | Conductive polymer composite and conductive polymer composition | |
| CN106147563A (en) | A kind of preparation method of polypyrrole/attapulgite electrically-conducting paint | |
| TWI570477B (en) | Organic conductive film | |
| CN105505187A (en) | Preparation technology of antistatic wall paint | |
| CN108342113A (en) | A kind of aqueous antistatic coating and preparation method thereof | |
| CN105505188A (en) | Noise-elimination antirust paint for communication machine room and preparation method thereof | |
| CN105331275A (en) | Closed low-voltage distribution box | |
| KR101564587B1 (en) | A composition comprising PEDOT/PSS and fluorinated polymer and a transparent electrode film using the same | |
| KR100726167B1 (en) | Method for Preparing Transparent Electrode Using Gold Nanoparticles, and Transparent Electrode Obtained by the Method | |
| KR20130020608A (en) | Organic conductive film | |
| JP2005314538A (en) | Conductive fine particle and method for producing the same | |
| CN114283964A (en) | Conductive silver paste and preparation method thereof | |
| CN105368295A (en) | Indoor distribution box | |
| EP3170188B1 (en) | Polymer thick film silver conductor with inverted cure profile behavior | |
| CN104151797A (en) | Antistatic anti-scratch PET | |
| CN105505189A (en) | Novel power distribution cabinet | |
| KR20220164714A (en) | Conductive polymer composition, substrate, and method for manufacturing the substrate | |
| JP2006182958A (en) | Conductive particulate and method for producing the same | |
| JP2021105072A (en) | Method for manufacturing high conductive composite, method for manufacturing aqueous dispersion of high conductive composite, method for manufacturing organic solvent dispersion of high conductive composite, conductive film and method for manufacturing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191216 Address after: 225200, No. nine, Zhang Xing Town, Jiangdu District, Jiangsu, Yangzhou Patentee after: JIANGSU JINLING SPECIAL PAINT Co.,Ltd. Address before: 276001 No. 130, Lu Shan Road, Lanshan District, Shandong, Linyi Co-patentee before: State Grid Corporation of China Patentee before: LINYI POWER SUPPLY COMPANY OF STATE GRID SHANDONG ELECTRIC POWER COMPANY Co-patentee before: STATE GRID SHANDONG FEIXIAN POWER SUPPLY Co. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221109 Address after: 214000 Dushan village, Guanlin Town, Yixing City, Wuxi City, Jiangsu Province Patentee after: Jiangsu Zhongren Paint Co.,Ltd. Address before: 225200 No.9 bridge, Zhanggang, Xiannu Town, Jiangdu District, Yangzhou City, Jiangsu Province Patentee before: JIANGSU JINLING SPECIAL PAINT Co.,Ltd. |