CN106590476A - Electrostatic flocking adhesive and preparation method thereof - Google Patents
Electrostatic flocking adhesive and preparation method thereof Download PDFInfo
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- CN106590476A CN106590476A CN201610952981.9A CN201610952981A CN106590476A CN 106590476 A CN106590476 A CN 106590476A CN 201610952981 A CN201610952981 A CN 201610952981A CN 106590476 A CN106590476 A CN 106590476A
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- electrostatic spinning
- ethyl acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Artificial Filaments (AREA)
- Catalysts (AREA)
Abstract
The invention discloses an electrostatic flocking adhesive and a preparation method thereof. The electrostatic flocking adhesive is prepared from ethyl acrylate, amyl acrylate, p-dioxanone, methyl tert butyl acrylate, ethyl ethyl acrylate, ethylacrylic acid-2-hydroxy butyl ester, ethyl methacrylate, dodecane phenol plyoxyethylene, sodium persulfate, sodium bicarbonate, nanometer titania and nano-zinc oxide. The invention further discloses the preparation method of the electrostatic flocking adhesive. The raw materials are subjected to emulsion copolymerization, and the electrostatic flocking adhesive is obtained. The electrostatic flocking adhesive prepared through cross-linking of all the raw materials has abrasion resistance and good hand feeling, and the electrostatic flocking adhesive has good antibacterial and bacteriostatic effects due to introduction of nanometer titania and nano-zinc oxide.
Description
Technical field：
The present invention relates to textile auxiliary synthesis field, more particularly, to a kind of electrostatic spinning adhesive and preparation method thereof.
Background technology：
Electrostatic spinning is the chopped fiber anticipated to be planted in the substrate surface for scribbling binding agent in high-voltage electrostatic field,
Fine hair is set to be fixed on base material through process again.It, can be to fabric, rubber, timber, metal used as a kind of Surface-micromachining process
It is surface-treated etc. various base materials, the base material processed through surface flocking is not only attractive in appearance, but also can be endowed wear-resisting, close
The various functions such as envelope, anti-corrosion, heat-insulated.
Static flocking technology needs base material, three kinds of raw materials of adhesive and fine hair, the adhesive of substrate surface to play floss
Hair is bonded in effect on base material, and its performance directly determines the quality of electrostatic spinning product, for example the fastness of flocking and
Feel quality, therefore, development function admirable, cheap adhesive have particularly significant meaning for the development of electrostatic spinning industry
Justice.Initial adhesive includes that the condensation containing formaldehyde is adhesive, neoprene adhesive, polyurethane adhesive etc., although
Glueability is excellent, but due to formaldehyde, the introducing of the noxious substance of chlorine, these adhesive more or less can be made in building-up process
Into environmental pollution, and the electrostatic spinning product carried out using such adhesive can also endanger user health.Polyacrylate
Class flocking adhesive is a kind of China's development electrostatic spinning adhesive faster, its have it is nontoxic, prepare easy advantage,
Become the favorable substitutes of poisonous flocking adhesive.But esters of acrylic acid adhesive is in wearability, feel, moisture-proof, antibacterial
Etc. aspect also there are many deficiencies, specifically how take into account wear-resisting and good feel, remain current electrostatic spinning
A problem urgently to be resolved hurrily in field.
The content of the invention：
The present invention relates to a kind of electrostatic spinning adhesive and preparation method thereof, this adhesive includes various soft or hard monomers and friendship
Connection agent, it is more excellent that the phase interworking between these raw materials causes the electrostatic spinning adhesive of the present invention to have compared with existing adhesive
Different physics, chemical property.
The technical solution adopted for the present invention to solve the technical problems is as follows：
A kind of electrostatic spinning adhesive, it is characterised in that Jing following raw materials according emulsion copolymerizations are formed：Ethyl acrylate, propylene
Sour pentyl ester, Lanthanum Isopropoxide, tert-butyl group acrylic acid methyl ester., ethyl acrylate, ethylacrylic acid -2- hydroxybutyls, first
Base ethyl acrylate, dodecyl phenol polyethenoxy ether are, sodium peroxydisulfate, sodium bicarbonate.
