CN103113838B - Novel environment-friendly aqueous joint adhesive and preparation method thereof - Google Patents
Novel environment-friendly aqueous joint adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN103113838B CN103113838B CN201310029213.2A CN201310029213A CN103113838B CN 103113838 B CN103113838 B CN 103113838B CN 201310029213 A CN201310029213 A CN 201310029213A CN 103113838 B CN103113838 B CN 103113838B
- Authority
- CN
- China
- Prior art keywords
- adhesive
- joint adhesive
- natural rubber
- aqueous joint
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention provides a novel environment-friendly aqueous joint adhesive which is mainly prepared by the reaction of butyl acrylate, methacrylic acid, a VAE (Vinyl Acetateethylene Emulsion), a PVAC (Polymer Vinyl Acetate) emulsion, lauryl sodium sulfate, rosin adhered resin, p-methylbenzene sulfonic acid, sodium polyacrylate protective colloid, ammonium persulfate, BL-100 organosilicone foam inhibitor, OP-10 dispersant and a magnesium chloride coupler. The invention further provides a preparation method of the aqueous joint adhesive. The aqueous joint adhesive is nontoxic, safe and environment-friendly and simple to operate, and can directly replace natural rubber joint adhesive without changing the device. Compared with natural rubber self-adhesive glue, the physical properties of the aqueous joint adhesive are substantially not changed, and the aqueous joint adhesive better carries forward the advantages of the original natural rubber self-adhesive glue. Compared with natural rubber self-adhesive glue, the cost of the aqueous joint adhesive is lowered to a greater extent, and the raw material source is easier and more convenient to get.
Description
Technical field
The present invention relates to a kind of novel aqueous environmental protection esters of acrylic acid laminating glue and preparation method thereof, be specifically related to a kind of aqueous plaster rubber alloy and preparation method thereof.
Background technology
The surfaces such as laminating glue is mainly coated on and weaves cotton cloth, non-woven fabrics, sponge, EVA sheet material, corium or PU leather, while only having coated face to be in contact with one another, just can produce viscosity, and generally, it is less that the surface that is coated with this glue shows cohesive force, but under the extruding that is subject to external force, cohesive strength can increase.Can be widely used in the processing of some shoemaking, clothes, wrapping material.
Adhesive glue is in the market mainly to adopt natural rubber for producing main raw material, not only raw materials cost is high, and in natural rubber, contain many separated harmful chemical substances that are difficult to, also must add a large amount of ammoniacal liquor aborning, along with improving constantly that the mankind require health and environment, the use range of bond rubber glue is more and more restricted.Therefore, the novel non-natural rubber of development and production, to environment and the harmless environment-friendly type aqueous adhesive glue of the mankind direction that is inevitable.
At present, the domestic bond rubber glue overwhelming majority need be from external import, in order to substitute the R&D and production blank out especially of the environment-friendly water-based adhesive glue of natural rubber laminating glue.Because the demand in market and the defect of existing adhesive glue itself exist obvious contradiction, greatly restricted the internationalization process of footwear, clothes and packaging industry.In view of this, environment-friendly water-based adhesive glue has huge development space.
Summary of the invention
Object of the present invention is exactly a kind of environment-friendly novel adhesive glue providing in order to address the above problem.
Another object of the present invention is to provide a kind of method of preparing this invention environment-friendly novel adhesive glue.
The object of the present invention is achieved like this:
An environment-friendly novel adhesive glue, is comprised of the raw material of following ratio of weight and number: deionized water 50.75, vinylformic acid 3; butyl acrylate 10, methacrylic acid 2, VAE emulsion 20; PVAC emulsion 8, sodium lauryl sulphate 0.5, rosin tackifying resin 5; p-methyl benzenesulfonic acid 0.4; sodium polyacrylate protective colloid 1, ammonium persulphate 0.05, the silicone based suds suppressor 0.1 of BL-100; OP-10 dispersion agent 0.3, magnesium chloride coupling agent 0.5.
Raw material of the present invention is general raw material, by market purchasing, obtains.
Preparation method's of the present invention concrete steps are as follows:
(1), in reactor, first add the deionized water of 50.75kg, then add the butyl acrylate of 10kg, then add the sodium lauryl sulphate of 0.5kg, carry out pre-emulsification 30 minutes.
(2), in the good liquid of emulsification, add respectively the vinylformic acid of 3kg, the methacrylic acid of 2kg, the sodium polyacrylate protective colloid of 1kg, then adds the ammonium persulphate catalyzer of 0.05kg, stirs and is warming up to 78 ~ 85 degrees Celsius.
(3), when being stabilized in 78 ~ 85 degrees Celsius, reactor temperature adds 0.1kg suds suppressor, add again the VAE emulsion of 20kg and the PVAC emulsion of 8kg, the magnesium chloride coupling agent that adds again 0.5kg, stirring reaction adds 5kg rosin tackifying resin to continue stirring reaction 20 minutes after 30 minutes, then order adds the p-methyl benzenesulfonic acid of 0.4kg, the Biocide BRC-R fungusproof anti-corrosion agent of 0.4kg stirs 30 minutes, cooling discharging, the canned finished product that is packaged into.
