CN103666325B - A kind of Corrugated Box reinstate tackiness agent - Google Patents
A kind of Corrugated Box reinstate tackiness agent Download PDFInfo
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- CN103666325B CN103666325B CN201310620503.4A CN201310620503A CN103666325B CN 103666325 B CN103666325 B CN 103666325B CN 201310620503 A CN201310620503 A CN 201310620503A CN 103666325 B CN103666325 B CN 103666325B
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- parts
- tackiness agent
- reinstate
- corrugated box
- water
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000001590 oxidative effect Effects 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000007800 oxidant agent Substances 0.000 claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 229940078916 carbamide peroxide Drugs 0.000 claims abstract description 12
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004327 boric acid Substances 0.000 claims abstract description 8
- 150000002815 nickel Chemical class 0.000 claims abstract description 8
- 239000004113 Sepiolite Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 5
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 5
- 229920002472 Starch Polymers 0.000 claims description 19
- 239000008107 starch Substances 0.000 claims description 19
- 235000019698 starch Nutrition 0.000 claims description 19
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 description 15
- 230000001070 adhesive effect Effects 0.000 description 13
- 238000003756 stirring Methods 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 4
- 235000013877 carbamide Nutrition 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of Corrugated Box reinstate tackiness agent, it is characterized in that it is made by the raw material of following weight proportion: W-Gum 25 ~ 30 parts, 50 ~ 55 parts, water, carbamide peroxide 3 ~ 13 parts, single nickel salt 0.005 ~ 0.05 part, boric acid 0.12 ~ 0.16 part, composite oxidant 0.3 ~ 0.45 part, Nano sepiolite powder 0.016 ~ 0.06 part, polyacrylamide 0.2 ~ 1 part.Advantage of the present invention is that fast drying, good combination property, production cost are low.The present invention adopts carbamide peroxide as primary oxidizers and coordinates single nickel salt, selects polyacrylamide to do properties-correcting agent simultaneously, effectively improves the performances such as the gel resistance of Sumstar 190, water absorbability, snappiness and toughness, receives the effect of achieving many things at one stroke.
Description
Technical field
The present invention relates to a kind of Starch Adhesive, particularly relate to a kind of Modified Starch Adhesive being exclusively used in binding paper box.
Background technology
Paper product particularly Corrugated Box are produced, and use sodium silicate in decades more.Because its alkalescence is large, the easy moisture absorption, normal accumulation of salt in the surface soil whiting causes paper product to be out of shape, to peel off, and even corrodes commodity, causing the rotten tremendous economic loss such as to scrap.Therefore, abroad from the fifties just replace sodium silicate with Starch Adhesive, the domestic Starch Adhesive that also begins one's study the end of the seventies, be applied to gradually the eighties paper product produce.
What disclose about the formula of Starch Adhesive and production technique in prior art has a lot, and the patented technology document being wherein seen in State Intellectual Property Office website just has hundreds of.Wherein comparatively typical patent application technology has: Yangjiang City Huamei Printing Packaging Co., Ltd. has applied for the patent of invention (number of patent application is 200410015298.X) of " a kind of fast drying starch adhesive " on February 6th, 2004, that application discloses a kind of fast drying starch adhesive, produced by following methods: 10 parts of starch are put into and added 40 parts of water in stirred pot and stir by (1), then add sodium hydroxide solution 0.8 ~ 1 part, manage row quaternization at normal temperatures; (2) add 0.04 part of hydrogen peroxide, 30 parts of water carry out oxidizing reaction 40 minutes; (3) add 0.04 part of tributyl phosphate, 0.04 part of borax, 0.15 part of sodium carbonate, 0.01 part of magnesium sulfate, stir 10 minutes, make liquid reactions become oyster white or light beige.The feature of this technology is that product density is little, bounding force strong, fast drying, good fluidity, not strike-through, not skinning, not easily turn to be yellow, and production cost is low, production unit is simple.
Henan Xindoucai Printing Co., Ltd. has applied for " corn starch adhesive agent " patent of invention (number of patent application is 200810141014.X) on August 13rd, 2008, its technical scheme is: a kind of corn starch adhesive agent is prepared according to following step: (1) first adds 50 weight parts waters in container, and the hydrogen peroxide then adding 2 ~ 2.5 weight parts stirs; (2) W-Gum adding 10 ~ 15 weight parts in above-mentioned gains stirs and obtains glue; (3) ferrous sulfate getting 0.04 ~ 0.08 weight part joins in second step gained glue after adding the water dilution of 1.5 ~ 2.5 weight parts, leaves standstill 20 ~ 40 minutes after stirring; (4) in the 3rd step gains, add the water of 25 ~ 35 weight parts, stir; (5) get the sodium hydroxide of 2 ~ 2.5 weight parts, join in the 4th step gains after adding the water dilution of 6.5 ~ 7.5 weight parts and stir 8 ~ 15 minutes; (6) join in the 5th step gains after the borax getting 1.2 ~ 1.5 weight parts adds the dissolved in boiled water of 2.5 ~ 3.5 weight parts, stir 4 ~ 8 minutes; (7) in the 6th step gains, add the water of proper quantity of defoaming agent and 4.5 ~ 5.5 weight parts, stir.Its advantage is nonpoisonous and tasteless, strong adhesion, can be used in food service industry packaging.
Above-mentioned patent has covered most starch producing technology technology.But from disclosed
Related art scheme, all also exists some shortcomings part, and some production cost is high, and some rate of drying is slow, and some is then that quality is unreliable.From market study, the Starch Adhesive product that on market, a kind of rate of drying of common requirements is fast, cost is low.
Summary of the invention
The present invention seeks to overcome weak point of the prior art, a kind of environmental friendliness is provided, the Modified Starch Adhesive of economical, modest viscosity.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical programs: a kind of Corrugated Box reinstate tackiness agent, is be made by the raw material of following weight proportion: W-Gum 25 ~ 30 parts, 50 ~ 55 parts, water, carbamide peroxide 3 ~ 13 parts, single nickel salt 0.005 ~ 0.05 part, boric acid 0.12 ~ 0.16 part, composite oxidant 0.3 ~ 0.45 part, Nano sepiolite powder 0.016 ~ 0.06 part, polyacrylamide 0.2 ~ 1 part.
Preferred version of the present invention is: W-Gum 25 parts, 50 parts, water, boric acid 0.15 part, composite oxidant 0.35 part, carbamide peroxide 7 parts, single nickel salt 0.035 part, polyacrylamide 0.65 part.
As further improvement of the present invention, described composite oxidant is mixed in 1:3 ~ 7 ratio by potassium permanganate and mineral acid.
Advantage of the present invention is:
1, good combination property of the present invention.In the present invention, carbamide peroxide is decomposed into urea (CO (NH2) 2), H2O2 and atomic oxygen (O) in water, H2O2 and atomic oxygen (O) are discharged gradually, oxidizing reaction can be carried out at normal temperatures and pressures, and it is strong that the existence of atomic oxygen (O) makes carbamide peroxide have stronger oxidisability than hydrogen peroxide.Meanwhile, carbamide peroxide or SYNTHETIC OPTICAL WHITNER, can make adhesive product whiter finer and smoother.In addition, the decomposition by-products urea of carbamide peroxide can as the filler of tackiness agent.The condensation that carbonyl in urea molecule can occur to a certain degree with the hydroxyl in starch chain, thus the denseness and the bonding force that increase tackiness agent.Meanwhile, urea has certain water absorbability, can have concurrently and urge dry effect.With regard to the oeverall quality of Starch Adhesive, it depends primarily on the oxidative deformation process of starch in former process.Generally speaking, the oxygenant that Starch Adhesive is selected is all potassium permanganate.But in actual production process, we find iff using single potassium permanganate as oxygenant, effect also and bad.Therefore, after lot of experiments, present invention employs and potassium permanganate and mineral acid are blended together composite oxidant, thus can controlled oxidization process better, promote oxidation effectiveness.Select contrast through actual, the Starch Adhesive obtained by the present invention is all higher than adopting conventional single its viscosity of potassium permanganate oxidant, whiteness and transparency.The present invention adopts polyacrylamide to do properties-correcting agent, effectively improves the performances such as the gel resistance of Sumstar 190, water absorbability, snappiness and toughness, receives the effect of achieving many things at one stroke.
