CN105524542B - A kind of floor paint for possessing antistatic property - Google Patents
A kind of floor paint for possessing antistatic property Download PDFInfo
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- CN105524542B CN105524542B CN201510485299.9A CN201510485299A CN105524542B CN 105524542 B CN105524542 B CN 105524542B CN 201510485299 A CN201510485299 A CN 201510485299A CN 105524542 B CN105524542 B CN 105524542B
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- 239000003973 paint Substances 0.000 title claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 11
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 8
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 11
- 239000007800 oxidant agent Substances 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical group [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 4
- 229930192474 thiophene Natural products 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 11
- -1 organic siliconresin Chemical compound 0.000 abstract description 6
- 230000005540 biological transmission Effects 0.000 abstract description 3
- 238000001338 self-assembly Methods 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 34
- 239000011248 coating agent Substances 0.000 description 30
- 239000011231 conductive filler Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000001723 curing Methods 0.000 description 5
- 230000002045 lasting effect Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 241000790917 Dioxys <bee> Species 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- 238000009288 screen filtration Methods 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Floor Finish (AREA)
Abstract
The present invention relates to a kind of floor paint for possessing antistatic property, and it is poly- by being modified（3,4 ethene dioxythiophenes）Polystyrolsulfon acid, aromatic urethane acrylate, organic siliconresin, dimethylaminoethyl acrylate, diluent, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite are prepared, its antistatic floor prepared has self assembly characteristic after painting film solidification, freely it can spread in substrate, and build high-effective conductive network, make antistatic film that there is high transmission rate, high conductivity and stability, have broad application prospects.
Description
Technical field
The invention belongs to coating preparation field, and in particular to a kind of floor paint for possessing antistatic property.
Background technology
Electrostatic is a kind of phenomenon of the accumulation caused by contacting or rubbing etc., in daily life, due to weather, ring
Border, physical influence can produce electrostatic, and the presence of electrostatic can bring harm to metal device, even result in stability and decline appearance
The defects of instrument failure, or the generation such as metallic oil pipeline burning or blast etc. seriously endanger.
Antistatic coating is with conductive and exclusion accumulation electrostatic charge ability functional coating.Antistatic coating is with existing
In generation, is scientific and technical and develops, and there are about the developing history of over half a century so far.Early in 1948, the U.S. was disclosed silver and epoxy
The patent of conducting resinl is made in resin, and this is earliest disclosed electrically-conducting paint.The 1950s Japan start production with silver system and
Anti-static coatings based on carbon system.The 1960s American and Britain, Deng states develop antistatic coating in succession.80 years 20th century
Developed rapidly for external antistatic technique and electric-heating coatings technology, China also begins one's study and applied in the 1950s
Antistatic coating.
Antistatic coating is divided into addition type and the class of Intrinsical two, and Intrinsical antistatic coating technology is still immature, therefore mesh
The preceding antistatic coating largely used is generally addition type coating.Addition type antistatic coating is in nonconducting binder resin
The function that certain conductive filler realizes static conductive is added, the volume fraction of only conductive filler reaches certain degree could shape
Into conductive network or path, conductive property is embodied.Conventional conductive filler has：Carbon-based material (carbon black, graphite etc.), metal
Powder (silver powder, copper powder, nickel powder etc.), metal oxide semiconductor (tin oxide, iron oxide, zinc oxide), conducting nanoparticles and
Antistatic auxiliary agent etc..Wherein metal dust density is big, and forming conductive path needs larger volume fraction, and top layer is oxidizable, meeting
Reduce and even lose electric conductivity, and corrosion-resistant, so as to influence other performances of coating, therefore metal dust is as conductive
The application of filler is by a definite limitation；Antistatic additive temperature tolerance, water resistance, oil resistivity, corrosion resistance, poor durability, it is antistatic
Performance is unstable；Early stage antistatic coating is typically using carbon-based material as conductive filler, black conductive graphite and carbon black dispersion
Property is poor, and product color is black, it is not easy to is modulated to other shallower colors；With the development of science and technology, semiconductor gold is engendered
Belong to the novel conductive fillers such as oxide and nanometer conductive powder, and applied in antistatic coating, this kind of material color is shallow, easily
In toning, enrich the colour system of antistatic coating, but addition is big when this kind of material is used alone, dispersion stabilization compared with
Difference, can influence coating and and its coating performance, therefore be typically used cooperatively with carbon-based material.Occur in recent years using conductive
Antistatic coating of the fiber as conductive filler, because conductive fiber diameter is small, draw ratio is big, it is only necessary to minimal amount of conductive fiber
The network of conduction can be just formed in the coating, can reduce the influence to other performances of coating.
