CN103666324B - A kind of Corrugated Box reinstate tackiness agent - Google Patents
A kind of Corrugated Box reinstate tackiness agent Download PDFInfo
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- CN103666324B CN103666324B CN201310620219.7A CN201310620219A CN103666324B CN 103666324 B CN103666324 B CN 103666324B CN 201310620219 A CN201310620219 A CN 201310620219A CN 103666324 B CN103666324 B CN 103666324B
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- parts
- tackiness agent
- corrugated box
- reinstate
- starch
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000001590 oxidative effect Effects 0.000 claims abstract description 12
- 239000004113 Sepiolite Substances 0.000 claims abstract description 10
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004327 boric acid Substances 0.000 claims abstract description 10
- 239000007800 oxidant agent Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 10
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 10
- 229940037003 alum Drugs 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims abstract description 9
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 9
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 9
- -1 8 ~ 10 parts Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 12
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 238000009825 accumulation Methods 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 5
- 239000002689 soil Substances 0.000 abstract description 5
- 229920002472 Starch Polymers 0.000 description 33
- 235000019698 starch Nutrition 0.000 description 33
- 239000008107 starch Substances 0.000 description 33
- 239000000853 adhesive Substances 0.000 description 16
- 230000001070 adhesive effect Effects 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 8
- 239000003292 glue Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 239000001254 oxidized starch Substances 0.000 description 3
- 235000013808 oxidized starch Nutrition 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a kind of Corrugated Box reinstate tackiness agent, be made by the raw material of following weight proportion: W-Gum 35 ~ 45 parts, 40 ~ 55 parts, water, 8 ~ 10 parts, sodium hydroxide, boric acid 0.15 ~ 0.25 part, composite oxidant 1.2 ~ 3.6 parts, 0.15 ~ 0.25 part, sodium thiosulfate, Nano sepiolite powder 0.25 ~ 0.4 part, 0.05 ~ 0.20 part, alum.Advantage of the present invention is fast drying, the binding property well not easily moisture absorption accumulation of salt in the surface soil again, is particularly suitable for bonding Corrugated Box.
Description
Technical field
The present invention relates to a kind of Starch Adhesive, particularly relate to a kind of reinstate tackiness agent for Corrugated Box bonding.
Background technology
Paper product particularly Corrugated Box are produced, and use sodium silicate in decades more.Because its alkalescence is large, the easy moisture absorption, normal accumulation of salt in the surface soil whiting causes paper product to be out of shape, to peel off, and even corrodes commodity, causing the rotten tremendous economic loss such as to scrap.Therefore, abroad from the fifties just replace sodium silicate with Starch Adhesive, the domestic Starch Adhesive that also begins one's study the end of the seventies, be applied to gradually the eighties paper product produce.
What disclose about the formula of Starch Adhesive and production technique in prior art has a lot, and the patented technology document being wherein seen in State Intellectual Property Office website just has hundreds of.Wherein comparatively typical patent application technology has: Yangjiang City Huamei Printing Packaging Co., Ltd. has applied for the patent of invention (number of patent application is 200410015298.X) of " a kind of fast drying starch adhesive " on February 6th, 2004, that application discloses a kind of fast drying starch adhesive, produced by following methods: 10 parts of starch are put into and added 40 parts of water in stirred pot and stir by (1), then add sodium hydroxide solution 0.8 ~ 1 part, manage row quaternization at normal temperatures; (2) add 0.04 part of hydrogen peroxide, 30 parts of water carry out oxidizing reaction 40 minutes; (3) add 0.04 part of tributyl phosphate, 0.04 part of borax, 0.15 part of sodium carbonate, 0.01 part of magnesium sulfate, stir 10 minutes, make liquid reactions become oyster white or light beige.The feature of this technology is that product density is little, bounding force strong, fast drying, good fluidity, not strike-through, not skinning, not easily turn to be yellow, and production cost is low, production unit is simple.
In addition, Jiangyan City Huaguang Chemical Paper Co., Ltd. proposes the patent application (number of patent application is 200310106411.0) of " Starch Adhesive (SSS-85) " by name on November 25th, 2003, its technical scheme is: a kind of Starch Adhesive, with W-Gum and water for main component, containing stablizer, oxygenant, terminator, in composition, add compound agent, catalyzer.Compare with phosphate ester starch with treated starch such as the Sumstar 190 of routine, the feature of this technical scheme is that tackiness agent sticks with paste that the retrogradation of liquid is little, compatibleness good, be conducive to preparing high solids content, low viscous pigment coating, its paper properties is superior, and has outstanding cost performance.
