CN105349061A - Cold produced high-strength and quick-drying starch adhesive - Google Patents
Cold produced high-strength and quick-drying starch adhesive Download PDFInfo
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- CN105349061A CN105349061A CN201510726321.4A CN201510726321A CN105349061A CN 105349061 A CN105349061 A CN 105349061A CN 201510726321 A CN201510726321 A CN 201510726321A CN 105349061 A CN105349061 A CN 105349061A
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Abstract
A cold produced high-strength and quick-drying starch adhesive is formed by, by weight, 20-35 parts of starch, 0.01-0.03 parts of potassium permanganate, 0.03-0.05 parts of borax, 10-15 parts of sodium hydroxide, 0.5-1 part of polyvinyl alcohol, 0.1-0.3 parts of tributyl phosphate, 0.2-0.5 parts of sodium sulfite, 0.2-0.5 parts of a catalyst, 0.001-0.002 parts of a tackifier, 2-4 parts of an antifoaming agent, 0.6-0.8 parts of a curing agent and 60-80 parts of deionized water. Compared with carton adhesives in the prior art, the carton adhesive disclosed in the invention has the advantages of stable performances, simple process, no heating, no corrugated deflection, wire drawing, skinning or efflorescence, fast drying speed, extremely convenient packaging, storage and use, long storage life, low cost, and suitableness for adhering various carton products.
Description
Technical field
The present invention relates to technical field of adhesive, specifically a kind of cold made high-strength quick-acting Starch Adhesive.
Background technology
Prior art adopt its alkalescence of the tackiness agent that does of W-Gum large, easily moisture absorption, cohesive strength low, easily come unstuck; And its complex manufacturing, the production cycle is long, cost is high, rate of drying is slow, the shelf lives is short.Traditional tackiness agent is not containing siccative, and just speed is slow admittedly to make product, therefore, when adopting this tackiness agent bonding, easily occurs running stupefied phenomenon, tackiness agent wasted serious.In addition, conventional adhesive in process of production, all needs heating.Due to needs heating, big energy-consuming, production cost is higher.
Summary of the invention
The present invention aims to provide a kind of preparation method of high-intensity carton tackiness agent.
For realizing described object, the invention provides following technical scheme:
A kind of cold made high-strength quick-acting Starch Adhesive, it is made up of the composition of following weight part: starch 20 ~ 35 parts, 0.01 ~ 0.03 part, potassium permanganate, borax 0.03 ~ 0.05 part, 10 ~ 15 parts, sodium hydroxide, polyvinyl alcohol 0.5 ~ 1 part, tbp 0.1 ~ 0.3 part, S-WAT 0.2 ~ 0.5 part, catalyzer 0.2 ~ 0.5 part, tackifier 0.001 ~ 0.002 part, defoamer 2 ~ 4 parts, 0.6 ~ 0.8 part, solidifying agent, deionized water 60 ~ 80 parts.
A kind of cold made high-strength quick-acting Starch Adhesive, comprises the following steps:
(1) by weight starch, potassium permanganate and deionized water are added in reactor, make starch emulsion, after stirring, place 10 ~ 15 hours at normal temperatures, carry out oxidizing reaction, make starch emulsion become pure white starch emulsion;
(2) by weight by the cold-water solution of sodium hydroxide with 5 times, add in aforesaid reaction vessel and stir 20 ~ 50 minutes, then catalyzer is added in reactor stir;
(3) again borax is added in described reactor by the water dissolution of 10 times by weight, stir 3 ~ 5 minutes, then in reactor, add S-WAT, polyvinyl alcohol, tbp, the tackifier of above-mentioned weight successively, after stirring, be cooled to room temperature;
(4) in the mixture in described step (3), add defoamer and solidifying agent, stir, then Temperature fall, get product.
