CN103666341A - Electrostatic flocking adhesive and preparation method thereof - Google Patents
Electrostatic flocking adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN103666341A CN103666341A CN201310620023.8A CN201310620023A CN103666341A CN 103666341 A CN103666341 A CN 103666341A CN 201310620023 A CN201310620023 A CN 201310620023A CN 103666341 A CN103666341 A CN 103666341A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- vinylformic acid
- adhesive
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to an electrostatic flocking adhesive and a preparation method thereof, and belongs to the technical field of textile assistants. The adhesive comprises components in parts by weight as follows: 2-5 parts of acrylic acid, 10-13 parts of acrylic acid methyl ester, 25-29 parts of sec-octyl acrylate, 16-18 parts of isobornyl acrylate, 2-4 parts of N-methylol acrylamide, 6-10 parts of alkyl polyglucoside, 0.1-0.3 parts of potassium persulfate, 0.1-0.3 part of sodium hydrosulfite, 0.1-1 part of essence and 120-150 parts of deionized water. The preparation method is simple; the prepared electrostatic flocking adhesive has high binding power, excellent anti-aging property, water resisting property and softness, and good transparency, can be cured at the normal temperature and can bond various substrates; and simultaneously, the product is wider in application range, can be used as not only the electrostatic flocking adhesive but also a pigment printing paste adhesive, a non-woven fabric adhesive and the like, and is easy to popularize and apply.
Description
Technical field
The invention belongs to textile auxiliary agent technical field, be specifically related to a kind of static flocking gluing agent and preparation method thereof.
Background technology
The shortcomings such as the flocking sizing agent of existing market be take urethane as raw material, and high cost is expensive, easy xanthochromia, and use the fabric antistatic effect after flocking sizing agent bad, there is no mothproof function, also need separately to use finishing composition, just can there is mothproof function.Therefore how overcoming the deficiencies in the prior art is problems that current textile auxiliary agent technical field is needed solution badly.
Summary of the invention
The object of the invention is, in order to solve the deficiencies in the prior art, provides a kind of static flocking gluing agent and preparation method thereof.This static flocking gluing agent can be solidified under normal temperature, and the transparency is good, and preparation technology is simple.
The technical solution used in the present invention is as follows:
The agent of static flocking gluing, comprises the following component according to parts by weight meter: 2 ~ 5 parts, vinylformic acid, 10 ~ 13 parts of methyl acrylates, 25 ~ 29 parts, vinylformic acid Zhong Xin fat, 16 ~ 18 parts of isobornyl acrylate, 2 ~ 4 parts of N hydroxymethyl acrylamides, 6 ~ 10 parts of alkyl polyglycosides, 0.1 ~ 0.3 part of Potassium Persulphate, 0.1 ~ 0.3 part of V-Brite B, 0.1 ~ 1 part, essence, 120 ~ 150 parts of deionized waters.
Further preferably described essence is Flower of Aztec Marigold essential oil.
The preparation method of above-mentioned static flocking gluing agent, comprises the steps:
(1) in reactor, after vinylformic acid, methyl acrylate, vinylformic acid Zhong Xin fat and isobornyl acrylate are mixed, join together with alkyl polyglycoside in part deionization, be stirred to and mix;
(2) N hydroxymethyl acrylamide is dissolved in remaining deionized water; in nitrogen protection; temperature is under 50 ~ 60 ℃ of conditions; slowly be added in reactor; also slowly add Potassium Persulphate and V-Brite B simultaneously; isothermal reaction 2 ~ 5h, finally adds essence, obtains static flocking gluing of the present invention agent.
compared with prior art, its beneficial effect is in the present invention:(1) static flocking gluing agent cohesive force of the present invention is strong, has good anti-aging, water tolerance and flexibility, under normal temperature, solidifies, and the transparency is good, and multiple base material can bond; (2) application range of products of the present invention is wider, not only can be used as the agent of static flocking gluing, can also be as textile printing pigment sizing agent, the agent of non-woven fabrics gluing etc.; (3) product preparation method of the present invention is simple, is easy to apply.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
The agent of static flocking gluing, comprises the following component according to parts by weight meter: 2 parts, vinylformic acid, 10 parts of methyl acrylates, 25 parts, vinylformic acid Zhong Xin fat, 16 parts of isobornyl acrylate, 2 parts of N hydroxymethyl acrylamides, 6 parts of alkyl polyglycosides, 0.1 part of Potassium Persulphate, 0.1 part of V-Brite B, 0.1 part of Flower of Aztec Marigold essential oil, 120 parts of deionized waters.
