CN105462384A - Novel environment-friendly latex paint and preparation method thereof - Google Patents
Novel environment-friendly latex paint and preparation method thereof Download PDFInfo
- Publication number
- CN105462384A CN105462384A CN201511011632.9A CN201511011632A CN105462384A CN 105462384 A CN105462384 A CN 105462384A CN 201511011632 A CN201511011632 A CN 201511011632A CN 105462384 A CN105462384 A CN 105462384A
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- novel environment
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- acrylic acid
- acid copolymer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a novel environment-friendly latex paint which is prepared from the following raw materials in parts by weight: 10-25 parts of styrene-acrylate odor-removed emulsion, 2.2-4.8 parts of cyfluthrin, 10-15 parts of titanium dioxide, 2.5-4.8 parts of myrac aldehyde, 7.5-8.8 parts of deionized water, 1.7-3.8 parts of phenethylcumenyl phenol polyoxyethylene ether, 2.5-4.7 parts of butadiene resin film forming agent and 3.3-6.5 parts of ethylene-acrylic acid copolymer. Compared with the existing products, the novel environment-friendly latex paint disclosed by the invention has the following beneficial effects: due to the addition of styrene-acrylate odor-removed emulsion and cyfluthrin, the latex paint has good water resistance and alkali resistance; due to the addition of myrac aldehyde and butadiene resin film forming agent, the seepage force and adhesive force of the finished product are strong; and due to the addition of phenethylcumenyl phenol polyoxyethylene ether and ethylene-acrylic acid copolymer, the finished product covers wall cracks.
Description
Technical field
The present invention relates to a kind of novel environment friendly emulsion paint and preparation method thereof, belong to building material field.
Background technology
Emulsion paint is being commonly called as of latex coating, is inner-outer wall building coating popular at present.Coating refers to and is applied to body surface and forms solid-state film, has protection, decoration or a class I liquid I of property or the general name of solid material.Early stage coating is main raw material mainly with vegetables oil greatly, therefore has the title of " paint ".The wide range of coating, varnish, wood lacquer, insullac, automobile finish etc. all belong to the scope of coating.Along with the rise of home decoration trend, building coating is as one that grows stronger day by day in coating family, and consumer relations is day by day close.At present, the security of inner wall of building emulsion paint, health more and more cause the attention of people, and market demand superior performance, function are unique, the indoor paint product of health environment-friendly.The membrane formation mechanism of high molecular polymer emulsion paint is that particle piles up gathering, and film has ventilation property, water-permeable, and constrains the raising of emulsion paint glossiness.Therefore, in formulating of recipe, the coordinative role of the selection of the selection of emulsion particle size, the selection of stability, hardness, the selection of color stuffing system and various auxiliary agent is particularly important.
Summary of the invention
For the deficiency that prior art exists, technical problem to be solved by this invention is, provides a kind of novel environment friendly emulsion paint and preparation method thereof, good permeability, scrubbing resistance, can block body of wall crackle.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is, a kind of novel environment friendly emulsion paint, is made up of the raw material of following parts by weight: phenylpropyl alcohol clean taste emulsion 10-25 part, cyfloxylate 2.2-4.8 part, titanium dioxide 10-15 part, Myracaldehyde 2.5-4.8 part, deionized water 7.5-8.8 part, styroyl cumyl phenol polyethenoxy ether 1.7-3.8 part, butadiene resin membrane-forming agent 2.5-4.7 part and ethylene-acrylic acid copolymer 3.3-6.5 part.
Optimize, above-mentioned novel environment friendly emulsion paint, is made up of the raw material of following parts by weight: the clean taste emulsion of phenylpropyl alcohol 17 parts, cyfloxylate 2.8 parts, titanium dioxide 13.5 parts, Myracaldehyde 3.6 parts, deionized water 7.9 parts, styroyl cumyl phenol polyethenoxy ether 2.4 parts, butadiene resin membrane-forming agent 3.8 parts and ethylene-acrylic acid copolymer 4.5 parts.
A preparation method for novel environment friendly emulsion paint, comprises the following steps:
(1) by above-mentioned formula, clean for phenylpropyl alcohol taste emulsion and cyfloxylate are added deionized water mixing, insert in agitator and stir 25 ~ 30 minutes, stirring velocity 200 ~ 300r/min, is heated to 40 ~ 45 DEG C, and keeps temperature;
(2) then the titanium dioxide of formula ratio and Myracaldehyde are slowly added successively, stir 10 ~ 15 minutes, stirring velocity 300 ~ 400r/min, obtains milk sap;
(3) milk sap that step (2) obtains is cooled to 14 ~ 16 DEG C, then adds styroyl cumyl phenol polyethenoxy ether, reduce rotating speed and carry out dispersion stirring 10min with 200-250r/min;
(4) butadiene resin membrane-forming agent and the ethylene-acrylic acid copolymer of formula ratio is finally added, continuously stirring 30min;
(5) homogeneous 10-25min in the high pressure homogenizer of 25-30MPa, homogenization pressure 25-35Mpa, then cool to room temperature.