In terms of parts by weight, the ethyl acrylate is 3-3.5, the amyl acrylate is 4-5, described to dioxocyclohex
Ketone is 1-2, the tert-butyl group acrylic acid methyl ester. is 2-2.5, the ethyl acrylate is 3-4, the ethylacrylic acid -2-
Hydroxybutyl is 1-2, the ethyl methacrylate is 1-2, the dodecyl phenol polyethenoxy ether is 5-10, the over cure
Sour sodium is 0.2-0.5, the sodium bicarbonate is 0.8-1.2.
The raw material also includes nano titanium oxide and nano zine oxide.
In terms of parts by weight, the nano titanium oxide is 0.01-0.02, the nano zine oxide is 0.01-0.02.
A kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) a certain amount of ethyl acrylate, amyl acrylate, Lanthanum Isopropoxide, the tert-butyl group third are added in reactor
E pioic acid methyl ester, ethyl acrylate, ethylacrylic acid -2- hydroxybutyls, ethyl methacrylate, are uniformly mixed, and rise
Temperature is to 92-95 DEG C；
(2) deionized water and dodecyl phenol polyethenoxy ether are added in reactor, continues to stir, control reaction kettle temperature
Spend for 92-95 DEG C；
(3) to Deca sodium persulfate aqueous solution in reactor, 92-95 DEG C of insulation 2-2.5 hour is down to room temperature；
(4) sodium bicarbonate is added in reactor, a certain amount of deionized water is added after stirring, obtain electrostatic spinning gluing
Agent.
In terms of parts by weight, the ethyl acrylate is 3-3.5, the amyl acrylate is 4-5, described to dioxocyclohex
Ketone is 1-2, the tert-butyl group acrylic acid methyl ester. is 2-2.5, the ethyl acrylate is 3-4, the ethylacrylic acid -2-
Hydroxybutyl is 1-2, the ethyl methacrylate is 1-2, the dodecyl phenol polyethenoxy ether is 5-10, the over cure
Sour sodium is 0.2-0.5, the sodium bicarbonate is 0.8-1.2.
The step (1) also includes adding nano titanium oxide and nano zine oxide in reactor.
In terms of parts by weight, the nano titanium oxide is 0.01-0.02, the nano zine oxide is 0.01-0.02.
The invention has the advantages that：
By by ethyl acrylate, amyl acrylate, Lanthanum Isopropoxide, tert-butyl group acrylic acid methyl ester., ethylacrylic acid
Ethyl ester, ethylacrylic acid -2- hydroxybutyls, ethyl methacrylate as electrostatic spinning adhesive raw material, using each raw material
Crosslinking prepared by electrostatic spinning adhesive take into account wearability and excellent handle, nano titanium oxide and nano zine oxide
Introduce also cause the present invention electrostatic spinning adhesive there is good antibacterial bacteriostatic effect.
Specific embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of electrostatic spinning adhesive, in terms of parts by weight, Jing following raw materials according emulsion copolymerizations are formed：Ethyl acrylate be 3,
It is that 2, ethyl acrylate is 3, ethyl propylene for 1, tert-butyl group acrylic acid methyl ester. that amyl acrylate is 4, Lanthanum Isopropoxide
It is that 5, sodium peroxydisulfate is 0.2, carbonic acid for 1, dodecyl phenol polyethenoxy ether that acid -2- hydroxybutyls are 2, ethyl methacrylate
Hydrogen sodium is 0.8.
Embodiment 2
A kind of electrostatic spinning adhesive, in terms of parts by weight, Jing following raw materials according emulsion copolymerizations are formed：Ethyl acrylate is
3.5th, amyl acrylate be 5, Lanthanum Isopropoxide be 2, tert-butyl group acrylic acid methyl ester. be 2.5, ethyl acrylate be 4, second
It is that 2, dodecyl phenol polyethenoxy ether is for 10, sodium peroxydisulfate that base acrylic acid -2- hydroxybutyls are 2, ethyl methacrylate
0.5th, sodium bicarbonate be 1.2, nano titanium oxide be 0.01, nano zine oxide be 0.02.
