CN105476916A - Anti-hair loss shampoo containing nano diamondene and preparation method thereof - Google Patents
Anti-hair loss shampoo containing nano diamondene and preparation method thereof Download PDFInfo
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
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- A—HUMAN NECESSITIES
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Abstract
The invention discloses anti-hair loss shampoo containing nano diamondene, and belongs to the filed of household chemical goods. The shampoo is prepared from the following raw materials in parts by weight: 1 to 5 parts of nano diamondene, 15 to 20 parts of radix sophorae flavescentis, 10 to 15 parts of radix ginseng, 15 to 20 parts of cacumen platycladi, 15 to 20 parts of radix polygoni multiflori, 20 to 25 parts of radix astragali, 20 to 25 parts of Chinese angelica and 10 to 15 parts of lucid ganoderma. The invention also discloses a preparation method of the shampoo, comprising the steps of (1) smashing the nano diamondene, the radix sophorae flavescentis, the radix ginseng, the cacumen platycladi, the radix polygoni multiflori, the radix astragali, the Chinese angelica and the lucid ganoderma, drying, sterilizing, soaking for 0.5 to 1h, then boiling at high heat and decocting for 15 to 30 min, and then decocting for 2 to 4h at low heat, cooling, and filtering to obtain an extracting solution; (2) adding the nano diamondene into the extracting solution under stirring, heating, concentrating, performing heat preservation and cooling to room temperature; (3) adding citric acid to adjust the pH value to 6.5 to 7.5.
Description
Technical field
The invention belongs to daily chemicals field, be specifically related to a kind of anticreep shampoo containing nanometer diamond alkene and preparation method thereof.
Background technology
Alopecia refers to the phenomenon of alopecia, and the hair normally come off is all the hair being in catagen and resting stage, is constantly in dynamic equilibrium, so can maintain the hair of normal quantity owing to entering catagen with the hair newly entering trophophase.Along with the raising of people's living standard, diet is based on pungent and living habit is irregular, and the operating pressure of people increases gradually simultaneously, and the infection of various pathogen, and especially youngster can be had hair dyed, be permed, and the crowd of alopecia is increasing.At present, commercially available anticreep shampoo DeGrain, the chemicals that adopts is mixed more, and large to human injury, cost is high.
The Chinese patent document of publication number to be CN104997696A and publication number be CN104971017A all discloses a kind of anticreep shampoo, main generation by Chinese medicine prevents alopecia and antipruritic effect, but add a small amount of antiseptic, although consumption is low, there is good antiseptic effect, make cosmetics not by the pollution of microorganism, but also potential threat and certain stimulation are brought to skin simultaneously, easily cause skin allergy.At present, shampoo just towards the trend development of naturalization, nutrient laden and curative effect, with the effective ingredient of plant, Chinese medicine or quintessence oil reach removing scurf and relieving itching or anti-loss be current study hotspot.But the additives such as most of shampoo silicate-containing oil, guar gum, silicone oil and guar gum cause the problems such as alopecia, alopecia and scalp itch.Therefore, a kind of pure natural anti-dandruff anticreep shampoo with curative effect and Nutrition of development is needed to have wide market prospect.
Summary of the invention
The object of the present invention is to provide a kind of anticreep shampoo containing nanometer diamond alkene, provide the preparation method of this anticreep shampoo to be then another object of the present invention.
Based on above-mentioned purpose, the present invention is by the following technical solutions: a kind of anticreep shampoo containing nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from: nanometer diamond alkene 1-5 part, Radix Sophorae Flavescentis 15-20 part, Radix Ginseng 10-15 part, Cacumen Platycladi 15-20 part, Radix Polygoni Multiflori 15-20 part, Radix Astragali 20-25 part, Radix Angelicae Sinensis 20-25 part and Ganoderma 10-15 part.
