CN103666326B - A kind of quick-dry type adhesive for paper box - Google Patents
A kind of quick-dry type adhesive for paper box Download PDFInfo
- Publication number
- CN103666326B CN103666326B CN201310620580.XA CN201310620580A CN103666326B CN 103666326 B CN103666326 B CN 103666326B CN 201310620580 A CN201310620580 A CN 201310620580A CN 103666326 B CN103666326 B CN 103666326B
- Authority
- CN
- China
- Prior art keywords
- parts
- vinyl acetate
- water
- starch
- quick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 21
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- 229920002472 Starch Polymers 0.000 claims abstract description 29
- 235000019698 starch Nutrition 0.000 claims abstract description 29
- 239000008107 starch Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 10
- 229920003023 plastic Polymers 0.000 claims abstract description 9
- 229940037003 alum Drugs 0.000 claims abstract description 8
- 239000004113 Sepiolite Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 6
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 238000009825 accumulation Methods 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 5
- 239000002689 soil Substances 0.000 abstract description 5
- 239000000123 paper Substances 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 17
- 238000003756 stirring Methods 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- -1 phosphate ester Chemical class 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of quick-dry type adhesive for paper box, be made by the raw material of following weight proportion: treated starch 40 ~ 55 parts, 50 ~ 66 parts, water, Nano sepiolite powder 0.15 ~ 0.25 part, 0.4 ~ 0.45 part, potassium permanganate, vinyl acetate between to for plastic base emulsion 0.18 ~ 0.25 part, vinyl acetate 6.5 ~ 8 parts, 0.4 ~ 0.55 part, sodium hydroxide, 0.05 ~ 0.20 part, alum.Advantage of the present invention is into that paper is better, mobility is good and the not easily moisture absorption accumulation of salt in the surface soil.
Description
Technical field
The present invention relates to a kind of Starch Adhesive, particularly relate to a kind of quick-dry type adhesive for paper box for binding paper box.
Background technology
Paper product particularly Corrugated Box are produced, and use sodium silicate in decades more.Because its alkalescence is large, the easy moisture absorption, normal accumulation of salt in the surface soil whiting causes paper product to be out of shape, to peel off, and even corrodes commodity, causing the rotten tremendous economic loss such as to scrap.Therefore, abroad from the fifties just replace sodium silicate with Starch Adhesive, the domestic Starch Adhesive that also begins one's study the end of the seventies, be applied to gradually the eighties paper product produce.
What disclose about the formula of Starch Adhesive and production technique in prior art has a lot, and the patented technology document being wherein seen in State Intellectual Property Office website just has hundreds of.Wherein comparatively typical patent application technology has: Yangjiang City Huamei Printing Packaging Co., Ltd. has applied for the patent of invention (number of patent application is 200410015298.X) of " a kind of fast drying starch adhesive " on February 6th, 2004, that application discloses a kind of fast drying starch adhesive, produced by following methods: 10 parts of starch are put into and added 40 parts of water in stirred pot and stir by (1), then add sodium hydroxide solution 0.8 ~ 1 part, manage row quaternization at normal temperatures; (2) add 0.04 part of hydrogen peroxide, 30 parts of water carry out oxidizing reaction 40 minutes; (3) add 0.04 part of tributyl phosphate, 0.04 part of borax, 0.15 part of sodium carbonate, 0.01 part of magnesium sulfate, stir 10 minutes, make liquid reactions become oyster white or light beige.The feature of this technology is that product density is little, bounding force strong, fast drying, good fluidity, not strike-through, not skinning, not easily turn to be yellow, and production cost is low, production unit is simple.