Embodiment 3
A kind of electrostatic spinning adhesive, in terms of parts by weight, Jing following raw materials according emulsion copolymerizations are formed：Ethyl acrylate be 3,
It is that 2.5, ethyl acrylate is 3, ethyl third for 1, tert-butyl group acrylic acid methyl ester. that amyl acrylate is 5, Lanthanum Isopropoxide
It is that 8, sodium peroxydisulfate is 0.5, carbon for 1, dodecyl phenol polyethenoxy ether that olefin(e) acid -2- hydroxybutyls are 2, ethyl methacrylate
It is that 0.02, nano zine oxide is 0.01 that sour hydrogen sodium is 1.2, nano titanium oxide.
Embodiment 4
A kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) count by weight, following raw material is added in reactor：Ethyl acrylate is 3, amyl acrylate is 4, right
Dioxanone is 1, tert-butyl group acrylic acid methyl ester. is 2, ethyl acrylate is 3, ethylacrylic acid -2- hydroxybutyls are 2,
Ethyl methacrylate is 1, is uniformly mixed, and is warming up to 92-95 DEG C；
(2) add deionized water and parts by weight to be calculated as 5 dodecyl phenol polyethenoxy ether in reactor, continue to stir
Mix, control temperature of reaction kettle for 92-95 DEG C；
(3) to Deca sodium persulfate aqueous solution in reactor, wherein sodium peroxydisulfate parts by weight are 0.5,92-95 DEG C of insulation
2 hours, it is down to room temperature；
(4) sodium bicarbonate that weight fraction is 1.2 is added in reactor, a certain amount of deionized water is added after stirring, obtained
To electrostatic spinning adhesive.
Embodiment 5
A kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) count by weight, following raw material is added in reactor：Ethyl acrylate is 3.5, amyl acrylate is 5,
It is that 2.5, ethyl acrylate is 4, ethylacrylic acid -2- hydroxybutyls that Lanthanum Isopropoxide is 2, tert-butyl group acrylic acid methyl ester.
It is 2 for 2, ethyl methacrylate, is uniformly mixed, is warming up to 92-95 DEG C；
(2) add deionized water and parts by weight to be calculated as 10 dodecyl phenol polyethenoxy ether in reactor, continue
Stirring, controls temperature of reaction kettle for 92-95 DEG C；
(3) to Deca sodium persulfate aqueous solution in reactor, wherein sodium peroxydisulfate parts by weight are 0.2,92-95 DEG C of insulation
2 hours, it is down to room temperature；
(4) sodium bicarbonate that weight fraction is 0.8 is added in reactor, a certain amount of deionized water is added after stirring, obtained
To electrostatic spinning adhesive.
Embodiment 6
A kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) count by weight, following raw material is added in reactor：Ethyl acrylate is 3.5, amyl acrylate is 5,
It is that 2.5, ethyl acrylate is 4, ethylacrylic acid -2- hydroxybutyls that Lanthanum Isopropoxide is 2, tert-butyl group acrylic acid methyl ester.
For 2, ethyl methacrylate be 2, nano titanium oxide be 0.02, nano zine oxide be 0.01, be uniformly mixed, be warming up to
92-95℃；
(2) add deionized water and parts by weight to be calculated as 8 dodecyl phenol polyethenoxy ether in reactor, continue to stir
Mix, control temperature of reaction kettle for 92-95 DEG C；
(3) to Deca sodium persulfate aqueous solution in reactor, wherein sodium peroxydisulfate parts by weight are 0.5,92-95 DEG C of insulation
2 hours, it is down to room temperature；
(4) sodium bicarbonate that mass fraction is 1.2 is added in reactor, a certain amount of deionized water is added after stirring, obtained
To electrostatic spinning adhesive.
