CN108864873A - Non-woven fabrics adhesive - Google Patents
Non-woven fabrics adhesive Download PDFInfo
- Publication number
- CN108864873A CN108864873A CN201710327407.9A CN201710327407A CN108864873A CN 108864873 A CN108864873 A CN 108864873A CN 201710327407 A CN201710327407 A CN 201710327407A CN 108864873 A CN108864873 A CN 108864873A
- Authority
- CN
- China
- Prior art keywords
- woven fabrics
- added
- parts
- ammonium persulfate
- fabrics adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of non-woven fabrics adhesives.Raw material of the present invention is easy to get, simple process, and long shelf-life is easy to use, is firmly bonded, and is used as non-woven fabrics adhesive.It is characterized in that：1. 3 parts of lauryl sodium sulfate and 0.12 part of sodium bicarbonate are added in 80 parts of deionized waters, mixed dissolution；0.8 part of ammonium persulfate is dissolved in 42 parts of water again, it is mixed in monomer；2. emulsifier aqueous solution is added in a kettle, it is warming up to 65~70 DEG C under stirring, 1/3 mix monomer is added under constant temperature, then in being added dropwise ammonium persulfate solution and remaining mix monomer simultaneously in 2h, add rear insulation reaction 2h, natural thermal insulation is neutralized after cooling with weak aqua ammonia to obtain the final product.
Description
Technical field
The present invention relates to a kind of non-woven fabrics adhesives and preparation method thereof, belong to technical field of fine.
Background technique
Non-woven fabrics adhesive system is with methyl acrylate, methyl methacrylate, butyl acrylate, acrylic acid, styrene, ten
Sodium dialkyl sulfate, ammonium persulfate, sodium bicarbonate, deionized water, ammonium hydroxide etc. are that raw material is rationally formulated.
Non-woven fabrics adhesive is a kind of new product of adhesive, is mainly characterized in that：Raw material is easy to get, simple process, saves
Phase is long, easy to use, is firmly bonded, and is used as non-woven fabrics adhesive.
The proportion of this non-woven fabrics adhesive is seen in the report of scientific and technical literature not yet.
Summary of the invention
The technical problem to be solved in the invention, which is that, to be overcome the deficiencies of existing technologies, and a kind of non-woven fabrics adhesive is provided
And preparation method thereof, its raw material is easy to get, simple process, and long shelf-life is easy to use, is firmly bonded, and is used as non-woven fabrics adhesive.
To solve the above problems, the present invention adopts the following technical scheme that：
The invention discloses a kind of non-woven fabrics adhesive preparation method, the non-woven fabrics adhesive is by following weight
Raw material is prepared：Methyl acrylate methyl acrylate 10%~15%, methyl methacrylate 10%~15%, butyl acrylate
10%~20%, acrylic acid 0.5%~1%, styrene 3%~5%, lauryl sodium sulfate 1%~2%, ammonium persulfate 0.1%~0.5%,
Appropriate sodium bicarbonate, deionized water 50%~60%, appropriate ammonium hydroxide.
The present invention provides a kind of preparation method of non-woven fabrics adhesive, it is characterised in that：1. by 3 parts of lauryl sodium sulfate
It is added in 80 parts of deionized waters with 0.12 part of sodium bicarbonate, mixed dissolution；0.8 part of ammonium persulfate is dissolved in 42 parts of water again, it will
It is mixed in monomer；2.Emulsifier aqueous solution is added in a kettle, 65~70 DEG C are warming up under stirring, is added 1/3 under constant temperature
Mix monomer, then in 2h simultaneously ammonium persulfate solution and remaining mix monomer is added dropwise, add rear insulation reaction 2h, from
So heat preservation is neutralized after cooling with weak aqua ammonia to obtain the final product.
A kind of non-woven fabrics adhesive system of the invention methyl acrylate, methyl methacrylate, butyl acrylate, acrylic acid,
Styrene, lauryl sodium sulfate, ammonium persulfate, sodium bicarbonate, deionized water, ammonium hydroxide solid binder as main component.
It is used as non-woven fabrics adhesive, there is excellent cementability, easy-to-use.
