CN105484069A - 一种多功能印花增稠剂及其制备方法 - Google Patents

一种多功能印花增稠剂及其制备方法 Download PDF

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CN105484069A
CN105484069A CN201610012996.7A CN201610012996A CN105484069A CN 105484069 A CN105484069 A CN 105484069A CN 201610012996 A CN201610012996 A CN 201610012996A CN 105484069 A CN105484069 A CN 105484069A
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王锦江
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HUZHOU QIANJIN SILK Co Ltd
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Abstract

本发明公开了一种多功能印花增稠剂，包括如下组分：磷酸三丁酯；聚丙烯酸酯；脂肪醇聚氧乙烯醚；甜菜碱；醚化瓜耳豆胶；亚甲基双丙烯酰胺；山梨糖醇酐甘油酸酯；引发剂；软油；N-羟甲基丙烯酰胺；去离子水。本发明的印花增稠剂增稠效果显著，可以有效改善手感、提高着色量、亲水性等优点，且制备工艺简单，可有效降低企业成本。

Description

一种多功能印花增稠剂及其制备方法
技术领域
本发明涉及一种纺织印花领域。更具体地说，本发明涉及一种多功能印花增稠剂及其制备方法。
背景技术
印花增稠剂是一种在印花行业中使用最普遍的增稠剂。印花过程中使用的两种主要材料为胶浆和色浆，在高剪切力作用下，导致胶浆和色浆稠度降低，所以需要增稠剂以增加印花材料的稠度。
印花增稠剂的主要作用是提供良好的流变性能，将印网，印辊上的胶浆或色浆转移到织物上，使染料与纤维结合在一起，保证印花花纹轮廓分明，图案清晰，色彩鲜艳，均匀，当染料固着后，反应产物与残留物于下游工序易于除去，使织物手感柔软。由此可见，印花增稠剂在印花工业中起着相当重要的作用。
申请号为CN03151285.2的中国专利公开了一种利用分散染料印花用糊料及其制备工艺，其糊料的组分、重量百分比为：羟甲基淀粉20～74.5％，海藻酸钠20～70％，矿物油0.5～2％。它的制备方法为：按配方比例取料，将原料粉碎至20～50目；放入混合器重，才常温下搅拌，混合，同时喷入雾状轻润油，继续搅拌直至完全均匀，得成品印花糊料。此方法制得的糊料虽有得色量高、冷水溶解性好等优点，但主体成分均为天然产物，尤其海藻酸钠用量太高，成本高昂。
发明内容
本发明的目的是提供一种改善手感，提高得色量，亲水性的能改善涂料印花手感的增稠剂及其制备方法。
为了实现上述目的，本发明采用的技术方案如下：
一种多功能印花增稠剂，包括如下重量份的组分：
磷酸三丁酯：5～10份；聚丙烯酸酯：12～28份；
脂肪醇聚氧乙烯醚：2～9份；甜菜碱：3～10份；
醚化瓜耳豆胶：3～10份；亚甲基双丙烯酰胺：4～18份；
山梨糖醇酐甘油酸酯：0.3～6份；引发剂：1～3份；
软油：0.5～5份；N-羟甲基丙烯酰胺：2～15份；
去离子水：20～40份。
优选的是，所述软油的成分为摩尔比为30:20:1的甘油、异丙醇、对甲苯磺酸。
优选的是，所述软油的制备方法为：按配比，将甘油加入到异丙醇中混合均匀，在加入对甲苯磺酸，在175℃反应4小时后制得合成软油。
优选的是，所述引发剂选自过硫酸钾、过硫酸钠、过硫酸铵中的一种。
优选的是，所述脂肪醇聚氧乙烯醚的分子式为CxH2x+ 1O(CH2CH2O)yOH，x＝10～18，y＝3～6。
本发明的另一个目的是提供一种多功能印花增稠剂的制备方法，包括如下步骤：
步骤1)：按配比，将聚丙烯酸酯、N-羟甲基丙烯酰胺、亚甲基双丙烯酰胺溶解在去离子水中，开动搅拌器，滴加碱性溶液，使得pH值调制5.5～6.5；
步骤2)：加入软油，山梨糖醇酐甘油酸酯、磷酸三丁酯、甜菜碱、醚化瓜耳豆胶、引发剂，乳化30分钟，通入氮气5分钟后加热升温，在40～80℃反应2小时；
步骤3)：减压蒸馏掉水分和溶剂油，冷却后加入脂肪醇聚氧乙烯醚搅拌均匀即得多功能印花增稠剂。
优选的是，所述碱性溶液选自碳酸钠溶液、氢氧化钠溶液、碳酸氢钠溶液中的一种或组合。
本发明的有益效果：本发明印花增稠剂增稠效果显著，可以有效改善手感、提高着色量、亲水性等优点。
具体实施方式
以下将结合具体实施例来详细说明本发明的实施方式，借此对本发明如何应用技术手段来解决技术问题，并达到技术效果的实现过程能充分理解并据以实施。