The content of the invention
Present invention aim to address many defects of antistatic coating in the prior art, by a large amount of creative works,
Change its raw material composition and formula, there is provided a kind of formulation for coating material with antistatic property, compared with prior art, can build
High-effective conductive network, make antistatic film that there is high transmission rate, high conductivity and stability, while can also make to have after curing of coatings
There is more preferable mechanical property, particularly with activeness and quietness effect and the characteristics of high-wearing feature, make it have preferably antistatic
Durability.
To achieve these goals, the floor paint that the present invention has antistatic property is made up of the material of following weight parts：
It is modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid 5-8 parts, aromatic urethane acrylate 15-20
Part, organic siliconresin 10-13 parts, dimethylaminoethyl acrylate 10-15 parts, diluent 45-50 parts, levelling agent 0.5-0.8 parts,
Graphene 15-20 parts, magnesium chloride 5-7 parts, nano-silver powder 5-7 parts, organobentonite 0.5-0.8 parts.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 10-72h, remove afterwards
Foreign ion in reaction product mixture, is produced；
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid is scattered in the shearing of high speed dispersor high speed, turns
1000 turns/min of speed, 60min is stirred, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite, which are added thereto, to be uniformly mixed, stirring
15-60min, after 200 mesh filter screen filtrations, produce.
The present invention uses graphene anti-corrosion, has good collective effect, and an effect stability with photocuring system, during effect
Effect length；
The present invention uses nano-silver powder and nano silver antimicrobials synergy, when having stronger antibacterial effect, and continuing
Between it is long, there is good compatibility with photocuring system；
Modification prepared by the present invention gathers（3,4- ethene dioxythiophenes）- polystyrolsulfon acid can not only meet anlistatig
It is required that and there is good compatibility, dilution oligomer, regulation system viscosity with photocuring system.
It is mutually coordinated between each component material of the present invention, pass through big change of variable condition, parameter, by Dan Yin for the applicant
Son experiment, factorial experiment obtain, and the application operating parameter is that inventor obtains through creative work operation, and it is prepared anti-quiet
There is self assembly characteristic after the solidification of electrocoating paint film forming, freely can spread in substrate, and build high-effective conductive network, make to resist
Electrostatic film has high transmission rate, high conductivity and stability, while can also make have more preferable mechanical property after curing of coatings,
Particularly there is the characteristics of activeness and quietness effect and high-wearing feature, make it have more preferable antistatic durability.
Embodiment
Embodiment 1
A kind of floor paint with antistatic property, it is made up of the material of following weight parts：
It is modified poly-（3,4- ethene dioxythiophenes）5 parts of-polystyrolsulfon acid, 15 parts of aromatic urethane acrylate, have
10 parts of machine silicones, 10 parts of dimethylaminoethyl acrylate, 45 parts of diluent, 0.5 part of levelling agent, 15 parts of graphene, magnesium chloride 5
Part, 5 parts of nano-silver powder, 0.5 part of organobentonite.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 60h, remove mixing afterwards
Foreign ion in reaction product, is produced, and the oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer；
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid is scattered in the shearing of high speed dispersor high speed, turns
1000 turns/min of speed, 60min is stirred, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite, which are added thereto, to be uniformly mixed, stirring
15min, after 200 filter screen filtrations, produce.
Correlated performance after coating and film forming is tested, rapid curing is dried, environment-protecting and non-poisonous, not tacky, do not return viscous, and scratch resistance is resistance to
Mill；Antistatic property is excellent and lasting stability, coating surface resistance are 7.2 × 105Ω/sq, coating surface electricity after placing 1 year
Resistance 7.5 × 105Ω/sq, antistatic property are lasting.800 DEG C of resistance to elevated temperatures, 6h is intact, coating hardness 5H, and adhesion 1 grade is soft
Toughness 1mm, impact strength 50kg.cm.
Embodiment 2
A kind of floor paint for possessing antistatic property, it is made up of the material of following weight parts：
It is modified poly-（3,4- ethene dioxythiophenes）8 parts of-polystyrolsulfon acid, 20 parts of aromatic urethane acrylate, have
13 parts of machine silicones, 15 parts of dimethylaminoethyl acrylate, 50 parts of diluent, 0.8 part of levelling agent, 20 parts of graphene, magnesium chloride 7
Part, 7 parts of nano-silver powder, 0.8 part of organobentonite.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 72h, remove mixing afterwards
Foreign ion in reaction product, is produced, and the oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid is scattered in the shearing of high speed dispersor high speed, turns
1000 turns/min of speed, 60min is stirred, successively by aromatic urethane acrylate, organic siliconresin, acrylate second
Ester, diluent, levelling agent, graphene, magnesium chloride, nano-silver powder, organobentonite, which are added thereto, to be uniformly mixed, stirring
60min, after 200 filter screen filtrations, produce.
