CN102433084A - Preparation method of starch adhesive for adhering cartons - Google Patents
Preparation method of starch adhesive for adhering cartons Download PDFInfo
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- CN102433084A CN102433084A CN2011103448162A CN201110344816A CN102433084A CN 102433084 A CN102433084 A CN 102433084A CN 2011103448162 A CN2011103448162 A CN 2011103448162A CN 201110344816 A CN201110344816 A CN 201110344816A CN 102433084 A CN102433084 A CN 102433084A
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- binding paper
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Abstract
The invention discloses a preparation method of a starch adhesive for adhering cartons, which belongs to the technical field of adhesive preparation, and comprises: adding 450 to 600 weight parts of water and 100 weight parts of starch into a reaction kettle; uniformly stirring, and adding 3 to 8 weight parts of hydrogen peroxide; reacting for 0.5 to 1 hour, and slowing adding 5 to 12 weight parts of aqueous solution of sodium hydroxide; stirring and reacting for 110 to 130 minutes, adding 0.2 to 0.8 weight part of crosslinking agent, 0.01 to 0.05 weight part of ferrous sulfate, 9 to 16 weight parts of water-proof agent, 10 to 20 weight parts of catalyst, 0.2 to 1.2 weight parts of tackifier, 0.05 to 0. 1 weight part of preservative, 15 to 18 weight parts of quick drying agent, and 0.5 to 1 weight part of tributyl phosphate in turn; stirring and reacting for 55 to 65 minutes; and obtaining the starch adhesive for adhering cartons. The method has the advantages that: the starch adhesive is stable in storage and is environment-friendly; the drying time is short, and the water-proof time is long; and the starch adhesive meets national standards.
Description
Technical field
The invention belongs to the tackiness agent preparing technical field, be specifically related to the preparation method of a kind of binding paper box with starch adhesive.
Background technology
Starch adhesive more and more receives the favor of carton production firm as environmentally friendly natural adhesive; But at present at the used starch adhesive of carton production industry; Mainly be to be made with starting material such as starch, water, sodium hydroxide, oxygenants; Shortcoming is that rate of drying is slow, bonding strength is low, poor water resistance and storge quality instability etc., thereby has limited its application in the carton production industry to a certain extent.Chinese patent CN101760148A relates to a kind of tackiness agent made from W-Gum, is mainly used in the bonding of paper, timber, cloth; Chinese patent CN101885952A relates to a kind of corn starch adhesive and preparation method thereof; Chinese patent CN1778855 relates to a kind of method of manufacture of starch adhesive, and this type invention product all belongs to traditional starch adhesive, promptly has the described shortcoming of applicant.
Based on above-mentioned, the inventor has done a large amount of further investigation work, has invented the technical scheme that solves above-mentioned shortcoming.
Summary of the invention
Top priority of the present invention is to provide the preparation method of a kind of binding paper box with starch adhesive, and the tackiness agent that is obtained by this method has that rate of drying is fast, water-tolerant, storge quality is stable, bonding strength is high strong point.
Task of the present invention is accomplished like this, and a kind of binding paper box may further comprise the steps with the preparation method of starch adhesive:
By weight ratio; Earlier water 450-600 part and starch are added in the reaction kettle for 100 parts, stir, add ydrogen peroxide 50 3-8 part; Reaction 0.5～1h; Slowly add aqueous sodium hydroxide solution 5-12 part again, stirring reaction 110-130min adds linking agent 0.2-0.8 part, ferrous sulfate 0.01-0.05 part, water-proofing agent 9-16 part, catalyzer 10-20 part, tackifier 0.2-1.2 part, sanitas 0.05-0.1 part, quick dry agent 15-18 part, tributyl phosphate 0.5-1 part successively; Restir reaction 55-65min obtains binding paper box and uses starch adhesive.
In a concrete embodiment of the present invention, described starch is at least a in W-Gum, sorghum starch, the sweet potato starch.
In another concrete embodiment of the present invention, described linking agent is a borax.
In another concrete embodiment of the present invention, described catalyzer is a urea.
In another concrete embodiment of the present invention, described sanitas is a Sodium Benzoate.
Also have among the concrete embodiment of the present invention, described tackifier are sodium cellulose glycolate.
more of the present invention and among concrete embodiment, described water-proofing agent is a Z 150PH.
In of the present invention and then concrete embodiment, described quick dry agent is an inorganic bentonite.
Of the present invention again more and among concrete embodiment, the mass percent concentration of described aqueous sodium hydroxide solution is 28-32%.
Therefore technical scheme provided by the invention has the stable strong point of storge quality because the product that obtains is emulsion; Owing to need not with an organic solvent, therefore can not undermine environment; Be merely 10-15min time of drying, water resisting time is more than or equal to 4h; Bonding strength >=2 and meet CNS GB6543-2008.
