CN105507030A - Pure cotton cloth dyeing method - Google Patents

Pure cotton cloth dyeing method Download PDF

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Publication number
CN105507030A
CN105507030A CN201610066333.3A CN201610066333A CN105507030A CN 105507030 A CN105507030 A CN 105507030A CN 201610066333 A CN201610066333 A CN 201610066333A CN 105507030 A CN105507030 A CN 105507030A
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Prior art keywords
colouring method
textile cotton
dyeing
minutes
textile
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CN201610066333.3A
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不公告发明人
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Priority to CN201610066333.3A priority Critical patent/CN105507030A/en
Publication of CN105507030A publication Critical patent/CN105507030A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/6008Natural or regenerated cellulose using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/66Natural or regenerated cellulose using reactive dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a pure cotton cloth dyeing method. The dyeing method comprises the steps of dyeing, primary water washing, soaping, secondary water washing, softening, dehydrating, scutching and drying, and is characterized in that a dye used in the step of dyeing is selected from neutral fixation reactive dye and acid dye series, the use amount of the dye is 6-12 (%, o.w.f), the use amount of salt is 40-60 (g/L), and the pH of an adopted buffer solution is adjusted to be 7. Through adoption of the dyeing method, a dyed product is good in effect, high in quality, full in color, washable, and free of fading, so that the dryness fastness and the water washing fastness of cotton cloth are greatly improved.

Description

A kind of textile cotton colouring method
Technical field
The present invention relates to Colour Difference field, particularly relate to a kind of textile cotton colouring method.
Background technology
Pure cotton fabric dyeing is main uses general REACTIVE DYES and reducing dye.REACTIVE DYES has the features such as lovely luster, wet fastness is excellent, applicability is strong, easy to use and with low cost, is suitable in dye.Reducing dye has the advantages that chromatogram is complete, fastness is high, is suitable for light color in dye.COLOR FASTNESS is one of important indicator weighing textiles inherent quality, and textiles, taking the different in kind of suffered external influence in process, just has various corresponding COLOR FASTNESS, such as Exposure to Sunlight, soap, weather, friction, sweat stain, flatiron, chlorine drift COLOR FASTNESS etc.
Although reducing dye pigment pad dyeing and arising in reactive pad-dry-pad-steaming dyeing are maturation process all already, but in production practices, due to the reason of the aspect such as dyestuff or technology controlling and process, still the underproof problem of a certain COLOR FASTNESS of final finished product can be encountered, reducing dye is mainly manifested on the fastness to chlorine-bleaching of cobalt blue and the wet ironing fastness of M ash, publication number is that the new cold rolling dyeing side of the one of 104264518A have employed reducing dye, but in dyeing course, employ alkali lye, add the generation of sewage.General REACTIVE DYES is mainly manifested on the fastness to light of middle light coloured fabrics and the crock fastness of fabric; Publication number is a kind of REACTIVE DYES padding auxiliary agent of 104372691A and its preparation method and application, employ REACTIVE DYES, but also added a lot of auxiliary agent and complex process simultaneously, in general REACTIVE DYES in textile technique, dry wet fastness and washing fastness, be difficult to the satisfaction reaching consumer, therefore, how choosing suitable dyestuff and optimizing dyeing is the key factor determining Color.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of textile cotton colouring method is provided.Adopt this colouring method, dyeing product is not only effective, and quality is high, full color fastness to washing, substantially increases dry wet fastness and the washing fastness of cotton.
