CN105505451B - 焦油裂解的装置以及进行焦油裂解的方法 - Google Patents
焦油裂解的装置以及进行焦油裂解的方法 Download PDFInfo
- Publication number
- CN105505451B CN105505451B CN201610005890.4A CN201610005890A CN105505451B CN 105505451 B CN105505451 B CN 105505451B CN 201610005890 A CN201610005890 A CN 201610005890A CN 105505451 B CN105505451 B CN 105505451B
- Authority
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- China
- Prior art keywords
- catalyst
- cracking
- catalytic pyrolysis
- tar
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 238000005336 cracking Methods 0.000 title claims abstract description 163
- 239000011285 coke tar Substances 0.000 title claims abstract description 114
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000003054 catalyst Substances 0.000 claims abstract description 286
- 238000007233 catalytic pyrolysis Methods 0.000 claims abstract description 143
- 238000004227 thermal cracking Methods 0.000 claims abstract description 107
- 230000004913 activation Effects 0.000 claims abstract description 59
- 238000007599 discharging Methods 0.000 claims abstract description 35
- 239000011269 tar Substances 0.000 claims description 125
- 238000012545 processing Methods 0.000 claims description 112
- 238000001994 activation Methods 0.000 claims description 75
- 239000000567 combustion gas Substances 0.000 claims description 50
- 238000000197 pyrolysis Methods 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 38
- 238000009826 distribution Methods 0.000 claims description 28
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 23
- 239000003546 flue gas Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 22
- 239000002737 fuel gas Substances 0.000 claims description 18
- 239000000779 smoke Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 230000002779 inactivation Effects 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 8
- 239000000047 product Substances 0.000 description 45
- 239000000203 mixture Substances 0.000 description 23
- 238000006555 catalytic reaction Methods 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- 229910052799 carbon Inorganic materials 0.000 description 19
- 239000000571 coke Substances 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 230000008859 change Effects 0.000 description 9
- 230000009089 cytolysis Effects 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- 230000003213 activating effect Effects 0.000 description 5
- 229910001882 dioxygen Inorganic materials 0.000 description 5
- 238000002309 gasification Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 238000005235 decoking Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000000415 inactivating effect Effects 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 238000010129 solution processing Methods 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910052609 olivine Inorganic materials 0.000 description 2
- 239000010450 olivine Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
- C10G51/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
- C10G51/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only including only thermal and catalytic cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610005890.4A CN105505451B (zh) | 2016-01-04 | 2016-01-04 | 焦油裂解的装置以及进行焦油裂解的方法 |
Applications Claiming Priority (1)
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---|---|---|---|
CN201610005890.4A CN105505451B (zh) | 2016-01-04 | 2016-01-04 | 焦油裂解的装置以及进行焦油裂解的方法 |
Publications (2)
Publication Number | Publication Date |
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CN105505451A CN105505451A (zh) | 2016-04-20 |
CN105505451B true CN105505451B (zh) | 2017-07-11 |
Family
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CN201610005890.4A Active CN105505451B (zh) | 2016-01-04 | 2016-01-04 | 焦油裂解的装置以及进行焦油裂解的方法 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114317025B (zh) * | 2021-11-30 | 2022-09-16 | 南京林业大学 | 一种焦油热催化裂解装置与催化剂持续气化再生方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1405272A (zh) * | 2001-09-19 | 2003-03-26 | 中国石油化工股份有限公司 | 新型供热方式的裂解炉及用其进行热裂解的方法 |
WO2015128036A1 (en) * | 2014-02-25 | 2015-09-03 | Saudi Basic Industries Corporation | Process for upgrading refinery heavy hydrocarbons to petrochemicals |
CN205328951U (zh) * | 2016-01-04 | 2016-06-22 | 北京神雾环境能源科技集团股份有限公司 | 焦油裂解的装置 |
-
2016
- 2016-01-04 CN CN201610005890.4A patent/CN105505451B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1405272A (zh) * | 2001-09-19 | 2003-03-26 | 中国石油化工股份有限公司 | 新型供热方式的裂解炉及用其进行热裂解的方法 |
WO2015128036A1 (en) * | 2014-02-25 | 2015-09-03 | Saudi Basic Industries Corporation | Process for upgrading refinery heavy hydrocarbons to petrochemicals |
CN205328951U (zh) * | 2016-01-04 | 2016-06-22 | 北京神雾环境能源科技集团股份有限公司 | 焦油裂解的装置 |
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Publication number | Publication date |
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CN105505451A (zh) | 2016-04-20 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 102200 Beijing city Changping District Machi Town cow Road No. 18 Patentee after: Shenwu Technology Group Co.,Ltd. Address before: 102200 Beijing city Changping District Machi Town cow Road No. 18 Patentee before: BEIJING SHENWU ENVIRONMENT AND ENERGY TECHNOLOGY Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Tar cracking device and method Effective date of registration: 20180322 Granted publication date: 20170711 Pledgee: The Bank of Beijing Limited by Share Ltd. Anwar Road Branch Pledgor: Shenwu Technology Group Co.,Ltd. Registration number: 2018990000210 |
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PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20190121 Granted publication date: 20170711 |
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PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20220921 Granted publication date: 20170711 |
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PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20220921 Granted publication date: 20170711 |