Embodiment
Embodiment 1:
By weight; Earlier 500 parts in water and W-Gum are added in the reaction kettle for 100 parts, stir, add 5 parts in ydrogen peroxide 50; Reaction 30min; Slowly adding mass percent concentration again is 10 parts of 30% aqueous sodium hydroxide solutions, and stirring reaction 110min adds 0.6 part of 0.8 part of borax, 0.03 part in ferrous sulfate, 10 parts of Z 150PH, 18 parts in urea, 0.6 part of sodium cellulose glycolate, 0.1 part of Sodium Benzoate, 16 parts of inorganic bentonites and tributyl phosphate successively; Restir reaction 55min obtains binding paper box and uses starch adhesive.
Embodiment 2:
By weight; Earlier 450 parts in water and sorghum starch are added in the reaction kettle for 100 parts, stir, add 3 parts in ydrogen peroxide 50; Reaction 60min; Slowly adding mass percent concentration again is 5 parts of 28% aqueous sodium hydroxide solutions, and stirring reaction 130min adds 0.5 part of 0.2 part of borax, 0.01 part in ferrous sulfate, 9 parts of Z 150PH, 12 parts in urea, 0.3 part of sodium cellulose glycolate, 0.05 part of Sodium Benzoate, 15 parts of inorganic bentonites and tributyl phosphate successively; Restir reaction 60min obtains binding paper box and uses starch adhesive.
Embodiment 3:
By weight; Earlier 550 parts in water and sweet potato starch are added in the reaction kettle for 100 parts, stir, add 6 parts in ydrogen peroxide 50; Reaction 50min; Slowly adding mass percent concentration again is 7 parts of 29% aqueous sodium hydroxide solutions, and stirring reaction 120min adds 0.7 part of 0.6 part of borax, 0.04 part in ferrous sulfate, 15 parts of Z 150PH, 17 parts in urea, 0.8 part of sodium cellulose glycolate, 0.09 part of Sodium Benzoate, 18 parts of inorganic bentonites and tributyl phosphate successively; Restir reaction 65min obtains binding paper box and uses starch adhesive.
Embodiment 4:
By weight; Earlier 520 parts in water, 60 parts of sweet potato starch and W-Gum are added in the reaction kettle for 40 parts, stir, add 4 parts in ydrogen peroxide 50; Reaction 40min; Slowly adding mass percent concentration again is 9 parts of 31% aqueous sodium hydroxide solutions, and stirring reaction 125min adds 0.6 part of 0.5 part of borax, 0.03 part in ferrous sulfate, 11 parts of Z 150PH, 12 parts in urea, 0.3 part of sodium cellulose glycolate, 0.06 part of Sodium Benzoate, 16 parts of inorganic bentonites and tributyl phosphate successively; Restir reaction 62min obtains binding paper box and uses starch adhesive.
Embodiment 5:
By weight; Earlier 600 parts in water, 50 parts of W-Gums and sorghum starch are added in the reaction kettle for 50 parts, stir, add 8 parts in ydrogen peroxide 50; Reaction 45min; Slowly adding mass percent concentration again is 12 parts of 31.5% aqueous sodium hydroxide solutions, and stirring reaction 115min adds 0.6 part of 0.8 part of borax, 0.05 part in ferrous sulfate, 16 parts of Z 150PH, 20 parts in urea, 0.9 part of sodium cellulose glycolate, 0.1 part of Sodium Benzoate, 18 parts of inorganic bentonites and tributyl phosphate successively; Restir reaction 58min obtains binding paper box and uses starch adhesive.
Use starch adhesive by the resulting binding paper box of the present invention of the foregoing description, have the technique effect of the excellence shown in the following table, and can find out that by following table the present invention has accomplished the invention task well.
Claims (9)
1.
a kind of binding paper box is with the preparation method of starch adhesive; It is characterized in that may further comprise the steps: by weight ratio; Earlier water 450-600 part and starch are added in the reaction kettle for 100 parts, stir, add ydrogen peroxide 50 3-8 part; Reaction 0.5～1h; Slowly add aqueous sodium hydroxide solution 5-12 part again, stirring reaction 110-130min adds linking agent 0.2-0.8 part, ferrous sulfate 0.01-0.05 part, water-proofing agent 9-16 part, catalyzer 10-20 part, tackifier 0.2-1.2 part, sanitas 0.05-0.1 part, quick dry agent 15-18 part, tributyl phosphate 0.5-1 part successively; Restir reaction 55-65min obtains binding paper box and uses starch adhesive.
2.
binding paper box according to claim 1 is with the preparation method of starch adhesive, it is characterized in that described starch is at least a in W-Gum, sorghum starch, the sweet potato starch.