Object of the present invention is achieved by following scheme:
A kind of textile cotton colouring method, described colouring method comprises: dyeing, first time wash, soap, second time washing, softness, dehydration, open-width, oven dry, it is characterized in that: the dyestuff adopted in described staining procedure is neutral fixation REACTIVE DYES and ACID DYES series, dye dosage is 6 ~ 12 (%, o.w.f), salt consumption is 40 ~ 60 (g/L), adopts cushioning liquid to regulate pH to be 7;
Described cushioning liquid is Britton-Robinson, Britton-Robinson cushioning liquid is wide area cushioning liquid, and buffering range is comparatively large, has higher buffer capacity;
Levelling agent is also added in described staining procedure, concentration is 1g/L, levelling agent is a kind of textile auxiliary, the dyeing of fabric is made to want even, very effective method uses the levelling agent having slow dye or move dye effect to reach even dyeing effect, not only can make functions of textile fabrics, and can make that it is superior, have more sense of the times, most important to the surcharge improving textiles;
In described staining procedure, dyeing temperature 80 ~ 95 DEG C, 50 ~ 60 minutes time.The higher Color of temperature will be got well, and the economy of comprehensive energy consumption to consider, optimum temperature is 80 ~ 95 DEG C;
The detergent adopted in described soaping steps is anionic or non-ionic cleaning agent, described anionic detergent is one or more mixing in SN-S, FLUIDOLW-100, LOCANITB, ERIOPONR, in described soaping steps, temperature of soaping 80 ~ 95 DEG C, 15 ~ 20 minutes time, detergent concentration is 2g/L;
Described first time washing adopts normal temperature mass-flow to rinse, second time washing employing 50 ~ 60 DEG C of Warm Wash; Rinse with large cold water stream and wash away unreacted dyestuff on cotton as far as possible, improve cotton feel;
The softener adopted in described soft step is organic silicon modified by polyether, softener is a kind of important textile auxiliary, soft finish is the important finishing process in dyeing and printing process, textiles is in process, and after repeatedly processing, feel can become coarse, and general synthetic fabrics is poorer, especially Superfine Fibre Fabric, in order to make fabric have softness, smooth, comfortable feel, just need to arrange it, widely used is at present arrange with softener;
The color-fixing agent added in described staining procedure is MESI-TOLNBS01, consumption is 2 ~ 4 (%, o.w.f), with color-fixing agent process can improve cotton through soaping, washing, spot, water stain, friction after fastness performance, also can be used for the fixation of silk, wool cotton fabric and other fiber.
A kind of textile cotton colouring method of the present invention, has following beneficial effect:
The first, the present invention chooses high efficiency, high fixation rate, the neutral fixation REACTIVE DYES series of high fastness and ACID DYES, not only coloured light symbol sample, and there is dry wet fastness and washing fastness preferably, neutral fixation REACTIVE DYES Series Reactive Dyes can dissolve rapidly in cold water, even if prepare good concentration, without the need to using alkali, also without the need to using urea.
The second, add levelling agent, easily control left, center, right look, favorable reproducibility, has high rinsing fastness and light fastness compared to general REACTIVE DYES.
Three, first step washing adopts large cold water stream to rinse and washes away unreacted dyestuff on cotton as far as possible, improve cotton feel, choose in soft step organic silicon modified by polyether both can not cause arrangement as softener after changing color of textile, the fastness to light of fabric can not be affected again.
Detailed description of the invention
In order to make those skilled in the art person understand technical scheme of the present invention better, below in conjunction with embodiment, technical scheme of the present invention is described in further detail.
Embodiment 1
Fabric: textile cotton to be dyed
The yellow NF-GR6 (%, o.w.f) of dyestuff prescription: Argazol
Salt consumption is 45 (g/L)
Levelling agent 1g/L
Cushioning liquid Britton-Robinson bath raio 1:40
Color fixing agent M ESI-TOLNBS012 (%, o.w.f) bath raio 1:40
Technological process:
(1) dye: room temperature adds levelling agent, add the yellow NF-GR of dyestuff Argazol, adopt normal temperature and pressure overflow dyeing machine, run 10 minutes, salt adds short dye at twice, add follow-up reforwarding row 20 minutes, adopt cushioning liquid Britton-Robinson to regulate pH to be 7, and then 1 ~ 1.5 DEG C/min is warming up to 70 DEG C, continue operation 10 minutes, be warming up to dyeing temperature 85 DEG C again, run 20 minutes, totally 60 minutes time;
(2) first time washing: adopt normal temperature mass-flow to rinse, fully wash away residual unreacted dyestuff;
(3) soap: adopt SN-S detergent, detergent concentration is 2g/L, and 95 DEG C are carried out soaping 15 minutes;
(4) second time washing: adopt 50 DEG C of warm water to carry out multipass flushing;
(5) soft: adding concentration is after the softener softness of the organic silicon modified by polyether of 45g/L, dehydration;
(6) fixation: the color-fixing agent of interpolation is MESI-TOLNBS01, consumption is 2 (%, o.w.f) bath raio 1:40, processes 20 minutes at 50 DEG C;
(7) open-width: the speed of a motor vehicle of open-width is generally 10 ~ 15m/min, the too high meeting of the speed of a motor vehicle causes circular fabric running tension irregular, also easily produces folding line and fine wrinkle;
(8) dry: at 100 DEG C, dry with dryer;
(9) finishing and packing, obtains product, and product physical index test result is in table 1.