Compared with prior art, the invention has the beneficial effects as follows: the product performance of high-intensity carton tackiness agent of the present invention are stablized, technique is simple, do not need heating, this tackiness agent does not run stupefied, not wire drawing, not skinning, the not accumulation of salt in the surface soil, rate of drying is fast, packaging, storage, uses all extremely convenient, and storage period is long, and with low cost, be suitable for the bonding of various box paper product.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1 one kinds of cold made high-strength quick-acting Starch Adhesives, it is made up of the composition of following weight part: starch 20 parts, 0.01 part, potassium permanganate, borax 0.03 part, 10 parts, sodium hydroxide, polyvinyl alcohol 0.5 part, tbp 0.1 part, S-WAT 0.2 part, catalyzer 0.2 part, tackifier 0.001 part, defoamer 2 parts, 0.6 part, solidifying agent, deionized water 60 parts.
A kind of cold made high-strength quick-acting Starch Adhesive, comprises the following steps:
(1) by weight starch, potassium permanganate and deionized water are added in reactor, make starch emulsion, after stirring, place 10 ~ 15 hours at normal temperatures, carry out oxidizing reaction, make starch emulsion become pure white starch emulsion;
(2) by weight by the cold-water solution of sodium hydroxide with 5 times, add in aforesaid reaction vessel and stir 20 ~ 50 minutes, then catalyzer is added in reactor stir;
(3) again borax is added in described reactor by the water dissolution of 10 times by weight, stir 3 ~ 5 minutes, then in reactor, add S-WAT, polyvinyl alcohol, tbp, the tackifier of above-mentioned weight successively, after stirring, be cooled to room temperature;
(4) in the mixture in described step (3), add defoamer and solidifying agent, stir, then Temperature fall, get product.
Embodiment 2 one kinds of cold made high-strength quick-acting Starch Adhesives, it is made up of the composition of following weight part: starch 35 parts, 0.03 part, potassium permanganate, borax 0.05 part, 15 parts, sodium hydroxide, polyvinyl alcohol 1 part, tbp 0.3 part, S-WAT 0.5 part, catalyzer 0.5 part, tackifier 2 parts, defoamer 4 parts, 0.8 part, solidifying agent, deionized water 80 parts.
A kind of cold made high-strength quick-acting Starch Adhesive, comprises the following steps:
(1) by weight starch, potassium permanganate and deionized water are added in reactor, make starch emulsion, after stirring, place 10 ~ 15 hours at normal temperatures, carry out oxidizing reaction, make starch emulsion become pure white starch emulsion;
(2) by weight by the cold-water solution of sodium hydroxide with 5 times, add in aforesaid reaction vessel and stir 20 ~ 50 minutes, then catalyzer is added in reactor stir;
(3) again borax is added in described reactor by the water dissolution of 10 times by weight, stir 3 ~ 5 minutes, then in reactor, add S-WAT, polyvinyl alcohol, tbp, the tackifier of above-mentioned weight successively, after stirring, be cooled to room temperature;
(4) in the mixture in described step (3), add defoamer and solidifying agent, stir, then Temperature fall, get product.
Embodiment 3 one kinds of cold made high-strength quick-acting Starch Adhesives, it is made up of the composition of following weight part: starch 30 parts, 0.02 part, potassium permanganate, borax 0.04 part, 12 parts, sodium hydroxide, polyvinyl alcohol 0.8 part, tbp 0.2 part, S-WAT 0.3 part, catalyzer 0.4 part, tackifier 0.001 part, defoamer 3 parts, 0.6 part, solidifying agent, deionized water 80 parts.
A kind of cold made high-strength quick-acting Starch Adhesive, comprises the following steps:
(1) by weight starch, potassium permanganate and deionized water are added in reactor, make starch emulsion, after stirring, place 10 ~ 15 hours at normal temperatures, carry out oxidizing reaction, make starch emulsion become pure white starch emulsion;
(2) by weight by the cold-water solution of sodium hydroxide with 5 times, add in aforesaid reaction vessel and stir 20 ~ 50 minutes, then catalyzer is added in reactor stir;
(3) again borax is added in described reactor by the water dissolution of 10 times by weight, stir 3 ~ 5 minutes, then in reactor, add S-WAT, polyvinyl alcohol, tbp, the tackifier of above-mentioned weight successively, after stirring, be cooled to room temperature;
(4) in the mixture in described step (3), add defoamer and solidifying agent, stir, then Temperature fall, get product.