Henan Xindoucai Printing Co., Ltd. has applied for " Modified Starch Adhesive " patent of invention (number of patent application is 200810141014.X) on August 13rd, 2008, its technical scheme is: a kind of Modified Starch Adhesive is prepared according to following step: (1) first adds 50 weight parts waters in container, and the hydrogen peroxide then adding 2 ~ 2.5 weight parts stirs; (2) treated starch adding 10 ~ 15 weight parts in above-mentioned gains stirs and obtains glue; (3) ferrous sulfate getting 0.04 ~ 0.08 weight part joins in second step gained glue after adding the water dilution of 1.5 ~ 2.5 weight parts, leaves standstill 20 ~ 40 minutes after stirring; (4) in the 3rd step gains, add the water of 25 ~ 35 weight parts, stir; (5) get the sodium hydroxide of 2 ~ 2.5 weight parts, join in the 4th step gains after adding the water dilution of 6.5 ~ 7.5 weight parts and stir 8 ~ 15 minutes; (6) join in the 5th step gains after the borax getting 1.2 ~ 1.5 weight parts adds the dissolved in boiled water of 2.5 ~ 3.5 weight parts, stir 4 ~ 8 minutes; (7) in the 6th step gains, add the water of proper quantity of defoaming agent and 4.5 ~ 5.5 weight parts, stir.Its advantage is nonpoisonous and tasteless, strong adhesion, can be used in food service industry packaging.
Jiangyan City Huaguang Chemical Paper Co., Ltd. proposes the application for a patent for invention (number of patent application is 200310106411.0) of " Starch Adhesive (SSS-85) " by name on November 25th, 2003, its technical scheme is: a kind of Starch Adhesive, with treated starch and water for main component, containing stablizer, oxygenant, terminator, in composition, add compound agent, catalyzer.Compare with phosphate ester starch with treated starch such as the Sumstar 190 of routine, the feature of this technical scheme is that tackiness agent sticks with paste that the retrogradation of liquid is little, compatibleness good, be conducive to preparing high solids content, low viscous pigment coating, its paper properties is superior, and has outstanding cost performance.
Above-mentioned patent has covered most starch producing technology technology.But from disclosed related art scheme, all there is some shortcomings part, be not production cost higher, be unfavorable for marketing and sale, the quality being exactly product is bad, become paper poor, mobility is not good.Therefore, along with the surge of high-grade paper product Production requirement, market common requirements a kind of become the strong and novel paper product tackiness agent that cost performance is good of good, the mobility of paper.For this demand, I have submitted " paper product adhesive specially " patent application by name last year, disclose a kind of preparation method of paper product adhesive specially, be made by the raw material of following weight proportion: treated starch 40 ~ 55 parts, 50 ~ 66 parts, water, Nano sepiolite powder 0.2 ~ 0.35 part, 0.4 ~ 0.45 part, potassium permanganate, vinyl acetate between to for plastic base emulsion 0.25 ~ 0.35 part, vinyl acetate 6.5 ~ 10 parts, 0.4 ~ 0.55 part, sodium hydroxide.But in actual use, this patented technology is still weak, and mainly rate of drying is fast not enough, still there is certain moisture absorption accumulation of salt in the surface soil phenomenon.
Summary of the invention
The present invention seeks to overcome weak point of the prior art, provide a kind of become paper better, paint-flow is stronger, cost performance is more excellent and can urge adhesive for paper box that is dry, the not easily moisture absorption accumulation of salt in the surface soil fast.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical programs: a kind of quick-dry type adhesive for paper box, is made by the raw material of following weight proportion: treated starch 40 ~ 55 parts, 50 ~ 66 parts, water, Nano sepiolite powder 0.15 ~ 0.25 part, 0.4 ~ 0.45 part, potassium permanganate, vinyl acetate between to for plastic base emulsion 0.18 ~ 0.25 part, vinyl acetate 6.5 ~ 8 parts, 0.4 ~ 0.55 part, sodium hydroxide, 0.05 ~ 0.20 part, alum.
Preferred plan of the present invention is: treated starch 45 parts, 60 parts, water, Nano sepiolite powder 0.22 part, 0.44 part, potassium permanganate, vinyl acetate between to for plastic base emulsion 0.22 part, vinyl acetate 7 parts, 0.5 part, sodium hydroxide, 0.12 part, alum.
Advantage of the present invention is:
1, the good fluidity of tackiness agent.After being oxidized by treated starch with potassium permanganate oxidant, the bonding force of starch and anticorrosion, mildew-resistant ability can be improve.On the other hand, oxygenizement can reduce again the polymerization degree of starch molecule, and its molecular chain is shortened, and makes the adhesive flow that obtains good.