若未特别指明，实施例中所采用的技术手段为本领域技术人员所熟知的常规手段，所采用的原料也均为可商业获得的。未详细描述的各种过程和方法是本领域中公知的常规方法。
实施例1
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯5份；聚丙烯酸酯12份；脂肪醇聚氧乙烯醚2份；甜菜碱3份；醚化瓜耳豆胶3份；亚甲基双丙烯酰胺4份；山梨糖醇酐甘油酸酯0.3份；引发剂1份；软油0.5份；N-羟甲基丙烯酰胺2份；去离子水20份。
实施例2
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯10份；聚丙烯酸酯28份；脂肪醇聚氧乙烯醚9份；甜菜碱10份；醚化瓜耳豆胶10份；亚甲基双丙烯酰胺18份；山梨糖醇酐甘油酸酯6份；引发剂3份；软油5份；N-羟甲基丙烯酰胺15份；去离子水40份。
实施例3
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯6份；聚丙烯酸酯18份；脂肪醇聚氧乙烯醚6份；甜菜碱5份；醚化瓜耳豆胶7份；亚甲基双丙烯酰胺9份；山梨糖醇酐甘油酸酯2份；引发剂2份；软油4份；N-羟甲基丙烯酰胺3份；去离子水30份。
对比例1
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯4份；聚丙烯酸酯10份；脂肪醇聚氧乙烯醚1份；甜菜碱2份；醚化瓜耳豆胶2份；亚甲基双丙烯酰胺3份；山梨糖醇酐甘油酸酯0.2份；引发剂1份；软油0.3份；N-羟甲基丙烯酰胺1份；去离子水10份。
对比例2
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯14份；聚丙烯酸酯30份；脂肪醇聚氧乙烯醚10份；甜菜碱12份；醚化瓜耳豆胶11份；亚甲基双丙烯酰胺20份；山梨糖醇酐甘油酸酯7份；引发剂4份；软油6份；N-羟甲基丙烯酰胺16份；去离子水50份。
对比例3
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯6份；聚丙烯酸酯18份；脂肪醇聚氧乙烯醚6份；甜菜碱5份；醚化瓜耳豆胶7份；亚甲基双丙烯酰胺9份；山梨糖醇酐甘油酸酯2份；引发剂2份；甘油4份；N-羟甲基丙烯酰胺3份；去离子水30份。
对比例4
多功能印花增稠剂，包括如下重量份的组分：磷酸三丁酯6份；聚丙烯酸酯18份；脂肪醇聚氧乙烯醚6份；甜菜碱5份；醚化瓜耳豆胶7份；亚甲基双丙烯酰胺9份；山梨糖醇酐甘油酸酯2份；引发剂2份；软油4份；N-羟甲基丙烯酰胺3份；去离子水30份。
实施例1～3和对比例1～2的软油的制备方法为：取30摩尔甘油加入到20摩尔异丙醇中混合均匀，再加入对1摩尔甲苯磺酸，在175℃反应4小时后制得合成软油。
对比例4中的软油的制备方法为：取10摩尔甘油加入到10摩尔异丙醇中混合均匀，再加入对1摩尔甲苯磺酸，在175℃反应4小时后制得合成软油。
实施例1～3和对比例1～4的多功能印花增稠剂的制备方法，包括如下步骤：
步骤1)：按配比，将聚丙烯酸酯、N-羟甲基丙烯酰胺、亚甲基双丙烯酰胺溶解在去离子水中，开动搅拌器，滴加碱性溶液，使得pH值调制5.5～6.5；
步骤2)：加入软油，山梨糖醇酐甘油酸酯、磷酸三丁酯、甜菜碱、醚化瓜耳豆胶、引发剂，乳化30分钟，通入氮气5分钟后加热升温，在40～80℃反应2小时；
步骤3)：减压蒸馏掉水分和溶剂油，冷却后加入脂肪醇聚氧乙烯醚搅拌均匀即得多功能印花增稠剂。
处理工艺：
调制色浆-----印花------烘干(100℃×1min)-----烘焙(190℃×90s)-----水洗-----烘干-----性能评价。
应用性能测试
白桨粘度测试
测试设备：BrookfieldDV-Ⅱ+Pro粘度计
测试条件：6号转子20转/分
用去离子水配置5％浓度增稠剂的原糊，在恒定转速20转/分在室温下测定白浆粘度。
耐电解质性能测试
耐电解质性能以粘度保留率表示，测定上述增稠剂白浆加入0.5％的固定硫酸钠白浆粘度，粘度保留率越高则耐电解质性越好。
得色量测试
用Datacolor测色仪进行测试
以加分散印花增稠剂处理样为测试样，在Datacolor测色仪上进行测试。用K/S来表示织物的表观得色量，K/S值越大，得色量就越深。
手感评价
以多人有丰富手感经验者来评价，分为1～5级，等级越高，手感越柔软，一般未经处理的原布手感认为5级。
保水性：是指1cm宽的中性滤纸插入印花色浆后，颜色通过滤纸渗出的高度，高度越长，产品性能越差。
表1测试结果
尽管本发明的实施方案已公开如上，但其并不仅仅限于说明书和实施方式中所列运用，它完全可以被适用于各种适合本发明的领域，对于熟悉本领域的人员而言，可容易地实现另外的修改，因此在不背离权利要求及等同范围所限定的一般概念下，本发明并不限于特定的细节。