The present invention compared with prior art excellent results is as follows:
Nontoxicity, safety and environmental protection.Simple to operate, do not change equipment, can directly substitute the coating of natural rubber laminating glue.With natural rubber plaster rubber alloy, compare, physicals does not have change substantially, good succession the advantage of former natural rubber laminating glue.Cost is compared with natural rubber laminating glue, have larger cost to decline, and raw material sources is more prone to convenient.
Embodiment
Embodiment introduction below, can make those skilled in the art more comprehensively understand the present invention, but not limit the present invention in any way.
Implementation column
Get raw material weight deionized water 50.75kg, vinylformic acid 3kg, butyl acrylate 10kg; methacrylic acid 2kg, VAE emulsion 20kg, PVAC emulsion 8kg; sodium lauryl sulphate 0.5kg; rosin tackifying resin 5kg, p-methyl benzenesulfonic acid 0.4kg, sodium polyacrylate protective colloid 1kg; ammonium persulphate 0.05kg; the silicone based suds suppressor 0.1kg of BL-100, OP-10 dispersion agent 0.3kg, magnesium chloride coupling agent 0.5kg.
The concrete steps of working method are as follows: in reactor, first add the deionized water of 50.75kg, then add the butyl acrylate of 10kg, then add the sodium lauryl sulphate of 0.5kg, carry out pre-emulsification 30 minutes; The vinylformic acid that adds respectively 3kg in the good liquid of emulsification, the methacrylic acid of 2kg, the sodium polyacrylate protective colloid of 1kg, then adds the ammonium persulphate catalyzer of 0.05kg, stirs and is warming up to 78 ~ 85 degrees Celsius.When being stabilized in 78 ~ 85 degrees Celsius, reactor temperature adds the silicone based suds suppressor of 0.1kg BL-100, add again the VAE emulsion of 20kg and the PVAC emulsion of 8kg, the magnesium chloride coupling agent that adds again 0.5kg, stirring reaction adds 5kg rosin tackifying resin to continue stirring reaction 20 minutes after 30 minutes, then order adds the p-methyl benzenesulfonic acid of 0.4kg, the Biocide BRC-R fungusproof anti-corrosion agent of 0.4kg stirs 30 minutes, cooling discharging, the canned finished product that is packaged into.
Claims (1)
1. environment-friendly water-based laminating glue, is characterized in that being comprised of the raw material of following ratio of weight and number:
Deionized water 50.75, vinylformic acid 3, butyl acrylate 10; methacrylic acid 2, VAE emulsion 20, PVAC emulsion 8; sodium lauryl sulphate 0.5, rosin tackifying resin 5, p-methyl benzenesulfonic acid 0.4; sodium polyacrylate protective colloid 1; ammonium persulphate 0.05, the silicone based suds suppressor 0.1 of BL-100, OP-10 dispersion agent 0.3; magnesium chloride 0.5, Biocide BRC-R fungusproof anti-corrosion agent 0.4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310029213.2A CN103113838B (en) | 2013-01-27 | 2013-01-27 | Novel environment-friendly aqueous joint adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310029213.2A CN103113838B (en) | 2013-01-27 | 2013-01-27 | Novel environment-friendly aqueous joint adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103113838A CN103113838A (en) | 2013-05-22 |
| CN103113838B true CN103113838B (en) | 2014-11-26 |
Family
ID=48412259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310029213.2A Expired - Fee Related CN103113838B (en) | 2013-01-27 | 2013-01-27 | Novel environment-friendly aqueous joint adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103113838B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320088A (en) * | 2013-06-27 | 2013-09-25 | 苏州工业园区依利电子贸易有限公司 | Silencing adhesive |
| CN105860097A (en) * | 2016-05-12 | 2016-08-17 | 广西融水闽兴树脂有限公司 | Emulsifier special for tackifier resin emulsion |
| CN106008999A (en) * | 2016-05-12 | 2016-10-12 | 广西融水闽兴树脂有限公司 | Special emulsifier for rosin emulsion |
| CN105838297B (en) * | 2016-05-19 | 2018-03-20 | 维大树脂化工（台山）有限公司 | The preparation method of environment-protecting thermoplastic resin aqueous adhesive |
| CN105838267B (en) * | 2016-05-19 | 2019-01-29 | 江苏泰特尔新材料科技有限公司 | A kind of environment-protecting thermoplastic resin aqueous adhesive |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120060A (en) * | 1994-10-07 | 1996-04-10 | 福州市建筑科学研究所 | Adhesive for building and its production method |
| WO2000049054A1 (en) * | 1999-02-18 | 2000-08-24 | Konishi Co., Ltd. | Process for producing vinyl acetate resin emulsion and water-based adhesive |