2, reasonable finished product effect of filling a prescription is better.Sodium hydroxide is most important as the quality height of its dosage size of catalyzer to tackiness agent.If its consumption is inadequate, then tackiness agent is opaque, poor fluidity, and bonding force reduces, can retrogradation when storage period is long.If its consumption too much there will be alkali dirt, tackiness agent pH value increases, the easy moisture absorption of cardboard.The consumption of its consumption also with terminator, stablizer, compound agent is closely related, through combination and compatibility repeatedly, the present invention the most at last sodium hydroxide concentration is limited between 0.4 ~ 0.55 part, ensures the whiteness of finished product of the present invention, luminance brightness and opaqueness by the integrated use of appropriate oxygenant, stablizer, compound agent, terminator.Add the alum solution having and urge dry, clarification, strong papery effect, thus simplified operation, shorten Production Time, make adhesives carton fast drying, do not invade paper, nonhygroscopic, the not accumulation of salt in the surface soil.
3, comprehensive cost performance is high.The present invention with treated starch and water for major ingredient, only add the assistant agents such as Nano sepiolite powder, potassium permanganate, vinyl acetate between to for plastic base emulsion, vinyl acetate, sodium hydroxide on a small quantity, on the total cost of tackiness agent without too large impact, but obviously improve the over-all properties of tackiness agent, the tackiness agent making the present invention obtain obviously is better than common paper product tackiness agent in cost performance.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: getting 40kg granularity is that 100 object treated starches mix with 50kg water, adds 0.4kg potassium permanganate oxidant successively, fully reacts at normal temperatures, make starch pasting, add 0.18kg vinyl acetate between to for plastic base emulsion terminator after 100 minutes; Then carry out solid-liquid separation, be separated after terminating, add water, make emulsion concentration reach 38%, add 6.5kg vinyl acetate compound agent, 0.4kg sodium hydroxide catalyst, 0.05kg alum, react 4 hours, pH value more than 7, and then carries out solid-liquid separation, washing, oven dry, packaging warehouse-in.
Embodiment 2: getting 55kg granularity is that 100 object treated starches mix with 50kg water, adds 0.45kg potassium permanganate oxidant successively, fully reacts at normal temperatures, make starch pasting, add 0.25kg vinyl acetate between to for plastic base emulsion terminator after 100 minutes; Then carry out solid-liquid separation, be separated after terminating, add water, make emulsion concentration reach 42%, add 8kg vinyl acetate compound agent, 0.55kg sodium hydroxide catalyst, 0.2kg alum, react 4.5 hours, pH value more than 7, and then carries out solid-liquid separation, washing, oven dry, packaging warehouse-in.
Embodiment 3: getting 45kg granularity is that 100 object treated starches mix with 60kg water, adds 0.44kg potassium permanganate oxidant successively, fully reacts at normal temperatures, make starch pasting, add 0.35kg vinyl acetate between to for plastic base emulsion terminator after 120 minutes.Then carry out solid-liquid separation, be separated after terminating, add water, make emulsion concentration reach 40%, add 7kg vinyl acetate compound agent and 0.5kg sodium hydroxide catalyst and 0.2kg alum, react 5 hours, pH value more than 7, and then carries out solid-liquid separation, washing, oven dry, packaging warehouse-in.