Preferably, described nanometer diamond alkene is lamellar mono-crystalline structures, is sp between the carbon atom of same lamella
3orbital hybridization carbon bond connects, and is sp between carbon atom between layers
2hydridization carbon bond connects, and C content is 99 ~ 100%, and spacing of lattice is 0.21nm; Particle diameter is R, 20≤R≤500nm.
Preferably, carry out surface-functionalized process to described nanometer diamond alkene, processing procedure is: nanometer diamond alkene is placed in the dense HNO that mass ratio is 1 ﹕ (2 ~ 5)
3/ dense H
2sO
4mixed liquor in, centrifugation after reflux; Taking precipitate deionized water wash is 5.0-6.0 to cleaning mixture pH, uses 0.1-0.5molL
-1na
2siO
39H
2the while that O solution washing being sedimentary, ultrasonic disperse 1-2h, then uses 0.1-0.5molL
-1ultrasonic disperse 1-2h while that HCL solution washing being sedimentary, finally uses deionized water wash post-drying.
Preferably, the pH value of this anticreep shampoo is 6.5-7.5.
The preparation method of the described anticreep shampoo containing nanometer diamond alkene, step is:
(1) Radix Sophorae Flavescentis, Radix Ginseng, Cacumen Platycladi, Radix Polygoni Multiflori, the Radix Astragali, Radix Angelicae Sinensis, Ganoderma are pulverized, dry, sterilization, after soaking 0.5-1h, big fire is boiled and decoct 15-30min, less fire decocts 2-4h, cools, filter to obtain extracting solution;
(2) in extracting solution, add nanometer diamond alkene under agitation, heating concentrates, is incubated, is cooled to room temperature;
(3) adding citric acid adjust ph is 6.5-7.5.
Further, in step (2), after carrying out surface-functionalized process to nanometer diamond alkene, then add in extracting solution, processing procedure is: nanometer diamond alkene is placed in the dense HNO that mass ratio is 1 ﹕ (2 ~ 5)
3/ dense H
2sO
4mixed liquor in, centrifugation after reflux; Taking precipitate deionized water wash is 5.0-6.0 to cleaning mixture pH, uses 0.1-0.5molL
-1na
2siO
39H
2the while that O solution washing being sedimentary, ultrasonic disperse 1-2h, then uses 0.1-0.5molL
-1ultrasonic disperse 1-2h while that HCL solution washing being sedimentary, finally uses deionized water wash post-drying.
Raw material of the present invention has following effect:
Radix Sophorae Flavescentis has heat clearing and damp drying, effect of parasite killing; Be used in shampoo and can balance hair follicle fat secretion, dredge and restrain hair follicle, remove the toxin impurity in hair follicle, abundant herbal nutrition, promotes growth and the reparation of impaired hair follicle cell, recovers hair follicle cell vigor.
In shampoo, add the telangiectasis that Radix Ginseng can make head, the nutrition of hair can be increased, improve the toughness of hair, reduce alopecia, disconnectedly to send out, to the hair of damage, there is protective effect.
Cacumen Platycladi has the effect reaching clearing heat and expelling damp, and scalp can be made pure and fresh no longer greasy.
Radix Polygoni Multiflori has blood-enriching tranquillizing effect, again because it contains aminoacid, emodin and lecithin etc., can moisten scalp hair follicles, promote melanic generation.
The Radix Astragali contains the various trace elements such as Saponin, sucrose, polysaccharide, several amino acids, folic acid and selenium, zinc, copper, and the immunologic function of energy enhancing body, has anti-stress, antibacterial effect; Be used in shampoo, the toxin in scalp hair follicles can be cleared up, kill the antibacterial on scalp and hair, promote the growth of hair.
Radix Angelicae Sinensis contains the nutrients such as vitamin A, vitamin B12, vitamin E and essential amino acid, and can promote natural on-off cycles of hair growth, adding Radix Angelicae Sinensis in shampoo can make hair soft shinny, is easy to combing.
Ganoderma is used in shampoo and hair can be made to have the effects such as gloss.