Above-mentioned patent has covered most starch producing technology technology.But from disclosed related art scheme, all there is some shortcomings part, some production cost is high, some rate of drying is slow, and some is then that quality is unreliable.From market study, the Starch Adhesive product that on market, a kind of rate of drying of common requirements is fast, cost is low.For this demand, I have submitted " fast-drying type adhesive for paper box " patent application by name last year, disclose a kind of new type bonding agent, its each Ingredients Weight proportioning is: W-Gum 25 ~ 30 parts, 50 ~ 55 parts, water, 8 ~ 10 parts, sodium hydroxide, boric acid 0.12 ~ 0.16 part, composite oxidant 0.3 ~ 0.45 part, 0.3 ~ 0.45 part, sodium thiosulfate, Nano sepiolite powder 0.25 ~ 0.4 part.But in actual use, this patented technology is still weak, and the Harmony between related component does not also reach optimum regime, obtained tackiness agent rate of drying is fast not enough, still there is certain moisture absorption accumulation of salt in the surface soil phenomenon.
Summary of the invention
The present invention seeks to overcome weak point of the prior art, provide a kind of and be applicable to Corrugated Box feature, the reinstate tackiness agent of fast drying, the binding property well not easily moisture absorption accumulation of salt in the surface soil again.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical programs: a kind of Corrugated Box reinstate tackiness agent, is made by the raw material of following weight proportion: W-Gum 35 ~ 45 parts, 40 ~ 55 parts, water, 8 ~ 10 parts, sodium hydroxide, boric acid 0.15 ~ 0.25 part, composite oxidant 1.2 ~ 3.6 parts, 0.15 ~ 0.25 part, sodium thiosulfate, Nano sepiolite powder 0.25 ~ 0.4 part, 0.05 ~ 0.20 part, alum.
Preferred version of the present invention is: W-Gum 40 parts, 45 parts, water, 9 parts, sodium hydroxide, boric acid 0.18 part, composite oxidant 1.6 parts, 0.2 part, sodium thiosulfate, Nano sepiolite powder 0.3 part, 0.18 part, alum.
As further improvement of the present invention, described composite oxidant is mixed in 1:3 ~ 7 ratio by potassium permanganate and mineral acid.
Advantage of the present invention is:
1, good combination property of the present invention, bond properties is more excellent.With regard to the oeverall quality of Starch Adhesive, it depends primarily on the oxidative deformation process of starch in former process.Generally speaking, the oxygenant that Starch Adhesive is selected is all potassium permanganate.But in actual production process, we find iff using single potassium permanganate as oxygenant, effect also and bad.Therefore, after lot of experiments, present invention employs and potassium permanganate and mineral acid are blended together composite oxidant, thus can controlled oxidization process better, promote oxidation effectiveness.Select contrast through actual, the Starch Adhesive obtained by the present invention is higher by 15% than adopting conventional single its viscosity of potassium permanganate oxidant, and whiteness and transparency want high by about 25%.The alum added in the present invention has urges dry, clarification, strong papery effect, can simplify operation, shorten Production Time, and effectively can reduce the moisture absorption, the accumulation of salt in the surface soil phenomenon in tackiness agent use procedure.
2, the drying effect of tackiness agent is good.Tackiness agent adds boric acid, and it can make the starch of short chain form complex compound with its hydroxyl or hydroxyl and boron atom, irregular crosslinked by these, form reticulated structure, there is crosslinked viscosifying action, be conducive to improving initial bonding strength and accelerating rate of drying, also play anticorrosion, antiseepage effect.Adding the rate of drying that siccative then obviously can improve tackiness agent, selecting Nano sepiolite powder better than selecting the effect of bentonite again as siccative.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: under room temperature, get 35kg W-Gum to mix with 40kg water, slow interpolation also stirs to milky starch slurry, gets sodium hydroxide 8kg and is mixed with certain density sodium hydroxide solution and it is slowly added in starch slurry, obtains the milky white thickness starch paste of pre-gelatinized; Then get potassium permanganate 0.3kg, phosphoric acid 0.9kg, prepared certain density combined oxidation agent solution with hot water, add in above-mentioned starch paste; Get again boric acid 0.15kg hot water dissolving be made into certain density solution add starch paste formed glue, finally get sodium thiosulfate 0.15kg and alum 0.05kg is mixed with certain concentration solution, add in glue and finally obtain oxidized starch adhesive, tackiness agent is constantly stirred and slowly adds Nano sepiolite powder 0.25kg again, finally obtain finished product.