Claims (7)

1.一种多功能印花增稠剂，其特征在于，包括如下重量份的组分：
磷酸三丁酯：5～10份；聚丙烯酸酯：12～28份；
脂肪醇聚氧乙烯醚：2～9份；甜菜碱：3～10份；
醚化瓜耳豆胶：3～10份；亚甲基双丙烯酰胺：4～18份；
山梨糖醇酐甘油酸酯：0.3～6份；引发剂：1～3份；
软油：0.5～5份；N-羟甲基丙烯酰胺：2～15份；
去离子水：20～40份。
2.如权利要求1所述的多功能印花增稠剂，其特征在于，所述软油的成分为摩尔比为30:20:1的甘油、异丙醇、对甲苯磺酸。
3.如权利要求2所述的多功能印花增稠剂，其特征在于，所述软油的制备方法为：按配比，将甘油加入到异丙醇中混合均匀，在加入对甲苯磺酸，在175℃反应4小时后制得合成软油。
4.如权利要求1所述的多功能印花增稠剂，其特征在于，所述引发剂选自过硫酸钾、过硫酸钠、过硫酸铵中的一种。
5.如权利要求1所述的多功能印花增稠剂，其特征在于，所述脂肪醇聚氧乙烯醚的分子式为CxH2x+1O(CH2CH2O)yOH，x＝10～18，y＝3～6。
6.如权利要求1所述的多功能印花增稠剂的制备方法，其特征在于，包括如下步骤：
步骤1)：按权利要求1的配比，将聚丙烯酸酯、N-羟甲基丙烯酰胺、亚甲基双丙烯酰胺溶解在去离子水中，开动搅拌器，滴加碱性溶液，使得pH值调制5.5～6.5；
步骤2)：加入软油，山梨糖醇酐甘油酸酯、磷酸三丁酯、甜菜碱、醚化瓜耳豆胶、引发剂，乳化30分钟，通入氮气5分钟后加热升温，在40～80℃反应2小时；
步骤3)：减压蒸馏掉水分和溶剂油，冷却后加入脂肪醇聚氧乙烯醚搅拌均匀即得多功能印花增稠剂。
7.如权利要求6所述的多功能印花增稠剂的制备方法，其特征在于，所述碱性溶液选自碳酸钠溶液、氢氧化钠溶液、碳酸氢钠溶液中的一种或组合。
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