CN105462396A - Novel building coating and preparation method thereof - Google Patents

Novel building coating and preparation method thereof Download PDF

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Publication number
CN105462396A
CN105462396A CN201511011648.XA CN201511011648A CN105462396A CN 105462396 A CN105462396 A CN 105462396A CN 201511011648 A CN201511011648 A CN 201511011648A CN 105462396 A CN105462396 A CN 105462396A
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China
Prior art keywords
parts
water
high speed
methyl methacrylate
silicone oil
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Pending
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CN201511011648.XA
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Chinese (zh)
Inventor
辛范范
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Individual
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Individual
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Priority to CN201511011648.XA priority Critical patent/CN105462396A/en
Publication of CN105462396A publication Critical patent/CN105462396A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a novel building coating. The novel building coating is prepared from the following raw materials in parts by weight: 2.5-6.3 parts of isopropyl alcohol, 2.4-7.4 parts of borax, 10-16 parts of calcite powder, 5.4-8.6 parts of organosiloxane, 4.6-7.5 parts of water-based silicone oil, 7.6-8.5 parts of deionized water, 2.7-6.5 parts of phenylacetaldehyde, 25-30 parts of white emulsion, 5-7.5 parts of rosin-polyethylene oxide ester and 2.5-6.3 parts of methyl methacrylate. Compared with existing products, the novel building coating has the beneficial effects that as the calcite powder and the water-based silicone oil are added, the novel building coating has good water and alkali resistance; as phenylacetaldehyde and white emulsion are added, the finished product of the novel building coating has strong penetration and adhesion; as rosin-polyethylene oxide ester and methyl methacrylate are added, the finished product of the novel building coating shields wall cracks.