2, the drying effect of tackiness agent is good.Tackiness agent adds boric acid, and it can make the starch of short chain form complex compound with its hydroxyl or hydroxyl and boron atom, irregular crosslinked by these, form reticulated structure, there is crosslinked viscosifying action, be conducive to improving initial bonding strength and accelerating rate of drying, also play anticorrosion, antiseepage effect.Adding the rate of drying that siccative then obviously can improve tackiness agent, selecting light calcium carbonate better than selecting the effect of bentonite again as siccative.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: first potassium permanganate and mineral acid are mixed into composite oxidant in the ratio of 1:3.Take W-Gum 25KG, water 50KG, carbamide peroxide 3KG, single nickel salt 0.005KG, boric acid 0.12KG, composite oxidant 0.3KG, Nano sepiolite powder 0.016KG, polyacrylamide 0.2KG more in proportion, the preparation method of treated starch is prepared routinely, obtains Corrugated Box reinstate tackiness agent.
Embodiment 2: first potassium permanganate and mineral acid are mixed into composite oxidant in the ratio of 1:5.Take W-Gum 30KG, water 55KG, carbamide peroxide 13KG, single nickel salt 0.05KG, boric acid 0.16KG, composite oxidant 0.45KG, Nano sepiolite powder 0.06KG, polyacrylamide 1KG more in proportion, the preparation method of treated starch is prepared routinely, obtains Corrugated Box reinstate tackiness agent.
Embodiment 3: first potassium permanganate and mineral acid are mixed into composite oxidant in the ratio of 1:5.Take W-Gum 25KG, water 50KG, boric acid 0.15KG, composite oxidant 0.35KG, carbamide peroxide 7KG, single nickel salt 0.035KG, polyacrylamide 0.65KG more in proportion, the preparation method of treated starch is prepared routinely, obtains Corrugated Box reinstate tackiness agent.
Claims (1)
1. a Corrugated Box reinstate tackiness agent, it is characterized in that it is prepared from by following methods: first potassium permanganate and mineral acid are mixed into composite oxidant in the ratio of 1:3, take W-Gum 25KG, water 50KG, carbamide peroxide 3KG, single nickel salt 0.005KG, boric acid 0.12KG, composite oxidant 0.3KG, Nano sepiolite powder 0.016KG, polyacrylamide 0.2KG more in proportion, the preparation method of treated starch is prepared routinely, obtains Corrugated Box reinstate tackiness agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620503.4A CN103666325B (en) | 2013-11-29 | 2013-11-29 | A kind of Corrugated Box reinstate tackiness agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620503.4A CN103666325B (en) | 2013-11-29 | 2013-11-29 | A kind of Corrugated Box reinstate tackiness agent |
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| Publication Number | Publication Date |
|---|---|
| CN103666325A CN103666325A (en) | 2014-03-26 |
| CN103666325B true CN103666325B (en) | 2016-03-30 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095741A (en) * | 1993-05-29 | 1994-11-30 | 龚经强 | High strength and quick drying starch binder for paper products and preparation technology thereof |
| CN101838508A (en) * | 2010-05-27 | 2010-09-22 | 湖州思伊淀粉工业有限公司 | Preparation method of starch base paper packing adhesive |
| CN103102829A (en) * | 2012-12-10 | 2013-05-15 | 铜陵市松马食品包装机械制造有限责任公司 | Binder without foaming |
-
2013
- 2013-11-29 CN CN201310620503.4A patent/CN103666325B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095741A (en) * | 1993-05-29 | 1994-11-30 | 龚经强 | High strength and quick drying starch binder for paper products and preparation technology thereof |
| CN101838508A (en) * | 2010-05-27 | 2010-09-22 | 湖州思伊淀粉工业有限公司 | Preparation method of starch base paper packing adhesive |
| CN103102829A (en) * | 2012-12-10 | 2013-05-15 | 铜陵市松马食品包装机械制造有限责任公司 | Binder without foaming |
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| Publication number | Publication date |
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| CN103666325A (en) | 2014-03-26 |
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Inventor after: Cao Feng Inventor after: Pan Guoxiang Inventor after: Zhang Yujian Inventor before: Tang Yingjie |
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Effective date of registration: 20160307 Address after: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Applicant after: Huzhou Teachers College Address before: Room 20, building 201, station village, Chaoyang Street, Wuxing District, Zhejiang, Huzhou, 313000 Applicant before: Tang Yingjie |
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Effective date of registration: 20170420 Address after: 528000 Guangdong, Shunde, Beijiao Town, Beijiao Industrial Park, Albert Road, No. 1, No. 5 Patentee after: Shunde City, Foshan District, the world of packaging materials Co., Ltd. Address before: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Patentee before: Huzhou Teachers College |
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