CN105442164A - Knitted fabric having flame retardant and temperature regulating function and production method thereof - Google Patents
Knitted fabric having flame retardant and temperature regulating function and production method thereof Download PDFInfo
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Abstract
The invention relates to knitted fabric having a flame retardant and temperature regulating function and a production method thereof. The knitted fabric is formed by spinning 30-40 wt% of anti-frayon fiber, 20-30 wt% of phase change energy storage fiber, 20-30 wt% of cotton and 20-30 wt% of Jutecell fiber by feeding yarn uniformly. A spinning method of siro compact spinning is utilized, and a knitted fabric preliminary finished product is made from blended yarn through the spinning of a double-faced machine and undergoes pre-dyeing preshaping treatment, pre-dyeing treatment, dyeing, neutralization, soaping, fixation, drying and shaping treatment to obtain the novel anti-frayon and phase change energy storage fiber knitted fabric with the flame retardant and temperature regulating function. Compared with the prior art, the knitted fabric has moisture absorption, heating and flame retardant effects, and the fabric surface texture is full and smooth when a user wears the knitted fabric.
Description
Technical field
The present invention relates to a kind of knit fabric and preparation method thereof, especially relate to one and there is flame-resistant temperature-adjustmenon-woven functional knitted fabric and preparation method thereof.
Background technology
Knitwear development be rapidly will come " speaking " with product, how product is the theme of current knit fabric and garment development with comfortableness, functional, fashion, security and the feature of environmental protection.Nowadays market, autonomous creative design had sternly so had update relative to the past.China's innovation is still in very rudimentary level in the past ten years, too worries that vested capital and technology do not obtain the market effect of expection.The investigation in market is the most important factor of market reaction, is also the received the only way which must be passed of any product.
Nowadays, global textile industry is the most prosperity epoch, and everybody focuses on taste in clothes, inherent comfort.What people had higher standard, requirements at the higher level to propose more renewals to knitwear to dress day by day takes requirement, to the demand of product function, also by single function to the Mobyneb transformation such as comfortable, healthy, safe.
Chinese patent CN102433631A discloses a kind of method that 40s Siro-spun yarn produced by An Fuli fire resistance fibre.An Fuli fire resistance fibre through blowing, comb and parallel cotton fibers prior to spinning, three road draftings, then produces the cylinder yarn of needs through rove, spun yarn, winding procedure.This invention carding procedure reduces short flannel to be produced, reduces electrostatic, prevents lap licking; And strip adoption three road drafting, reduce the weight unevenness of strip; Roving Frames prevents sliver, rove bar scared, improves yarn channel and each parts fineness; Fine spining machine installs Siro-spun yarn device additional; Winding procedure adopts the clear technique of electricity.And the application emphasizes how scientific system ground comprehensive exploitation and uses these Fresh fats, make it adapt to and lead market toward science and technology-oriented future development and consumption, and rise to a brand-new science and technology market aspect, Palladio company has made and comparatively successfully having attempted.Make thermal protection knitted fabric have anti-flaming function concurrently and become possibility, from fire prevention angle, add the security function of fabric to human body, in the exploitation of knit fabric function, impart the meaning of new and high technology, the science and technology of knit fabric is made the transition and has gone up a new step.
Summary of the invention
Object of the present invention be exactly in order to overcome above-mentioned prior art exist defect and provide a kind of can underwear produce in use there is flame-resistant temperature-adjustmenon-woven functional knitted fabric and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
One has flame-resistant temperature-adjustmenon-woven functional knitted fabric, evenly send yarn to spin form by 30-40wt% An Fuli fiber, 20-30wt% phase-change energy-storage fibre, 20-30wt% cotton and the numb Sai Er fiber of 20-30wt%.
This knit fabric preferably evenly send yarn to spin by An Fuli fiber 35%, phase-change energy-storage fibre 25%, cotton fiber 20% and numb Sai Er fiber 20% and forms.