Embodiment 2
Fabric: textile cotton to be dyed
The red NF-3B9 (%, o.w.f) of dyestuff prescription: Argazol
Salt consumption is 50 (%, o.w.f)
Levelling agent 1g/L
Cushioning liquid Britton-Robinson bath raio 1:50
Color fixing agent M ESI-TOLNBS012 (%, o.w.f) bath raio 1:50
(1) dye: room temperature adds levelling agent, add the red NF-3B of Argazol, adopt normal temperature and pressure overflow dyeing machine, run 10 minutes, salt adds short dye at twice, add follow-up reforwarding row 15 minutes, adopt cushioning liquid Britton-Robinson to regulate pH to be 7, and then 1 ~ 1.5 DEG C/min is warming up to 80 DEG C, continue operation 10 minutes, be warming up to dyeing temperature 90 DEG C again, run 25 minutes, totally 60 minutes time;
(2) first time washing: adopt normal temperature mass-flow to rinse, fully wash away residual unreacted dyestuff;
(3) soap: adopt FLUIDOLW-100 detergent, 95 DEG C are carried out soaping 20 minutes;
(4) second time washing: adopt 50 DEG C of warm water to carry out multipass flushing;
(5) soft: adding concentration is after the softener softness of the organic silicon modified by polyether of 40g/L, dehydration;
(6) fixation: the color-fixing agent of interpolation is MESI-TOLNBS01, consumption is 2 (%, o.w.f) bath raio 1:50, processes 20 minutes at 50 DEG C;
(7) open-width: the speed of a motor vehicle of open-width is generally 10 ~ 15m/min, the too high meeting of the speed of a motor vehicle causes circular fabric running tension irregular, also easily produces folding line and fine wrinkle;
(8) dry: at 100 DEG C, dry with dryer;
(9) finishing and packing, obtains product, and product physical index test result is in table 1.
Embodiment 3
Fabric: textile cotton to be dyed
The blue NF-BG12 (%, o.w.f) of dyestuff prescription: Argazol
Salt consumption is 55 (%, o.w.f)
Levelling agent 1g/L
Cushioning liquid Britton-Robinson bath raio 1:50
Color fixing agent M ESI-TOLNBS013 (%, o.w.f) bath raio 1:50
Technological process:
(1) dye: room temperature adds levelling agent, add the blue NF-BG of Argazol, adopt normal temperature and pressure overflow dyeing machine, run 10 minutes, salt adds short dye at twice, add follow-up reforwarding row 10 minutes, adopt cushioning liquid Britton-Robinson to regulate pH to be 7, and then 1 ~ 1.5 DEG C/min is warming up to 75 DEG C, continue operation 10 minutes, be warming up to dyeing temperature 90 DEG C again, run 30 minutes, totally 60 minutes time;
(2) first time washing: adopt normal temperature mass-flow to rinse, fully wash away residual unreacted dyestuff;
(3) soap: adopt SN-S detergent, 95 DEG C are carried out soaping 20 minutes;
(4) second time washing: adopt 50 DEG C of warm water to carry out multipass flushing;
(5) soft: adding concentration is after the softener softness of the organic silicon modified by polyether of 40g/L, dehydration;
(6) fixation: the color-fixing agent of interpolation is MESI-TOLNBS01, consumption is 3 (%, o.w.f) bath raio 1:50, processes 20 minutes at 50 DEG C;
(7) open-width: the speed of a motor vehicle of open-width is generally 10 ~ 15m/min, the too high meeting of the speed of a motor vehicle causes circular fabric running tension irregular, also easily produces folding line and fine wrinkle;
(8) dry: at 100 DEG C, dry with dryer;
(9) finishing and packing, obtains product, and product physical index test result is in table 1.