| CN1415684A (en) * | 2001-10-31 | 2003-05-07 | 揭阳市天银化工实业有限公司 | Adhesive of modified polyvinyl acetate emulsion with properties of thermosetting and self interlinkage |
| CN101979453A (en) * | 2010-11-17 | 2011-02-23 | 湖南神力铃胶粘剂制造有限公司 | Display shell spreading-ball sealing glue and preparation method thereof |
| CN101984010A (en) * | 2010-10-20 | 2011-03-09 | 韩志龙 | Multipurpose environmental protection adhesive for industrial use |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7872063B2 (en) * | 2006-09-22 | 2011-01-18 | Genovique Specialties Holdings Corporation | Film forming compositions containing mixtures of benzoic acid esters |
-
2013
- 2013-01-27 CN CN201310029213.2A patent/CN103113838B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120060A (en) * | 1994-10-07 | 1996-04-10 | 福州市建筑科学研究所 | Adhesive for building and its production method |
| WO2000049054A1 (en) * | 1999-02-18 | 2000-08-24 | Konishi Co., Ltd. | Process for producing vinyl acetate resin emulsion and water-based adhesive |
| CN1415684A (en) * | 2001-10-31 | 2003-05-07 | 揭阳市天银化工实业有限公司 | Adhesive of modified polyvinyl acetate emulsion with properties of thermosetting and self interlinkage |
| CN101984010A (en) * | 2010-10-20 | 2011-03-09 | 韩志龙 | Multipurpose environmental protection adhesive for industrial use |
| CN101979453A (en) * | 2010-11-17 | 2011-02-23 | 湖南神力铃胶粘剂制造有限公司 | Display shell spreading-ball sealing glue and preparation method thereof |
Non-Patent Citations (6)
| Title |
|---|
| "VAc/BA/AA共聚乳液胶粘剂的制备与性能研究";高振忠等;《中国胶粘剂》;20090430;第18卷(第4期);第5-8页 * |
| "VAE乳液及其胶粘剂";李子东等;《粘接》;20011231;第22卷(第6期);第27-30页 * |
| "丙烯酸丁酯/VAE互穿聚合物乳液的研究";陈艳军等;《粘接》;20040430;第25卷(第2期);第6-9页 * |
| 李子东等."VAE乳液及其胶粘剂".《粘接》.2001,第22卷(第6期),第27-30页. * |
| 陈艳军等."丙烯酸丁酯/VAE互穿聚合物乳液的研究".《粘接》.2004,第25卷(第2期),第6-9页. * |
| 高振忠等."VAc/BA/AA共聚乳液胶粘剂的制备与性能研究".《中国胶粘剂》.2009,第18卷(第4期),第5-8页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103113838A (en) | 2013-05-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103113838B (en) | Novel environment-friendly aqueous joint adhesive and preparation method thereof | |
| CN106117421B (en) | A kind of aqueous environment protection ceramic tile gum lotion and its manufacturing method | |
| CN103342784A (en) | Frankincense-modified acrylate emulsion and its preparation method and use | |
| CN105315413A (en) | Novel modified acrylate emulsion adhesive and preparation method thereof | |
| CN105176457A (en) | Environmentally-friendly aqueous binder | |
| CN104558368B (en) | A kind of high temperature resistant wallpaper basement membrane and preparation method thereof | |
| CN103320065A (en) | Emulsion pressure-sensitive adhesive for protecting adhesive tape and preparation method thereof | |
| CN103232745A (en) | Transparent elastic putty and preparation method thereof | |
| CN103304724A (en) | Vinyl chloride-acrylic acid ester-vinyl acetate-acrylic acid copolymerized emulsion | |
| CN103965816A (en) | Low-VOC (Volatile Organic Compound) high-performance emulsion adhesive for non-woven fabric material and preparation method thereof | |
| CN104449118A (en) | Environment-friendly reflective coating | |
| CN105778004A (en) | Environment-friendly water-based adhesive and preparation method thereof | |
| CN107286863B (en) | A kind of high intensity plant base adhesive and preparation method thereof | |
| CN103342781B (en) | Vinyl chloride-butyl acrylate-epoxy resin copolymerization emulsion and preparation method thereof | |
| CN103755865B (en) | soap-free polymerization acrylic emulsion and preparation method thereof | |
| CN104673141A (en) | Composite adhesive for environment-friendly paper bag | |
| CN103666341A (en) | Electrostatic flocking adhesive and preparation method thereof | |
| CN104194463B (en) | A kind of self-closing polymer cement waterproof paint | |
| CN104211853A (en) | Acrylate emulsion for water-based inks | |
| CN103725232B (en) | A kind of neoprene modified acrylic acid emulsion with fast viscosity and preparation method thereof | |
| CN106752416A (en) | A kind of digit printing weaving face fabric surface conditioning agent | |
| CN103361005A (en) | Anti-attenuation acrylate binder for waterproof roll tire fabric and preparation method thereof | |
| CN103666340B (en) | A kind of water soluble acrylic acid ester pressure-sensitive and manufacturing process thereof | |
| CN108864873A (en) | Non-woven fabrics adhesive | |
| CN105219322A (en) | Novel environment friendly note pressure footwear use tackiness agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141126 Termination date: 20210127 |