Claims (1)
1. a quick-dry type adhesive for paper box, is characterized in that it is made by the raw material of following weight proportion: treated starch 45 parts, 60 parts, water, Nano sepiolite powder 0.22 part, 0.44 part, potassium permanganate, vinyl acetate between to for plastic base emulsion 0.22 part, vinyl acetate 7 parts, 0.5 part, sodium hydroxide, 0.12 part, alum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620580.XA CN103666326B (en) | 2013-11-29 | 2013-11-29 | A kind of quick-dry type adhesive for paper box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620580.XA CN103666326B (en) | 2013-11-29 | 2013-11-29 | A kind of quick-dry type adhesive for paper box |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666326A CN103666326A (en) | 2014-03-26 |
| CN103666326B true CN103666326B (en) | 2016-03-16 |
Family
ID=50305119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310620580.XA Active CN103666326B (en) | 2013-11-29 | 2013-11-29 | A kind of quick-dry type adhesive for paper box |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666326B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109468070A (en) * | 2018-11-28 | 2019-03-15 | 贵州众旺包装有限公司 | A kind of carton aldehyde-free cement and preparation method thereof |
| CN112608694A (en) * | 2020-11-26 | 2021-04-06 | 仲恺农业工程学院 | Quick-drying environment-friendly starch adhesive and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041381A (en) * | 1988-09-26 | 1990-04-18 | 鹿中原 | High strength binder for cardboard case |
| CN101892024A (en) * | 2010-07-02 | 2010-11-24 | 浙江大学 | Adhesive for wood and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310620580.XA patent/CN103666326B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041381A (en) * | 1988-09-26 | 1990-04-18 | 鹿中原 | High strength binder for cardboard case |
| CN101892024A (en) * | 2010-07-02 | 2010-11-24 | 浙江大学 | Adhesive for wood and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666326A (en) | 2014-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104861892B (en) | Oxidized starch adhesive and preparation method thereof | |
| CN102627924A (en) | Starch adhesive and preparation method thereof | |
| CN103642425A (en) | Production technology for starch adhesive | |
| CN101343513A (en) | Corn starch adhesive agent | |
| CN101967355B (en) | Paper starch adhesive and preparation method thereof | |
| CN102329581A (en) | Starch adhesive for compounding paperboards and preparation method thereof | |
| CN105440972A (en) | Nano-compound biomass waterborne adhesive | |
| CN104629647B (en) | A kind of environment-friendly type starch adhesive | |
| CN105176457A (en) | Environmentally-friendly aqueous binder | |
| CN103333641A (en) | Quick-drying cassava starch adhesive and preparation method thereof | |
| CN103666326B (en) | A kind of quick-dry type adhesive for paper box | |
| CN104974696A (en) | Biomass environment-friendly water-based adhesive | |
| CN104559831A (en) | Modified starch adhesive for coating | |
| CN105419696B (en) | A kind of green beer Labeling Adhesive with Super and preparation method | |
| CN103709958B (en) | Low-temperature boron-free paper starch adhesive and preparation method thereof | |
| CN103087651A (en) | Adhesive and preparation method thereof | |
| CN109456707A (en) | A kind of adhesive for corrugated board bonding | |
| CN103666324B (en) | A kind of Corrugated Box reinstate tackiness agent | |
| CN106833087B (en) | A kind of preparation method of organic phosphate starch adhesive base formaldehyde-free building inner wall putty | |
| CN106753040A (en) | Composite paper box adhesive | |
| CN105349061A (en) | Cold produced high-strength and quick-drying starch adhesive | |
| CN105255371A (en) | Paper box adhesive containing nano sepiolite powder | |
| CN86105145A (en) | The making method of Starch Adhesive | |
| CN101979452B (en) | Method for preparing waterproof adhesive for corrugated paper production | |
| CN105368345A (en) | Method for preparing reinstated sepiolite adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cao Feng Inventor after: Zhang Yujian Inventor after: Pan Guoxiang Inventor before: Tang Yingjie |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160216 Address after: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Applicant after: Huzhou Teachers College Address before: Room 20, building 201, station village, Chaoyang Street, Wuxing District, Zhejiang, Huzhou, 313000 Applicant before: Tang Yingjie |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Du Huixin Inventor before: Cao Feng Inventor before: Zhang Yujian Inventor before: Pan Guoxiang |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170418 Address after: Chenghai District 515833 of Guangdong province Shantou Lian Industrial District Town Industrial Zone Liannan orchid Patentee after: Chenghai District of Shantou city wide Hongda Paper Co. Ltd. Address before: 313000 Zhejiang City, Huzhou Province, No. 2 East Road, Wuxing District No. 759 Patentee before: Huzhou Teachers College |