Embodiment 4
Fabric: textile cotton to be dyed
Dyestuff prescription: neutral dark yellow GRL8 (%, o.w.f)
Salt consumption is 60 (%, o.w.f)
Levelling agent 1g/L
Cushioning liquid Britton-Robinson bath raio 1:45
Color fixing agent M ESI-TOLNBS012 (%, o.w.f) bath raio 1:45
Technological process:
(1) dye: room temperature adds levelling agent, add neutral dark yellow GRL, adopt normal temperature and pressure overflow dyeing machine, run 15 minutes, salt adds short dye at twice, add follow-up reforwarding row 10 minutes, adopt cushioning liquid Britton-Robinson to regulate pH to be 7, and then 1 ~ 1.5 DEG C/min is warming up to 80 DEG C, continue operation 10 minutes, be warming up to dyeing temperature 95 DEG C again, run 25 minutes, totally 55 minutes time;
(2) first time washing: adopt normal temperature mass-flow to rinse, fully wash away residual unreacted dyestuff;
(3) soap: adopt SN-S detergent, 95 DEG C are carried out soaping 15 minutes;
(4) second time washing: adopt 50 DEG C of warm water to carry out multipass flushing;
(5) soft: adding concentration is after the softener softness of the organic silicon modified by polyether of 40g/L, dehydration;
(6) fixation: the color-fixing agent of interpolation is MESI-TOLNBS01, consumption is 2 (%, o.w.f) bath raio 1:45, processes 20 minutes at 50 DEG C;
(7) open-width: the speed of a motor vehicle of open-width is generally 10 ~ 15m/min, the too high meeting of the speed of a motor vehicle causes circular fabric running tension irregular, also easily produces folding line and fine wrinkle;
(8) dry: at 100 DEG C, dry with dryer;
(9) finishing and packing, obtains product, and product physical index test result is in table 1.
Embodiment 5
Fabric: textile cotton to be dyed
Dyestuff prescription: weak acid red 10B10 (%, o.w.f)
Salt consumption is 55 (%, o.w.f)
Levelling agent 1g/L
Cushioning liquid Britton-Robinson bath raio 1:50
Color fixing agent M ESI-TOLNBS014 (%, o.w.f) bath raio 1:50
Technological process:
(1) dye: room temperature adds levelling agent, add weak acid red 10B, adopt normal temperature and pressure overflow dyeing machine, run 15 minutes, salt adds short dye at twice, add follow-up reforwarding row 10 minutes, adopt cushioning liquid Britton-Robinson to regulate pH to be 7, and then 1 ~ 1.5 DEG C/min is warming up to 80 DEG C, continue operation 10 minutes, be warming up to dyeing temperature 95 DEG C again, run 25 minutes, totally 60 minutes time;
(2) first time washing: adopt normal temperature mass-flow to rinse, fully wash away residual unreacted dyestuff;
(3) soap: adopt SN-S detergent, 95 DEG C are carried out soaping 15 minutes;
(4) second time washing: adopt 50 DEG C of warm water to carry out multipass flushing;
(5) soft: adding concentration is after the softener softness of the organic silicon modified by polyether of 40g/L, dehydration;
(6) fixation: the color-fixing agent of interpolation is MESI-TOLNBS01, consumption is 4 (%, o.w.f) bath raio 1:50, processes 20 minutes at 50 DEG C;
(7) open-width: the speed of a motor vehicle of open-width is generally 10 ~ 15m/min, the too high meeting of the speed of a motor vehicle causes circular fabric running tension irregular, also easily produces folding line and fine wrinkle;
(8) dry: at 100 DEG C, dry with dryer;
(9) finishing and packing, obtains product, and product physical index test result is in table 1.