3.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described linking agent is a borax.
4.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described catalyzer is a urea.
5.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described sanitas is a Sodium Benzoate.
6.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described tackifier are sodium cellulose glycolate.
7.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described water-proofing agent is a Z 150PH.
8.
binding paper box according to claim 1 is characterized in that with the preparation method of starch adhesive described quick dry agent is an inorganic bentonite.
9.
Binding paper box according to claim 1 is with the preparation method of starch adhesive, and the mass percent concentration that it is characterized in that described aqueous sodium hydroxide solution is 28-32%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103448162A CN102433084A (en) | 2011-11-04 | 2011-11-04 | Preparation method of starch adhesive for adhering cartons |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103448162A CN102433084A (en) | 2011-11-04 | 2011-11-04 | Preparation method of starch adhesive for adhering cartons |
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| CN102433084A true CN102433084A (en) | 2012-05-02 |
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| CN2011103448162A Pending CN102433084A (en) | 2011-11-04 | 2011-11-04 | Preparation method of starch adhesive for adhering cartons |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766422A (en) * | 2012-05-16 | 2012-11-07 | 杭州嘉力丰化工有限公司 | Glutinous rice wet glue and preparation method thereof |
| CN102827296A (en) * | 2012-08-29 | 2012-12-19 | 赵贵喜 | Method for producing compound modified starch |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN105111966A (en) * | 2015-09-10 | 2015-12-02 | 江苏国胶化学科技有限公司 | Production method for producing paper tube glue through solid waste salt |
| CN105295774A (en) * | 2015-05-15 | 2016-02-03 | 陈素素 | Moisture-proof water-tolerant starch-based adhesive and preparation method thereof |
| CN105349061A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Cold produced high-strength and quick-drying starch adhesive |
| CN105820777A (en) * | 2016-05-20 | 2016-08-03 | 江苏金沃机械有限公司 | Quick drying adhesive for paper products and preparation method of quick drying adhesive |
| CN105950059A (en) * | 2016-07-01 | 2016-09-21 | 宋俊柳 | Quick-drying starch adhesive |
| CN106753035A (en) * | 2016-12-08 | 2017-05-31 | 苏州纳贝通环境科技有限公司 | A kind of starch base corrugation adhesive for paper and preparation method thereof |
| CN106854440A (en) * | 2016-12-06 | 2017-06-16 | 钦州市高新技术产业服务中心 | A kind of starch adhesive and preparation method thereof |
| CN107163876A (en) * | 2017-06-07 | 2017-09-15 | 巢湖市荷花渔网有限公司 | A kind of preparation method of waterproof monofilament fishing net binding agent |
| CN107502226A (en) * | 2017-10-10 | 2017-12-22 | 枣庄市恒宇纸业有限公司 | One kind is used for corrugated paper board production line low-temperature quick-drying type starch adhesive |
| CN107523233A (en) * | 2017-09-16 | 2017-12-29 | 常州力纯数码科技有限公司 | A kind of mongolicum Turcz. with Modified Starch Adhesive and preparation method thereof |
| CN107793950A (en) * | 2017-09-26 | 2018-03-13 | 望江县红和木业灯饰有限公司 | A kind of high bond strength paper lantern glutinous rice glue |
| CN107868627A (en) * | 2017-11-15 | 2018-04-03 | 上海鎏彩建材科技股份有限公司 | Timber industry vegetable adhesive and preparation method thereof |
| CN108047989A (en) * | 2017-12-13 | 2018-05-18 | 阜阳市福旺食品有限公司 | A kind of fast-drying type amylan |
| CN108130009A (en) * | 2017-12-07 | 2018-06-08 | 明光市永德包装有限公司 | A kind of corrugated case shelf-stable starch adhesive |
| CN109518522A (en) * | 2018-11-29 | 2019-03-26 | 钱加丰 | A kind of additive for paper making and its application method enhancing ring Asia and water resistant moisture resistance |
| CN110218532A (en) * | 2019-06-03 | 2019-09-10 | 东莞市金田纸业有限公司 | A kind of quick-drying cardboard adhesive specially and preparation method thereof |
| CN111087946A (en) * | 2019-12-20 | 2020-05-01 | 株洲工大彩色印刷有限公司 | Fiber-reinforced starch adhesive and preparation method thereof |
| CN112322226A (en) * | 2020-11-26 | 2021-02-05 | 仲恺农业工程学院 | Antibacterial starch adhesive for coating and preparation method thereof |