The present invention, compared with existing product, the invention has the beneficial effects as follows: owing to adding the clean taste emulsion of phenylpropyl alcohol and cyfloxylate, have good water-fast, alkali resistance; Owing to adding Myracaldehyde and butadiene resin membrane-forming agent, its finished product seepage force, strong adhesion; Owing to adding styroyl cumyl phenol polyethenoxy ether and ethylene-acrylic acid copolymer, its finished product blocks body of wall crackle.
Embodiment
Embodiment 1
The present invention is a kind of novel environment friendly emulsion paint, is made up of the raw material of following parts by weight: the clean taste emulsion of phenylpropyl alcohol 10 parts, cyfloxylate 2.2 parts, titanium dioxide 10 parts, Myracaldehyde 2.5 parts, deionized water 7.5 parts, styroyl cumyl phenol polyethenoxy ether 1.7 parts, butadiene resin membrane-forming agent 2.5 parts and ethylene-acrylic acid copolymer 3.3 parts.
A preparation method for novel environment friendly emulsion paint, comprises the following steps:
(1) by above-mentioned formula, clean for phenylpropyl alcohol taste emulsion and cyfloxylate are added deionized water mixing, insert in agitator and stir 25 minutes, stirring velocity 200r/min, is heated to 40 DEG C, and keeps temperature;
(2) then the titanium dioxide of formula ratio and Myracaldehyde are slowly added successively, stir 10 minutes, stirring velocity 300r/min, obtains milk sap;
(3) milk sap that step (2) obtains is cooled to 14 DEG C, then adds styroyl cumyl phenol polyethenoxy ether, reduce rotating speed and carry out dispersion stirring 10min with 200r/min;
(4) butadiene resin membrane-forming agent and the ethylene-acrylic acid copolymer of formula ratio is finally added, continuously stirring 30min;
(5) homogeneous 10min in the high pressure homogenizer of 25-30MPa, homogenization pressure 25Mpa, then cool to room temperature.
Embodiment 2
The present invention is a kind of novel environment friendly emulsion paint, is made up of the raw material of following parts by weight: the clean taste emulsion of phenylpropyl alcohol 25 parts, cyfloxylate 4.8 parts, titanium dioxide 15 parts, Myracaldehyde 4.8 parts, deionized water 8.8 parts, styroyl cumyl phenol polyethenoxy ether 3.8 parts, butadiene resin membrane-forming agent 4.7 parts and ethylene-acrylic acid copolymer 6.5 parts.
A preparation method for novel environment friendly emulsion paint, comprises the following steps:
(1) by above-mentioned formula, clean for phenylpropyl alcohol taste emulsion and cyfloxylate are added deionized water mixing, insert in agitator and stir 30 minutes, stirring velocity 300r/min, is heated to 45 DEG C, and keeps temperature;
(2) then the titanium dioxide of formula ratio and Myracaldehyde are slowly added successively, stir 15 minutes, stirring velocity 400r/min, obtains milk sap;
(3) milk sap that step (2) obtains is cooled to 16 DEG C, then adds styroyl cumyl phenol polyethenoxy ether, reduce rotating speed and carry out dispersion stirring 10min with 250r/min;
(4) butadiene resin membrane-forming agent and the ethylene-acrylic acid copolymer of formula ratio is finally added, continuously stirring 30min;
(5) homogeneous 25min in the high pressure homogenizer of 25-30MPa, homogenization pressure 35Mpa, then cool to room temperature.
Embodiment 3
The present invention is a kind of novel environment friendly emulsion paint, is made up of the raw material of following parts by weight: the clean taste emulsion of phenylpropyl alcohol 17 parts, cyfloxylate 2.8 parts, titanium dioxide 13.5 parts, Myracaldehyde 3.6 parts, deionized water 7.9 parts, styroyl cumyl phenol polyethenoxy ether 2.4 parts, butadiene resin membrane-forming agent 3.8 parts and ethylene-acrylic acid copolymer 4.5 parts.