Description

A kind of NEW PAINT SYSTEMS FOR BUILDINGS and preparation method thereof
Technical field
The present invention relates to a kind of NEW PAINT SYSTEMS FOR BUILDINGS and preparation method thereof, belong to building material field.
Background technology
Emulsion paint is being commonly called as of latex coating, is inner-outer wall building coating popular at present.Coating refers to and is applied to body surface and forms solid-state film, has protection, decoration or a class I liquid I of property or the general name of solid material.Early stage coating is main raw material mainly with vegetables oil greatly, therefore has the title of " paint ".The wide range of coating, varnish, wood lacquer, insullac, automobile finish etc. all belong to the scope of coating.Along with the rise of home decoration trend, building coating is as one that grows stronger day by day in coating family, and consumer relations is day by day close.At present, the security of inner wall of building emulsion paint, health more and more cause the attention of people, and market demand superior performance, function are unique, the indoor paint product of health environment-friendly.The membrane formation mechanism of high molecular polymer emulsion paint is that particle piles up gathering, and film has ventilation property, water-permeable, and constrains the raising of emulsion paint glossiness.Therefore, in formulating of recipe, the coordinative role of the selection of the selection of emulsion particle size, the selection of stability, hardness, the selection of color stuffing system and various auxiliary agent is particularly important.
Summary of the invention
For the deficiency that prior art exists, technical problem to be solved by this invention is, provides a kind of NEW PAINT SYSTEMS FOR BUILDINGS and preparation method thereof, good permeability, scrubbing resistance, can block body of wall crackle.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is, a kind of NEW PAINT SYSTEMS FOR BUILDINGS, is made up of the raw material of following parts by weight: Virahol 2.5-6.3 part, borax 2.4-7.4 part, calcite in powder 10-16 part, organo-siloxane 5.4-8.6 part, water-based silicone oil 4.6-7.5 part, deionized water 7.6-8.5 part, phenylacetic aldehyde 2.7-6.5 part, white glue with vinyl 25-30 part, polyoxylethylene abietate 5-7.5 part and methyl methacrylate 2.5-6.3 part.
Optimize, above-mentioned NEW PAINT SYSTEMS FOR BUILDINGS, is made up of the raw material of following parts by weight: Virahol 5.4 parts, borax 3.5 parts, calcite in powder 12 parts, organo-siloxane 6.3 parts, water-based silicone oil 5.7 parts, deionized water 7.9 parts, phenylacetic aldehyde 3.7 parts, white glue with vinyl 28 parts, polyoxylethylene abietate 6.2 parts and methyl methacrylate 4.2 parts.
A preparation method for NEW PAINT SYSTEMS FOR BUILDINGS, comprises the following steps:
1) first Virahol, borax and deionized water are pressed formula ratio and drop into high speed dispersor high speed stirring 10-12min;
2) take calcite in powder and the organo-siloxane of formula ratio again, join high speed dispersor high speed and stir 5-8min;
3) add water-based silicone oil, deionized water, phenylacetic aldehyde and white glue with vinyl successively after reducing stirring velocity, stir;
4) polyoxylethylene abietate and methyl methacrylate are added in the mixture of step 3), with emulsification pretreatment machine at the emulsified 20-30min of 200-220r/min;
5) be finally heated to 100 DEG C, be cooled to room temperature after thermostatically heating 15min and be finished product.
The present invention, compared with existing product, the invention has the beneficial effects as follows: owing to adding calcite in powder and water-based silicone oil, have good water-fast, alkali resistance; Owing to adding phenylacetic aldehyde and white glue with vinyl, its finished product seepage force, strong adhesion; Owing to adding polyoxylethylene abietate and methyl methacrylate, its finished product blocks body of wall crackle.
Embodiment
embodiment 1
The present invention is a kind of NEW PAINT SYSTEMS FOR BUILDINGS, is made up of the raw material of following parts by weight: Virahol 2.5 parts, borax 2.4 parts, calcite in powder 10 parts, organo-siloxane 5.4 parts, water-based silicone oil 4.6 parts, deionized water 7.6 parts, phenylacetic aldehyde 2.7 parts, white glue with vinyl 25 parts, polyoxylethylene abietate 5 parts and methyl methacrylate 2.5 parts.
A preparation method for NEW PAINT SYSTEMS FOR BUILDINGS, comprises the following steps:
1) first Virahol, borax and deionized water are pressed formula ratio and drop into high speed dispersor high speed stirring 10min;
2) take calcite in powder and the organo-siloxane of formula ratio again, join high speed dispersor high speed and stir 5min;
3) add water-based silicone oil, deionized water, phenylacetic aldehyde and white glue with vinyl successively after reducing stirring velocity, stir;
4) polyoxylethylene abietate and methyl methacrylate are added in the mixture of step 3), with emulsification pretreatment machine at the emulsified 20min of 200r/min;
5) be finally heated to 100 DEG C, be cooled to room temperature after thermostatically heating 15min and be finished product.
embodiment 2
The present invention is a kind of NEW PAINT SYSTEMS FOR BUILDINGS, is made up of the raw material of following parts by weight: Virahol 6.3 parts, borax 7.4 parts, calcite in powder 16 parts, organo-siloxane 8.6 parts, water-based silicone oil 7.5 parts, deionized water 8.5 parts, phenylacetic aldehyde 6.5 parts, white glue with vinyl 30 parts, polyoxylethylene abietate 7.5 parts and methyl methacrylate 26.3 parts.
A preparation method for NEW PAINT SYSTEMS FOR BUILDINGS, comprises the following steps:
1) first Virahol, borax and deionized water are pressed formula ratio and drop into high speed dispersor high speed stirring 12min;
2) take calcite in powder and the organo-siloxane of formula ratio again, join high speed dispersor high speed and stir 8min;
3) add water-based silicone oil, deionized water, phenylacetic aldehyde and white glue with vinyl successively after reducing stirring velocity, stir;
4) polyoxylethylene abietate and methyl methacrylate are added in the mixture of step 3), with emulsification pretreatment machine at the emulsified 30min of 220r/min;
5) be finally heated to 100 DEG C, be cooled to room temperature after thermostatically heating 15min and be finished product.
embodiment 3
The present invention is a kind of NEW PAINT SYSTEMS FOR BUILDINGS, is made up of the raw material of following parts by weight: Virahol 5.4 parts, borax 3.5 parts, calcite in powder 12 parts, organo-siloxane 6.3 parts, water-based silicone oil 5.7 parts, deionized water 7.9 parts, phenylacetic aldehyde 3.7 parts, white glue with vinyl 28 parts, polyoxylethylene abietate 6.2 parts and methyl methacrylate 4.2 parts.
A preparation method for NEW PAINT SYSTEMS FOR BUILDINGS, comprises the following steps:
1) first Virahol, borax and deionized water are pressed formula ratio and drop into high speed dispersor high speed stirring 11min;
2) take calcite in powder and the organo-siloxane of formula ratio again, join high speed dispersor high speed and stir 6min;
3) add water-based silicone oil, deionized water, phenylacetic aldehyde and white glue with vinyl successively after reducing stirring velocity, stir;
4) polyoxylethylene abietate and methyl methacrylate are added in the mixture of step 3), with emulsification pretreatment machine at the emulsified 25min of 210r/min;
5) be finally heated to 100 DEG C, be cooled to room temperature after thermostatically heating 15min and be finished product.
Contrasted by coating finished product in the coating finished product produced in above-described embodiment 1-3 and prior art, detected result is as follows:
The evaluation of application property is difficult to floating coating thickness for standard with obviously sagging during the thick painting of visual inspection generation with during scumbling;
Water-permeable evaluation is tested with reference to JISA6909;
Water tolerance evaluation is soaked in the warm water of 50 DEG C, to occur that the obvious albefaction time is for standard;
Freeze-thaw resistance evaluation is soaked 1 hour in 10 DEG C of water after coating is freezed 2h under-20 DEG C of environment, so repeatedly, to occur significantly ftractureing back number for standard;
Curing shrinkage rate is measured after 30 days in coating standing and drying.Through the interior wall paint that formula of the present invention and preparation technology obtain, there is excellent use properties and workability, the service requirements day by day improved can be met.Owing to adding calcite in powder and water-based silicone oil, have good water-fast, alkali resistance; Owing to adding phenylacetic aldehyde and white glue with vinyl, its finished product seepage force, strong adhesion; Owing to adding polyoxylethylene abietate and methyl methacrylate, its finished product blocks body of wall crackle.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.