| CN112521887A (en) * | 2020-11-26 | 2021-03-19 | 仲恺农业工程学院 | Preparation method of antibacterial starch adhesive capable of being repeatedly adhered to plastic film |
| CN112608695A (en) * | 2020-11-26 | 2021-04-06 | 仲恺农业工程学院 | Preparation method of paper-plastic composite starch adhesive |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001164213A (en) * | 1999-12-13 | 2001-06-19 | Tokan Kogyo Co Ltd | Corrugated cardboard and adhesive paste for corrugated cardboard |
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001164213A (en) * | 1999-12-13 | 2001-06-19 | Tokan Kogyo Co Ltd | Corrugated cardboard and adhesive paste for corrugated cardboard |
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766422A (en) * | 2012-05-16 | 2012-11-07 | 杭州嘉力丰化工有限公司 | Glutinous rice wet glue and preparation method thereof |
| CN102766422B (en) * | 2012-05-16 | 2014-03-05 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice wet glue and preparation method thereof |
| CN102827296A (en) * | 2012-08-29 | 2012-12-19 | 赵贵喜 | Method for producing compound modified starch |
| CN102877360A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN102877360B (en) * | 2012-09-05 | 2015-02-25 | 喻小琦 | Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof |
| CN105295774A (en) * | 2015-05-15 | 2016-02-03 | 陈素素 | Moisture-proof water-tolerant starch-based adhesive and preparation method thereof |
| CN105111966B (en) * | 2015-09-10 | 2018-02-23 | 江苏国胶化学科技有限公司 | A kind of solid abraum salt is used to produce paper tube gel |
| CN105111966A (en) * | 2015-09-10 | 2015-12-02 | 江苏国胶化学科技有限公司 | Production method for producing paper tube glue through solid waste salt |
| CN105349061A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Cold produced high-strength and quick-drying starch adhesive |
| CN105820777A (en) * | 2016-05-20 | 2016-08-03 | 江苏金沃机械有限公司 | Quick drying adhesive for paper products and preparation method of quick drying adhesive |
| CN105950059A (en) * | 2016-07-01 | 2016-09-21 | 宋俊柳 | Quick-drying starch adhesive |
| CN106854440A (en) * | 2016-12-06 | 2017-06-16 | 钦州市高新技术产业服务中心 | A kind of starch adhesive and preparation method thereof |
| CN106753035A (en) * | 2016-12-08 | 2017-05-31 | 苏州纳贝通环境科技有限公司 | A kind of starch base corrugation adhesive for paper and preparation method thereof |
| CN107163876A (en) * | 2017-06-07 | 2017-09-15 | 巢湖市荷花渔网有限公司 | A kind of preparation method of waterproof monofilament fishing net binding agent |
| CN107523233A (en) * | 2017-09-16 | 2017-12-29 | 常州力纯数码科技有限公司 | A kind of mongolicum Turcz. with Modified Starch Adhesive and preparation method thereof |
| CN107793950A (en) * | 2017-09-26 | 2018-03-13 | 望江县红和木业灯饰有限公司 | A kind of high bond strength paper lantern glutinous rice glue |
| CN107502226A (en) * | 2017-10-10 | 2017-12-22 | 枣庄市恒宇纸业有限公司 | One kind is used for corrugated paper board production line low-temperature quick-drying type starch adhesive |
| CN107868627A (en) * | 2017-11-15 | 2018-04-03 | 上海鎏彩建材科技股份有限公司 | Timber industry vegetable adhesive and preparation method thereof |
| CN108130009A (en) * | 2017-12-07 | 2018-06-08 | 明光市永德包装有限公司 | A kind of corrugated case shelf-stable starch adhesive |
| CN108047989A (en) * | 2017-12-13 | 2018-05-18 | 阜阳市福旺食品有限公司 | A kind of fast-drying type amylan |
| CN109518522A (en) * | 2018-11-29 | 2019-03-26 | 钱加丰 | A kind of additive for paper making and its application method enhancing ring Asia and water resistant moisture resistance |
| CN110218532A (en) * | 2019-06-03 | 2019-09-10 | 东莞市金田纸业有限公司 | A kind of quick-drying cardboard adhesive specially and preparation method thereof |
| CN111087946A (en) * | 2019-12-20 | 2020-05-01 | 株洲工大彩色印刷有限公司 | Fiber-reinforced starch adhesive and preparation method thereof |
| CN112322226A (en) * | 2020-11-26 | 2021-02-05 | 仲恺农业工程学院 | Antibacterial starch adhesive for coating and preparation method thereof |
| CN112521887A (en) * | 2020-11-26 | 2021-03-19 | 仲恺农业工程学院 | Preparation method of antibacterial starch adhesive capable of being repeatedly adhered to plastic film |
| CN112608695A (en) * | 2020-11-26 | 2021-04-06 | 仲恺农业工程学院 | Preparation method of paper-plastic composite starch adhesive |
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Application publication date: 20120502 |