A preparation method for novel environment friendly emulsion paint, comprises the following steps:
(1) by above-mentioned formula, clean for phenylpropyl alcohol taste emulsion and cyfloxylate are added deionized water mixing, insert in agitator and stir 28 minutes, stirring velocity 260r/min, is heated to 42 DEG C, and keeps temperature;
(2) then the titanium dioxide of formula ratio and Myracaldehyde are slowly added successively, stir 12 minutes, stirring velocity 360r/min, obtains milk sap;
(3) milk sap that step (2) obtains is cooled to 15 DEG C, then adds styroyl cumyl phenol polyethenoxy ether, reduce rotating speed and carry out dispersion stirring 10min with 220r/min;
(4) butadiene resin membrane-forming agent and the ethylene-acrylic acid copolymer of formula ratio is finally added, continuously stirring 30min;
(5) homogeneous 15min in the high pressure homogenizer of 25-30MPa, homogenization pressure 28Mpa, then cool to room temperature.
Contrasted by coating finished product in the coating finished product produced in above-described embodiment 1-3 and prior art, detected result is as follows:
Can find out, the indices of coating of the present invention is considerably beyond GB, and its production technique is simple, is convenient to large-scale popularization.Compared with existing product, the invention has the beneficial effects as follows: owing to adding the clean taste emulsion of phenylpropyl alcohol and cyfloxylate, have good water-fast, alkali resistance; Owing to adding Myracaldehyde and butadiene resin membrane-forming agent, its finished product seepage force, strong adhesion; Owing to adding styroyl cumyl phenol polyethenoxy ether and ethylene-acrylic acid copolymer, its finished product blocks body of wall crackle.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (3)
1. a novel environment friendly emulsion paint, is characterized in that: be made up of the raw material of following parts by weight: benzene emulsion 10-25 part, cyfloxylate 2.2-4.8 part, titanium dioxide 10-15 part, Myracaldehyde 2.5-4.8 part, deionized water 7.5-8.8 part, styroyl cumyl phenol polyethenoxy ether 1.7-3.8 part, butadiene resin membrane-forming agent 2.5-4.7 part and ethylene-acrylic acid copolymer 3.3-6.5 part.
2. novel environment friendly emulsion paint according to claim 1, is characterized in that: be made up of the raw material of following parts by weight: the clean taste emulsion of phenylpropyl alcohol 17 parts, cyfloxylate 2.8 parts, titanium dioxide 13.5 parts, Myracaldehyde 3.6 parts, deionized water 7.9 parts, styroyl cumyl phenol polyethenoxy ether 2.4 parts, butadiene resin membrane-forming agent 3.8 parts and ethylene-acrylic acid copolymer 4.5 parts.
3. the preparation method of the novel environment friendly emulsion paint according to claims 1 or 2, comprises the following steps:
(1) by above-mentioned formula, clean for phenylpropyl alcohol taste emulsion and cyfloxylate are added deionized water mixing, insert in agitator and stir 25 ~ 30 minutes, stirring velocity 200 ~ 300r/min, is heated to 40 ~ 45 DEG C, and keeps temperature;
(2) then the titanium dioxide of formula ratio and Myracaldehyde are slowly added successively, stir 10 ~ 15 minutes, stirring velocity 300 ~ 400r/min, obtains milk sap;
(3) milk sap that step (2) obtains is cooled to 14 ~ 16 DEG C, then adds styroyl cumyl phenol polyethenoxy ether, reduce rotating speed and carry out dispersion stirring 10min with 200-250r/min;
(4) butadiene resin membrane-forming agent and the ethylene-acrylic acid copolymer of formula ratio is finally added, continuously stirring 30min;
(5) homogeneous 10-25min in the high pressure homogenizer of 25-30MPa, homogenization pressure 25-35Mpa, then cool to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511011632.9A CN105462384A (en) | 2015-12-30 | 2015-12-30 | Novel environment-friendly latex paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511011632.9A CN105462384A (en) | 2015-12-30 | 2015-12-30 | Novel environment-friendly latex paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105462384A true CN105462384A (en) | 2016-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511011632.9A Pending CN105462384A (en) | 2015-12-30 | 2015-12-30 | Novel environment-friendly latex paint and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693378A (en) * | 2005-05-13 | 2005-11-09 | 上海玉平化学材料有限公司 | Environmental protection type insecticide coating and its preparation tech. |
| CN103130448A (en) * | 2011-11-30 | 2013-06-05 | 李建国 | Efficient and environment-friendly emulsion paint |
-
2015
- 2015-12-30 CN CN201511011632.9A patent/CN105462384A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693378A (en) * | 2005-05-13 | 2005-11-09 | 上海玉平化学材料有限公司 | Environmental protection type insecticide coating and its preparation tech. |
| CN103130448A (en) * | 2011-11-30 | 2013-06-05 | 李建国 | Efficient and environment-friendly emulsion paint |
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Application publication date: 20160406 |