Specific embodiment
Example 1
Non-woven fabrics adhesive is prepared by the raw material of following weight：Methyl acrylate 11.8%, methyl methacrylate
11.8%, butyl acrylate 13.6%, acrylic acid 0.7%, styrene 4.5%, lauryl sodium sulfate 1.3%, ammonium persulfate 0.3%,
Appropriate sodium bicarbonate, deionized water 55.5%, appropriate ammonium hydroxide.
1. 3 parts of lauryl sodium sulfate and 0.12 part of sodium bicarbonate are added in 80 parts of deionized waters, mixed dissolution；Again will
0.8 part of ammonium persulfate is dissolved in 42 parts of water, it is mixed in monomer；2.Emulsifier aqueous solution is added in a kettle, under stirring
65~70 DEG C are warming up to, 1/3 mix monomer is added under constant temperature, then in ammonium persulfate solution and remaining is added dropwise in 2h simultaneously
Mix monomer, adds rear insulation reaction 2h, and natural thermal insulation is neutralized after cooling with weak aqua ammonia to obtain the final product.
Example 2
Methyl acrylate 12.8%, methyl methacrylate 10.8%, butyl acrylate 13.6%, acrylic acid 0.7%, styrene
4.5%, lauryl sodium sulfate 1.3%, ammonium persulfate 0.3%, appropriate sodium bicarbonate, deionized water 55.5%, appropriate ammonium hydroxide.
1. 3 parts of lauryl sodium sulfate and 0.12 part of sodium bicarbonate are added in 80 parts of deionized waters, mixed dissolution；Again will
0.8 part of ammonium persulfate is dissolved in 42 parts of water, it is mixed in monomer；2.Emulsifier aqueous solution is added in a kettle, under stirring
65~70 DEG C are warming up to, 1/3 mix monomer is added under constant temperature, then in ammonium persulfate solution and remaining is added dropwise in 2h simultaneously
Mix monomer, adds rear insulation reaction 2h, and natural thermal insulation is neutralized after cooling with weak aqua ammonia to obtain the final product.
Example 3
Methyl acrylate 11.8%, methyl methacrylate 11.8%, butyl acrylate 14.6%, acrylic acid 0.7%, styrene
4.7%, lauryl sodium sulfate 2%, ammonium persulfate 0.3%, appropriate sodium bicarbonate, deionized water 56%, appropriate ammonium hydroxide.
1. 3 parts of lauryl sodium sulfate and 0.12 part of sodium bicarbonate are added in 80 parts of deionized waters, mixed dissolution；Again will
0.8 part of ammonium persulfate is dissolved in 42 parts of water, it is mixed in monomer；2.Emulsifier aqueous solution is added in a kettle, under stirring
65~70 DEG C are warming up to, 1/3 mix monomer is added under constant temperature, then in ammonium persulfate solution and remaining is added dropwise in 2h simultaneously
Mix monomer, adds rear insulation reaction 2h, and natural thermal insulation is neutralized after cooling with weak aqua ammonia to obtain the final product.
Finally it should be noted that：Obviously, the above embodiment is merely an example for clearly illustrating the present invention, and simultaneously
Restriction to embodiment.For those of ordinary skill in the art, it can also make on the basis of the above description
Other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.And it is thus amplified
Obvious changes or variations out are still in the protection scope of this invention.
Claims (3)
1. raw material of the present invention is easy to get, simple process, long shelf-life is easy to use, is firmly bonded, and is used as non-woven fabrics adhesive.
2. a kind of non-woven fabrics adhesive preparation method, which is characterized in that the non-woven fabrics adhesive is by following weight
Raw material is prepared：Methyl acrylate 11.8%, methyl methacrylate 11.8%, butyl acrylate 13.6%, acrylic acid 0.7%,
Styrene 4.5%, lauryl sodium sulfate 1.3%, ammonium persulfate 0.3%, appropriate sodium bicarbonate, deionized water 55.5%, ammonium hydroxide are suitable
Amount.