The preparation method of the present embodiment static flocking gluing agent, comprises the steps:
(1) in reactor, after vinylformic acid, methyl acrylate, vinylformic acid Zhong Xin fat and isobornyl acrylate are mixed, join together with alkyl polyglycoside in part deionization, be stirred to and mix;
(2) N hydroxymethyl acrylamide is dissolved in remaining deionized water; in nitrogen protection; temperature is under 50 ℃ of conditions; slowly be added in reactor; also slowly add Potassium Persulphate and V-Brite B simultaneously; isothermal reaction 2h, finally adds Flower of Aztec Marigold essential oil, obtains the static flocking gluing agent of the present embodiment.
Embodiment 2
The agent of static flocking gluing, comprises the following component according to parts by weight meter: 5 parts, vinylformic acid, 13 parts of methyl acrylates, 29 parts, vinylformic acid Zhong Xin fat, 18 parts of isobornyl acrylate, 4 parts of N hydroxymethyl acrylamides, 10 parts of alkyl polyglycosides, 0.3 part of Potassium Persulphate, 0.3 part of V-Brite B, 1 part of Flower of Aztec Marigold essential oil, 150 parts of deionized waters.
The preparation method of the present embodiment static flocking gluing agent, comprises the steps:
(1) in reactor, after vinylformic acid, methyl acrylate, vinylformic acid Zhong Xin fat and isobornyl acrylate are mixed, join together with alkyl polyglycoside in part deionization, be stirred to and mix;
(2) N hydroxymethyl acrylamide is dissolved in remaining deionized water; in nitrogen protection; temperature is under 60 ℃ of conditions; slowly be added in reactor; also slowly add Potassium Persulphate and V-Brite B simultaneously; isothermal reaction 5h, finally adds Flower of Aztec Marigold essential oil, obtains the static flocking gluing agent of the present embodiment.
Embodiment 3
The agent of static flocking gluing, comprises the following component according to parts by weight meter: 4 parts, vinylformic acid, 12 parts of methyl acrylates, 28 parts, vinylformic acid Zhong Xin fat, 17 parts of isobornyl acrylate, 3 parts of N hydroxymethyl acrylamides, 8 parts of alkyl polyglycosides, 0.2 part of Potassium Persulphate, 0.25 part of V-Brite B, 0.5 part of Flower of Aztec Marigold essential oil, 140 parts of deionized waters.
The preparation method of the present embodiment static flocking gluing agent, comprises the steps:
(1) in reactor, after vinylformic acid, methyl acrylate, vinylformic acid Zhong Xin fat and isobornyl acrylate are mixed, join together with alkyl polyglycoside in part deionization, be stirred to and mix;
(2) N hydroxymethyl acrylamide is dissolved in remaining deionized water; in nitrogen protection; temperature is under 55 ℃ of conditions; slowly be added in reactor; also slowly add Potassium Persulphate and V-Brite B simultaneously; isothermal reaction 4h, finally adds Flower of Aztec Marigold essential oil, obtains the static flocking gluing agent of the present embodiment.
During use, by after 1 ~ 5 times of this product dilution, be coated in equably on flocking base-material, then by vertical the sticking on base material of short ultimate fibre.
The performance of the present embodiment 1 ~ 3 product and commercially available common flocking sizing agent are detected to contrast, and its detected result is as shown in table 1.
Table 1 detected result
Claims (3)
1. a static flocking gluing agent, is characterized in that comprising the following component according to parts by weight meter: 2 ~ 5 parts, vinylformic acid, 10 ~ 13 parts of methyl acrylates, 25 ~ 29 parts, vinylformic acid Zhong Xin fat, 16 ~ 18 parts of isobornyl acrylate, 2 ~ 4 parts of N hydroxymethyl acrylamides, 6 ~ 10 parts of alkyl polyglycosides, 0.1 ~ 0.3 part of Potassium Persulphate, 0.1 ~ 0.3 part of V-Brite B, 0.1 ~ 1 part, essence, 120 ~ 150 parts of deionized waters.
2. static flocking gluing according to claim 1 agent, is characterized in that described essence is Flower of Aztec Marigold essential oil.
