CN105462625B - 一种具有强抗爆性能的混醇汽油 - Google Patents
一种具有强抗爆性能的混醇汽油 Download PDFInfo
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 239000000203 mixture Substances 0.000 claims abstract description 53
- 239000006079 antiknock agent Substances 0.000 claims abstract description 30
- 230000003389 potentiating effect Effects 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 26
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 18
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 18
- -1 dibromo normal octane Chemical compound 0.000 claims description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 230000007071 enzymatic hydrolysis Effects 0.000 claims description 9
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 9
- 238000000855 fermentation Methods 0.000 claims description 9
- 230000004151 fermentation Effects 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 239000011572 manganese Substances 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- SNCZNSNPXMPCGN-UHFFFAOYSA-N butanediamide Chemical class NC(=O)CCC(N)=O SNCZNSNPXMPCGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000000052 comparative effect Effects 0.000 description 8
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 150000001408 amides Chemical class 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 238000001514 detection method Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000003254 radicals Chemical group 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- ADVGKWPZRIDURE-UHFFFAOYSA-N 2'-Hydroxyacetanilide Chemical group CC(=O)NC1=CC=CC=C1O ADVGKWPZRIDURE-UHFFFAOYSA-N 0.000 description 1
- SKZKKFZAGNVIMN-UHFFFAOYSA-N Salicilamide Chemical compound NC(=O)C1=CC=CC=C1O SKZKKFZAGNVIMN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002883 o-cresols Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- C—CHEMISTRY; METALLURGY
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C10L1/20—Organic compounds containing halogen
- C10L1/201—Organic compounds containing halogen aliphatic bond
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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- C10L2300/00—Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
- C10L2300/20—Mixture of two components
Abstract
本发明涉及一种具有强抗爆性能的混醇汽油，该汽油是由以下重量份的各组分为原料制成：汽油44～62份，木质纤维素醇类混合物30～45份，石脑油1～8份，SDA强效抗爆剂2～3份。本发明以秸秆为原料发酵生产木质纤维素醇类混合物，并将该混合物作为原料应用于汽油生产行业，极大地降低了汽油的生产成本；本发明将木质纤维素醇类混合物与强效抗爆剂采用更为合理的配比进行生产，极大提高了该产品的抗爆性能。
Description
技术领域
本发明属于燃油技术领域，具体涉及一种具有强抗爆性能的混醇汽油。
背景技术
现有理论认为：汽油在汽缸中按自由基链反应机理燃烧，包括链引发、链传递、链支化、链终止等步骤。爆震是一种当汽油机的压缩比与汽油燃料的辛烷值不匹配时出现的不正常燃烧现象，产生爆震的原因是：汽油/空气混合气点火后，随着最初火焰中的在汽缸中的传播，未燃混合气受到已燃气体燃烧产生的压力和热的作用，氧化反应增强，过氧化物迅速分解，自由基支链反应剧增，未燃混合气的温度在最初火焰前锋到达之前已经发生自燃而爆炸燃烧，在汽缸内产生多个燃烧中心，各火焰前锋同时向前推进，产生爆震波发生爆震现象。
汽油抗爆剂的作用是抑制燃烧反应的自动加速，将汽油的燃烧速度限制在正常的范围内，即在火焰的前锋到达之前，抑制烃类自燃，使未燃烧的混合气体的自燃诱导期延长，使火焰的传播速度增加，达到消除燃料爆震燃烧的目的。
辛烷值是车用汽油最重要的质量指标，它综合反映一个国家炼油工业水平和车辆设计水平，采用抗爆剂是提高车用汽油辛烷值的重要手段。添加汽油抗爆剂可提高汽油的抗爆性能，即车用无铅汽油国家标准《GB17930-20061》的研究法辛烷值和抗爆指数，是生产高标号汽油的主要手段。
中国专利文献CN102093919B(申请号200910231176.7)公开了一种汽油抗爆剂，其主要组分包括邻乙酰胺基苯酚、间羟基苯酰胺及2-甲基苯酚，用量的重量比例为3:5:2。
从上述公开的文献来看，现在还未研发出一种添加了抗爆剂、具有较强抗爆性能的混醇汽油。
发明内容
本发明的目的在于提供一种添加了强效抗爆剂的具有强抗爆性能的混醇汽油，利用该发明技术生产的汽油配比科学合理，所生产的混醇汽油具有非常强的抗爆性能。
本发明是通过如下技术方案实施的：
一种具有强抗爆性能的混醇汽油，该汽油是由以下重量份的原料组分制成：
汽油44～62份，
木质纤维素醇类混合物30～45份，
石脑油1～8份，
SDA强效抗爆剂2～3份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
根据本发明优选的，所述木质纤维素醇类混合物与SDA强效抗爆剂按照重量比15:1的比例添加混合。
根据本发明进一步优选的，该汽油是由以下重量份的各组分为原料制成：汽油54份，木质纤维素醇类混合物37.5份，石脑油6份，SDA强效抗爆剂2.5份。
根据本发明进一步优选的，该汽油是由以下重量份的各组分为原料制成：汽油50份，木质纤维素醇类混合物45份，石脑油2份，SDA强效抗爆剂3份。
本发明的有益效果：
(1)本发明以秸秆为原料发酵生产木质纤维素醇类混合物，并将该混合物作为原料应用于汽油生产行业，极大地降低了汽油的生产成本；
(2)本发明将木质纤维素醇类混合物与强效抗爆剂采用更为合理的配比进行生产，极大提高了该产品的抗爆性能。
具体实施方式：
以下是本发明的具体实施例，对本发明的技术方案做进一步描述，但是本发明的保护范围并不限于这些实施例。凡是不背离本发明构思的改变或等同替代均包括在本发明的保护范围之内。
实施例1
以以下原料生产具有强抗爆性能的混醇汽油：
汽油54份；
木质纤维素醇类混合物37.5份；
石脑油6份；
SDA强效抗爆剂2.5份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
实施例2
以以下原料生产具有强抗爆性能的混醇汽油：
汽油50份；
木质纤维素醇类混合物45份；
石脑油2份；
SDA强效抗爆剂3份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
实施例3
以以下原料生产具有强抗爆性能的混醇汽油：
汽油44份；
木质纤维素醇类混合物45份；
石脑油4份；
SDA强效抗爆剂3份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
实施例4
以以下原料生产具有强抗爆性能的混醇汽油：
汽油62份；
木质纤维素醇类混合物30份；
石脑油8份；
SDA强效抗爆剂2份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
实施例5
以以下原料生产具有强抗爆性能的混醇汽油：
汽油60份；
木质纤维素醇类混合物30份；
石脑油1份；
SDA强效抗爆剂2份。
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1。
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
对比例1：
以以下成分为原料生产混醇汽油：
汽油53份；
木质纤维素醇类混合物45份；
石脑油2份；
所述的木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的重量比为33:1:1。
所述的SDA强效抗爆剂是由甲基环戊二烯三羰基锰(MMT)、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
在该对比例中，汽油未添加任何抗爆剂。
对比例2：
以以下成分为原料生产混醇汽油：
汽油52份；
木质纤维素醇类混合物40份；
石脑油6份；
SDA强效抗爆剂2份。
所述的木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的重量比为33:1:1。
所述的SDA强效抗爆剂是由甲基环戊二烯三羰基锰(MMT)、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成。
在该对比例中虽然添加了抗爆剂，但木质纤维素醇类混合物与SDA强效抗爆剂没有按照重量比15:1的最优比例添加混合。
试验例1：
下面通过试验进一步阐述本发明混醇汽油的强抗爆性能的特点。
分别以实施例1-5的混醇汽油为检测对象，以对比例1、对比例2的混醇汽油为对比检测对象，按照国家标准GB/T503-1995《汽油辛烷值测定法测定》的要求对上述四种产品分别进行抗爆性能的检测，具体结果见下表：
| 汽油种类 | 辛烷值 |
| 实施例1 | 98.2 |
| 实施例2 | 98.8 |
| 实施例3 | 98.4 |
| 实施例4 | 98.3 |
| 实施例5 | 98.7 |
| 对比例1 | 93.5 |
| 对比例2 | 91.1 |
实验结果表明，按本发明技术方案生产的混醇汽油辛烷值较高，抗爆性能较好。
Claims (3)
1.一种具有强抗爆性能的混醇汽油，其特征在于，该汽油是由以下重量份的原料组分制成：汽油44～62份，木质纤维素醇类混合物30～45份，石脑油1～8份，SDA强效抗爆剂2～3份；
所述木质纤维素醇类混合物是以秸秆为原料经酶解发酵制成，该混合物的主要构成组分为纤维素乙醇、纤维素丁醇与丙酮，上述三种成分的比例为重量比33:1:1；
所述SDA强效抗爆剂是由甲基环戊二烯三羰基锰、二溴正辛烷、异辛酸锰、双丁二酰胺按照重量比5:7:3:1的比例添加混合而成；
所述木质纤维素醇类混合物与SDA强效抗爆剂按照重量比15:1的比例添加混合。
2.如权利要求1所述的具有强抗爆性能的混醇汽油，其特征在于，该汽油是由以下重量份的各组分为原料制成：汽油54份，木质纤维素醇类混合物37.5份，石脑油6份，SDA强效抗爆剂2.5份。
3.如权利要求1所述的具有强抗爆性能的混醇汽油，其特征在于，该汽油是由以下重量份的各组分为原料制成：汽油50份，木质纤维素醇类混合物45份，石脑油2份，SDA强效抗爆剂3份。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5693106A (en) * | 1992-07-22 | 1997-12-02 | Platinum Plus, Inc. | Platinum metal fuel additive for water-containing fuels |
| CN1401743A (zh) * | 2001-08-28 | 2003-03-12 | 济南开发区星火科学技术研究院 | 乙醇混醇汽油 |
| CN1434103A (zh) * | 2002-01-23 | 2003-08-06 | 张明全 | 汽油抗爆剂 |
| CN101955807A (zh) * | 2009-07-17 | 2011-01-26 | 东莞市智造生物科技有限公司 | 生物质纳米汽油液体燃料 |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5693106A (en) * | 1992-07-22 | 1997-12-02 | Platinum Plus, Inc. | Platinum metal fuel additive for water-containing fuels |
| CN1401743A (zh) * | 2001-08-28 | 2003-03-12 | 济南开发区星火科学技术研究院 | 乙醇混醇汽油 |
| CN1434103A (zh) * | 2002-01-23 | 2003-08-06 | 张明全 | 汽油抗爆剂 |
| CN101955807A (zh) * | 2009-07-17 | 2011-01-26 | 东莞市智造生物科技有限公司 | 生物质纳米汽油液体燃料 |
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