Anticreep shampoo containing nanometer diamond alkene provided by the invention has following beneficial effect:
(1) the present invention adopts nanometer diamond alkene to be raw material, and the diamond alkene granule of Nano grade is comparatively thin, and specific surface area is large, and adsorptivity is strong, can adsorb shampoo active component.Nanometer diamond alkene surface has a lot of active groups and avtive spot, easily carries out special surface-functionalized process to nanometer diamond alkene, effectively prevents the reunion again of nano-particle, can be dispersed in shampoo uniformly.Through surface-functionalized process nanometer diamond alkene can adsorb in shampoo each Chinese medicine extraction liquid in active substance, excite hair follicle cell to regenerate, promote the growth of hair, play the effect of hair strengthening anti-avulsion.The active component of the Radix Sophorae Flavescentis in the nanometer diamond alkene and shampoo of surface-functionalized process, Radix Ginseng, Cacumen Platycladi, Radix Polygoni Multiflori, the Radix Astragali, Radix Angelicae Sinensis and Ganoderma is combined closely, is mutually worked in coordination with, when having one's hair wash, nanometer diamond alkene discharges the active component stored act on scalp and hair, can not only acute activation hair follicle cell, effectively can also promote that hair follicle is bred quickly, division, induction kainogenesis is long.The nanometer size effect of nanometer diamond alkene make it evenly be dispersed in shampoo, improve the dispersibility of nanometer diamond alkene in shampoo and between the compatibility.
(2) nanometer diamond alkene is stratified pieces structure, then defines between layers " storeroom " of shampoo active component, can store more shampoo active component.The layer structure of nanometer diamond alkene has slow-release function, during hair washing, active component in plant discharges from the lamella of nanometer diamond alkene with certain speed, be continuously hair follicle cell and nutrition is provided, decompose the various toxin eliminated in hair follicle, the secretion of balancing head haze wax fat, gets through the Rhizoma Imperatae nutrition channel of blocking, activate the hair follicle of dormancy, impel hair follicle to regenerate in a large number.Shampoo provided by the invention effectively can not only remove dirt, antibacterial, scurf and oils and fats on hair and scalp, can also repair cellular elements structure between dermal papilla, recovers biological activity, hair follicle cell of reviving, hair strengthening anti-avulsion.
(3) nanometer diamond alkene is pure C element composition, nontoxic, has high biocompatibility, is completely after the washing excluded external by various approach and can not produces potential healthy hidden danger.
Preparation method technique provided by the invention is simple, finished product stability good, have the advantages such as easy to use, principle is reliable, environmental protection, the product prepared has good anticreep and hair restoration effect, uses rear number of hairs showed increased, thickness increases, and alopecia every day quantity reduces.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in detail.
The preparation of embodiment 1 nanometer diamond alkene
Following methods is adopted to prepare nanometer diamond alkene:
(1) tentatively broken: diamond raw material is sent into the broken granule sifting out more than 70 orders in ball milling shaping barrel, the broken time is 1-5h, the coarse fodder below 70 orders returns ball milling shaping barrel and carries out again broken; Granule sieves out the fines of more than 800 orders through multistage vibrating sieving machine, and the sieve time of shaking is 30min-2h, and this fines repeats to sieve once;
(2) again broken: to be delivered to sieving out the above fines of 800 order in airflow crash machine, sieve out the fine powder of more than 8000 orders after utilizing high pressure draught to pulverize fines, residue on sieve Returning flow disintegrating machine carries out again broken;
(3) pickling:: first fine powders more than 8000 orders is placed in concentrated sulphuric acid and concentrated nitric acid mixed liquor pickling 2 ~ 7h, filtration, cleaning, described concentrated sulphuric acid and concentrated nitric acid mixed liquor are that 5:1 mixes by mass fraction to be 98% concentrated sulphuric acid and mass fraction be 10% concentrated nitric acid according to mass ratio; Then fine powder is placed in dilute hydrochloric acid 4 ~ 9h, filtration that 140 DEG C ~ 160 DEG C mass fractions are 5% ~ 8%; Again this fine powder is placed in Fluohydric acid. 10 ~ 20h, the impurity removed the metal impurities in material and be attached in ball milling shaping, airflow crash process on material, then uses washed with de-ionized water to cleanout fluid pH close to 7;
(4) sorting: the material after cleaning is carried out centrifugalize, gets supernatant liquid and carries out the sorting of 1-5 days precipitations, remove the supernatant, by the nanometer diamond alkene that gets product after the drying of lower sediment thing; In step with centrifugal separation, centrifugation time is 30min-2h, and rotating speed is 8000rpm-15000rpm.