Described An Fuli fiber is Fire resistant viscose fiber, take regenerated cellulose as raw material, add the phosphorus flame retardant of independent development, employing adds blending technology before spinning, both ensure that fiber quality was soft, smooth, achieve again the characteristics such as permanent fire retardant, low cigarette, nontoxic, not melting drippage, the trade mark preferably adopting Heng Tian sea otter company to produce is the fiber with flame-retardant and anti-dripping performance of Anti-frayon.
Described phase-change energy-storage fibre is the viscose adopting encapsulation phase-change material, and can store with the form of latent heat and release energy, the environmentally change of temperature, can be solid-state, and liquid state transforms mutually, thus reach the effect of heat absorption, heat release.
There is a preparation method for flame-resistant temperature-adjustmenon-woven functional knitted fabric, adopt following steps:
(1) prepare raw material according to formula and evenly send yarn making to obtain blended yarn;
(2) adopt the spinning method of match network compact spinning that blended yarn is made knit fabric just finished product by Double-plate machine weaving;
(3) by knit fabric just finished product pre-setting process before dyeing, dyeing pre-treatment, dyeing, neutralize, soap, fixation, oven dry and heat treatment, namely make and obtain flame-resistant temperature-adjustmenon-woven functional knitted fabric.
The yarn count of described blended yarn is 32S-40S, and blended yarn controls the twist at 900-950, and twist factor is between 360-380.
Described blended yarn is woven into the fabric of bilateral structure, and every road 32-40S compact spinning blended yarn and 30D elastic spandex fiber are formed, and the loop length on each road is 15.5-16.5cm/50 pin.
The theory that the present invention does not go the skin-friendly broken through to extend in the middle of underwear industry is carried out in reality.Analyze: this fiber of An Fuli fiber with aftergrowth fiber for raw material, phosphorus flame retardant is added in production process, employing adds blending technology before spinning, and both ensure that fiber quality was soft, smooth, achieves again the characteristics such as permanent fire retardant, low cigarette, nontoxic, not melting drippage.And the key problem in technology that phase-change accumulation energy viscose also has is the phase-change material using encapsulation.This material can store with the form of latent heat and release energy.The environmentally change of temperature, can be solid-state, and liquid state transforms mutually, thus reach the effect of heat absorption, heat release.It is when temperature is higher than phase transition temperature, absorb heat to undergo phase transition (thawing heat-accumulating process), when temperature is lower than phase transition temperature, there is reverse alternating temperature (solidifying exothermic process), good miniclimate is defined between health and clothes (or other products), corresponding reaction is made in the change of environment temperature on skin to external world, thus realizes the object regulating temperature.Participating in the maximum advantage of cotton fiber is exactly strengthen the spinnability also increasing several fiber, and cotton fiber natural convolution has certain cohesive force, is conducive to spinning process.Cotton fiber has good hygroscopicity and certain ABRASION RESISTANCE, and regain reaches 8%.Do not have electrostatic, moisture absorbing and sweat releasing property is better, and good permeability, compares to press close to human body, makes clothes comfortable and easy to wear with it, without pilling effect, soft, has the following advantages:
(1) An Fuli fiber claims fire resistance fibre, also known as resistance to combustion, and difficult combustion or flame-proof fibre.It refers to only glows in flame, and itself flame does not occur, and leaves burning things which may cause a fire disaster, the chemical fibre of the self-extinguish that glows.Fire-retardant approach be generally to be gone there being the fire retardant of anti-flaming function to join in chemical fibre by polymer polymerizing, blended, copolymerization, the method such as composite spinning and graft modification or with afterfinish method by the inside of fire retardant coating at fiber surface or infiltrated fiber.
(2) weave the two-sided weave of employing, soft, good springiness, cloth cover are neat and well spaced, lines is clear, its stability is better than single jersey and rib fabric.Be lining into spandex fibre in fabric simultaneously and make that fabric is originally more stable, solid sense is stronger, enhance skin-friendly and warmth retention property.Formulate technique by smooth with cloth cover with the effect of comfortable feel, make cloth covering weave plentiful smooth.