3. the preparation method of non-woven fabrics adhesive as claimed in claim 2, it is characterised in that：1. by 3 parts of dodecyl sulphates
Sodium and 0.12 part of sodium bicarbonate are added in 80 parts of deionized waters, mixed dissolution；0.8 part of ammonium persulfate is dissolved in 42 parts of water again,
It is mixed in monomer；2. emulsifier aqueous solution is added in a kettle, it is warming up to 65~70 DEG C under stirring, is added 1/ under constant temperature
3 mix monomer adds rear insulation reaction 2h then in ammonium persulfate solution and remaining mix monomer is added dropwise simultaneously in 2h,
Natural thermal insulation is neutralized after cooling with weak aqua ammonia to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710327407.9A CN108864873A (en) | 2017-05-11 | 2017-05-11 | Non-woven fabrics adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710327407.9A CN108864873A (en) | 2017-05-11 | 2017-05-11 | Non-woven fabrics adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108864873A true CN108864873A (en) | 2018-11-23 |
Family
ID=64319241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710327407.9A Pending CN108864873A (en) | 2017-05-11 | 2017-05-11 | Non-woven fabrics adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108864873A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643310A (en) * | 2019-10-29 | 2020-01-03 | 江苏金荣泰新材料科技有限公司 | Adhesive for non-woven fabrics |
| CN110964464A (en) * | 2019-10-22 | 2020-04-07 | 山东宇龙高分子科技有限公司 | Preparation method of marble adhesive |
-
2017
- 2017-05-11 CN CN201710327407.9A patent/CN108864873A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964464A (en) * | 2019-10-22 | 2020-04-07 | 山东宇龙高分子科技有限公司 | Preparation method of marble adhesive |
| CN110643310A (en) * | 2019-10-29 | 2020-01-03 | 江苏金荣泰新材料科技有限公司 | Adhesive for non-woven fabrics |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102603960B (en) | Preparation method of acrylic emulsion with core-shell structure for redispersible emulsion powder | |
| CN104261720A (en) | Ether polycarboxylate superplasticizer and preparation method thereof | |
| CN104356314A (en) | Normal-temperature synthetizing method for slow release type polycarboxylate water-reducer and product produced by same | |
| CN103708759B (en) | A kind of modified aliphatic high efficiency water reducing agent and preparation method thereof | |
| CN103937484B (en) | Shale gas well slickwater fracturing fluid system high-efficiency emulsion quick water-soluble drag reducer | |
| CN108864873A (en) | Non-woven fabrics adhesive | |
| CN105315413A (en) | Novel modified acrylate emulsion adhesive and preparation method thereof | |
| CN105418834B (en) | Paper-plastic water-based adhesive and preparation method thereof | |
| CN105417986A (en) | Early-strength waterproof agent for ordinary Portland cement | |
| CN105694642A (en) | Acrylate waterproof coating emulsion and preparation method thereof | |
| CN103333645B (en) | Formaldehyde-free polyvinyl acetate wood adhesive and preparation method thereof | |
| CN106046243A (en) | Environment-friendly high-solid-content PVC (Polyvinyl Chloride) floor glue emulsion and preparation method thereof | |
| CN107325219A (en) | A kind of self-crosslinking aqueous neoprene latex modification acrylate and vinyl acetate emulsion of cold curing and preparation method | |
| CN103254369A (en) | Preparation method of water reducer | |
| CN102643047A (en) | Amide polyamine polycarboxylic acid high-polymer cement grinding aid and preparation method thereof | |
| CN104177556A (en) | Plastic stabilizer and preparation method thereof | |
| CN104891851A (en) | High-strength concrete strength exciting agent and preparation method thereof | |
| CN104108904A (en) | Texture coating and preparation method thereof | |
| CN103665253A (en) | High-performance water-based acrylate pressure-sensitive adhesive and manufacturing process thereof | |
| CN108083673A (en) | The method for having alkali liquid quick-setting agent is prepared using the tail washings for producing methacrylaldehyde | |
| CN104194687A (en) | Formula and preparation process of styrene and polyether urethane copolymer adhesive | |
| CN101633710A (en) | Elastic emulsion for building putties and preparation method thereof | |
| CN104817251B (en) | A kind of composite high-molecular sludge dehydrating agent and preparation method thereof | |
| CN108864349A (en) | Self-Crosslinking Styrene/Acrylate Copolymer Emulsion for Glass Fiber | |
| CN103922629A (en) | Polycarboxylic acid high-performance water reducer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181123 |
|
| WD01 | Invention patent application deemed withdrawn after publication |