Preparing nanometer diamond alkene is lamellar mono-crystalline structures, is sp between the carbon atom of same lamella
3orbital hybridization carbon bond connects, and is sp between carbon atom between layers
2hydridization carbon bond connects, and C content is 99 ~ 100%, and spacing of lattice is 0.21nm; Particle diameter is R, 20≤R≤500nm.
The nanometer diamond alkene that embodiment 2-6 all adopts embodiment 1 to prepare is as raw material.
Embodiment 2
An anticreep shampoo containing nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from: 4 parts, nanometer diamond alkene (not carrying out surface-functionalized process), Radix Sophorae Flavescentis 15 parts, Radix Ginseng 10 parts, Cacumen Platycladi 18 parts, Radix Polygoni Multiflori 20 parts, the Radix Astragali 20 parts, Radix Angelicae Sinensis 20 parts and Ganoderma 15 parts.
The above-mentioned anticreep shampoo containing nanometer diamond alkene adopts following methods preparation, the steps include:
(1) Radix Sophorae Flavescentis, Radix Ginseng, Cacumen Platycladi, Radix Polygoni Multiflori, the Radix Astragali, Radix Angelicae Sinensis, Ganoderma are pulverized, dry, sterilization, after soaking 0.5-1h, big fire is boiled and decoct 15-30min, less fire decocts 2-4h, cools, filter to obtain extracting solution;
(2) in extracting solution, add nanometer diamond alkene under agitation, heating concentrates, is incubated, is cooled to room temperature;
(3) adding citric acid adjust ph is 6.5-7.5.
Embodiment 3
Containing the anticreep shampoo of nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from: through 4 parts, the nanometer diamond alkene of surface-functionalized process, Radix Sophorae Flavescentis 15 parts, Radix Ginseng 10 parts, Cacumen Platycladi 18 parts, Radix Polygoni Multiflori 20 parts, the Radix Astragali 20 parts, Radix Angelicae Sinensis 20 parts and Ganoderma 15 parts.
The above-mentioned anticreep shampoo containing nanometer diamond alkene adopts following methods preparation, the steps include:
(1) Radix Sophorae Flavescentis, Radix Ginseng, Cacumen Platycladi, Radix Polygoni Multiflori, the Radix Astragali, Radix Angelicae Sinensis, Ganoderma are pulverized, dry, sterilization, after soaking 0.5-1h, big fire is boiled and decoct 15-30min, less fire decocts 2-4h, cools, filter to obtain extracting solution;
(2) carry out surface-functionalized process to nanometer diamond alkene, its process is: nanometer diamond alkene is placed in the dense HNO that mass ratio is 1 ﹕ 2
3/ dense H
2sO
4mixed liquor in, centrifugation after reflux 24h at 90 DEG C, taking precipitate deionized water wash is 5.0-6.0 to pH, uses 0.1-0.5molL
-1na
2siO
39H
2o solution washing precipitate, and ultrasonic disperse 1-2h, then use 0.1-0.5molL
-1hCL washing precipitate, and ultrasonic disperse 1-2h, finally dry in an oven with after deionized water wash; In extracting solution, add the nanometer diamond alkene through surface-functionalized process under agitation, heating concentrates, is incubated, is cooled to room temperature;
(3) adding citric acid adjust ph is 6.5-7.5.