(3) how fire resistance fibre is applied on knitted underwear, slows down and the time of afterignition and chance, will important safety guarantee effect be had for life.The starting point of these research and development is just the basic wearability using this fiber in conjunction with underwear, is aided with moisture absorption heating technical functionality, and attempting research and development aly can have fire-retardant fireproof security function, has again a Novel hosiery fabric of cold-proof comfort.An Fuli Fire resistant viscose fiber is high technical fibre, not only has good anti-flaming function, and has heat-insulation and heat-preservation function, is the ideal material manufacturing fire-retardant double cold-proof knitted underwear shell fabric; Phase-change accumulation energy viscose is ripe heat-accumulation temperature-adjustment new textile material, is also the ideal fibres producing moisture absorption heating insulation knitted underwear; An Fuli fire resistance fibre adds moisture absorption heating holds concurrently the exploitation of thermal protection knitted fabric, there is pioneering meaning undoubtedly, make thermal protection knitted fabric have anti-flaming function concurrently and become possibility, from fire prevention angle, add the security function of fabric to human body, in the exploitation of knit fabric function, impart the meaning of new and high technology, the science and technology of knit fabric is made the transition and has gone up a new step.
(4) fabric that the proportioning of blended yarn is knitted enhances moisture absorption heating effect, the data of examining report display reach more than industry standard: moisture absorption heating intensification value (most promotion temperature value) 9.1 DEG C (standard-required >=4.0 DEG C), moisture absorption heating intensification value (in 30 minutes average intensification value) 4.1 DEG C (standard-required >=3.0 DEG C), insulation rate reaches 32.38% (standard-required must not lower than 30%).
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Feedstock portions:
A, the ratio of blended yarn: An Fuli fiber 35wt%, phase-change energy-storage fibre 25wt%, cotton 20wt% and numb Sai Er 20wt%, the yarn count of spinning is tried to spin by scope 32S-40S, finally take 32S, play An Fuli fire resistance fibre to add moisture absorption heating and to hold concurrently the exploitation of thermal protection knitted fabric, there is pioneering meaning undoubtedly, make thermal protection knitted fabric have anti-flaming function concurrently and become possibility, from fire prevention angle, add the security function of fabric to human body, in the exploitation of knit fabric function, impart the meaning of new and high technology, the science and technology of knit fabric is made the transition and has gone up a new step.Detect through National Knitting Product Quality Supervision Inspection Center of authoritative institution, its insulation rate is in industry standard more than 30%.In addition, this fiber has antibacterial effect.
B, spinning method adopt match network compact spinning: get the optimal twist with this method regulation and control yarn and strengthen the brute force of yarn and reduce the filoplume of yarn, make yarn all claim that ultimate strength is weakened brighter and cleaner.
The twist factor of C, yarn: select suitable twist factor, yarn controls too tightly do not have submissive sense, and Tai Song loses intensity again, adopts between suitable 360-380, makes the anti-pilling property of yarn control to some extent both can.
E, yarn arrays: every Lu Junyong 32S compact spinning blended yarn and 30D elastic spandex fiber
F, loop length: 32S compact spinning blended yarn: 16CM/50 pin
30D elastic spandex fiber: 5CM/50 pin
G, line yarn tension: 32S compact spinning blended yarn is: 5.3CN; 30D elastic spandex fiber 6-7CN
H, blank grammes per square metre: 280-290G/m
2
Dyeing and finishing part:
A, pre-setting process:
Pre-setting equipment is setting machine, and for guaranteeing the door web stabilization of stockinette finished fabric, and the requirement of washing shrinkage must make technological requirement, before dyeing and finishing processing, have to pass through pre-setting process.General temperature 180 DEG C, the speed of a motor vehicle 25 meters points, the speed of a motor vehicle wants uniformity, must strict Controlling Technology condition, and the too high or speed of a motor vehicle of temperature is crossed and finished fabric elasticity can be caused slowly not enough, and door is excessive.
B, dyeing pre-treatment:
Selected applicable degreaser, high-efficient penetrant, chelated dispersants.To guarantee the stability dyeed.Process conditions are: bath raio 1:15, and temperature at the uniform velocity rises to 100 DEG C by normal temperature, and the time is 60 minutes, temperature retention time 20 minutes.