Claims (2)
1. a cold made high-strength quick-acting Starch Adhesive, it is made up of the composition of following weight part: starch 20 ~ 35 parts, 0.01 ~ 0.03 part, potassium permanganate, borax 0.03 ~ 0.05 part, 10 ~ 15 parts, sodium hydroxide, polyvinyl alcohol 0.5 ~ 1 part, tbp 0.1 ~ 0.3 part, S-WAT 0.2 ~ 0.5 part, catalyzer 0.2 ~ 0.5 part, tackifier 0.001 ~ 0.002 part, defoamer 2 ~ 4 parts, 0.6 ~ 0.8 part, solidifying agent, deionized water 60 ~ 80 parts.
2. a cold made high-strength quick-acting Starch Adhesive, is characterized in that, comprises the following steps:
(1) by weight starch, potassium permanganate and deionized water are added in reactor, make starch emulsion, after stirring, place 10 ~ 15 hours at normal temperatures, carry out oxidizing reaction, make starch emulsion become pure white starch emulsion;
(2) by weight by the cold-water solution of sodium hydroxide with 5 times, add in aforesaid reaction vessel and stir 20 ~ 50 minutes, then catalyzer is added in reactor stir;
(3) again borax is added in described reactor by the water dissolution of 10 times by weight, stir 3 ~ 5 minutes, then in reactor, add S-WAT, polyvinyl alcohol, tbp, the tackifier of above-mentioned weight successively, after stirring, be cooled to room temperature;
(4) in the mixture in described step (3), add defoamer and solidifying agent, stir, then Temperature fall, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510726321.4A CN105349061A (en) | 2015-10-28 | 2015-10-28 | Cold produced high-strength and quick-drying starch adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510726321.4A CN105349061A (en) | 2015-10-28 | 2015-10-28 | Cold produced high-strength and quick-drying starch adhesive |
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| CN105349061A true CN105349061A (en) | 2016-02-24 |
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| CN201510726321.4A Pending CN105349061A (en) | 2015-10-28 | 2015-10-28 | Cold produced high-strength and quick-drying starch adhesive |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184106A (en) * | 2019-04-23 | 2019-08-30 | 武汉理工大学 | Oil-based drill cuttings cinder resourceization utilizes method |
| CN110511696A (en) * | 2019-08-20 | 2019-11-29 | 马鞍山市康辉纸箱纸品有限公司 | A kind of preparation method of the adhesive of corrugated paper production |
| CN110605871A (en) * | 2019-08-20 | 2019-12-24 | 马鞍山市康辉纸箱纸品有限公司 | Bonding process for improving strength of corrugated board |
| CN112080224A (en) * | 2020-09-27 | 2020-12-15 | 湖南安翔科技有限公司 | Starch adhesive for beer label paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
| CN102433084A (en) * | 2011-11-04 | 2012-05-02 | 常熟市凯力达蜂窝包装材料有限公司 | Preparation method of starch adhesive for adhering cartons |
-
2015
- 2015-10-28 CN CN201510726321.4A patent/CN105349061A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
| CN102433084A (en) * | 2011-11-04 | 2012-05-02 | 常熟市凯力达蜂窝包装材料有限公司 | Preparation method of starch adhesive for adhering cartons |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110184106A (en) * | 2019-04-23 | 2019-08-30 | 武汉理工大学 | Oil-based drill cuttings cinder resourceization utilizes method |
| CN110511696A (en) * | 2019-08-20 | 2019-11-29 | 马鞍山市康辉纸箱纸品有限公司 | A kind of preparation method of the adhesive of corrugated paper production |
| CN110605871A (en) * | 2019-08-20 | 2019-12-24 | 马鞍山市康辉纸箱纸品有限公司 | Bonding process for improving strength of corrugated board |
| CN112080224A (en) * | 2020-09-27 | 2020-12-15 | 湖南安翔科技有限公司 | Starch adhesive for beer label paper |
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Application publication date: 20160224 |
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