Claims (3)

1. a NEW PAINT SYSTEMS FOR BUILDINGS, is characterized in that: be made up of the raw material of following parts by weight: Virahol 2.5-6.3 part, borax 2.4-7.4 part, calcite in powder 10-16 part, organo-siloxane 5.4-8.6 part, water-based silicone oil 4.6-7.5 part, deionized water 7.6-8.5 part, phenylacetic aldehyde 2.7-6.5 part, white glue with vinyl 25-30 part, polyoxylethylene abietate 5-7.5 part and methyl methacrylate 2.5-6.3 part.
2. NEW PAINT SYSTEMS FOR BUILDINGS according to claim 1, is characterized in that: be made up of the raw material of following parts by weight: Virahol 5.4 parts, borax 3.5 parts, calcite in powder 12 parts, organo-siloxane 6.3 parts, water-based silicone oil 5.7 parts, deionized water 7.9 parts, phenylacetic aldehyde 3.7 parts, white glue with vinyl 28 parts, polyoxylethylene abietate 6.2 parts and methyl methacrylate 4.2 parts.
3. the preparation method of the NEW PAINT SYSTEMS FOR BUILDINGS according to claims 1 or 2, comprises the following steps:
1) first Virahol, borax and deionized water are pressed formula ratio and drop into high speed dispersor high speed stirring 10-12min;
2) take calcite in powder and the organo-siloxane of formula ratio again, join high speed dispersor high speed and stir 5-8min;
3) add water-based silicone oil, deionized water, phenylacetic aldehyde and white glue with vinyl successively after reducing stirring velocity, stir;
4) polyoxylethylene abietate and methyl methacrylate are added in the mixture of step 3), with emulsification pretreatment machine at the emulsified 20-30min of 200-220r/min;
5) be finally heated to 100 DEG C, be cooled to room temperature after thermostatically heating 15min and be finished product.
CN201511011648.XA 2015-12-30 2015-12-30 Novel building coating and preparation method thereof Pending CN105462396A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511011648.XA CN105462396A (en) 2015-12-30 2015-12-30 Novel building coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511011648.XA CN105462396A (en) 2015-12-30 2015-12-30 Novel building coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105462396A true CN105462396A (en) 2016-04-06

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101565580A (en) * 2009-05-26 2009-10-28 鳄鱼制漆(上海)有限公司 Preparation and construction process for bottom-coating used for mineral cotton ceiling floor
JP2010248306A (en) * 2009-04-13 2010-11-04 Aica Kogyo Co Ltd One-component aqueous coating composition which imparts architectural design to outer wall of building
CN102206448A (en) * 2010-03-31 2011-10-05 王胜美 Production method of emulsion paint for interior wall
CN104177978A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Building house coating material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010248306A (en) * 2009-04-13 2010-11-04 Aica Kogyo Co Ltd One-component aqueous coating composition which imparts architectural design to outer wall of building
CN101565580A (en) * 2009-05-26 2009-10-28 鳄鱼制漆(上海)有限公司 Preparation and construction process for bottom-coating used for mineral cotton ceiling floor
CN102206448A (en) * 2010-03-31 2011-10-05 王胜美 Production method of emulsion paint for interior wall
CN104177978A (en) * 2013-05-27 2014-12-03 青岛极致节能环保有限公司 Building house coating material

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Application publication date: 20160406

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