C, dyeing:
Dyestuff is normal temperature REACTIVE DYES (Chinese red, violet, dark blue, black), and auxiliary agent is water softener, levelling agent, glauber salt, soda ash.Process conditions are: bath raio 1:12, heating and heat preservation of keeping under strict control curve, and temperature rises to 60 DEG C from normal temperature, and heating rate is 0.5 DEG C/min, and during temperature to 60 DEG C, sample cutting is checked colors.
D, neutralization:
Auxiliary agent is weaving neutralizing acid, by proportioning temperature regulating 60 DEG C, each 20 minutes of time, crosses twice.
E, to soap:
Soaping agent, by proportioning temperature regulating 90 DEG C, each 20 minutes of time, crosses twice.
F, fixation:
Color-fixing agent, by proportioning temperature regulating 60 DEG C, each 20 minutes of time.
G, oven dry:
Adopt tower drier, steam pressure 2KG, 30 minutes time
H, sizing:
Employing equipment is 8 joint baking oven tentering heat setting machines, and auxiliary agent is hydrophilic soft additive, smooth agent, leavening agent, by proportioning temperature regulating 180 DEG C, and regulation speed 12 ms/min, upper overfeeding+25%, lower overfeeding+5%, slope 3%;
Trimmed size: grammes per square metre 280-290G/m
2(by regulation same level fabric gram five grammes per square metres, be 286G/m
2), effective gate width 160CM (rim charge respectively stays 1.5CM, controls not waste as far as possible)
Processing technology routine
Spin → weave → grey cloth checks → joins before cloth → row's cylinder → dyeing that pre-setting process → dyeing pre-treatment → dye → neutralize → → fixation → oven dry → sizing → finished product fabric → packaging → warehouse-in of soaping
Feedstock portions: select An Fuli Fire resistant viscose fiber, this fiber for raw material, can add phosphorus flame retardant with aftergrowth fiber in process of production, adopts before spinning and adds blending technology, both ensure that the high strength of fiber, and achieved permanent fire retardant again.It is the high-tech product in regenerated celulose fibre with distinct thermal property.Fire resistance fibre, also known as resistance to combustion, difficult combustion or flame-proof fibre.It refers in flame only fire-retardant, and itself flame does not occur, and leaves burning things which may cause a fire disaster, the chemical fibre of fire-retardant self-extinguish.The fabric made not only has good skin-friendly, moisture absorption heating, is the good anti-flammability of itself and heat insulating ability the most significantly, is conducive to spinning process, not balling-up, good hygroscopicity, is applicable to pro-skin.This is be worth developing and application in underwear industry.
How in underwear fabric, effectively to utilize An Fuli Fire resistant viscose fiber, can give full play to the advantage of this fiber, can reach again the requirement of fabric comfortableness, this is the key technology needing specific aim development in many ways.This process choice dynamic be lost wheel fiber, An Fuli fiber and cotton fiber blending.Consider from fabric performance and consumer, the ratio is preferably: the preferred 35wt% of An Fuli fiber, phase-change energy-storage fibre 25wt%, cotton 20wt% and numb Sai Er 20wt%.
The spinning method that blended yarn is selected is match network compact spinning, and yarn controls the twist at 900-950, and twist factor is between 360-380.This spinning method strictly in the process of spinning must control the twist and twist factor, the data therefrom obtained should embody An Fuli Fire resistant viscose fiber and not only have good skin-friendly, moisture absorption heating, the good anti-flammability of itself and heat insulating ability the most significantly, in conjunction with quality softness, smooth phase-change energy-storage fibre, cotton fiber and numb Sai Er fiber, achieve An Fuli fire resistance fibre to add moisture absorption heating and to hold concurrently the exploitation of thermal protection knitted fabric, there is pioneering meaning undoubtedly, make thermal protection knitted fabric have anti-flaming function concurrently and become possibility, from fire prevention angle, add the security function of fabric to human body, in the exploitation of knit fabric function, impart the meaning of new and high technology, the science and technology of knit fabric is made the transition and has gone up a new step.