Embodiment 2: under room temperature, get 45kg W-Gum to mix with 55kg water, slow interpolation also stirs to milky starch slurry, gets sodium hydroxide 10kg and is mixed with certain density sodium hydroxide solution and it is slowly added in starch slurry, obtains the milky white thickness starch paste of pre-gelatinized; Then get potassium permanganate 0.45kg, phosphoric acid 3.15kg, prepared certain density combined oxidation agent solution with hot water, add in above-mentioned starch paste; Get again boric acid 0.25kg hot water dissolving be made into certain density solution add starch paste formed glue, finally get sodium thiosulfate 0.25kg and alum 0.20kg is made into certain concentration solution, add in glue and finally obtain oxidized starch adhesive, tackiness agent is constantly stirred and slowly adds Nano sepiolite powder 0.25kg again, finally obtain finished product.
Embodiment 3: under room temperature, get 40kg W-Gum to mix with 45kg water, slow interpolation also stirs to milky starch slurry, gets sodium hydroxide 9kg and is mixed with certain density sodium hydroxide solution and it is slowly added in starch slurry, obtains the milky white thickness starch paste of pre-gelatinized; Then get potassium permanganate 0.35kg, phosphatase 11 .25kg, prepared certain density combined oxidation agent solution with hot water, add in above-mentioned starch paste; Get again boric acid 0.18kg hot water dissolving be made into certain density solution add starch paste formed glue, finally get sodium thiosulfate 0.2kg and alum 0.18kg is made into certain concentration solution, add in glue and finally obtain oxidized starch adhesive, tackiness agent is constantly stirred and slowly adds Nano sepiolite powder 0.3kg again, finally obtain finished product.
Claims (2)
1. a Corrugated Box reinstate tackiness agent, is characterized in that it is made by the raw material of following weight proportion: W-Gum 35 ~ 45 parts, 40 ~ 55 parts, water, 8 ~ 10 parts, sodium hydroxide, boric acid 0.15 ~ 0.25 part, composite oxidant 1.2 ~ 3.6 parts, 0.15 ~ 0.25 part, sodium thiosulfate, Nano sepiolite powder 0.25 ~ 0.4 part, 0.05 ~ 0.20 part, alum;
Described composite oxidant is mixed in 1:3 ~ 7 ratio by potassium permanganate and mineral acid.
2. Corrugated Box reinstate tackiness agent according to claim 1, is characterized in that it is made by the raw material of following weight proportion: W-Gum 40 parts, 45 parts, water, 9 parts, sodium hydroxide, boric acid 0.18 part, composite oxidant 1.6 parts, 0.2 part, sodium thiosulfate, Nano sepiolite powder 0.3 part, 0.18 part, alum.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310620219.7A CN103666324B (en) | 2013-11-29 | 2013-11-29 | A kind of Corrugated Box reinstate tackiness agent |
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| CN201310620219.7A CN103666324B (en) | 2013-11-29 | 2013-11-29 | A kind of Corrugated Box reinstate tackiness agent |
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| CN103666324A CN103666324A (en) | 2014-03-26 |
| CN103666324B true CN103666324B (en) | 2016-03-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105907334A (en) * | 2016-06-01 | 2016-08-31 | 安阳华森纸业有限责任公司 | Preparation method of oxidized starch cellulose composite adhesive |
| CN107286867A (en) * | 2017-06-21 | 2017-10-24 | 合肥龙发包装有限公司 | A kind of preparation technology of corrugated case high-quality adhesive |
| CN112608694A (en) * | 2020-11-26 | 2021-04-06 | 仲恺农业工程学院 | Quick-drying environment-friendly starch adhesive and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329581A (en) * | 2011-08-02 | 2012-01-25 | 张家港市鹿苑淀粉厂 | Starch adhesive for compounding paperboards and preparation method thereof |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329581A (en) * | 2011-08-02 | 2012-01-25 | 张家港市鹿苑淀粉厂 | Starch adhesive for compounding paperboards and preparation method thereof |
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| CN103666324A (en) | 2014-03-26 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cao Feng Inventor after: Zhang Yujian Inventor after: Pan Guoxiang Inventor before: Tang Yingjie |
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Effective date of registration: 20160204 Address after: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Applicant after: Huzhou Teachers College Address before: Room 20, building 201, station village, Chaoyang Street, Wuxing District, Zhejiang, Huzhou, 313000 Applicant before: Tang Yingjie |
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Effective date of registration: 20170421 Address after: Shunde District of Guangdong province 528000 Foshan City Chencun Hirotaka Bi Jiao Village Industrial Zone, fifteen Industrial Road No. 4 Patentee after: Shunde District, Foshan Han Yu Paper Products Co., Ltd. Address before: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Patentee before: Huzhou Teachers College |
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