Embodiment 7
A kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) count by weight, following raw material is added in reactor：Ethyl acrylate is 3.5, amyl acrylate is 5,
It is that 2.5, ethyl acrylate is 4, ethylacrylic acid -2- hydroxybutyls that Lanthanum Isopropoxide is 2, tert-butyl group acrylic acid methyl ester.
For 2, ethyl methacrylate be 2, nano titanium oxide be 0.01, nano zine oxide be 0.02, be uniformly mixed, be warming up to
92-95℃；
(2) add deionized water and parts by weight to be calculated as 5 dodecyl phenol polyethenoxy ether in reactor, continue to stir
Mix, control temperature of reaction kettle for 92-95 DEG C；
(3) to Deca sodium persulfate aqueous solution in reactor, wherein sodium peroxydisulfate parts by weight are 0.5,92-95 DEG C of insulation
2 hours, it is down to room temperature；
(4) sodium bicarbonate that mass fraction is 0.8 is added in reactor, a certain amount of deionized water is added after stirring, obtained
To electrostatic spinning adhesive.
Claims (8)
1. a kind of electrostatic spinning adhesive, it is characterised in that the adhesive Jing following raw materials according emulsion copolymerizations are formed：Acrylic acid second
Ester, amyl acrylate, Lanthanum Isopropoxide, tert-butyl group acrylic acid methyl ester., ethyl acrylate, ethylacrylic acid -2- hydroxyls
Butyl ester, ethyl methacrylate, dodecyl phenol polyethenoxy ether, sodium peroxydisulfate, sodium bicarbonate.
2. electrostatic spinning adhesive according to claim 1, it is characterised in that in terms of parts by weight, the acrylic acid second
Ester is 3-3.5, the amyl acrylate is 4-5, the Lanthanum Isopropoxide is 1-2, the tert-butyl group acrylic acid methyl ester. is 2-
2.5th, the ethyl acrylate be 3-4, the ethylacrylic acid -2- hydroxybutyls be 1-2, the ethyl methacrylate
For 1-2, the dodecyl phenol polyethenoxy ether be 5-10, the sodium peroxydisulfate be 0.2-0.5, the sodium bicarbonate be 0.8-
1.2。
3. electrostatic spinning adhesive according to claim 1 and 2, it is characterised in that：The raw material also includes nano-silica
Change titanium and nano zine oxide.
4. electrostatic spinning adhesive according to claim 3, it is characterised in that：In terms of parts by weight, the nano-silica
Change titanium is 0.01-0.02, the nano zine oxide is 0.01-0.02.
5. a kind of preparation method of electrostatic spinning adhesive, it is characterised in that comprise the following steps：
(1) a certain amount of ethyl acrylate, amyl acrylate, Lanthanum Isopropoxide, tert-butyl group acrylic acid are added in reactor
Methyl ester, ethyl acrylate, ethylacrylic acid -2- hydroxybutyls, ethyl methacrylate, are uniformly mixed, and are warming up to
92-95℃；
(2) deionized water and dodecyl phenol polyethenoxy ether are added in reactor, continues to stir, controlling temperature of reaction kettle is
92-95℃；
(3) to Deca sodium persulfate aqueous solution in reactor, 92-95 DEG C of insulation 2-2.5 hour is down to room temperature；
(4) sodium bicarbonate is added in reactor, a certain amount of deionized water is added after stirring, obtain electrostatic spinning adhesive.
6. the preparation method of electrostatic spinning adhesive according to claim 5, it is characterised in that：In terms of parts by weight, institute
State ethyl acrylate for 3-3.5, the amyl acrylate be 4-5, the Lanthanum Isopropoxide be 1-2, the tert-butyl group propylene
Sour methyl ester is 2-2.5, the ethyl acrylate is 3-4, the ethylacrylic acid -2- hydroxybutyls are 1-2, the methyl
Ethyl acrylate is 1-2, the dodecyl phenol polyethenoxy ether is 5-10, the sodium peroxydisulfate is 0.2-0.5, the carbonic acid
Hydrogen sodium is 0.8-1.2.