The An Fuli fiber of this fabric not only has good anti-flaming function, and there is heat-insulation and heat-preservation function, it is the ideal material manufacturing fire-retardant double cold-proof knitted underwear shell fabric, having phase-change accumulation energy viscose to be ripe heat-accumulation temperature-adjustment new textile material again, is also the ideal fibres producing moisture absorption heating insulation knitted underwear.Cotton fiber great advantage is spinnability, has certain cohesive force, is conducive to spinning process, not balling-up, good hygroscopicity, is applicable to pro-skin.More pro-skin worn by the fabric adopting this fiber to be made into, and moisture absorption heating, heat insulating ability and fire resistance are further enhanced, fibrous woven processing and wearability better.
Embodiment 2
A kind of An Fuli+phase-change energy-storage fibre novel flame-retardant temperature adjustment function knit fabric, this knit fabric evenly send yarn to spin by An Fuli fiber 30wt%, phase-change energy-storage fibre 20wt%, cotton 20wt% and numb Sai Er 20wt% and forms.An Fuli Fire resistant viscose fiber.It is the weaving Fire resistant viscose fiber having a kind of high-tech content that sea otter company develops after An Fusai fire resistance fibre.This fiber for raw material, adds phosphorus flame retardant in production process with aftergrowth fiber, adopts before spinning and adds blending technology, both ensure that the high strength of fiber, and achieved permanent fire retardant again.The textile yarn with high-low temperature resistant characteristic, anti-flammability and splendid thermal insulation can be spun into.An Fuli is in normal temperature and low temperature environment, and feel even can match in excellence or beauty with cashmere, can apply cold-proof aspect completely.
An Fuli+phase-change energy-storage fibre novel flame-retardant temperature adjustment function knit fabric preparation method, comprises the following steps:
(1) preferred for An Fuli fiber 30wt%, phase-change energy-storage fibre 30wt%, cotton 20wt% and numb Sai Er 20wt% are evenly sent yarn to make and obtain blended yarn;
(2) adopt the spinning method of match network compact spinning that blended yarn is made knit fabric just finished product by two-sided large circle machine weaving, blended yarn controls the twist 920, twist factor is 350, the yarn count of blended yarn is 40S, blended yarn is woven into the fabric of cotton wool structure, every road 40S compact spinning blended yarn and 30D elastic spandex fiber are formed, and the loop length on each road is 16cm/50 pin, and elastic fibers length is every 4.8cm/50 pin;
(3) by knit fabric just finished product pre-setting process before dyeing, dyeing pre-treatment, dyeing, neutralize, soap, fixation, oven dry and heat treatment, namely make and obtain the composite functional fiber knit fabric with moisture absorption heating.
The fabric that the proportioning of above ratio institute spinning mixed yarn is knitted enhances moisture absorption heating effect, the data of examining report display reach more than industry standard: moisture absorption heating intensification value (most promotion temperature value) 7.8 DEG C (standard-required >=4.0 DEG C), moisture absorption heating intensification value (in 30 minutes average intensification value) 3.3 DEG C (standard-required >=3.0 DEG C), insulation rate reaches 30.67% (standard-required must not lower than 30%).
Embodiment 3
A kind of An Fuli+phase-change energy-storage fibre novel flame-retardant temperature adjustment function knit fabric, this knit fabric evenly send yarn to spin by An Fuli fiber 35wt%, phase-change energy-storage fibre 25wt%, cotton 20wt% and numb Sai Er 20wt% and forms.An Fuli Fire resistant viscose fiber.This fiber for raw material, adds phosphorus flame retardant in production process with aftergrowth fiber, adopts before spinning and adds blending technology, both ensure that the high strength of fiber, and achieved permanent fire retardant again.It is the high-tech product in regenerated celulose fibre with distinct thermal property.Fire resistance fibre, also known as resistance to combustion, difficult combustion or flame-proof fibre.It refers in flame only fire-retardant, and itself flame does not occur, and leaves burning things which may cause a fire disaster, the chemical fibre of fire-retardant self-extinguish.
The preparation method of An Fuli+phase-change energy-storage fibre novel flame-retardant temperature adjustment function knit fabric, comprises the following steps:
(1) preferred for An Fuli fiber 35wt%, phase-change energy-storage fibre 25wt%, cotton 20wt% and numb Sai Er 20wt% cotton fiber are evenly sent yarn to make and obtain blended yarn;
(2) adopt the spinning method of match network compact spinning that blended yarn is made knit fabric just finished product by single knitting machine weaving, blended yarn controls the twist 950, twist factor is 380, the yarn count of blended yarn is 40S, blended yarn is woven into the fabric of single jersey structure, every road 40S compact spinning blended yarn and 30D elastic spandex fiber are formed, and the loop length on each road is 17.3cm/50 pin, and elastic fibers is every 4.8cm/50 pin;
(3) by knit fabric just finished product pre-setting process before dyeing, dyeing pre-treatment, dyeing, neutralize, soap, fixation, oven dry and heat treatment, namely make and obtain the composite functional fiber knit fabric with moisture absorption heating.
The fabric that the proportioning of above ratio institute spinning mixed yarn is knitted enhances moisture absorption heating effect, the data of examining report display have one not reach more than industry standard: moisture absorption heating intensification value (most promotion temperature value) 8.1 DEG C (standard-required >=4.0 DEG C), moisture absorption heating intensification value (in 30 minutes average intensification value) 3.2 DEG C (standard-required >=3.0 DEG C), insulation rate reaches 28.97% (standard-required must not lower than 30%).
Implementing finally to select embodiment 1,32S proportioning to be cotton 20/ numb Sai Er 20 yarn of An Fuli 35/ phase-change energy-storage fibre 25/ in example, is the blending proportioning effect comparing science.
Claims (9)
1. have a flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, this knit fabric evenly send yarn to spin by 30-40wt% An Fuli fiber, 20-30wt% phase-change energy-storage fibre, 20-30wt% cotton and the numb Sai Er fiber of 20-30wt% and forms.
2. one according to claim 1 has flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, this knit fabric preferably evenly send yarn to spin by An Fuli fiber 35%, phase-change energy-storage fibre 25%, cotton fiber 20% and numb Sai Er fiber 20% and forms.
3. one according to claim 1 and 2 has flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, described An Fuli fiber is Fire resistant viscose fiber.
4. one according to claim 3 has flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, described An Fuli fiber is the trade mark that Heng Tian sea otter company produces is the fiber with flame-retardant and anti-dripping performance of Anti-frayon.
5. one according to claim 1 and 2 has flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, described phase-change energy-storage fibre is viscose.
6. one according to claim 5 has flame-resistant temperature-adjustmenon-woven functional knitted fabric, it is characterized in that, described viscose is grafted with the microcapsule phase-change energy-storage fibre of coating phase-change materials.
7. a kind of preparation method with flame-resistant temperature-adjustmenon-woven functional knitted fabric according to any one of claim 1-6, is characterized in that, the method adopts following steps:
(1) prepare raw material according to formula and evenly send yarn making to obtain blended yarn;
(2) adopt the spinning method of match network compact spinning that blended yarn is made knit fabric just finished product by Double-plate machine weaving;
(3) by knit fabric just finished product pre-setting process before dyeing, dyeing pre-treatment, dyeing, neutralize, soap, fixation, oven dry and heat treatment, namely make and obtain flame-resistant temperature-adjustmenon-woven functional knitted fabric.
8. a kind of preparation method with flame-resistant temperature-adjustmenon-woven functional knitted fabric according to claim 7, is characterized in that, the yarn count of described blended yarn is 32S-40S, and blended yarn controls the twist at 900-950, and twist factor is between 360-380.
9. a kind of preparation method with flame-resistant temperature-adjustmenon-woven functional knitted fabric according to claim 7, it is characterized in that, described blended yarn is woven into the fabric of bilateral structure, every road 32-40S compact spinning blended yarn and 30D elastic spandex fiber are formed, and the loop length on each road is 15.5-16.5cm/50 pin.
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| CN114481425A (en) * | 2021-12-30 | 2022-05-13 | 惠州家和新材料科技有限公司 | Flame-retardant elastic rib fabric and flame-retardant fabric |
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Application publication date: 20160330 |