3. the preparation method of static flocking gluing claimed in claim 1 agent, is characterized in that comprising the steps:
(1) in reactor, after vinylformic acid, methyl acrylate, vinylformic acid Zhong Xin fat and isobornyl acrylate are mixed, join together with alkyl polyglycoside in part deionization, be stirred to and mix;
(2) N hydroxymethyl acrylamide is dissolved in remaining deionized water; in nitrogen protection; temperature is under 50 ~ 60 ℃ of conditions; slowly be added in reactor; also slowly add Potassium Persulphate and V-Brite B simultaneously; isothermal reaction 2 ~ 5h, finally adds essence, obtains static flocking gluing of the present invention agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620023.8A CN103666341B (en) | 2013-11-29 | 2013-11-29 | A kind of static flocking gluing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620023.8A CN103666341B (en) | 2013-11-29 | 2013-11-29 | A kind of static flocking gluing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666341A true CN103666341A (en) | 2014-03-26 |
| CN103666341B CN103666341B (en) | 2015-12-09 |
Family
ID=50305133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310620023.8A Active CN103666341B (en) | 2013-11-29 | 2013-11-29 | A kind of static flocking gluing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666341B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531012A (en) * | 2014-12-26 | 2015-04-22 | 苏州龙腾万里化工科技有限公司 | Novel adhesive for flocking |
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
| CN106590476A (en) * | 2016-11-03 | 2017-04-26 | 东莞市联洲知识产权运营管理有限公司 | Electrostatic flocking adhesive and preparation method thereof |
| CN109749673A (en) * | 2019-01-11 | 2019-05-14 | 张新生 | A kind of preparation method of formaldehydeless static flocking adhesive |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280159A (en) * | 1999-07-09 | 2001-01-17 | 盐城冬阳化工有限公司 | Method for low-temperature synthesizing water emulsion type flocking adhesive |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310620023.8A patent/CN103666341B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280159A (en) * | 1999-07-09 | 2001-01-17 | 盐城冬阳化工有限公司 | Method for low-temperature synthesizing water emulsion type flocking adhesive |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王书乐 等主编: "《胶黏剂生产工艺实例》", 30 November 2010 * |
| 车广波 等: "低温固化静电植绒胶的研制", 《化学与黏合》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531012A (en) * | 2014-12-26 | 2015-04-22 | 苏州龙腾万里化工科技有限公司 | Novel adhesive for flocking |
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
| CN106590476A (en) * | 2016-11-03 | 2017-04-26 | 东莞市联洲知识产权运营管理有限公司 | Electrostatic flocking adhesive and preparation method thereof |
| CN109749673A (en) * | 2019-01-11 | 2019-05-14 | 张新生 | A kind of preparation method of formaldehydeless static flocking adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666341B (en) | 2015-12-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102605648B (en) | Textile water-based pigment printing binding agent and preparation method | |
| CN103666341A (en) | Electrostatic flocking adhesive and preparation method thereof | |
| CN101864025B (en) | Preparation method of polyacrylate microgel emulsion and application thereof | |
| CN102863929A (en) | Anti-yellowing emulsion polyacrylic ester pressure-sensitive adhesive and preparation method thereof | |
| CN102344771A (en) | Preparation method of redispersible waterborne pressure sensitive rubber latex | |
| CN105219316A (en) | A kind of high adhesion energy medical polyacrylate pressure-sensitive adhesive sticks agent | |
| CN102533177A (en) | High water resistance emulsion polyacrylate pressure-sensitive adhesive and preparation method and application thereof | |
| CN102134465A (en) | Self-crosslinking aqueous complex film adhesive and preparation method thereof | |
| CN103602296B (en) | Environment-friendly adhesion agent for coated abrasive tool product | |
| CN102250567B (en) | Aqueous laser film composite glue and preparation method thereof | |
| CN103113838B (en) | Novel environment-friendly aqueous joint adhesive and preparation method thereof | |
| CN103254370B (en) | A kind of waterborne preprinting emulsion and preparation method thereof | |
| CN103396746B (en) | A kind of high-performance water-based pressure sensitive adhesive and preparation method thereof | |
| CN103965816A (en) | Low-VOC (Volatile Organic Compound) high-performance emulsion adhesive for non-woven fabric material and preparation method thereof | |
| CN104710562B (en) | Styrene-modified acrylate pressure-sensitive adhesive emulsion and preparation method thereof | |
| CN108084927A (en) | A kind of water soluble acrylic acid adhesive and preparation method thereof | |
| CN102796476A (en) | Preparation method for water-soluble acrylic ester printing table glue | |
| CN101736608A (en) | Pigment printing thickener and method for preparing same | |
| CN103936917A (en) | Novel acrylic emulsion adhesion agent | |
| CN101942772A (en) | Low-formaldehyde soaping-resistant adhesive for textile pigment printing and preparation method thereof | |
| CN102120802A (en) | Preparation method of polyurethane macromonomer modified emulsion-type thickening agent | |
| CN108505365B (en) | Preparation method of salt-resistant printing thickener | |
| CN103665324B (en) | A kind of epoxy resin lalent solidifying agent and corresponding epoxypaint | |
| CN101134862A (en) | Aqueous gold aluminium ink resin and method for synthesizing the same | |
| CN102757749A (en) | Modified poly-acetate cotton spraying adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |