CN101161750A - Macromolecule plant binding agent and preparation method - Google Patents
Macromolecule plant binding agent and preparation method Download PDFInfo
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- CN101161750A CN101161750A CNA2007100727073A CN200710072707A CN101161750A CN 101161750 A CN101161750 A CN 101161750A CN A2007100727073 A CNA2007100727073 A CN A2007100727073A CN 200710072707 A CN200710072707 A CN 200710072707A CN 101161750 A CN101161750 A CN 101161750A
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- potassium permanganate
- sodium hydroxide
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Abstract
The invention discloses a macromolecule vegetable bonding agent and the preparation method thereof, which belongs to the bonding agent technical field. The technical proposal adopted by the invention for solving the technical problem is that: the material compositions and proportions are as follows: vegetable starch 20-30 percent, potassium permanganate 0.5-1 percent, 10 percent dilute sulfuric acid 1.8-5.4 percent, sodium hydroxide 2-4 percent, sodium borate 0.4-1 percent, kaolin 4-10 percent, tributyl phosphate 0.05-0.1 percent, clear water 65-75 percent; firstly the potassium permanganate is dissolved in hot water above 90 DEG in proportion for future use, the sodium hydroxide is also dissolved in water in proportion for future use, and the sodium borate is also dissolved in hot water above 90 DEG in proportion for future use; then part of clear water is added into a reaction kettle with agitator, the potassium permanganate aqueous solution is added, the 10 percent dilute sulfuric acid is added in for even agitation after the starch is added in for even agitation and oxidation treatment, the sodium hydroxide aqueous solution is added in for carrying out gelatinization treatment, the rest clear water is added in for dilution after the gelatinization treatment, the additive agent of kaolin is added in for even agitation, the sodium borate aqueous solution is added in for carrying out complexing treatment, and at last the antifoaming agent of tributyl phosphate is added in for defoaming.
Description
Technical field
The present invention relates to a kind of macromolecule plant binding agent and preparation method, the binding agent of the carton class that is used to specifically to bond belongs to the adhesive techniques field.
Background technology
At present, known paper shell class binding agent adopts sodium silicate solution promptly to be commonly called as the binding agent of water glass mostly, the accumulation of salt in the surface soil, moisture absorption phenomenon appear in sodium silicate solution in actual use, adhesive is come off, effect is bad, because sodium silicate solution is to be main starting material by silica sand, soda ash, than great, food has adsorption to it, and is harmful; Other kind binding agent cost height cause cost to improve to the user.
Summary of the invention
In order to overcome above-mentioned deficiency, the invention provides a kind of macromolecule plant binding agent and preparation method, utilize macromolecule plant binding agent bonding paper shell type objects to avoid the accumulation of salt in the surface soil, moisture absorption phenomenon, and harmless.
The technical scheme that the present invention is adopted for its technical problem of solution is: its material composition and proportioning are as follows:
Plant amylum 20-30% potassium permanganate (kmno
4) 0.5-1%
10% dilute sulphuric acid (H
2So
4) 1.8-5.4% sodium hydroxide (NaoH) 2-4%
Sodium tetraborate (Na
2B
4O10H
2O) 0.4-1% kaolin 4-10%
Tributyl phosphate ((CH
3CH
2CH
2CH
2O)
3PO) 0.05-0.1% clear water 65-75%.
Its preparation method is:
Earlier that potassium permanganate and hot water more than 90 ° is standby by 1: 6 or ratio dissolving in 1: 9, sodium hydroxide and water dissolved standby in 1: 3 or 1: 7 ratio, sodium tetraborate and more than 90 ° hot water dissolve standby in 1: 5 or 1: 7 ratio; In the reactor of belt stirrer, add the part clear water earlier, add potassium permanganate solution, adding starch stirs after the neutral oxide treatment, add 10% dilute sulphuric acid and stir, add aqueous sodium hydroxide solution and carry out the gelatinization processing, gelatinization is handled back adding residue clear water and is diluted, adding additive kaolin stirs, add the sodium tetraborate aqueous solution and carry out Lip river and processing, add defoamer tributyl phosphate froth breaking at last, make a kind of macromolecule plant binding agent of the present invention; Packing into seals in 50kg, 40kg, 30kg, 20kg, the 10kg container, and warehouse-in is preserved.
The invention has the beneficial effects as follows, be main raw material(s) with the plant amylum, nontoxic, odorless, and environmental protection, the accumulation of salt in the surface soil, nonhygroscopic not, proportion is little, and cost is low.
Embodiment
Embodiment 1
Its material composition and proportioning are as follows: (kilogram):
Starch 250 potassium permanganate 10 10% dilute sulphuric acids 2 sodium hydroxide 25 sodium tetraborates 11 kaolin 30 tributyl phosphates 2 clear water 670
Earlier that potassium permanganate and hot water more than 90 ° is standby by ratio dissolving in 1: 9, sodium hydroxide and water dissolved standby in 1: 7 ratio, sodium tetraborate and more than 90 ° hot water dissolve standby in 1: 7 ratio; In the reactor of belt stirrer, add 375 kilograms of clear water earlier, add potassium permanganate solution, adding starch stirs after the neutral oxide treatment, adding 10% dilute sulphuric acid stirs, add aqueous sodium hydroxide solution and carry out the gelatinization processing, gelatinization is handled back adding residue clear water and is diluted, and adds additive kaolin and stirs, add the sodium tetraborate aqueous solution and carry out Lip river and processing, add defoamer tributyl phosphate froth breaking at last.
Embodiment 2
Its material composition and proportioning are as follows: (kilogram):
Starch 220 potassium permanganate 9 10% dilute sulphuric acids 2 sodium hydroxide 29 sodium tetraborates 9 kaolin 30 tributyl phosphates 1 clear water 700
Earlier that potassium permanganate and hot water more than 90 ° is standby by ratio dissolving in 1: 6, sodium hydroxide and water dissolved standby in 1: 3 ratio, sodium tetraborate and more than 90 ° hot water dissolve standby in 1: 5 ratio; In the reactor of belt stirrer, add 330 kilograms of clear water earlier, add potassium permanganate solution, adding starch stirs after the neutral oxide treatment, adding 10% dilute sulphuric acid stirs, add aqueous sodium hydroxide solution and carry out the gelatinization processing, gelatinization is handled back adding residue clear water and is diluted, and adds additive kaolin and stirs, add the sodium tetraborate aqueous solution and carry out Lip river and processing, add defoamer tributyl phosphate froth breaking at last.
Embodiment 3
Its material composition and proportioning are as follows: (kilogram):
Starch 240 potassium permanganate 7 10% dilute sulphuric acids 2 sodium hydroxide 31 sodium tetraborates 7 kaolin 31 tributyl phosphates 2 clear water 680
Earlier that potassium permanganate and hot water more than 90 ° is standby by ratio dissolving in 1: 8, sodium hydroxide and water dissolved standby in 1: 6 ratio, sodium tetraborate and more than 90 ° hot water dissolve standby in 1: 6 ratio; In the reactor of belt stirrer, add 360 kilograms of clear water earlier, add potassium permanganate solution, after adding the neutral evenly oxide treatment of starch stirring, adding 10% dilute sulphuric acid stirs, add aqueous sodium hydroxide solution and carry out the gelatinization processing, gelatinization is handled back adding residue clear water and is diluted, and adds additive kaolin and stirs, add the sodium tetraborate aqueous solution and carry out Lip river and processing, add defoamer tributyl phosphate froth breaking at last.
Claims (1)
1. macromolecule plant binding agent and preparation method is characterized in that: its material form and proportioning as follows:
Plant amylum 20-30% potassium permanganate (kmno
4) 0.5-1%
10% dilute sulphuric acid (H
2So
4) 1.8-5.4% sodium hydroxide (NaoH) 2-4%
Sodium tetraborate (Na
2B
4O10H
2O) 0.4-1% kaolin 4-10%
Tributyl phosphate ((CH
3CH
2CH
2CH
2O)
3PO) 0.05-0.1% clear water 65-75%
Its preparation method is, and was earlier that potassium permanganate and hot water more than 90 ° is standby by 1: 6 or ratio dissolving in 1: 9, and sodium hydroxide and water dissolve standby in 1: 3 or 1: 7 ratio, sodium tetraborate and more than 90 ° hot water dissolve standby in 1: 5 or 1: 7 ratio; In the reactor of belt stirrer, add the part clear water earlier, add potassium permanganate solution, adding starch stirs after the neutral oxide treatment, adding 10% dilute sulphuric acid stirs, add aqueous sodium hydroxide solution and carry out the gelatinization processing, gelatinization is handled back adding residue clear water and is diluted, and adds additive kaolin and stirs, add the sodium tetraborate aqueous solution and carry out Lip river and processing, add defoamer tributyl phosphate froth breaking at last.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2007100727073A CN101161750A (en) | 2007-08-24 | 2007-08-24 | Macromolecule plant binding agent and preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2007100727073A CN101161750A (en) | 2007-08-24 | 2007-08-24 | Macromolecule plant binding agent and preparation method |
Publications (1)
Publication Number | Publication Date |
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CN101161750A true CN101161750A (en) | 2008-04-16 |
Family
ID=39296740
Family Applications (1)
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CNA2007100727073A Pending CN101161750A (en) | 2007-08-24 | 2007-08-24 | Macromolecule plant binding agent and preparation method |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102139340A (en) * | 2011-02-01 | 2011-08-03 | 福州大学 | Composite powder binding agent containing gelatinized phosphate starch and kaolin and preparation method thereof |
CN102977965A (en) * | 2012-12-20 | 2013-03-20 | 武汉钢铁(集团)公司 | Biomass briquette for lime shaft kiln and preparation method thereof |
CN101591582B (en) * | 2009-07-07 | 2013-08-14 | 凤城市宇达节能环保型煤有限公司 | Waterproof adhesive and production method thereof |
CN103305155A (en) * | 2013-06-28 | 2013-09-18 | 宁波清风纳米涂料有限公司 | Mounting adhesive |
CN103320058A (en) * | 2013-06-28 | 2013-09-25 | 宁波清风纳米涂料有限公司 | Adhesive for paper tube |
-
2007
- 2007-08-24 CN CNA2007100727073A patent/CN101161750A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101591582B (en) * | 2009-07-07 | 2013-08-14 | 凤城市宇达节能环保型煤有限公司 | Waterproof adhesive and production method thereof |
CN102139340A (en) * | 2011-02-01 | 2011-08-03 | 福州大学 | Composite powder binding agent containing gelatinized phosphate starch and kaolin and preparation method thereof |
CN102139340B (en) * | 2011-02-01 | 2012-10-10 | 福州大学 | Composite powder binding agent containing gelatinized phosphate starch and kaolin and preparation method thereof |
CN102977965A (en) * | 2012-12-20 | 2013-03-20 | 武汉钢铁(集团)公司 | Biomass briquette for lime shaft kiln and preparation method thereof |
CN103305155A (en) * | 2013-06-28 | 2013-09-18 | 宁波清风纳米涂料有限公司 | Mounting adhesive |
CN103320058A (en) * | 2013-06-28 | 2013-09-25 | 宁波清风纳米涂料有限公司 | Adhesive for paper tube |
CN103320058B (en) * | 2013-06-28 | 2015-07-08 | 宁波清风纳米涂料有限公司 | Adhesive for paper tube |
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Open date: 20080416 |