7. the preparation method of electrostatic spinning adhesive according to claim 5, it is characterised in that：The step (1) is also wrapped
Include and nano titanium oxide and nano zine oxide are added in reactor.
8. the preparation method of electrostatic spinning adhesive according to claim 7, it is characterised in that：In terms of parts by weight, institute
It is 0.01-0.02 that nano titanium oxide is stated for 0.01-0.02, the nano zine oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610952981.9A CN106590476A (en) | 2016-11-03 | 2016-11-03 | Electrostatic flocking adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610952981.9A CN106590476A (en) | 2016-11-03 | 2016-11-03 | Electrostatic flocking adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106590476A true CN106590476A (en) | 2017-04-26 |
Family
ID=58589488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610952981.9A Pending CN106590476A (en) | 2016-11-03 | 2016-11-03 | Electrostatic flocking adhesive and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107904980A (en) * | 2017-12-26 | 2018-04-13 | 泉州静杰企业管理咨询有限公司 | The production method of flocking synthetic leather technique |
| CN110951428A (en) * | 2018-09-26 | 2020-04-03 | 浙江久大纺织科技有限公司 | APEO-free acrylate electrostatic flocking adhesive and preparation method thereof |
| CN111331968A (en) * | 2020-03-10 | 2020-06-26 | 东莞市古德木业有限公司 | Aluminum-wood multilayer composite board and preparation process thereof |
| CN111452452A (en) * | 2020-03-10 | 2020-07-28 | 东莞市古德木业有限公司 | Multilayer composite board containing aluminum honeycomb core and preparation process thereof |
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|---|---|---|---|---|
| CN101423735A (en) * | 2008-12-05 | 2009-05-06 | 武汉科技学院 | Method for preparing environment-friendly type organosilicon modified acrylic ester binding agent |
| CN103666341A (en) * | 2013-11-29 | 2014-03-26 | 江苏中新资源集团有限公司 | Electrostatic flocking adhesive and preparation method thereof |
| CN104419359A (en) * | 2013-08-28 | 2015-03-18 | 广东彩格科技有限公司 | Flocking adhesive as well as preparation method thereof |
| CN104745126A (en) * | 2015-01-21 | 2015-07-01 | 奚济孝 | Flocking adhesive as well as processing method and foaming process thereof |
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2016
- 2016-11-03 CN CN201610952981.9A patent/CN106590476A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423735A (en) * | 2008-12-05 | 2009-05-06 | 武汉科技学院 | Method for preparing environment-friendly type organosilicon modified acrylic ester binding agent |
| CN104419359A (en) * | 2013-08-28 | 2015-03-18 | 广东彩格科技有限公司 | Flocking adhesive as well as preparation method thereof |
| CN103666341A (en) * | 2013-11-29 | 2014-03-26 | 江苏中新资源集团有限公司 | Electrostatic flocking adhesive and preparation method thereof |
| CN104745126A (en) * | 2015-01-21 | 2015-07-01 | 奚济孝 | Flocking adhesive as well as processing method and foaming process thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107904980A (en) * | 2017-12-26 | 2018-04-13 | 泉州静杰企业管理咨询有限公司 | The production method of flocking synthetic leather technique |
| CN110951428A (en) * | 2018-09-26 | 2020-04-03 | 浙江久大纺织科技有限公司 | APEO-free acrylate electrostatic flocking adhesive and preparation method thereof |
| CN111331968A (en) * | 2020-03-10 | 2020-06-26 | 东莞市古德木业有限公司 | Aluminum-wood multilayer composite board and preparation process thereof |
| CN111452452A (en) * | 2020-03-10 | 2020-07-28 | 东莞市古德木业有限公司 | Multilayer composite board containing aluminum honeycomb core and preparation process thereof |
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Application publication date: 20170426 |