Embodiment 4
An anticreep shampoo containing nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from 1 part, surface-functionalized nanometer diamond alkene, Radix Sophorae Flavescentis 18 parts, Radix Ginseng 15 parts, Cacumen Platycladi 20 parts, Radix Polygoni Multiflori 15 parts, the Radix Astragali 22 parts, Radix Angelicae Sinensis 22 parts and Ganoderma 12 parts.
The preparation method that the above-mentioned preparation method reference example 3 containing the anticreep shampoo of nanometer diamond alkene provides, is with the difference of embodiment 3: dense HNO
3/ dense H
2sO
4mixed liquor in dense HNO
3with dense H
2sO
4mass ratio is 1:5, Na
2siO
39H
2the concentration of O aqueous solution is 0.5molL
-1, the concentration of HCL aqueous solution is 0.5molL
-1.
Embodiment 5
An anticreep shampoo containing nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from: 5 parts, surface-functionalized nanometer diamond alkene, Radix Sophorae Flavescentis 20 parts, Radix Ginseng 12 parts, Cacumen Platycladi 15 parts, Radix Polygoni Multiflori 18 parts, the Radix Astragali 24 parts, Radix Angelicae Sinensis 24 parts and Ganoderma 10 parts.
The preparation method that the above-mentioned preparation method reference example 3 containing the anticreep shampoo of nanometer diamond alkene provides, is with the difference of embodiment 3: dense HNO
3/ dense H
2sO
4mixed liquor in dense HNO
3with dense H
2sO
4mass ratio is 1:3, Na
2siO
39H
2the concentration of O aqueous solution is 0.4molL
-1, the concentration of HCL aqueous solution is 0.4molL
-1.
Embodiment 6
An anticreep shampoo containing nanometer diamond alkene, the raw material primarily of following portions by weight is prepared from: 3 parts, surface-functionalized nanometer diamond alkene, Radix Sophorae Flavescentis 20 parts, Radix Ginseng 13 parts, Cacumen Platycladi 15 parts, Radix Polygoni Multiflori 18 parts, the Radix Astragali 25 parts, Radix Angelicae Sinensis 25 parts and Ganoderma 10 parts.
The preparation method that the above-mentioned preparation method reference example 3 containing the anticreep shampoo of nanometer diamond alkene provides, is with the difference of embodiment 3: dense HNO
3/ dense H
2sO
4mixed liquor in dense HNO
3with dense H
2sO
4mass ratio is 1:4, Na
2siO
39H
2the concentration of O aqueous solution is 0.3molL
-1, the concentration of HCL aqueous solution is 0.3molL
-1.
Comparative example
A kind of shampoo, is prepared from Radix Sophorae Flavescentis 15 parts, Radix Ginseng 10 parts, Cacumen Platycladi 18 parts, Radix Polygoni Multiflori 20 parts, the Radix Astragali 20 parts, Radix Angelicae Sinensis 20 parts and Ganoderma 15 parts by the raw material of following weight percentage ratio, not containing surface-functionalized nanometer diamond alkene.
The preparation method reference example 2 of above-mentioned shampoo.
Effect test
Contrast test 1
Subjects: the crowd in 150 18-60 years.
Test method: 150 subjects are divided into 3 groups at random, be designated as test 1 group, test 2 groups, test 3 groups, test 1 group and use commercially available anticreep shampoo, test 2 groups of shampoos using comparative example to prepare (not containing surface-functionalized nanometer diamond alkene), test 3 groups of anticreep shampoos contained through the nanometer diamond alkene of surface-functionalized process using embodiment 3 to prepare.The life cycle of 3 groups of tests is 3 months, and on average within every 3 days, use 1 time, result of the test is in table 1.
Remarks: effective: comb is sent out before test alopecia radical is comparatively tried out and reduced more than 60%;
Effective: comb is sent out before test alopecia radical is comparatively tried out and reduced more than 30%, but is less than 60%;
Invalid: comb is sent out before test alopecia radical is comparatively tried out and reduced less than 30%.
As shown in Table 1, the Anti-hair loss successful testing 3 groups is better than test 1 group and test 2 groups.Because test in 3 groups of shampoos used containing surface-functionalized nanometer diamond alkene, during hair washing, nanometer diamond alkene discharges its pure plant essence factor stored as the hair follicle cell in scalp provides nutrition, the rapid various toxin decomposed in elimination hair follicle, the secretion of balancing head haze wax fat, get through the Rhizoma Imperatae nutrition channel of blocking, activate the hair follicle of dormancy, impel hair follicle to regenerate in a large number.The shampoo provided of the present invention effectively can not only remove dirt, antibacterial, scurf and oils and fats on hair and scalp, can also repair cellular elements structure between dermal papilla, recovers biological activity, hair follicle cell of reviving, hair strengthening anti-avulsion.
Contrast test 2
Subjects: 50 28-60 year volunteer, wherein suffer from serious baldness for 30, send out amount less and have alopecia to be inclined to for 20.
Test method: use the shampoo that embodiments of the invention 3 provide, the time is 3 months, uses once for 2 days, and within average 2 weeks, the number of hairs to volunteer, hair thickness and hair quality carry out observation statistics.
Result of the test:
1, suffer from volunteer's head hair follicle increased number of serious baldness for 30, and alopecia district has the hair of more than 50% again to grow, therapeutic effect is remarkable, does not occur side effect simultaneously.
2,20 volunteer's number of hairs showed increased having alopecia to be inclined to, and alopecia every day quantity reduces.
3, the hair quality of original hair of volunteer is smooth flexible, and send out tip bifurcation and disappear, hair gloss degree is good, and toughness is strong, customer satisfaction is high.
From above result, shampoo provided by the invention has good Anti-hair loss, short hair-growing effects; During hair washing, the pure plant essence factor that nanometer diamond alkene stores between layers is released and enters in hair follicle, necessary material is grown containing the abundant hair follicle such as aminoacid, vegetable protein, vitamin in these essential ingredient, not only can promote the blood circulation of hair follicle, improve metabolism, strengthen hair follicle to the absorption of nutrient, improve the growing environment of hair, promote the growth of hair, make that chroma of hair is good, toughness is strong, and can also hair follicle cell be activated, promote that hair follicle is bred faster, divided, induction kainogenesis is long.
Claims (6)
1. the anticreep shampoo containing nanometer diamond alkene, it is characterized in that, the raw material primarily of following portions by weight is prepared from: nanometer diamond alkene 1-5 part, Radix Sophorae Flavescentis 15-20 part, Radix Ginseng 10-15 part, Cacumen Platycladi 15-20 part, Radix Polygoni Multiflori 15-20 part, Radix Astragali 20-25 part, Radix Angelicae Sinensis 20-25 part and Ganoderma 10-15 part.
2. the anticreep shampoo containing nanometer diamond alkene according to claim 1, it is characterized in that, described nanometer diamond alkene is lamellar mono-crystalline structures, is sp between the carbon atom of same lamella
3orbital hybridization carbon bond connects, and is sp between carbon atom between layers
2hydridization carbon bond connects, and C content is 99 ~ 100%, and spacing of lattice is 0.21nm; Particle diameter is R, 20≤R≤500nm.
3. the anticreep shampoo containing nanometer diamond alkene according to claim 1 and 2, it is characterized in that, described nanometer diamond alkene is through surface-functionalized process, and processing procedure is: nanometer diamond alkene is placed in the dense HNO that mass ratio is 1 ﹕ (2 ~ 5)
3/ dense H
2sO
4mixed liquor in, centrifugation after reflux; Taking precipitate deionized water wash is 5.0-6.0 to cleaning mixture pH, uses 0.1-0.5molL
-1na
2siO
39H
2the while that O solution washing being sedimentary, ultrasonic disperse 1-2h, then uses 0.1-0.5molL
-1ultrasonic disperse 1-2h while that HCL solution washing being sedimentary, finally uses deionized water wash post-drying.
4. the anticreep shampoo containing nanometer diamond alkene according to claim 3, it is characterized in that, the pH value of this anticreep shampoo is 6.5-7.5.
5. the preparation method of the anticreep shampoo containing nanometer diamond alkene according to claim 1 and 2, it is characterized in that, step is:
(1) Radix Sophorae Flavescentis, Radix Ginseng, Cacumen Platycladi, Radix Polygoni Multiflori, the Radix Astragali, Radix Angelicae Sinensis, Ganoderma are pulverized, dry, sterilization, after soaking 0.5-1h, big fire is boiled and decoct 15-30min, less fire decocts 2-4h, cools, filter to obtain extracting solution;
(2) in extracting solution, add nanometer diamond alkene under agitation, heating concentrates, is cooled to room temperature;
(3) adding citric acid adjust ph is 6.5-7.5.
6. the preparation method of the anticreep shampoo containing nanometer diamond alkene according to claim 5, it is characterized in that, in step (2), after surface-functionalized process is carried out to nanometer diamond alkene, add in extracting solution, processing procedure is again: nanometer diamond alkene is placed in the dense HNO that mass ratio is 1 ﹕ (2 ~ 5)
3/ dense H
2sO
4mixed liquor in, centrifugation after reflux; Taking precipitate deionized water wash is 5.0-6.0 to cleaning mixture pH, uses 0.1-0.5molL
-1na
2siO
39H
2the while that O solution washing being sedimentary, ultrasonic disperse 1-2h, then uses 0.1-0.5molL
-1ultrasonic disperse 1-2h while that HCL solution washing being sedimentary, finally uses deionized water wash post-drying.
Priority Applications (1)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106587425A (en) * | 2016-12-14 | 2017-04-26 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Novel water purifier filter core |
| CN107157909A (en) * | 2017-06-29 | 2017-09-15 | 芜湖凌梦电子商务有限公司 | A kind of Hair-loss-preventingshampoo shampoo |
| CN111000778A (en) * | 2019-11-23 | 2020-04-14 | 广东天仁科技有限公司 | Hair loss preventing and hair growing liquid and preparation method thereof |
| CN114028309A (en) * | 2021-12-02 | 2022-02-11 | 江西中医药大学 | Shampoo and preparation method thereof |
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| CN103386111A (en) * | 2013-08-05 | 2013-11-13 | 谢明臣 | Special prescription for seborrhoeic alopecia |
| CN104739704A (en) * | 2013-12-28 | 2015-07-01 | 大连美乐生物技术开发有限公司 | Traditional Chinese medicinal soup and preparation method thereof |
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| CN103386111A (en) * | 2013-08-05 | 2013-11-13 | 谢明臣 | Special prescription for seborrhoeic alopecia |
| CN104739704A (en) * | 2013-12-28 | 2015-07-01 | 大连美乐生物技术开发有限公司 | Traditional Chinese medicinal soup and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587425A (en) * | 2016-12-14 | 2017-04-26 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Novel water purifier filter core |
| CN107157909A (en) * | 2017-06-29 | 2017-09-15 | 芜湖凌梦电子商务有限公司 | A kind of Hair-loss-preventingshampoo shampoo |
| CN111000778A (en) * | 2019-11-23 | 2020-04-14 | 广东天仁科技有限公司 | Hair loss preventing and hair growing liquid and preparation method thereof |
| CN114028309A (en) * | 2021-12-02 | 2022-02-11 | 江西中医药大学 | Shampoo and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN105476916B (en) | 2018-03-13 |
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