Table 1 five kinds of color finished product physical index test results
Above data show, the cotton using above-mentioned neutral fixation REACTIVE DYES and ACID DYES to dye, all has comparatively ideal physical index, and also can reach after the washing of 30 times and wash rank preferably.
The above, be only preferred embodiment of the present invention, not does any pro forma restriction to the present invention; The those of ordinary skill of all industry all can shown in by specification and the above and implement the present invention swimmingly; But all those skilled in the art are not departing within the scope of technical solution of the present invention, disclosed above technology contents can be utilized and make a little change, modify with differentiation equivalent variations, be Equivalent embodiments of the present invention; Meanwhile, all according to substantial technological of the present invention to the change of any equivalent variations that above embodiment is done, modify and differentiation etc., within the protection domain all still belonging to technical scheme of the present invention.

Claims (10)

1. a textile cotton colouring method, described colouring method comprises: dyeing, first time wash, soap, second time washing, softness, dehydration, open-width, oven dry, it is characterized in that: the dyestuff adopted in described staining procedure is neutral fixation REACTIVE DYES and ACID DYES series, dye dosage is 6 ~ 12 (%, o.w.f), salt consumption is 40 ~ 60 (g/L), adopts cushioning liquid to regulate pH to be 7.
2. textile cotton colouring method according to claim 1, is characterized in that: described cushioning liquid is Britton-Robinson.
3. textile cotton colouring method according to claim 1, is characterized in that: in described staining procedure, also added levelling agent, and concentration is 1g/L.
4. the textile cotton colouring method according to claim 1 or 2 or 3, is characterized in that: in described staining procedure, dyeing temperature 80 ~ 95 DEG C, 50 ~ 60 minutes time.
5. textile cotton colouring method according to claim 1, is characterized in that: the detergent adopted in described soaping steps is anionic or non-ionic cleaning agent.
6. textile cotton colouring method according to claim 5, is characterized in that: described anionic detergent is one or more mixing in SN-S, FLUIDOLW-100, LOCANITB, ERIOPONR.
7. the textile cotton colouring method according to claim 5 or 6, is characterized in that: in described soaping steps, temperature of soaping 80 ~ 95 DEG C, and 15 ~ 20 minutes time, detergent concentration is 2g/L.
8. textile cotton colouring method according to claim 1, is characterized in that: described first time washing adopts normal temperature mass-flow to rinse, second time washing employing 50 ~ 60 DEG C of Warm Wash.
9. textile cotton colouring method according to claim 1, is characterized in that: the softener adopted in described soft step is organic silicon modified by polyether.
10. textile cotton colouring method according to claim 1, is characterized in that: the color-fixing agent added in described staining procedure is MESI-TOLNBS01, and consumption is 2 ~ 4 (%, o.w.f).
CN201610066333.3A 2016-01-29 2016-01-29 Pure cotton cloth dyeing method Pending CN105507030A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486915A (en) * 2018-03-26 2018-09-04 陕西理工大学 A kind of dyeing method of cotton fiber
CN109763362A (en) * 2019-01-02 2019-05-17 鲁泰纺织股份有限公司 A kind of garment dyeing clothes preparation method with uneven effect
CN112144303A (en) * 2020-09-30 2020-12-29 山东轻工职业学院 Printing process of Lafei straw braided fabric

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CN101195952A (en) * 2006-12-06 2008-06-11 丹东优耐特纺织品有限公司 Cotton fibre and blended fabric printing and dyeing method
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486915A (en) * 2018-03-26 2018-09-04 陕西理工大学 A kind of dyeing method of cotton fiber
CN109763362A (en) * 2019-01-02 2019-05-17 鲁泰纺织股份有限公司 A kind of garment dyeing clothes preparation method with uneven effect
CN112144303A (en) * 2020-09-30 2020-12-29 山东轻工职业学院 Printing process of Lafei straw braided fabric

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