Correlated performance after coating and film forming is tested, rapid curing is dried, environment-protecting and non-poisonous, not tacky, do not return viscous, and scratch resistance is resistance to
Mill；Antistatic property is excellent and lasting stability, coating surface resistance are 6.9 × 105Ω/sq, coating surface electricity after placing 1 year
Resistance 7.3 × 105Ω/sq, antistatic property are lasting.800 DEG C of resistance to elevated temperatures, 6h is intact, coating hardness 5H, and adhesion 1 grade is soft
Toughness 1mm, impact strength 50kg.cm.
By the inventive method antistatic floor paint, its antistatic property is lasting, high temperature resistant, and rapid curing is dried, environmental protection
Nontoxic, not tacky, do not return viscous, scratch resistance is wear-resisting, has broad application prospects.
Claims (1)
1. a kind of floor paint for possessing antistatic property, it is characterised in that the floor paint is made up of the material of following weight parts：
Polymer-modified 8 parts, 20 parts of aromatic urethane acrylate, 13 parts of organic siliconresin, dimethylaminoethyl acrylate
15 parts, 50 parts of diluent, 0.8 part of levelling agent, 20 parts of graphene, 7 parts of magnesium chloride, 7 parts of nano-silver powder, 0.8 part of organobentonite；
The polymer-modified preparation method comprises the following steps：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in deionization
In water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethylene dioxies
Thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/min's
Speed is stirred, while adds oxidant and catalyst, and the mass ratio of wherein oxidant and 3,4-rthylene dioxythiophene is 1:
2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 10-72h, produce；
The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride；
The diluent is：Water：Isopropanol：Ethanol=1:7:1, the ratio is volume ratio；
The levelling agent is：Dimethyl silicone polymer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510485299.9A CN105524542B (en) | 2015-08-10 | 2015-08-10 | A kind of floor paint for possessing antistatic property |
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| CN201510485299.9A CN105524542B (en) | 2015-08-10 | 2015-08-10 | A kind of floor paint for possessing antistatic property |
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| CN105524542A CN105524542A (en) | 2016-04-27 |
| CN105524542B true CN105524542B (en) | 2018-02-23 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479276A (en) * | 2016-09-30 | 2017-03-08 | 天津宝兴威科技有限公司 | A kind of nano-silver conductive coating |
| CN107163830B (en) * | 2017-07-19 | 2019-04-02 | 安徽三品技术服务有限公司 | A kind of wear-resisting sterilization floor paint |
| CN109694640A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of wear-resisting floor wearing floor |
| CN109694598A (en) * | 2017-10-24 | 2019-04-30 | 江苏凤凰木业有限公司 | A kind of antistatic floor paint |
| CN108676347A (en) * | 2018-05-18 | 2018-10-19 | 许水仙 | A kind of preparation method of the special antistatic agent of polyurethane plastics |
| CN111171552A (en) * | 2020-02-20 | 2020-05-19 | 上海超碳石墨烯产业技术有限公司 | Graphene flexible conductive composite film and preparation method thereof |
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| CN103173108A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Environment-friendly washing-resistant antistatic coating and preparation method thereof |
| CN103788859A (en) * | 2014-01-08 | 2014-05-14 | 华东理工大学 | Antistatic coating for ultraviolet curing and preparation method thereof |
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2015
- 2015-08-10 CN CN201510485299.9A patent/CN105524542B/en active Active
Patent Citations (4)
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|---|---|---|---|---|
| EP1996657A1 (en) * | 2006-03-14 | 2008-12-03 | Suh, Kwang Suck | Antistatic coating composition for polarizer films and antistatic polarizer film using the same |
| CN102558772A (en) * | 2011-12-15 | 2012-07-11 | 河海大学 | Poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel and preparation method thereof |
| CN103173108A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Environment-friendly washing-resistant antistatic coating and preparation method thereof |
| CN103788859A (en) * | 2014-01-08 | 2014-05-14 | 华东理工大学 | Antistatic coating for ultraviolet curing and preparation method thereof |
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